Thin films of yttria-stabilized zirconia (YSZ) nanoparticles were prepared using a low-temperature deposition and crystallization process involving successive ionic layer adsorption and reaction (SILAR) or SILAR-Air spray Plus (SILAR-A+) methods, coupled with hydrothermal (175 °C) and furnace (500 °C) post-annealing. The annealed YSZ films resulted in crystalline products, and their phases of monoclinic, tetragonal, and cubic were categorized through X-ray diffraction analysis. The morphologies of the as-prepared films, fabricated by SILAR and SILAR-A+ processes, including hydrothermal dehydration and annealing, were characterized by the degree of surface cracking using scanning electron microscopy images. Additionally, the thicknesses of the YSZ thin films were compared by removing diffusion layers such as spectator anions and water accumulated during the air spray plus process. Crack-free YSZ thin films were successfully fabricated on glass substrates using the SILAR-A+ method, followed by hydrothermal and furnace annealing, making them suitable for application in solid oxide fuel cells.

본 논문에서는 전산점근해석기법을 사용하여 복합재료 보에 대한 경계층 해를 계산하고, ANSYS 결과와 비교 검증하였다. 경계층 해는 내부해와 순수 경계층 효과의 합으로 표현되기 때문에, 내부 및 경계층에 대한 수학적으로 엄밀한 정식화를 요구한다. 전산점근 해석기법은 수학적으로 매우 강력한 기법으로, 이러한 문제에 유용하다. 그러나 경계층과 내부 해들의 연결을 시키기 쉽지 않은데, 본 연구에서는 가상일의 원리를 통해 생브낭의 원리와 내부 및 경계층 문제를 체계적으로 분리하였다. 경계층 해는 팝코비치-패들 고유 벡터를 계산하여, 실수부와 허수부 벡터들의 선형 조합으로 표현하고, 내부 해의 워핑 함수들을 보상할 수 있도록 최소오차 자승법을 적용하였다. 계산된 해들은 2차원 유한요소 해석 결과와 비교하여 정성적일 뿐만 아니라 정량적으로도 잘 일치하는 결과를 얻었다.

For practical applications of graphene sheets in a variety of fields, mass production of high-quality graphene sheets is necessary. Herein, we reported a cost-effective, green, and simple approach to synthesizing mass production exfoliated graphene (EG) flakes employing electrochemical exfoliation of pencil graphite in neutral aqueous electrolytes. Pencil graphite cores of different grades were applied as anode and cathode electrodes and exposed to the electrolyte solution at a different voltage. Several parameters were examined and optimized, including pencil grade (2,4,6,8 B), applied voltage (10, 15, 20, 30 V), different inorganic electrolytes ((NH4)2SO4, Na2SO4, NaNO3, NaCl, and CH3COONa), and the concentration of electrolytes. The optimal condition was chosen by considering the mass of produced graphene and the conductivity of the graphene solution. The optimal conditions were as follow: pencil grade: 6B; applied voltage: 10 V; electrolyte type: Na2SO4; electrolyte concentration: 0.1 M. Under these conditions, the production yield was > 95% within 3 h and 9 min. The EG was characterized by utilizing FT-IR, XRD, Raman spectroscopy, FE-SEM, Cyclic Voltammetry, and Electrochemical Impedance Spectroscopy (EIS). Characterization indicates that the synthesized EG had an XRD peak at 2θ = 26.6° and an ID/ IG ratio of 0.36. Furthermore, the EG showed good conductivity when tested by cyclic voltammetry and EIS whereas the R2 values were 985.8 and 76.3 Ω for bare GCE and EG/GCE, respectively. In addition, EG effectively removed cadmium (Cd(II)) with an adsorption level of 8.72 mg/g. The results from this study suggest that EG can be scaled up and commercialized in an environmentally friendly and low-cost manner, especially in low-income countries, and using it to rectify metal ions.

