It is valuable research area regarding to developing manufacturing process of biogas from organic wastes take a side view of alternative for fossil energy and to improve the environmental atmosphere leads to decrease the greenhouse gas be discharged. The regulation which is prepared by environmental department shows that biogas as a transportation fuel is required to purity of above 95%, while it of natural gas is above 88%. However, in this situation it is necessary to prepare the regulation which is distributed by department of transportation as for the fuel be connected to vehicles as well in order to take step forward, and it is suggest to develop the technics of biogas this country's own original one, not be the technics imported from foreign countries, and also to turn to higher practical use of biogas for transportation area, since it shows far much less ratio have compared to other application areas.
Biodiesel is one of the most important renewable energy, since it is one of the most important alternative and eco-friendly energy source compared to fossil energy, especially for diesel engineequipped vehicles. It is now coming up for preparation of biodiesel as the alternative that
applies the hetrogeneous catalyst, super critical state and various methods used in order to reduce the stages of the processes be converted and separation stages started from oil and fat which are originated from animals and wastes, and those new methods bring eco-friendly as well, though some of those are stand on research step so far. It is necessary that nation provides the tax exemption program for the supplier and strengthen the research system for the farming crops relate to fat and oil. It can improve the development of biodiesel which sustains stability against oxidation and keeps good mobility over the low temperatures in the winter season by new additives and develops new processes to show good harmony with diesel engine.
바이오디젤은 식물성유지, 동물성유지 그리고 폐식용유를 전이에스테르화 반응을 시켜 만들어진 것으로 경유를 대체할 수 있는 연료이다. 본 연구에서는 다양한 원료의 식물성유지 (대두유, 폐식용유, 유채유, 면실유, 팜유)로부터 얻어진 바이오디젤의 연료 특성을 알아보았다. 다양한 식물성유지 원료로부터 얻어진 바이오디젤은 지방산메틸에스테르 함량, 동점도, 인화점, 필터막힘점, 글리세린 함량을 분석하였다. 바이오디젤의 품질기준과 시험방법은 한국 표준과 유럽 표준인 EN14214에 따라 시험하였다. 대두유, 폐식용유, 유채유, 면실유 바이오디젤은 불포화지방산이 많이 포함되어 있는 반면에 팜유 바이오디젤은 포화지방산이 많이 함유되어 있다. 저온특성, 동점도, 산화안정도와 같은 바이오디젤의 연료 특성은 지방산메틸에스테르의 구성 성분과 관련이 깊다.
본 연구는 바이오매스에 기인한 에너지와 관련하여, 첨부된 문헌에 의하여 작성되었으며, 바이오에탄올, 바이오디젤 및 바이오가스에 대하여 본 논문을 작성하게 된 배경, 제조공정, 각국의 생산량, 시장현황, 규격 및 정책을 다루었다. 이 논문은 바이오 에너지와 관련하여 전반적인 지식과 장차 바람직한 방향을 모색하는 데에 도움을 줄 것이다. 바이오에너지는 신재생에너지로서 유용한 에너지이며, 다각도로 활용 방안을 모색하여야 한다. 결론에 현재의 상황을 고려하여 몇가지 방향을 제시하였다.
본 논문은 바이오폴리우레탄의 연구동향에 관한 것이다. 바이오폴리우레탄은 원료 중의 식물유 폴리올과 이소시아네이트의 중부가 고분자이다. 피마자유의 주성분은 히드록시기를 갖는 리시놀산의 트리글리세라이드이다. 이외의 히드록시기가 없는 식물유는 이중결합 위치에서 에폭시화 후 고리열림, 히드로포르밀화 후 수소첨가, 가오존분해 후 수소첨가, 티올-엔 반응으로 히드록시기를 부여한다. 폴리올의 반응성 및 마이크로도메인의 모폴로지 조절을 위한 하이퍼브랜치 폴리올, 일차 알코올 폴리올, 다당류 폴리올이 있다. 의료용의 생분해성 폴리락트산 폴리올, 가수분해 방지용 지방산 다이머 폴리올, 이온성 기를 함유한 수 분산 폴리우레탄용 폴리올이 있다. 바이오폴리올을 이용한 바이오폴리우레탄은 경질 및 연질 폼, 코팅제, 접착제, 실런트, 엘라스토머에 쓰인다.
가솔린과 에탄올의 혼합물인 가소홀은, 현재 세계 각국에서 가솔린 차량에 사용되고 있다. 본 연구는 바이오에탄올을 도입하게 된 배경, 제조공정, 생산량, 특성, 규격, 적용방법, 규정, 정책 등에 대하여 세계적인 관점에서 자료들을 조사하여 연구를 수행하였다. 따라서, 바람직한 방향을 모색하는 사람들이 참고로 할 수 있도록 하기 위하여, 여러 각도로 가소홀과 관련된 정보를 수집하고 조사하였다. 조사 결과, 바이오에탄올과 가소홀은 여전히 유용한 신재생에너지의 하나이므로, 각국이 처한 현재의 상황과 입장에 따라서 여러 가지 각도로 사용방법을 마련할 수 있도록 접근하여 관련공업에서 일보전진할 수 있도록 방향을 제시하였다.
