This study explores the integration of ChatGPT, OpenAI’s conversational AI, into English as a Foreign Language (EFL) classrooms at Korean universities, focusing on student interactions and language learning strategy preferences. It categorises interactions using the Strategy Inventory for Language Learning (SILL) and Strategic Self-Regulation (S2R) frameworks to evaluate the pedagogical effectiveness of AIassisted learning. Ninety-nine university students participated in training sessions with ChatGPT prompts tailored to different learning strategies. Data were collected through surveys, chat transcripts, and qualitative feedback. Results indicate frequent student interactions with ChatGPT, averaging 4.49 strategies in initial training chats. Compensatory strategies like error correction and adaptive difficulty received high ratings, while social strategies were rated lowest. Metacognitive strategies, especially planning and summarising, were also well-received. The study concludes that ChatGPT supports diverse learning strategies, enhancing linguistic competence and promoting self-regulated learning. However, limitations such as AI accuracy and authenticity issues highlight the need for continued human interaction in language education.
최근 국내외 화장품과 식품산업에서 다양하게 사용되어 지고 있는 콜라겐 단백질 제품은 점차 그 용도와 특성에 따라 보다 고도화, 기능화 되어 가고 있다. 피부 건강의 지표인 콜라겐은 다양한 용도로 개발되어 사용되고 있으 며, 콜라겐의 소비가 증가함에 따라 용도에 적합한 최적 화된 콜라겐 제품의 개발이 중요한 연구 분야이다. 특히 여러 기업과 연구기관들에 의해서 콜라겐의 흡수율을 높 이기 위한 다양한 노력이 이루어지고 있다. 따라서 본 연 구에서는 프란즈(Franz) 세포 시스템을 이용하여 국내에서 판매되는 다양한 분자량별 콜라겐 제품의 경피 및 구강 상피세포 투과성을 비교하였다. 그 결과, 피부 표피/진피 조직과 비교하여 구강점막 조직의 콜라겐 흡수율이 분자 량 500달톤과 1,000달톤의 경우 모두 통계적으로 유의하 게(각각 약 10배, 2배) 높은 것으로 확인되었다. 또한, 분 자량별 구강점막 조직 흡수율을 비교한 결과, 분자량 500 달톤의 콜라겐이 분자량 1,000달톤 제품에 비해 흡수율이 2-3배 증가함을 확인하였다. 분자량 500달톤의 경우 Cmax 와 AUCt 값이 가장 높게 나타났으며, 피부 표피/진피 세 포에 비해 구강점막세포 시험군의 모든 지표가 높은 것으 로 나타났다. 본 연구 결과는 피부 흡수보다는 구강 점막 세포를 통한 콜라겐의 흡수방법이 콜라겐 체내 흡수증가 에 유효한 수단임을 시사하며, 분자량 1,000달톤 이하에서 도 보다 더 작은 500달톤의 저분자 콜라겐의 흡수율이 증 가되는 것으로 보아 콜라겐의 분자량이 흡수율 증가의 주 요한 요소임을 확인할 수 있었다.
We presented foundational findings regarding the occurrence and acoustic characteristics of the finless porpoise through passive acoustic and visual surveys conducted on the southern coast of Korea, specifically at Hadong Jungpyeong Port. Over a survey period spanning from July 8 to August 16, 2023, totaling 40 days, we observed peaks in the number of clicks produced by this species on July 15, July 24, August 4, August 11, and August 16. The highest count, totaling 18,924 clicks, was recorded on July 15th, while the lowest count, at 3,888 clicks, occurred on August 8th. Examining the acoustic characteristics throughout the diurnal cycle, we found that the peak activity in terms of DPM (detection positive minute for one hour), DP10M (DPM for ten minutes), and overall number of click sounds was observed between 05:00 and 08:00, with a secondary peak occurring from 17:00 to 18:00. The quietest period was noted between 23:00 and 02:00. Furthermore, there was a significant increase in the number of clicks from sunrise, with the maximum count of 21,581 clicks recorded at 6 AM. This count gradually decreased until noon, experienced a slight increase thereafter, peaked again at sunset, and then declined. The dominant frequency mode of this species was 126 kHz, with a concentration ranging from 112 to 136 kHz. The average duration of a click sound was 127 ㎲, with approximately 16 sinusoids (cycles) within each click sound and an average cycle length of approximately 7.9 ㎲. These findings from our study are anticipated to serve as foundational data for the development of a Korean pinger and acoustic warning system.