The most comprehensive and particularly reliable method for non-destructively measuring the residual stress of the surface layer of metals is the sin method. When X-rays were used the relationship of sin measured on the surface layer of the processing metal did not show linearity when the sin method was used. In this case, since the effective penetration depth changes according to the changing direction of the incident X-ray,  becomes a sin function. Since  cannot be used as a constant, the relationship in sin cannot be linear. Therefore, in this paper, the orthogonal function method according to Warren’s diffraction theory and the basic profile of normal distribution were synthesized, and the X-ray diffraction profile was calculated and reviewed when there was a linear strain (stress) gradient on the surface. When there is a strain gradient, the X-ray diffraction profile becomes asymmetric, and as a result, the peak position, the position of half-maximum, and the centroid position show different values. The difference between the peak position and the centroid position appeared more clearly as the strain (stress) gradient became larger, and the basic profile width was smaller. The weighted average strain enables stress analysis when there is a strain (stress) gradient, based on the strain value corresponding to the centroid position of the diffracted X-rays. At the 1/5 max height of X-ray diffraction, the position where the diffracted X-ray is divided into two by drawing a straight line parallel to the background, corresponds approximately to the centroid position.

Recently, 3D printing has been actively studied. A representative material in this 3D printing technology is plastic, and PLA, an eco-friendly material, is widely used. FDM is widely used as a way to output these PLA materials. However, this method lacks mechanical properties compared to injection-molded products as it is a method of stacking materials by melting. Therefore, in this study, using an FDM-type 3D printer, a tensile test was performed after printing a tensile specimen with PLA filament with the layer angle and layer density as control factors. After that, changes in tensile properties according to the layer angle and density were compared and evaluated. As a result, to improve the tensile strength, the layer density had to be considered, and to improve the elastic modulus, both the layer angle and the layer density had to be considered.

페로브스카이트 태양전지는 빠른 속도로 효율 개선이 이루어지며 차세대 친환경 에너지원으로 각광받고 있다. 가공 매개변수의 영향을 강하게 받는 유-무기 혼합 페로브스카이트 태양전지에서 고품질의 광 활성층을 제조하는 것은 매우 중요하다. 본 연구에서는 Methylammonium Lead Iodide(MAPbI3) 광 활성층 제작 시, 결정화가 이루어지는 열처리 과정에서 압력을 가함으로써 용매가 증발하는 속도를 조절할 수 있는 가압열처리 공정방법(pressure assisted annealing process, PA method)을 개발하였다. 본 연구에서 개발한 광 활성층 제조방법은 보다 오래 용매를 활성층 내에 머물게 할 수 있어서 MAPbI3의 중간단계에서 그레인의 성장을 극대화 할 수 있으며, 이를 통해 고품질 페로브스카이트 광 활성층의 제조를 가능하게 한다. 또한 본 가압열처리 방법으로 형성시킨 페로브스카이트 광 활성층을 도입하여 태양전지를 제조하였을 경우, 소자의 최고 성능은 기존의 방법으로 제조된 소자와 비교하여 24.4 mA cm-2의 높은 단락 전류밀도, 0.96 V의 개방전압, 0.75의 필 팩터를 나타내며 17.3 %의 에너지 전환효율을 나타내었다.

In recent years, there have been applied methods for minimizing noise by adjusting the method of installing soundproof walls, soundproof tunnels, soundproofing rims, environmental facilities, etc., and the shape of the surface texture of tire treads and packaging materials for the purpose of reducing road noise. Low noise pavement methods such as rubber asphalt (CRM), open graded asphalt concrete (OGAC), permeable Friction Courses (PFC), open graded friction courses (OGFC) and porous asphalt have been applied to reduce road noise. Especially, porous pavement is the most widely used low noise pavement with porous structure, which can reduce noise and drain water through continuous void of pavement. On the other hand, porous asphalt pavement has problems such as reduction of noise reduction effect and difficulty of road surface management due to void closing and increase of construction cost. The purpose of this study is to develop ultra-thin layer hot mix asphalt pavement method which maximizes road noise reduction effect by surface micro voids (Recover asphalt pavement) to improve void clogging of present porous pavement method. For this study, maximum size 5mm aggregate and cationic-treated fiber reinforced asphalt modifier (CSM) were used. The Marshall design method was applied grain-size distribution curve was based on SMA mix design. Marshall test, TSR, MMLS3 test and Hamburg test were carried out to evaluate the mechanical properties of ultra -thin layered asphalt pavement method with surface micro voids. Also, the effect of road noise reduction was evaluated through field application in urban area.

