Environmental pollution has led to global warming, which threatens human life. In response, hydrogen is gaining attention as a next-generation energy source that does not emit carbon. Due to its explosive nature, special care must be taken in the safe storage and transportation of hydrogen. Among various storage methods, liquefied storage, which can reduce its volume to 1/800, is considered efficient. However, since its boiling point reaches -253°C, the design of an insulation system is essential. For the design of insulation systems applied to large containers, a membrane-type design is required, which necessitates the use of cryogenic adhesives. To evaluate whether the cryogenic adhesive is properly implemented, assessments such as tensile and shear tests are necessary. This study presents a methodology for shear evaluation. Conventional methods for shear evaluation of adhesives result in slippage, preventing proper assessment. Therefore, a method involving drilling holes in the gripper and pulling from the holes must be applied. Optimal design concerning the size and location of the holes is required, and this study derives optimal values based on finite element analysis. By conducting experiments based on the results of this study, it is expected that the risk of gripper damage will be minimized, allowing for accurate evaluation of the adhesive’s performance.

The emergence of ferrous-medium entropy alloys (FeMEAs) with excellent tensile properties represents a potential direction for designing alloys based on metastable engineering. In this study, an FeMEA is successfully fabricated using laser powder bed fusion (LPBF), a metal additive manufacturing technology. Tensile tests are conducted on the LPBF-processed FeMEA at room temperature and cryogenic temperatures (77 K). At 77 K, the LPBF-processed FeMEA exhibits high yield strength and excellent ultimate tensile strength through active deformation-induced martensitic transformation. Furthermore, due to the low stability of the face-centered cubic (FCC) phase of the LPBFprocessed FeMEA based on nano-scale solute heterogeneity, stress-induced martensitic transformation occurs, accompanied by the appearance of a yield point phenomenon during cryogenic tensile deformation. This study elucidates the origin of the yield point phenomenon and deformation behavior of the FeMEA at 77 K.

Conversion to modern hydrogen energy is required, and research on liquefied hydrogen cargo containment systems is needed for large-capacity transport and storage. In this study, changes in the mechanical properties of the adhesive required for storage and transport in liquid hydrogen were confirmed. The lap shear test was performed by realizing cryogenic conditions in a small chamber using liquid nitrogen and liquid helium. There was an increase of 11.0% in the -180℃ condition compared to room temperature, and an increase of 1.8% in the -230℃ condition compared to the -180℃ condition was confirmed. In the case of shear strain, it is known that it decreases as the temperature goes down. As a result of the experiment, it was confirmed that the value at room temperature and the value at -180℃ reduced the shear strain by 5.0%, and -230˚ compared to the -180℃ condition. An increase of 1.5% was confirmed in the C condition. In the case of the specimen tested at -230℃, the deformation in the gripper part was larger than in other tests, and it is judged that the maximum shear strength and shear strain were affected. In addition, in this study, there is a limitation in the experiment at -230°C rather than 253°C, which is the boiling point of hydrogen

Breakthrough analysis has widely been explored for the dynamic separation of gaseous mixtures in porous materials. In general, breakthrough experiments measure the components of a flowing gas when a gaseous mixture is injected into a column filled with an adsorbent material. In this paper, we report on the design and fabrication of a breakthrough curve measurement device to study the dynamic adsorptive separation of hydrogen isotopologues in porous materials. Using the designed system, an experiment was conducted involving a 1:1 mixture of hydrogen and deuterium passed through a column filled with zeolite 13X (1 g). At room temperature, both hydrogen and deuterium were adsorbed in negligible amounts; however, at a temperature of 77 K, deuterium was preferentially adsorbed over hydrogen. The selectivity was different from that in the existing literature due to the different sample shapes, measurement methods, and column structures, but was at a similar level to that of cryogenic distillation (1.5).