본 연구는 메이크업 화장품용 분체에 관한 리뷰논문이다. 분체는 피부 결함 은폐, 자외선 차단, 화장 지속성, 피부보호의 역할을 주요목적으로 한다. 이러한 기능은 분체의 형태제어, 표면처리, 캡슐화로 부여된다. 미래의 분체는 환경변화에 응답하는 스마트 형태로 진화할 것으로 보인다.
UV 경화기술은 라디칼 경화와 양이온 경화로서 크게 2 종류로 분류할 수 있다. 이 기술은 플라스틱과 금속간의 여러 기재에 대한 기능성을 개선하기 위해서 표면처리기술에 주로 초점이 맞추어져 왔다. 반면에, Electron beam 기술은 새로운 기능성 재료들을 창출하기 위해 중합공정뿐만 아니라 가교반응들을 다루었다. 이들 두 기술들은 종래의 열경화성 코팅과 비교할 때, 에너지이용 효율과 환경 친화적이어서, 건조와 경화 공정으로 부터 배출되는 탄산가스와 휘발성 유기물을 대폭 감소시킨다. 이 논문에서는 UV 경화 코팅에서 흔히 사용되는 라디칼 경화기술과, 최근의 있는 양이온 경화와 관련된 기술을 다룬 리뷰 논문이다.
The studied results of the gasohol, which is the mixture of gasoline and ethanol, were investigated for the promotion of applications on commercially by gasoline vehicle referring to octane number, minimum water contents be involved, and separation inhibitors for protecting phase separation etc. especially for the E10 and E20. The results showed that octane number will be revised by higher value as the ethanol is added more, and it's more effect in case of be added as a mixture than individually when inhibition agents is added for the inhibition of separation. and it's reasonable for the water contents of less than 1% by comparing with experimental results and in view of regulations of various countries.
The processes for the preparation of ZnO powder by using EAF(electric arc furnace)dust was studied by wetting method which are divided to two steps, carried out of the elution processes by various concentrations of sulfuric acid is reacted with EAF dust as the former, and the latter were performed by a number of specified processes, which are leaching process depends on various pH, cementation, ozone and heat treatment processes etc. Experimental results showed that the appropriate pH range is pH7.5~8.0 and the resulting zinc content is range of 37~38%, the residual quantities of the heavy metals are less than 3ppm individually by cementation process except Mn, even though the Mn metal could not be removed by cementation process but was removed up to 0.2ppm by the ozone process from 70ppm initially. Finally, 80.2% of ZnO was obtained by the heat treatment at 500℃.
Elution effect was studied by the reactions between Electric arc furnace(EAF)dust and conc. or dil. sulfuric acid for the purpose of recoverying of the useful metals afterwards. The methods of mixing with acids and EAF dust for the elutions were depend on the ratios of acid/EAF dust. Experimental results showed that increased the ratios of sulfuric acids, decreased the elution effects are on the Zn, Fe and Mn, and conc. sulfuric acid showed higher elution effects than dil. sulfuric acids for the all metals. But in case of Pb, dil. sulfuric acid showed higher elution effects than conc. sulfuric acids conversely. Furthermore, the reason of the extreamly low quantities of eluted Pb is caused by the low solubilities by sulfuric acids compared to the other metals, as the results of the insoluble Pb is removed by the process of filtering.
EAF dust which is contained around 30% of zinc, 15% of iron and 3% of lead individually, is chemically treated by ammonium chloride, ammonia water, ammonia gas and carbon dioxide, and also tested and identified the ratios of the recovery of In by applied the variations of particle size, pH and heating temperature as well, in order to getting optimized recovery of the In metal after performing all of those processes. Experimental results showed that the rate of Zn recovery is 97% when the mixture of 1.3 of NH4Cl/EAF is heated to the temperature of 400℃ and leached by water, and 95% recovery of In when ammonia gas and carbon dioxide is added simultaneously and adjust the 9.5 of pH to the same mixture above. For the purpose of remove the impurities in the mixed sample, which is prepared by the two samples, indicated above showing as the ratio of 95% and 97% recovery, in case of applied the cementation process to it, and also by electrolytic process, produced the In plate of 95~97%, and acquired 99-99.5% of In metal ingot finally by applied the heating process at 470~500℃.
We investigated phase separation by adding different concentrations of MTBE, to the mixtures of naphtha, ethanol and water. The phase separation temperatures of the Naphtha-Ethanol-Water solutions have dropped when the concentration of MTBE increases more. When adding IPA and IBA to the solutions of Gasoline-Ethanol and Gasoline base-Ethanol individually, IBA shows lower temperatures of phase separation than IPA, and it shows synergistic effect when mixtures of IPA and IBA is applied.
Gasohol, which is combined solution of gasoline and ethanol, is difficult to apply to the field, because it usually brings phase separation by mingling of water. We investigated phase separation by adding different concentrations of "Ethanol", anhydrous and fermentative, to "Gasolines", gasoline, gasoline base and naphtha, Placing ethanol itself open to the air, the concentrations of water are increased in length of time. The phase separation temperatures of the gasolines-ethanol solutions have dropped in the following order : gasoline, gasoline base and naphtha. When adding water to the solutions of gasolines and anhydrous ethanol, the temperatures of phase separation is higher when the concentration of water increases more. Thus, it is obvious that the water is sensitive in phase separation.