As ZIF materials have their unique properties such as high surface area, tunable pore structure, thermal and chemical stability, they can be used in various applications including gas separation and catalysis. For synthesis of ZIF membranes, fixing sub-micron ZIF seed particles on the support is challenging and important. In this work, ZIF-8 seed layer was synthesized by conversion synthesis of ZnO layer on support in H-mIm solution, followed by the secondary growth synthesis of ZIF-8 membranes. The parameters of conversion seeding had been investigated to control the reaction rate combining the dissolution rate of ZnO and the crystallization rate of ZIF-8. This ZIF-8 membranes showed the better coverage of seeding layer and improved gas separation properties compared with the membranes prepared by traditional dip-coating seeding method.

We report on a unique fabrication technique, DSC for high performance PA TFC RO membranes. DSC allows the simultaneous and continuous spreading of two reactive monomer solutions to create an unsupported PA layer, which is then adhered onto a porous support to form a membrane. DSC facilitates the characterization of the PA layer structure by easily isolating it. The DSC-PA layer exhibits a thinner and smoother structure with a more wettable and less negatively charged surface than one prepared via conventional interfacial polymerization (IP). DSC enables the formation of an extremely thin (~9 nm) and dense PA layer using a very low MPD concentration, which is not feasible by conventional IP. Importantly, the DSC-assembled membrane shows the excellent water flux and NaCl rejection, exceeding both the IP control and commercial RO membranes.

1차원 등엔트로피 모델과 통합된 경계층 적분법은 초음속 노즐의 설계과정에서 내열재 표면의 열전달을 예측하는데 효과 적으로 사용되고 있지만 노즐 목과 같이 2차원 효과와 경계층과 노즐 코어유동의 상호작용이 발생하는 지점에서는 경계층 외부유동 해석의 부정확성으로 해석의 정확도가 감소한다. 따라서 본 연구에서는 경계층 적분법을 이용한 열전달 예측의 정 확도를 향상시키기 위해 CFD를 이용하여 2차원 효과와 노즐 코어유동의 상호작용이 고려된 경계층 외부유동 조건을 도출 하고 이를 경계조건으로 하는 해석기법을 개발하였다. 오일러 모델과 SST k-ω 모델을 CFD로 해석하여 경계조건으로 적용 했으며 계산방법을 검증하기 위해 선행문헌의 실험노즐에 대해 해석을 수행하였다. 계산 결과 CFD를 통해 경계층 외부유동 조건을 도출한 해석에서 노즐 열전달의 정확도가 향상되는 것을 확인하였으며 특히 노즐 목 후방과 팽창부에서의 차이가 크 게 나타났다. SST k-ω모델로 도출된 계산결과는 1차원 등엔트로피 모델과 비교 시 팽창부에서 실험결과와의 오차가 16% 감소하였다. 본 연구에서 개발된 해석기법은 향후 로켓노즐의 내열설계에 유용하게 사용될 것으로 평가된다.