In modern times, where problems due to environmental pollution are continuously occurring, hydrogen is in the spotlight as the energy of the future. Hydrogen is an eco-friendly energy resource that does not even generate CO2, and is actively supporting research to utilize hydrogen energy at the national level. This study is a study on the cryogenic mechanical properties of the elements constituting the cargo hold during the transportation of liquid hydrogen. Among the various components, the evaluation of mechanical properties of the cryogenic adhesive under liquid helium conditions was confirmed. The related contents are summarized as follows. As a result of performing SSRT by curing the adhesive, it was confirmed that tensile strength and maximum strain were increased at cryogenic temperature (-230°C) compared to room temperature (25°C). It was confirmed that the adhesive-hardened specimen showed a brittle fracture mode at both room temperature and cryogenic temperature during tensile. Improvements in this study, such as pores occurring during adhesive curing, the use of standard specimens, and experiments at -253°C, the boiling point of hydrogen, exist, and are planned to be carried out in subsequent studies.

Hydrogen is one of the main candidates in replacing fossil fuels in the forthcoming years. However, hydrogen technologies must deal with safety aspects due to the specific sub�stance properties. This study aims to provide an overview on the loss of mechanical properties of cryogenic materials, which may lead to serious consequences, such as fires and explosions. The hydrogen embrittlement of cryogenic steels was investigated through slow strain rate tensile tests (SSRTs) and thermal desorption analyses of electrochemically H-charged specimens. As a prior study to confirm mechanical properties under liquid hydrogen conditions, the amount of diffusive hydrogen that causes hydrogen embrittlement was confirmed after charging hydrogen using an electrochemical method for 4 types of steel materials applied as cryogenic materials did. When exposed to the same hydrogen charging conditions, the amount of hydrogen diffused into the 9% nickel steel is the highest compared to the austenitic steel type. It is considered that this is because the diffusion and integration of hydrogen into the interior is easy. It is necessary to analyze the relationship between hydrogen loading and mechanical properties, and this will be carried out in a follow-up study.

Due to global warming and environmental pollution, environmental regulations are getting stronger, and the International Maritime Organization announced regulations to reduce CO2 emissions in 2018. In order to respond to this, interest in hydrogen energy is growing, and research on liquid hydrogen is spotlighted for storage and transport of large amounts of hydrogen. Hydrogen reduces in volume to 1/800 when liquefied, but its boiling point is close to absolute zero(-253°C), and hydrogen embrittlement that penetrates other materials and weakens mechanical properties. In this study, the change of mechanical properties under cryogenic conditions (-196 degrees below zero) was confirmed after charging hydrogen into existing cryogenic materials (Stainless steel, High Manganese steel, 9% Nickel steel). In Part I, hydrogen was charged using an electrochemical method and quantitative evaluation was performed. In all four materials, as the changing time increased, the diffusible hydrogen concentration increased. After 24 hours charging, the hydrogen loading of 20 wppm in 9% Ni steel and 15 wppm in high-Mn steel was confirmed. In a follow-up study, we plan to study the effect of hydrogen charging by comparing the results of the mechanical properties test with the above results.

The impact properties of two austenitic Fe-23Mn-0.4C steels with different Al contents for cryogenic applications are investigated in this study. The 4Al steel consists mostly of austenite single-phase microstructure, while the 5Al steel exhibits a two-phase microstructure of austenite and delta-ferrite with coarse and elongated grains. Charpy impact test results reveal that the 5Al steel with duplex phases of austenite and delta-ferrite exhibits a ductile-to-brittle transition behavior, while the 4Al steel with only single-phase austenite has higher absorbed energy over 100 J at -196 oC. The SEM fractographs of Charpy impact specimens show that the 4Al steel has a ductile dimple fracture regardless of test temperature, whereas the 5Al steel fractured at -100 oC and -196 oC exhibits a mixed fracture mode of both ductile and brittle fractures. Additionally, quasi-cleavage fracture caused by crack propagation of delta-ferrite phase is found in some regions of the brittle fracture surface of the 5Al steel. Based on these results, the delta-ferrite phase hardly has a significant effect on absorbed energy at room-temperature, but it significantly deteriorates low-temperature toughness by acting as the main site of the propagation of brittle cracks at cryogenic-temperatures.

