제주도 안디졸(Andisol) 토양 분포지역 중 화산성 쇄설물과 현무암으로부터 기원된 두 토양의 Bo층을 대상으로 완충능력을 계산하고 토양의 알루미늄 용해도가 완충능력에 미치는 영향을 연구하였다. 주상실험 결과는 pH 6.0과 4.0 부근에서 완충작용이 일어남을 보여 주며, 현무암기원의 토양보다 화산쇄설암기원 토양의 완충능력이 더 큰 것으로 나타났다. 다양한 pH조건에서의 배치평형실험 결과 다량의 알루미늄 함유 광물상을 갖는 제주도 안디졸 토양 Bo층에서의 알루미늄 거동은 Al(OH)3, 이모골라이트 혹은 프로토-이모골라이트 등의 고상에 주로 영향을 받는 것으로 나타났다. Bo층 토양의 광물조성, 배치 평형실험결과, 그리고 주상실험 결과를 종합해 볼 때, pH 4.0 부근에서 나타나는 뚜렷한 완충능력(β)은 깁사이트 및 프로토-이모골라이트의 용해도 특성에 의해서 좌우되는 것으로 해석된다. pH 6.0 내외의 완충작용은 규산염광물의 용해도 및 염기성양이온의 양이온교환반응에 의해 진행되고 있으나, 낮은 염기성 포화도는 토양산성화가 더 진행될 경우 이러한 완충효과가 오래 지속되지 못할 것임을 지시한다.

우리나라 최남단 난대림지역인 천지연계곡에 분포하고 있는 목본식물의 종조성, 분포현황 및 관속식물상을 조사하였다. 천지연계곡의 교목성 수종은 29종이었으며 , 그 중 침엽수인 해송을 제외한 활엽수종 중 낙엽활엽수가 13종이었다. 교목성 수종은 2,395본이었으며, 그 중 낙엽활엽수가 1,427본으로 상록활엽수보다 많았다. 교목성 수종의 피도는 상록활엽수와 낙엽활엽수가 각각 42.3%와 48.7%로 낙엽활엽수의 상대피도가 다소 높았다. 관목성 수종은 37종이 분포하는 것으로 밝혀졌으며, 개체수에 있어서는 교목성 수종과 달리 상록활엽수종들의 개체수가 많았다. 관목성 수종의 상대피도는 상록활엽수와 낙엽활엽수가 각각 35.4%와 64.4%로 상록활엽수의 비가 현저히 높았다. 천지연에 분포하고 있는 관속식물은 114과 320속 397종 1아종 39변종 9품종으로 총446 분류군이었으며, 그 중 제주도 특산식물은 가시딸기(Rubus hongnoensis Nakai)와 제주상사화(Lycoris chejuensis K. Tae et S. Ko) 2 분류군, 우리나라에서는 제주도에만 분포하는 식물은 괴불이끼(Crepidomanes insigne (v.d. Bosch) Fu) 등 17 분류군, 천연기념물은 담팔수(Elaeocarpus sylvestris (Loureiro) Poiret var. ellipticus (Thunb.) Hara) 1 분류군, 법정보호식물은 솔잎란(Psilotum nudum (L.) Griseb.)과 고란초(Crypsinus hastatus (Thunb.) Copeland) 2 분류군, 귀화식물은 수영(Rumex acetosa L.) 등 38 분류군, 식재식물은 은행나무(Gingo biloba L.)등 75 분류군이었다.

80,000 G/T급 크루즈선이 입항할 수 있는 터미널을 계획하고 있는 제주신항에 대하여 자연 ·환경 조건 및 방파제 등의 구조물 등을 고려하여 선박조종시뮬레이션을 실시하여 입 ·출항 및 접 이안의 안전성을 평가하고자 한다. 안전성 평가는 항로경계의 침범여부, 구조물과의 최근접거리, 선박조종자의 주관적 평가를 통계적으로 해석하는 방법을 이용하였다.