대부분의 사람들은 시궁창에 있지만, 니심 이지키엘처럼 그들 중 일부는 별을 바라본다. 그가 태어난 날부터 죽을 때까지, 그는 평범한 사람들이 가지고 있지 않은 특별한 무언가를 가지고 있었다. 그는 태어나지 않은 노래의 샘을 “휘젓는” 능력을 가지고 있었고, 그의 심장에 불이 붙은 바람을 느꼈다. 시인과 평범한 사람의 차이는 단어 사용에 숨겨져 있다. 이지키엘은 재치 있는 조각가와 같았다. 그는 자신의 시의 특정 줄에 적합한 단어와 구절을 선택하는 데 익숙했다. 만약 그가 원래 초안에 만족하지 못한다면, 그는 최종 작품이 오늘날에도 그 안에서 볼 수 있는 위엄으로 빛날 때까지 계속해서 썼다. 그는 모호함에 대해 반란의 깃발을 올렸다. 그는 표현이 명확하고 단순한 어법으로 이루어져야 한다는 것을 알고 있었다. 그 외에도 이지키엘에게 시는 단순한 시집이 아니라 그보다 더 위대한 것이다. 이 뛰어난 시인의 시적 신조가 발전하는 과정은 순탄하지 않았다. 그것은 물결처럼 출렁였다.
아일랜드의 민족주의자이자 작가인 윌리엄 버틀러 예이츠(1865-1939)의 문학적 재능에는 여러 측면이 있다. 아일랜드 신화와 민속을 영국 식민지주의에 대한 저항으로 활용하고, 1916년 부활절 봉기와 같은 아일랜드 민족주의 투쟁의 긴 역사에서 일어난 사건을 찬양하고, 철학적 묵상, 선견지명적 순간, 상징주의, 낭만주의 등 그는 다양한 문학 장르에서 이 모든 것을 다루었다. 예이츠의 시가 그의 문학 작품에서 가장 중요한 자리를 차지하고 있다는 것은 부인할 수 없다. 예이츠의 성격의 여러 측면 중에서 아일랜드 혁명가 모드 곤의 연인으로 묘사된 예이츠는 잘 알려져 있다. 그녀와 그의 삶에 들어온 다른 여성들에게 영감을 받아 그는 상당수의 연애시를 썼다. 이 논문의 목적은 예이츠의 선택된 연애시에서 여성에 대한 표현을 분석하여 남성의 여성에 대한 태도와 다양한 사랑의 뉘앙스에 대한 그들의 경험에 빛을 비추는 것이다. 이는 아일랜드와 세계 다른 지역의 여성 운동에서 일어난 사건으로 인해 여성의 지위가 변화했다는 점을 감안할 때 중요하다. 이 논문은 세기의 전환기에 공공 영역에서 활동하는 “새로운 여성”이 등장했음에도 불구하고 예이츠의 연애시를 포함한 연애시는 궁정 연애의 전통을 이어가며 사랑하는 사람의 아름다움과 수동성을 찬양한다고 주장한다. 이 논문은 페미니즘 이론의 통찰력을 이용하여 시를 분석한다.
Today, the principles of green chemistry are being fundamentally applied in the chemical industry, such as the nitrobenzene industry, which is an essential intermediate for various commercial products. Research on the application of response surface methodology (RSM) to optimize nitrobenzene synthesis was conducted using a sulfated silica (SO4/SiO2) catalyst and batch microwave reactor. The nitrobenzene synthesis process was carried out according to RSM using a central composite design (CCD) design for three independent variables, consisting of sulfuric acid concentration on the silica (%), stirring time (min), and reaction temperature (°C), and the response variable of nitrobenzene yield (%). The results showed that a three-factorial design using the response surface method could determine the optimum conditions for obtaining nitrobenzene products in a batch microwave reactor. The optimum condition for a nitrobenzene yield of 63.38 % can be obtained at a sulfuric acid concentration on the silica of 91.20 %, stirring time of 140.45 min, and reaction temperature of 58.14 °C. From the 20 experiments conducted, the SO4/SiO2 catalyst showed a selectivity of 100 %, which means that this solid acid catalyst can potentially work well in converting benzene to nitrobenzene.