폴리설폰막 위에 친수성 고분자를 Layer-by-Layer법으로 코팅하여 복합막을 제조하였다. FE-SEM 분석을 통하여 복합막 표면과 기공 내 코팅층을 확인하였다. 또한 100 ppm NaCl 용액에 대한 복합막의 투과성능 평가를 실시하였다. 복합 막 제조를 위한 코팅 고분자는 PVSA, PEI, PAA, PSSA, PSSA_MA를 사용하였다. 폴리설폰막 표면에 8,000 ppm PAA (이 온세기 0.35) 수용액을 3분 동안 코팅한 뒤 10,000 ppm PEI 수용액을 4분 동안 코팅하였다. 그 결과 PAA-PEI 복합막의 투과 도는 101 LMH, 제거율은 66.7%로 가장 좋은 투과성능을 나타내었다. PAA-PEI 복합막의 투과성능은 도레이케미칼의 NE 4040-70 (투과도 = 30 LMH, 염 배제율 = 40~70%) 제품과 유사한 성능을 보여주는 우수한 투과 특성을 나타내었다.

기술 표준은 기술적 특성과 사양에 대한 일종의 사회적 합의로서 기술의 발달 과 함께 모든 산업에 걸쳐 존속되어 왔으며 최근에는 정보통신 기술의 발달과 함께 기술의 상호호환성을 제공하고 시장의 우위를 선점할 수 있는 전략적인 요소로 각광받고 있다. 이에 기술 표준 연구(표준화 연구)는 기술 표준의 채택 과정과 이로 인한 경제적 효과를 분석하여 이론적 및 정책적 함의를 도출하는데 그 의의가 있다. 그러나 기존의 연구에서는 기술 고유 의 가치와 상호호환성에 대한 고려가 부족하다는 점에서 기술 중심의 분석 결과를 도출하는 데 있어 구조적 한계를 드러낸다. 본 연구는 기술 네트워크 분석을 통해 도출한 기술 차별화 정도와 기업별 기술 선호도 함 수를 두 단계 게임 이론 분석 방법에 반영하여 새로운 기술 중심 표준 연구 방법론을 제공하는 것을 목적으로 하고 있다. 그 실증 사례로 사물인터넷의 무선 팬 기술을 선정하였으며, 본 연구 방법론을 통해 해당 시장의 기술 구조 및 표준 관련 함의를 도출하였다.

중공사막 지지체에 계면중합반응을 통해 막을 형성하여 복합막을 제조하였으며 복합막의 성능평가를 위해 코팅용액의 농도, 코팅시간 및 건조온도 등을 변화시켜 실험을 수행하였다. PART 1 실험에서는 PVAm과 -NH 작용기를 갖는 수용상의 PEI, -COCl작용기를 갖는 유기상의 Trimesoyl chloride 사이의 계면중합 반응을 통해 복합막을 제조하였다. PART 2 실험에서는 PEI를 piperazine(PIP)으로 대체하여 계면중합반응을 하였다. PART 1에서는 PVAm 10,000ppm과 PEI 4,000ppm을 혼합하였을 때 투과도와 배제율 측면에서 가장 좋은 결과를 보였으며 PART 2에서는 PVAm과 PIP의 농도가 높아짐에 따라 투과도는 감소하고 배제율은 증가하는 결과를 얻었다.

(PDDA/SiO2) thin films that consisted of positively charged poly (diallyldimethylammonium chloride) (PDDA) and negatively charged SiO2 nanoparticles were fabricated on a glass substrate by an applying voltage layer-by-layer (LBL) self-assembly method. In this study, the microstructure and optical properties of the (PDDA/SiO2) thin films coated on glass substrate were measured as a function of the applied voltage on the Pt electrodes. When 1.0 V was applied to a Pt electrode in a PDDA and SiO2 solution, the thickness of the (PDDA/SiO2)10 thin film increased from 79 nm to 166 nm. The surface roughness also increased from 15.21 nm to 33.25 nm because the adsorption volume of the oppositely charged PDDA and SiO2 solution increased. Especially, when the voltage was applied to the Pt electrode in the SiO2 solution, the thickness increase of the (PDDA/SiO2) thin film was larger than that obtained when using the PDDA solution. The refractive index of the fabricated (PDDA/SiO2) thin film was ca. n = 1.31~1.32. The transmittance of the glass substrate coated by (PDDA/SiO2)6 thin film with a thickness of 106 nm increased from ca. 91.37 to 95.74% in the visible range.