제주 미기록 귀화식물 5종, 즉 왕도깨비가지(Solanum ciliatum Lam.), 서양산딸기 (Rubus fruticosus L.), 국화잎다닥냉이(Lepidium bonariense L.), 수잔루드베키아(Rudbeckia hirta L.), 민까마중(Solanum photeinocarpum Nakamura et Odashima)이 확인되어 국명을 신칭하여 보고한다. 왕도깨비가지, 서양산딸기, 국화잎다닥냉이, 민까마중의 4종은 한국미기록 귀화식물이고 수잔루드베키아는 원예종으로 재배되고 있는 식물이나 제주도에서는 자연상태로 일출되어 귀화된 것이 확인되었으므로 귀화식물로 보고하는 바이다

제주지역에서 파종기이동(4월 25일, 5월 10일, 5월 25일, 6월 10일, 6월 25일)에 따른 양마의 생육특성, 수량성 및 사료 가치를 구명하기 위하여 1999년 4월 25일에서 6월 25일까지 15일 간격으로 시험하였다. 1. 초장은 4월 25일 파종구에서 278.6 cm 였던 것이 파종기가 지연됨에 따라 점차적으로 작아져서 6월 25일 파종에서 초장은 205.7 cm로 짧아졌다. 엽수, 고엽수, 경직경, 분지수 및 개체당 무게는 초장과 비슷한 경향이었다. 2. 생초, 건초, 단백질 및 TDN수량은 4월 25일 파종구에서 각각 98.5MT/㏊, 20.7MT/㏊, 2.9MT/㏊, 11.6MT/㏊로 가장 높았으나 만파할수록 점차적으로 감수되어 6월 25일 파종에서 생초수량은 45.9MT/㏊, 건초수량은 8.2MT/㏊, 단백질수량은 1.3MT/㏊, TDN수량은 5MT/㏊로 감수되었다. 엽과 경의 생초, 건초, 단백질 및 TDN수량도 만파할수록 감소되었다. 3. 파종기가 4월 25일에서 6월 25일로 지연됨에 따라 엽의 단백질 함량은 21.5%에서 24.4%로, 조지방 함량은 5.2%에서 6.1%로, NFE 함량은 39.9%에서 41.2%로, TDN 함량은 64.3%에서 69.7%로 증가한 반면에 조섬유 함량은 엽에서 20.8%에서 17.5%로, 조회분 함량은 7.9%에서 7.0%로 감소되는 경향이었다. 경의 조단백, 조지방, NFE, TDN함량은 만파 할수록 증가되었으나 조회분 및 조섬유 함량은 반대의 경향이었다. 이상의 결과로 보아 제주도 기상, 토양의 환경조건하에서 양마의 파종적기는 4월 25일로 판단되었다.

제주도를 중심으로 하여 동쪽해역과 서쪽해역 해수의 일주 변화 특성을 규명하기 위하여 1997년 6월 20일부터 22일 까지 각 해역 1개 정점에서 24시간 동안 2시간 간격으로 연속 관측을 실시하여 그 결과를 고찰하였다. 동·서 해역의 수온은 표층에서는 거의 비슷하나 저층에서는 동쪽해역이 15.02℃, 서쪽해역이 13.8℃로 나타났으며, 염분분포는 동쪽해역 표층 33.81, 저층 34.33, 서쪽해역 33.34, 34.11로 동쪽해역이 서쪽해역 보다 고온 고염수가 분포하고 있다. 영양염류의 분포에 있어서 질산염 함량은 표층에서는 동,서해역이 거의 비슷하나 저층에서는 동쪽해역이 서쪽해역보다 더 높게 나타났으며, 인산염 함량은 다른 영양염류와 달리 전 수층에서 동쪽해역이 서쪽해역보다 높게 나타났다. 규산염은 질산염과 비슷한 경향을 보였으나, Chlorophyll-a는 서쪽해역이 동쪽해역 보다 2∼4배 높았다. 일주변화는 수온, 염분은 수온약층인 30m층에서 변동폭이 가장 크게 나타났으며, pH는 수심별 변화는 거의 없고 식물플랑크톤의 광합성 작용에 의하여 주간이 야간에 비해 높았다. 영양염류는 수심이 깊어짐에 따라 변동폭이 크게 나타났으며, 질산염과 인산염의 함량은 주간보다 야간이 높았다. 그러나 규산염은 주·야간 변화가 없었다. Cholrohpyll-a는 유광층인 30m층, 50m층에서 변화폭이 크게 나타났다. 영양염류의 구성비인 N/P비는 동쪽해역 13, 서쪽해역 16으로 동쪽해역보다 서쪽해역이 높은 질산염을 함유한 해수가 분포하고 있다. 동·서해역 모두 플랑크톤의 광합성 활동이 활발한 주간보다 야간에 2배 정도 높았다. Si/P비는 N/P비와 달리 주·야간 및 표·저층간 차이도 뚜렷한 경향을 나타내지 않았다. 질소와 인의 상관성은 동쪽해역는 유의성이 높은 정의 상관관계를, AOU와 질소.인의 상관성은 동쪽해역는 유의성이 좋은 정의 관계가 나타났으나, 서쪽해역에서는 유의성이 나타나지 않았다.