Copper, silver, and gold-reduced graphene oxide nanocomposite (Cu-rGO, Ag-rGO, and Au-rGO) were fabricated via the hydrothermal method, which shows unique physiochemical properties. Environment friendly electromagnetic radiation was employed to synthesize rGO from GO. The nonlinear optical phenomenon of noble metal decorated rGO is predominantly due to excited state absorption, which arises from surface plasmon resonance and increases in defects at the surface due to Cu, Ag, and Au incorporation. It is found that the third-order nonlinear absorption coefficient was in the order of 10− 10 m/W, with notable enhancements in the third-order properties of Au-rGO compared to other nanocomposites and their respective counterparts. Functionalizing rGO induces defect states ( sp3), increasing NLO response. Cu, Ag, and Au exhibit higher Surface-Enhanced Raman Scattering (SERS) activity due to rGO-induced structural modifications. SERS signals are influenced by dominant signals from Au nanorods. The electronic structures for pure and doped rGO were investigated through Density Functional Theory (DFT). The computed partial density of states (PDOS) confirms the enhancement of the state in Au-doped rGO is due to the charge transference from Au to C 2p orbital. The optical absorption spectra and PDOS reveal the possibility of free carrier absorption enhancement in Au which validates experimentally observed higher two-photon absorption (β) value of Au-doped rGO. The tuning of nonlinear optical and SERS behaviour with variation in the noble metal upon rGO provides an easy way to attain tuneable properties which are exceedingly required in both optoelectronics and photonics applications.
Electrochemical water splitting presents an optimal approach for generating hydrogen ( H2), a highly promising alternative energy source. Nevertheless, the slow kinetics of the electrochemical oxygen evolution reaction (OER) and the exorbitant cost, limited availability, and susceptibility to oxidation of noble metal-based electrocatalysts have compelled scientists to investigate cost-effective and efficient electrocatalysts. Bimetallic nanostructured materials have been demonstrated to exhibit improved catalytic performances for the oxygen evolution reaction (OER). Herein, we report carbon aerogel (CA) decorated with different molar ratios of Fe and Ni with enhanced OER activity. Microwave irradiation was involved as a novel strategy during the synthesis process. Inductively coupled plasma mass spectrometry (ICP-MS), X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscope (SEM), Energy dispersive X-ray spectroscopy (EDAX spectra and EDAX mapping), Transmission Electron Microscope (TEM), High-Resolution Transmission Electron Microscope (HR-TEM), and Selected Area Electron Diffraction (SAED) were used for physical characterizations of as-prepared material. Electrochemical potential towards OER was examined through cyclic voltammetry (CV), chronoamperometry, and electrochemical impedance spectroscopy (EIS). The FeNi/CA with optimized molar ratios exhibits low overpotential 377 mV at 10 mAcm− 2, smaller Tafel slope (94.5 mV dec− 1), and high turnover frequency (1.09 s− 1 at 300 mV). Other electrocatalytic parameters were also calculated and compared with previously reported OER catalysts. Additionally, chronoamperometric studies confirmed excellent electrochemical stability, as the OER activity shows minimal change even after a stability test lasting 3600 s. Moreover, the bimetallic (Fe and Ni) carbon aerogel exhibits faster catalytic kinetics and higher conductivity than the monometallic (Fe), which was observed through EIS investigation. This research opens up possibilities for utilizing bi- or multi-metallic anchored carbon aerogel with high conductivities and exceptional electrocatalytic performances in electrochemical energy conversion.
Energy storage is one of the leading problems being faced globally, due to the population explosion in recent times. The conventional energy sources that are available are on the verge of extinction, hence researchers are keen on developing a storage system that will face the upcoming energy needs. Supercapacitors, also known as ultracapacitors or electrochemical capacitors, are advanced energy storage devices characterised by high power density and rapid charge–discharge cycles. Unlike traditional batteries, supercapacitors store energy through electrostatic separation, offering quick energy release and prolonged operational life. They hold exceptional performance in various applications, from portable electronics to electric vehicles, where their ability to deliver bursts of energy efficiently complements or replaces conventional energy storage solutions. Ongoing research focuses on enhancing energy density and overall efficiency, positioning supercapacitors as pivotal components in the evolving landscape of energy storage technologies. A novel electrode material of NiO/CuO/Co3O4/rGO was synthesized which when used as a supercapacitor, the highest value of CS is 873.14 F/g which is achieved for a current density of 1 A/g under with an energy density of 190 Wh/kg and the highest power density of 2.5 kW/kg along with 87.3% retention after 5000 GCD cycles under 1 M KOH.
