To remove SO2 from flue gas, a thin film nanocomposite (TFN) hollow fiber membrane was decorated with Nafion/TiO2 nanoparticles. Morphological and structural analyses of the TFN membranes were performed using FTIR, SEM, EDX, TEM, and AFM. The gas permeation experiments were performed with pure gases and a mixed gas within a pressure range of 1-3 bar and feed gas flow rate of 0.03-0.15 L/min. The obtained experimental results suggest that the addition of Nf/TiO2 nanoparticles improved the membrane performance by introducing sulfonate and hydroxyl functional groups to the membrane, and thus increased SO2 permeability and selectivity. The SO2 permeability was found to be 411-1671 GPU, while the ideal selectivities achieved for SO2/N2 and SO2/CO2 were 2928 and 72, respectively. Overall, an SO2 removal efficiency of 93% was achieved by using the Nf/TiO2 incorporated TFN membrane.

We investigate the effect of the modification of cellulose acetate propionate as an organic vehicle for silver paste on solar cell efficiency. For the modification of cellulose acetate propionate, poly(ethylene glycol) is introduced to the hydroxyl groups of a cellulose acetate propionate backbone via esterification reaction. The chemical structure and composition of poly(ethylene glycol) functionalized cellulose acetate propionate is characterized by Attenuated total reflectance Fourier transform infrared, 1H nuclear magnetic resonance, differential scanning calorimetry and thermogravimetric analysis. Due to the effect of structural change for poly(ethylene glycol) functionalized cellulose acetate propionate on the viscosity of silver paste, the solar cell efficiency increases from 18.524% to 18.652 %. In addition, when ethylene carbonate, which has a structure similar to poly(ethylene glycol), is introduced to cellulose acetate propionate via ring opening polymerization, we find that the efficiency of the solar cell increases from 18.524% to 18.622%.

굴 패각과 같은 반응성 재료는 사용 목적에 적합한 전처리 조건을 선택할 필요가 있다. 본 연구에서는 인 농도 제어를 목적으로 효율적인 굴 패각 사용을 위한 전처리 조건을 제안하는데 목적을 둔다. 굴 패각의 전처리(소성 온도, 소성 시간, 입자 크기)에 따른 인산염 제거 효율을 조사하였다. 또한 XAFS 분석 및 등온 흡착 실험을 통해 굴 패각의 인산염 제거특성에 대해 조사하였다. 실험 결과 소성 온도는 600°C, 소성 시간은 6 h, 입자 크기는 0.355~0.075 mm에서 우수한 제거 효율을 확인하였다. 등온 흡착 실험 결과 Langmuir 모델이 굴 패각의 흡착에 적합한 것으로 나타났다. XAFS 분석 결과 600°C에서 소성시킨 굴 패각에는 인산칼슘이 생성된 것이 확인되었다. 즉 굴 패각의 칼슘 이온 용출에 의한 인산칼슘 형성이 인산염의 농도 감소에 기여하고 있음을 확인하였다.

Owing to the development in information and communications technologies have improved the technology for high-speed transmission of massive data, which has changed closed-circuit television (CCTV) video transmission technology. In particular, digitization of the CCTV video format and streaming technology has made it possible to minimize transmission loss and integrate video transmission and camera control(pan/tilt). It has also become possible to provide additional services like remote emergency warning broadcasting with just Internet Protocol (IP). However, because of the structural problems of IP, these changes have also brought about the threat of hacking of CCTV monitoring systems. In this study, we propose a methode to optimize network management by examining cases of enhancement of operational efficiency and security by improving the structure of CCTV monitoring network.

PURPOSES: This study evaluates the efficiency of snow removal operation resources using data envelopment analysis (DEA). The results of this study can help decision-making strategies, especially for resource allocation for snow removal works on national highways. METHODS: First, regional road management offices (DMUs) for efficiency evaluation were set up, and a database (for years 2012-2016) for analysis was formed. Second, DEA was carried out by selecting input and output variables based on the constructed database. Lastly, based on the results of the DEA, the efficiency of each regional road management office was evaluated. In addition, the potential for future improvement was determined. RESULTS: The results showed that there was a large variation in efficiency of snow removal operation resources by regional offices. CONCLUSIONS: The results of this study imply that the evaluation of efficiency for snow removal operation resources is important when decisions related to snow-removal strategies are made by road management offices.