Kiyomi tangor(Citus unshiu x sinensis) was stored at 3 and 85% relative humidity, and the changes in firmness, pectin degrading enzymes activity and other physicochemical properties of citrus fruits during storage were investigated. Decay ratio and weight loss during 180 days’ storage were increased gradually to 13.0% and 12.9%, respectively. Firmness of fruits with 2 mm probe was decreased gradually from 808.7 g-force to 406.4 g-force, and moisture of peel and flesh were decreased from 76.5% to from 89.6% to 87.6% during storage, respectively. Exo-polygalacturonase activity of peel after 150 days’ storage were increased gradually to 558.09 units/100g. Pectin methylesterase activity of peel and flesh were increased from 14.7 units/g to 2.3 units/g, and from 9.4 units/ml to 2.7 units/ml at 150days’ storage, respectively. Endo-polygalacturonase activities were not changed notably during storage. Alcohol-insoluble solid(AIS) of peel was not changed notably. During storage of the fruits water soluble pectin(WSP) of peel and flesh were increased from 474.49 mg/100g to 614.29mg/100g, and from 66.91mg/100g to 92.74mg/100g as wet basis, respectively. Hexameta-phosphate soluble pectin(HMP) of peel were decreased from 405.5mg/100g to 270.43mg/100g, hydochloric acid soluble pectin(HSP) of peel was also decreased from 544.02mg/100g to 412.64mg/100g during storage. Total pectin substance(TPS) of peel and flesh were decreased from 1,424.01mg/100g to 1,297.36mg/100g, and from 165.51mg/100g to 171.54mg/100g, respectively. Composition ratio of pectin was in order of WSP > HSP > HMP.

According to the results of the groundwater quality investigation about 230 holes all over the country, the groundwater which was in excess of standard grows larger every year and closed holes increased to 23,457 holes in 1997 from 15,724 holes in 1996. This is the major reasons that water quality contamination, shortage of water quantity, increasing of salinity and so on. There are 7 groundwater salinization sources which are considered as most important on a regional level. And among theses the Cheju Island groundwater salinization sources are (1) halite solution, (2) natural saline groundwater, (3) sea-water intrusion. The method of taking an isotopes is one of research methods of the origin of groundwater salinization and is used in so many studies because it has very high confidence. 18O, 2H, 3H, 14C and so on in an isotopes are frequently used in the method of them. Consequently on this study we analyzed major ions and 3H in groundwater, sea-water and rain of the eastern part of cheju island known as contaminated site from long time ago to examine the origin of groundwater salinization. Relation ratios of the major ions versus chloride ion shows similar tendency to sea-water. This indicates that sea-water entered the groundwater layer. And amount of 3H in holes of the land side is higher than that of the sea side. Relation of chloride ion versus 3H indicates negative character. Therefore we can think that the reason of groundwater salinization of this part is natural saline groundwater and halite solution by relation.