Flexible electrodes, particularly paper electrodes modified with polypyrrole, have shown promise in energy-related applications. We have earlier demonstrated the usage of paper electrodes modified with polypyrrole as a flexible and suitable photoanode for photoelectrochemical water splitting (PEC). Further, modification of this electrode system with an appropriate tandem absorber system for solar fuel production is interesting in developing efficient photoanodes. In this study, we study the PEC performance of flexible polypyrrole-based paper photoanodes (PPy-PAs) by decorating them with rGO@Cu2Zn- SnS4 chalcopyrites (rGO@CZTS/PPy-PAs). The lower bandgap (~ 1.5 eV) of the rGO@CZTS/PPy-PAs system allows for efficient visible light absorption, substantially improving PEC water-splitting reactions. The rGO@CZTS/PPy-PAs exhibited an enhanced current density of ~ 13.2 mA/cm2 at 1.23 V vs RHE, ABPE of ~ 1.5%, and a hydrogen evolution rate of 177 μmoles/min/cm2. Overall, rGO@CZTS/PPy-PAs showed 2.1-fold, 1.1-fold, and 1.4-fold enhancement in photocurrent activity over PPy-PAs, CZTS/PPy-PAs, and rGO/PPy-PAs, respectively. The usability of rGO@CZTS/PPy-PAs is established in the form of stable photocurrent for more than 200 min. These findings open new possibilities for developing modified PPy PAs as flexible PEs for efficient solar-driven PEC devices and give directions on improving flexible PEs for flexible and efficient solar-driven PEC systems.
Carbon dots (C-dots) are a developing subclass of nanomaterials which are characterized by a typical diameter of less than 10 nm. C-dots are a type of core–shell composites that feature a surface passivation with various functional groups, including amine, carboxyl, hydroxyl group, and a carbon core. Green C-dots, which have drawn a lot of interest from researchers due to their superior water solubility, excellent biocompatibility, and environmental-friendly behavior when compared to chemically generated C-dots, can be made from a variety of low-cost and renewable materials. Since green C-dots have heteroatoms on their surface in the form of carboxyl, amine, hydroxyl, or other functional groups, which can enhance their physicochemical characteristics, quantum yield (QY), and likelihood of visible light absorption, further surface passivation is not necessary. Green C-dots may find use in the areas of biosensing, catalysis, bioimaging, and gene and drug delivery. In this paper, the creation of C-dots was outlined, and its fluorescence process examined. This review represents the summary of synthesis, mechanism, properties, characterization, and applications of C-dots. This article aims at the green chemistry strategies for C-dot synthesis. Furthermore, a discussion on the applications of C-dots produced with green approaches is presented. The paper may help the researchers in the field to develop new C-dots with potential features to attract the attention of new applications.
Sustainable development goals reflect sustainability in multiple aspects of life from both business and consumers. In the Metaverse world, luxury brands and their consumption are working towards adopting sustainability in luxury fashion. The scholarship has stretched to multiple aspects across various themes and sectors to understand the developments in this field. It is apparent that sustainability and luxury have been the subject of scrutiny since long, but a refreshing perspective on this evolving dynamic is needed to analyze the surge in publications. This research aims to identify the existing literature in the area and gain in-depth knowledge of current trends with the help of bibliometric analysis. Further, the study aims to determine different clusters and identify the directions for future research in the sustainable luxury fashion domain.
This research aims to analyse consumers’ (Millennials and Gen Z) luxury consumption behaviour by focusing on the intrinsic and extrinsic motivations that drive consumption of luxury goods. Then, the study investigates whether they prefer to purchase offline or online for luxury goods. Lastly, it analyses which media most influences individuals when it comes to luxury consumption. An online survey is developed and distributed to Millennials and Gen Z. A first round of data collection took place in 2022 and a second round of data collection will take place at the beginning of 2024. Initial findings show that consumers are driven by intrinsic rather than extrinsic motivations when purchasing and who influences more when buying luxury online. Furthermore, it emerges that consumers prefer to shop offline, highlighting the importance of physical stores.
The study investigated the influence of website features on the purchase intention of online fashion among Generation Z consumers in South Africa. This topic has received increasing attention against the backdrop of the rapidly growing ‘Digital Generation’, or ‘Millennial consumers’, who are one of the most tech-savvy generations. Despite the benefits that online shopping offers to both the business and the consumer, the act of buying clothes online has presented some challenges to customers. This study therefore aims to gather further insight in an attempt to provide fashion businesses with guidance to better succeed in encouraging customers to shop online. This study selected two visual elements (website aesthetics and product presentation) and two functional website features (website navigation, and security and privacy) and social norms, the test the effect they have on perceived ease of use, attitude and intention to purchase clothing online. The proposed conceptual model tested seven hypotheses of which four were supported. By means of an empirical study, 166 online surveys were collected from individuals within the Generation Z cohort and the analysis was done using SPSS27 by running multiple regression analysis to test the relationships between the variables. The results from this study provide global and local fashion brands with valuable insight into the consumption habits of young consumers in an emerging economy, and factors that drive online fashion consumption.