본 연구에서는 질소산화물 제거용 환원제로 사용하는 요소 수용액을 암모니아로 전환하는데 있어 SCR 상용촉매의 활용가능성을 확인하기위해 촉매조성에 따른 반응온도, 공간속도의 영향에 대한 연구를 수행하였다. 연구결과 SCR 촉매로 널리 사용되는 V2O5/TiO2 촉매는 TiO2 및 WO3-V2O5/TiO2 촉매에 비해 암모니아 생성이 우수함을 보였다. 활성금속을 담지하지 않은 TiO2 촉매는 V2O5 혹은 WO3-V2O5를 담지 한 촉매에 비해 공간속도에 따른 암모니아 전환에 영향을 받지 않는 것으로 나타났으며, 활성금속을 담지 한 촉매는 공간속도가 증가함에 따라 암모니아 생성 농도가 감소됨을 확인하였다.

The purpoose of this paper is to analyze the relative effciency of dreid laver processing companies in Korea and provide the development direction and improvement plan for the dried laver industry. Data on 76 dried laver processing companies were selected as the subjects for Dea. As a result of Dea, the average efficiency rate is shown that the technical efficiency is 84.90%, the pure technical efficiency is 93.83%, and the scale efficiency is 86.65%. and based on BCC results 38 companies are relatively efficient. comparing pure technical efficiency and scale efficiency, it showed that inefficiencies caused by scale of the company was greater than inefficiencies caused by the scale of technical matter. It implies that expanding the size is essential for achieving high-efficiency of dried laver processing company. In the inefficiency factor analysis, the result reveals that unstable supply of raw materials, quality management, capital flexibility and distribution ability influence the efficiency of laver processing company.

Safety accidents, which are called industrial accidents in construction work, are often caused by unstable physical and personal conditions combined during preparation and execution of work. It is difficult to manage all the construction works, but especially in the field of apartment construction work, complex and many kinds of works are being carried out at the same time. In the current construction, safety regulations such as safety management guidelines are generally well maintained, but the execution of manpower resources that can fulfill them is limited, and it is difficult to reduce the accident rate and loss cost. Therefore, in this study, it is a reality that most of the types of construction work are under contruction by subcontracting contract, so they are limit by methods of manual maintenance and safety education. Currently, the subcontractor is also allowed to perform safety management through the composition of the safety management review body, but it is operated formally. So alternatives to this were studied. As a result, safety accidents occur in the subcontractor's worker due to vertical integration, which is characteristic of the construction industry, together to the contractor, the safety management system is based on a safety construction system in which a worker who has a certain qualification condition such as career experience of the work type, work understanding of the work type, and management experience of the work type among the subcontractor, when we manage based on mutual personality which is the personality of interpersonal relationship that can communicate with each other by work type, process and grouping, it is concluded that effective and practical safety management can be achieved to reduce the accident rate and loss cost.

Diagonally reinforced concrete coupling beams (DRCB) play an important role in coupled shear wall systems since these elements dissipate most of seismic input energy under earthquake loading. For reliable seismic performance evaluation using nonlinear response history analysis, it is important to use an accurate analytical model for DRCBs. In this study, the Pinching4 model is used as a base model to simulate the cyclic behavior of DRCBs. For simulating the cyclic behavior of DRCBs using the Pinching4 model, the analytical parameters for backbone curve, pinching and cyclic deterioration in strength and stiffness should be computed. To determine the proper values of the constituent analytical parameters efficiently and accurately, this study proposes the empirical equations for the analytical parameters using regression analyses. It is shown that the hysteretic behavior of coupling beams can be simulated efficiently and accurately using the proposed numerical model with the proposed empirical equations of model parameters.

This study investigated phosphorus removal from secondary treated effluent using coagulation-membrane separation hybrid treatment to satisfy strict regulation in wastewater treatment. The membrane separation process was used to remove suspended phosphorus particles after coagulation/settlement. Membrane separation with 0.2 μm pore size of micro filtration membrane could reduce phosphorus concentration to 0.02 mg P/L after coagulation with 1 mg Al/L dose of polyaluminum chloride (PACl). Regardless of coagulant, the residual concentration of phosphorus decreased as the dose increased from 1.5 to 3.5 mg Al/L, while the target concentration of 0.05 mg P/L or less was achieved at 2.5 mg Al/L for the aluminum sulfate (Alum) and 3.5 mg Al/L for PACl. Moreover, alum showed better membrane flux as make bigger particles than PACl. Alum showed a 40% of flux decrease at 2.5 mg Al/L dose, while PACl indicated a 50% decrease of membrane flux even with a higher dose of 3.5 mg Al/L. Thus, alum was more effective coagulant than PACl considering phosphorus removal and membrane flux as well as its dose. Consequently, the coagulation-membrane separation hybrid treatment could be mitigate regulation on phosphorus removal as unsettleable phosphorus particles were effectively removed by membrane after coagulation.