Butyltin compounds (BTs) in seawater, sediments and organisms (Thais clavigera, Liolophura japonica and Cellana nigrolineata), were quantitatively determined to evaluate their distribution inside Songsan Harbor of Cheju Island. In addition, imposex in T. clavigera was used to assess the effect on organisms of BTs. Analysis of the samples collected in seawater, sediments (March, June and August) and organisms (May, July and August) in 1998, confirmed the contamination of BTs in the aquatic environment inside Songsan Harbor. The main BTs species in seawater and sediments was monobutyltin (MBT), tributyltin (TBT), respectively, irrespective of survey time. In organisms, TBT and dibutyltin (DBT) were detected in similar concentrations for T. clavigera and L. japonica, but for C. nigrolineata, DBT concentration was the highest. TBT, the most toxic to aquatic organisms among BTs, was found at concentrations which were sufficient to have a serious effect on the sensitive organisms upon chronic exposure. The relatively high correlations (r>0.83) between BTs indicated that DBT and MBT were mainly degraded from TBT based on antifouling paint and their sources were negligible. The sedimentary organic matters did not have influence on the distribution of BTs in marine environment, and lipid content in T. clavigera did not show a correlation with TBT concentrations. The rate of occurrence of imposex in T. clavigera was 100 %, and the relative penis length index (RPLI) and the relative penis size index (RPSI) which represent the degree of imposex were 79.7%, 58.1%, respectively. Measurement of imposex in T. clavigera was expected to be a very helpful tool for preliminary survey of BTs prior to trace analysis of BTs.

The purpose of this study is to investigate the physicochemical characteristics of salinization of groundwater at the estern area of Cheju island. For this purpose, the major ions of groundwater. spring water are analyzed. The concentration of Cl- and Na-+K- contained in the groundwater at near the coastline are higher than those at inland area away from the coastline. The water quality components of groundwater observed at this area can be classified into 4 types such as Na-Cl, HCO3, Na-Cl-HCO3 and Ca-HCO3. The concentration ratio of SO4- to Cl- is 0.1354(R2=0.972) at this area. This value is very similar with Dittomer's ratio of 0.13. For Na-, K-, and Mg2+ versus Cl-, their ratios also show a significant relationship between sea water and groundwater in this area. From the chloride-bicarbonate ratio, it can be estimated that the intrusion distance of seawater from coastline to inland area is 2.8km at Onpyung-Nansan, Sangdo and Pyungdae areas, and 5.4㎞ at Kosung-Susan area. The mixing ratio between seawater and fresh water by the intrusion of seawater is decreased with the distance toward inland from coastline. This ratio(fresh water : seawater) is 80:20 in spring water adjacent the coastlines, Onpyung area and 99.8:0.2 in the well at No.3 of Susan located at inland away from the coastline. The concentration of Na- observed at field is 25∼45% lower than that theoretically calculated by this mixing ratio. Based on the data of EC, the equipotential line of 500μmhos/㎝ is located at 4∼5㎞ point at Kosung-Susan area and 2.5㎞ point at the other area. The equation of correlation between Cl- concentration and EC values is Cl-=0.1927EC-16.683 for the area lower than 500μmhos/㎝ and Cl-=0.2773EC for the area beyond 500 μmhos/㎝.

The purpose of this paper is to present the environment change of Cheju Island as land development process using GSIS(Geo-Spatial Information System) technique. We implemented the process based on the maps of soil color, underground water pollution points, land use, land development planning and land sight seeing supported by Cheju Province Office. To use the maps for GSIS data, first we transformed the picture data of the office into raster structured picture data using scanner. Second, the coordinate system was added to raster data using 1/50000 geographic map. Third, we estimated land planning process using GSIS technique(overlay and reclass technique). The results showed that land development effected the natural environment(forest, green field, farm land). However, the chemical pollution and land sight seeing was not so much effected by the land development that was found.

To study the residue of organophosphorus pesticides in the ocean environment on the Cheju island, EPN[O-ethyl-O-4-nitrophenyl phenylphosphonothioate] and monocrotophos [Dimethyl-1-methyl-2-methy] carbamoylvinylphosphate] of organophosphorus pesticides are surveyed on coastal environment of Cheju city and Wimi in May and October 1996. The qualified limit detection of EPN and monocrotophos are 0.005ng/mL and 0.006ng/mL., in the water by GC-FPD, respectively. The qualified limit detection of EPN and monocrotophos are 0.010ng/g and 0.012ng/g in the solid such as sediment and sea organism by GC-FPD, respectively. EPN and monocrotophos are not detected in seawater and sediment. Moreover EPN and monocrotophos are neither detected in seaweed cava (Ecklonia cava), Agar (Gelidium amansii), turban sell(Batillus cornutus) and sea urchin(Anthocidaris Crassispina). EPN, monocrotophos used in the farm on the Cheju island are not residued in the coastal environment in the Cheju island.