Because of the International Maritime Organization(IMO)'s regulation to regulate emissions of ships, a change is taking place to replace ship fuels from Heavy Fule Oil(HFO) to Liquefied Natural Gas(LNG). In the case of LNG, it is a material obtained by liquefying Natural Gas(NG), and it is -163 degrees below zero, and the volume is reduced to 1/600 level. The material of the tank that can store LNG must be a material that can safely store LNG in a cryogenic environment, and the materials of the tank that can store LNG are limited in the International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code). Among the materials listed in the IGC Code, 9% nickel steel is used as a material for LNG fuel propulsion tanks that are recently ordered because of relatively high mechanical properties under cryogenic environments. In this study, the mechanical properties of butt welds were measured following the weld reliability evaluation of Flux Cored Arc Welding(FCAW) butt welds made of 9% nickel steel by PARTI. The measured mechanical properties are tensile strength, bending strength, hardness, and cryogenic impact test required by the classification for Welding Procedure Specification(WPS) approval.

Because of the International Maritime Organization(IMO)'s regulation to regulate emissions of ships, a change is taking place to replace ship fuels from Heavy Fule Oil(HFO) to Liquefied Natural Gas(LNG). In the case of LNG, it is a material obtained by liquefying Natural Gas(NG), and it is -163 degrees below zero, and the volume is reduced to 1/600 level. The material of the tank that can store LNG must be a material that can safely store LNG in a cryogenic environment, and the materials of the tank that can store LNG are limited in the International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code). Among the materials listed in the IGC Code, 9% nickel steel is used as a material for LNG fuel propulsion tanks that are recently ordered because of relatively high mechanical properties under cryogenic environments. In this study, butt welding was performed on a 9% nickel steel material using Flux Cored Arc Welding(FCAW), the most widely used welding method in shipyards. In PARTI, after securing the welding conditions, cross-sectional observation results analysis, liquid penetrating test, and radiographic test were performed to verify the reliability of the weld.

As the International Maritime Organization (IMO)'s environmental regulations on ship emissions become strict, the demand for ships powered by Liquefied Natural Gas (LNG) is rapidly increasing worldwide. Compared to other materials, high manganese steel has the advantages of superior impact toughness at cryogenic temperatures, a small coefficient of thermal expansion, and low cost of base materials and welding rods. However, there is a limitation in that the mechanical properties of the filler material are lower than the base material having excellent mechanical properties. In this study, after performing a high manganese steel laser butt welding experiment, the welding performance was evaluated through mechanical property (yield strength, tensile strength, hardness, cryogenic impact strength) tests of the weld. As a result, it was observed that the yield strength and tensile strength of the high manganese steel laser welding part was 97.5% and 93.5% of the base metal respectively. Also the hardness of welding part was 84.2% of the base metal. The cryogenic impact strength of the welding part and the base metal were over the 27J, the level of welding part is 76.1% of the base metal.

LNG makes cryogenic conditions, so metals without low-temperature brittleness must be used. The International Maritime Organization (IMO) defines 9% Nickel steel, STS304L, 36% Nickel steel and Al5083 as metals that can be used in cryogenic conditions through the IGC Code. In this study, Al5083-O was studied to minimize welding distortion, and verified through finite element analysis and experiments. The block dumping method, which is advantageous in terms of analysis time and cost, was used, not the continuous heat source method. The constraint models with the thickness direction and the tensile force model were compared with the reference model, it was confirmed that the tensile force model had no significant effect. After verifying through the experiment, it was confirmed that the trend of the finite element analysis model was consistent with the experiment. Through this study, a welding distortion minimization model could be found with the block dumping method. It is judged that simulation of many models through short time analysis will be of great help in the field.