Recently, interest in the development of alternative water resources has been increasing rapidly due to environmental pollution and depletion of water resources. In particular, seawater desalination has been attracting the most attention as alternative water resources. As seawater desalination consumes a large amount of energy due to high operating pressure, many researches have been conducted to improve energy efficiency such as energy recovery device (ERD). Consequently, this study aims to compare the energy efficiency of RO process according to ERD of isobaric type which is applied in scientific control pilot plant process of each 100 m3/day scale based on actual RO product water. As a result, it was confirmed that efficiency, mixing rate, and permeate conductivity were different depending on the size of the apparatus even though the same principle of the ERD was applied. It is believed that this is caused by the difference in cross-sectional area of the contacted portion for pressure transfer inside the ERD. Therefore, further study is needed to confirm the optimum conditions what is applicable to the actual process considering the correlation with other factors as well as the factors obtained from the previous experiments.

본 논문에서는 주류공정의 고농도 CO2 제거를 위한 스크러버의 CO2 흡수 성능평가를 진행하였다. Lab-scale 실험을 통해서 설계인자인 액가스비(18 L/m3), 공탑속도(0.14 m/s)를 산정하였다. 설계인자를 기반으로 제작한 5 m3/min 급 CO2 흡수 반응기로 실험한 결과, 풍량이 1, 2, 3, 4, 5 m3/min 증가시 CO2 제거율은 98.47%, 96.46%, 92.95%, 89.71%, 85.49%로 감소하는 경향을 보였다. 또한 스크러버를 사용하기 전 후의 에너지 개선율(5.4%) 평가 및 에너지 절감량(11.5 TOE/year), 온실 가스 감축량(6.5 TC/year)를 산정하였다.

본 논문의 주 목적은 기존선형과 저항을 최소화하는 최적선형에 대한 에너지효율 성능을 평가하는 것이다. 설계 흘수와 설계 선속을 고려하여 대상선박의 선수부 형상을 검토하였다. 실제 운항 상태에서 대상선박의 저항성능을 평가하였다. 상용 전산유체역학(CFD) 코드와 수조 모형시험 자료는 유효마력 평가를 위해 사용되었다. 실제 운항 상태를 고려하여 최소저항을 가지는 최적선형을 제시하였다. 기존선형과 최적선형에 대하여 3가지 선속에서 유효마력을 추정하였다. 최적선형의 저항성능은 기존선형과 비교하여 볼 때 설계속도(12노 트)에서 약 6% 향상된 결과를 보여 주었다. 준추진효율 계수(ETAD, ηD)는 모형시험 자료를 활용하였다. 에너지 효율 성능은 년간 운항일 수, 벙커C유 가격, 1일 연료사용량 그리고 연료소비계수를 바탕으로 작성되었다. 최적선형의 에너지 효율 성능은 기존선형과 비교하였을 때 12노트에서 연간 약 3천만원 절약된 결과를 보여 주었다.

Recently, a low-impact development (LID) technic such as a wetland has been proposed as a Nature-friendly process for reducing pollutants caused by livestock wastewater. Therefore, the Daphnia magna toxicity was analyzed for livestock wastewater samples, to determine if a wetland system would also be effective in reducing this ecotoxicity. In the present study, acute D. magna toxicity was not significantly dependent on the presence and type of reed, nor type of media. However, when treated with construction wetlands, ecotoxicities decreased as well as TN, TP and COD concentrations. Therefore, it is considered that a construction wetland system with bio reeds and bio-media as well as general reeds would be effective to reduce the ecotoxicity of livestock wastewater. To apply a wetland system as the subsequent treatment process to a livestock waste water treatment facility, it is necessary to perform an integrated evaluation such as treatment efficiency and the ecotoxicity test for various characteristics of livestock wastewater.