The adsorption and leaching of organophosphorus pesticides (phenthoate, diazinon, methidathion) were investigated in Namwon soil(black volcanic soil), Aewol soil(very dark brown volcanic soil) and Mureung soil(dark brown nonvolcanic soil) sampled in Cheju Island. The Freundlich constant, K value, was 52.4, 31.3 and 27.7 for phenthoate, diazinon and methidathion in Namwon soil, respectively and decreased in the order of phenthoate, diazinon and methidathion among the pesticides. The K value of phenthoate was 52.4, 15.9 and 5.9 for Namwon, Aewol and Mureung soil, respectively and was the highest for Namwon soil with very high organic matter content and cation exchange capacity(CEC). The Freundlich constant, 1/n, showed a high correlation with organic matter content, i.e., its value was less than unity for organic matter rich soil(Namwon soil) and greater than unity for organic matter poor soil(Mureung soil). Total recoveries of pesticides in soil and leachate with leaching in soil column, were in the range of about 74∼86%. The leaching of pesticides was less for phenthate with high K values, and more for methidathion with low K values among the pesticides. It was slower for Namwon soil with high K values, and faster for Mureung soil with low K values among the soils.

제주산 감귤의 유통방법에 따른 선도 변화를 조사하고 저온유통의 효과를 검토하였다. 유통 중 성분변화는 상온(17)유통이 저온(5)유통에 비해서 중량감소는 6% 증가, vitamin C는 1.91mg 감소, 당산비는 20% 증가함을 보였다. 상온유통에서 중량감소로 인하여 당산비가 높아져서 (16.11에서 21.75) 감귤의 맛과 선도가 감소된다. 현행 감귤수송은 상온유통을 하고 있으나 고품질 감귤에는 부적합한 것으로 나타나며 고품질 소량생산 지향의

Based on the X-ray powder diffraction (XRD) and M ssbauer spectroscopy, the thermal behavior and phase transformations of two clays are investigated for raw and fired conditions, which are collected from Kwangryeongli and Ildo district in Cheju Island. M ssbauer spectra at room temperature and 20for two clays show that paramagnetic Fe3- is the structural iron of the layer silicate and ferrihydrite, and superparamagnetic goethite has about 50% of total iron contents. The XRD peaks of hematite for the fired clays appear from 800℃ in Kwangryeongli clay and from 600℃ in Ildo district clay, respectively. The structural Fe2+ was completely oxidized into Fe3- at 400℃ for Kwangryeongli clay and 500℃~600℃ for Ildo district clay, respectively. The structural Fe2+ was completely oxidized into Fe3- at 400℃. For the temperature ranging from 400℃ to 700℃~800℃, two fired clays exhibit the dehydroxylation of the clay mineral. A disintegration of the clay mineral structure is observed from 700℃~800℃ to 1100℃, followed by the onset and spread of vitrification process. It is also shown that well-crystallized hematite phase is formed at the temperature higher than 1100℃ and the relative absorption area decreases, which might be related to the recrystallization of alluminosilicate matrix.

In order to investigate the adsorption characteristics of organochlorine pesticides chlorothalonil and dicofol with soil colors and regions for soils of an orange orchard, the soils were sampled at 3 regions, respectively, among black volcanic, dark brown volcanic, and brown nonvolcanic soils. Every soil has a higher clay proportion (49-75%) in soil texture and the organic carbon content and cation exchange capacity with soil decreased in the following sequence: Black volcanic > Dark brown volcanic > Brown nonvolcanic soils. Especially those in black volcanic soils were much higher than others. The retention time, quantitative detection limit, and extractian, efficiencies of chlorothalonil and dicofol were 2.82min, 1.5ng/mL, 93.6% and 3.64min, 4.5ng/mL, 94.2%, repectively. The Freundlich constant, Kd, was higher in dicofol compared to chlorothalonil and in the black volcanic soils that have higher organic carbon content and cation exchange capacity. The Freundlich constant, 1/n, was in the range of 0.76-0.89 in the black volcanic soils that have a higher organic matter(16.4-19.8%), whereas it was in the range of 1.02-1.13 in the brown nonvolcanic soils that have a lower organic matter(2.4-3.4%), and so it was considered that 1/n was dependent on the organic matter.