Natural gas is the most realistic fuel among eco-friendly fuels. Natural gas production is limited, and in Korea, it is supplied and utilized in the form of liquefied natural gas (LNG). In the case of LNG, the vaporization point is 163 degrees below zero, so ordinary metal cannot be used due to its brittleness. The International Maritime Organization (IMO) defines metals that can be used in the IGC Code, and is used for storage containers, transportation containers, etc. based on the metals. Welding is essential in the manufacture of large structures such as LNG storage tanks. In this study, weldability studies related to cryogenic materials were conducted. In Part I of this study, high-manganese steel and part II were studied for two types of stainless steel (STS304L, STS316L), and in Part III, aluminum (AL5083). During laser welding, the shape of the Bead on Plate (BOP) was analyzed, and a total of nine cases were analyzed using laser power and welding speed as variables. It was confirmed that the penetration and the width of the welding width were linearly proportional to the amount of heat input. Based on this study, it is possible to conduct a follow-up study to find the optimal welding conditions for butt welding and fillet welding.

As the part of efforts to respond to the environmental pollution, the demand for clean energy is increasing. Natural gas is one of the most realistic alternatives, and interest in the storage and transportation containers to utilize the natural gas is growing. The production area of ​​natural gas is limited, and in Korea, it is imported in the form of liquefied natural gas. LNG is a cryogenic state with a vaporization point of -163°C, so the ordinary metal cannot be used due to its brittleness. The international maritime organization (IMO) defines the metals that can handle LNG in the IGC Code, and the research is ongoing. This study was a preliminary study to check the weldability of related metals and confirmed the shape of bead on plate (BOP) during the laser welding for each material. In part I, a study was conducted on the high manganese steel, and in part II, a study was conducted on the materials of STS304L and STS316L among the stainless steel. Based on this study, it can be used as an optimal welding condition for the butt and fillet welding.

As demand for eco-friendly energy increases, demand for natural gas and Liquefied natural gas (LNG) storage technologies continues to increase. LNG is a cryogenic environment with a temperature of -163°C, so ordinary metals cannot be used due to brittleness. Accordingly, IGC Code designates the cryogenic materials such as Invar, STS304L, Al5083-0, and High Manganese Steel. For fabricating those materials, research on welding possibility is the most important. Thus this study focused on the possibility of laser welding of the cryogenic materials. The weldability of High Manganese Steel was researched in this paper, the shape and the dimensions of the beads after bead on plate (BOP) welding were observed. The experiment was conducted on a total of 25 cases with laser power and welding speed of 5 cases each, and the width, height, and penetration of the beads were confirmed. It was confirmed that the paramenter of bead increased linearly with the laser power, and the paramenters of bead increased linearly with decreasing welding speed. Based on this study, high manganese steel can be applied in various industries by applying it to butt welding.

The gas adsorption isotherm requires accurate measurement for the analysis of porous materials and is used as an index of surface area, pore distribution, and adsorption amount of gas. Basically, adsorption isotherms of porous materials are measured conventionally at 77K and 87K using liquid nitrogen and liquid argon. The cold volume calibration in this conventional method is done simply by splitting a sample cell into two zones (cold and warm volumes) by controlling the level sensor in a Dewar filled with liquid nitrogen or argon. As a result, BET measurement for textural properties is mainly limited to liquefied gases (i.e. N2 or Ar) at atmospheric pressure. In order to independently investigate other gases (e.g. hydrogen isotopes) at cryogenic temperature, a novel temperature control system in the sample cell is required, and consequently cold volume calibration at various temperatures becomes more important. In this study, a cryocooler system is installed in a commercially available BET device to control the sample cell temperature, and the automated cold volume calibration method of temperature variation is introduced. This developed calibration method presents a reliable and reproducible method of cryogenic measurement for hydrogen isotope separation in porous materials, and also provides large flexibility for evaluating various other gases at various temperature.