In water treatment process using microfiltration membranes, manganese is a substance that causes inorganic membrane fouling. As a result of analysis on the operation data taken from I WTP(Water Treatment Plant), it was confirmed that the increase of TMP was very severe during the period of manganese inflow. The membrane fouling fastened the increase of TMP and shortened the service time of filtration or the cleaning cycle. The TMP of the membrane increased to the maximum of 2.13 kgf/cm2, but it was recovered to the initial level (0.17 kgf/cm2) by the 1st acid cleaning step. It was obvious that the main membrane fouling contaminants are due to inorganic substances. As a result of the analysis on the chemical waste, the concentrations of aluminum(146-164 mg/L) and manganese(110-126 mg/L) were very high. It is considered that aluminum was due to the residual unreacted during coagulation step as a pretreatment process. And manganese is thought to be due to the adsorption on the membrane surface as an adsorbate in feed water component during filtration step. For the efficient maintenance of the membrane filtration facilities, optimization of chemical concentration and CIP conditions is very important when finding the abnormal level of influent including foulants such as manganese.

Membrane filtration process is an advanced water treatment technology that has excellently removes turbidity and microorganisms. However, it is known that it has problems such as low economic efficiency and the operating stability. Therefore, this study was to evaluate on the economical feasibility and operational stability comparison of membrane and sand filtration process in Im-sil drinking water treatment plant. For the economic analysis of each process, the electricity cost and chemical consumption were compared. In the case of electric power consumption, electricity cost is 68.67KRW/㎥ for sand filtration and 79.98KRW/㎥ for membrane filtration, respectively. Therefore, membrane filtration process was about 16% higher than sand filtration process of electricity cost. While, the coagulant usage in the membrane filtration process was 43% lower than the sand filtration process. Thus, comparing the operation costs of the two processes, there is no significant difference in the operating cost of the membrane filtration process and the sand filtration process as 85.94KRW/m3 and 79.71KRW/m3 respectively (the sum of electricity and chemical cost). As a result of operating the membrane filtration process for 3 years including the winter season and the high turbidity period, the filtrated water turbidity was stable to less than 0.025 NTU irrespective of changes in the turbidity of raw water. And the CIP(Clean In Place) cycle turned out to be more than 1 year. Based on the results of this study, the membrane filtration process showed high performance of water quality, and it was also determined to have the economics and operation stability.

Phosphorus is one of the limiting nutrients for the growth of phytoplankton and algae and is therefore one of leading causes of eutrophication. Most phosphorous in water is present in the form of phosphates. Different technologies have been applied for phosphate removal from wastewater, such as physical, chemical precipitation by using ferric, calcium or aluminum salts, biological, and adsorption. Adsorption is one of efficient method to remove phosphates in wastewater. To find the optimal media for phosphate removal, physical characteristics of media was analysed, and the phosphate removal efficiency of media (silica sand, slag, zeolite, activated carbon) was also investigated in this study. Silica sand showed highest relative density and wear rate, and phosphate removal efficiency. Silica sand removed about 36% of phosphate. To improve the phosphate removal efficiency of silica sand, Fe coating was conducted. Fe coated silica sand showed 3 times higher removal efficiency than non-coated one.

본 논문에서는 국부좌굴 현상을 고려하여 강판 콘크리트 패널(SCP)의 유한요소 해석을 수행하고 설계지침과 비교하여 전 단 스터드의 효율적인 스터드 배치 간격을 연구하였다. 강판 콘크리트 구조의 설계 및 기술기준은 전단 균열의 전개와 국부 좌굴 현상을 방지하기 위하여 스터드의 최대 간격을 제한하고 있으나 이는 기존 강재-콘크리트 합성 구조의 설계기준을 토대로 산정되었다. 이에 유한요소 해석 프로그램을 이용한 강판 및 SCP의 국부좌굴 부재 해석을 통하여 스터드 최대 배치 간격을 구하고 설계지침에서 제시한 값과 비교하였다. 먼저, 단일 강판에 대하여 국부좌굴 해석을 수행하여 판좌굴 이론과 비교 검증하였고, 연속적인 스터드 배치에 따른 영향을 확인하기 위하여 다수의 강판이 연결된 경우에 대하여 해석을 수행하였다. 또한 강판 콘크리트 구조에서 콘크리트의 영향 및 합성 거동에 따른 영향을 확인하기 위하여 강판 콘크리트 구조를 모델링하고, 국부좌굴이 발생하지 않는 스터드 배치 최대 간격을 구하여 설계지침과 비교하였다.