Aqueous Zn-ion batteries (ZIBs) are very attractive owing to their high safety and low cost. Among various cathode materials, organic materials-based electrodes incorporating various redox functional groups have gained significant attention in the field of ZIBs due to their benefits of a tunable structural design, facility, eco-friendly, and possibility of multivalent energy storage. Herein, we demonstrate the nanostructured organic active materials deposited onto the CNT networks (HyPT@ CNT) for flexible ZIBs. This HyPT nanorods were obtained reassemblying the herringbone structured 3,4,9,10-tetracarboxylic dianhydride through a hydrothermal process in the presence of acid. These HyPT@CNT hybrids were electronically conductive and redox active, as well as could be fabricated into a flexible electrode achieving flexibility from mechanical integrity of robust networked structure. The as-fabricated flexible ZIBs delivered the high capacity of 100 Ah g− 1 at a current density of 0.1 A g− 1 and long-term cycling performance exceeding 5000 cycles. Consequently, these electrochemical performances are associated with the redox reactivity of carbonyl groups as verified by spectroscopic and electrochemical characterizations and the hybridization of HyPT nanorods with CNT networks.
Pitfall traps that use ethylene glycol as a preservative solution are commonly used in arthropod research. However, a recent surge in cases involving damage to these traps by roe deer or wild boars owing to the sweet taste of ethylene glycol has prompted the addition of quinone sulfate, a substance with a pungent taste, to deter such wildlife interference. This study aimed to assess the effects of quinone sulfate on arthropods collected from pitfall traps containing ethylene glycol. We strategically positioned 50 traps using ethylene glycol alone and 50 traps containing a small amount of quinone sulfate mixed with ethylene glycol in a grid pattern for systematic sampling at the Gwangneung Forest long-term ecological research (LTER) site. Traps were collected 10 days later. The results revealed a notable effect on ants when quinone sulfate was introduced. Specifically, it decreased the number of ants. In a species-specific analysis of ants, only Nylanderia flavipes showed a significant decline in response to quinone sulfate, whereas other ant species remained unaffected. Additionally, among the arthropod samples obtained in this survey, we identified species or morpho-species of spiders, beetles, and ants and assessed species diversity. Consequently, the utilization of quinone sulfate should be undertaken judiciously, taking into account the specific species composition and environmental characteristics of the monitoring site. Our study also highlighted the significant response of various arthropod groups to variations in leaf litter depth, underscoring the crucial role of the leaf litter layer in providing sustenance and shelter for ground-foraging arthropods. Furthermore, we have compiled comprehensive species lists of both spiders and ants in Gwangneung forest by amalgamating data from this investigation with findings from previous studies.
Advanced countries in the field of nuclear research and technology are currently examining the feasibility of deep geological disposal as the most appropriate method for the permanent management of high-level radioactive waste, with no intention of future retrieval. Deep geological disposal involves the placement of such waste deep underground within a stable geological formation, ensuring its permanent isolation from the human environment. To guarantee the enduring isolation and retardation of radionuclides with half-lives spanning tens of thousands to millions of years from the broader ecosystem, it is imperative to comprehend the long-term evolution of deep disposal systems, especially the role of natural barriers. These natural barriers, typically consisting of bedrock, encase the repository and undergo long-term evolutions due to tectonic movements and climate variations. For the effective disposal of high-level radioactive waste, a thorough assessment of the site’s long-term geological stability is essential. This necessitates a comprehensive understanding of its tectonic evolution and development characteristics, including susceptibility to seismic and magmatic events like earthquakes and intrusions. Furthermore, a detailed analysis of alterations in the hydrogeological and geochemical environment resulting from tectonic movements over extended time frames is required to assess the potential for the migration of radionuclides. In this paper, we have examined international evaluation methodologies employed to elucidate the predictive long-term evolution of natural barriers within disposal systems. We have extracted relevant methods from international case studies and applied a preliminary scenario illustrating the long-term evolution of the geological environment at the KURT (KAERI Underground Research Tunnel) site. Nevertheless, unlike international instances, the scarcity of quantitative data limits the depth of our interpretation. To present a dependable scenario in the future, it is imperative to develop predictive technologies aimed at comprehensively studying the geological evolution processes in the Korean peninsula, particularly within the context of radioactive waste disposal.
This study investigated the Texture Profile Analysis and Sensory characteristics analysis of 6 different Pork Meat-substituted Soybean Curd (PMSC) products with different gluten-fiber (GF) contentst. PMSC types were PMSC-GF 5%, PMSC-GF 10%, PMSC-GF 15%, PMSC-GF 20%, PMSC-GF 25%, and PMSC-GF 30%. The lightness (ΔL value) of cooked PMSC was decreased, whereas the redness (Δa value) and yellowness (Δb value) of cooked PMSC was not changed. Texturometer (TA XT Plus, England) was used for objective test and hardness, springiness, cohesiveness and chewiness of sensory characteristics were measured. PMSC with GF 5% to 15% were characterized high hardness score but PMSC with GF 20% to 30% were not significantly different. PMSC-GF 30% was the highest score in springiness and PMSC-GF 5% was the lowest. PMSC-GF 25% and 30% were high cohesiveness score but was not significantly different (p<0.05). Fourteen sensory descriptors were developed to evaluate the sensory characteristics of PMSC. The sensory characteristics of PMSC were sweetness, saltiness, springiness, hardness, chewiness, meat flavor, odor, loose particle and so on. Six different PMSC showed no significant difference in the attributes of loose particle. But PMSC-GF 5% and PMSC-GF 10% showed significant difference in the attributes of hardness. PMSC-GF 25% and PMSC-GF 30% showed no significant difference in the attributes of hardness. PMSC-GF 30% was the highest springiness score and PMSC-GF 5%, PMSC-GF 10% and PMSC-GF 15% showed no significant difference in the attributes of springiness. Overall consumer acceptance was surveyed. PMSC-GF 5%, PMSC-GF 10% and PMSC-GF 15% showed no significant difference in the attributes of color. PMSC-GF 25% and PMSC-GF 30% was the highest in the attributes of springiness and high moistureness, taste acceptance and overall acceptance. PMSC-GF 5%, PMSC-GF 10% and PMSC-GF 15% showed no significant difference in overall consumer preference but PMSC-GF 25% and PMSCGF 30% showed significant difference. Consequently it is indicated that texture of cooked PMSC-GF 25% and PMSC-GF 30% is very important sensory characteristics.
Athetis dissimilis (Hampson) (Lepidoptera: Noctuidae) [뒷흰날개담색밤나방] was attracted to pheromone traps for Euzophera batangesis (Lepidoprera Pyrimidae) [밤알락명나방], when occurrence of E. batangesis was monitored in sweet persimmon orchard with its pheromone, (Z)-9-tetradecenol (Z9-14OH), (Z9,E12)-9,12-teradecadienol (Z9,E12-14OH) and their mixture. With the components, we monitored the seasonal occurrence of A. dissimilis, tested response of the moth to single or mixed components, and compared efficacy of three different types of traps. A. dissimilis was trapped on May 14 for the first time. First occurrence peak was observed during June 4-24 and second peak during August 20 – September 10. A. dissimilis was attracted to single component of Z9-14OH and Z9,E12-14OH and to their mixture at Jinju, Sancheong, and Sacheon. In trap efficacy tests, delta traps with white color caught most number of the moths significantly at Sacheon. However, at Sancheong, there was no statistical difference among the traps, although funnel trap caught most number of A. dissimilis. Pest status of A. dissimilis is not known eg. whether it is a pest of persimmon or other fruits. However, with Z9-14OH, E9,E12-14OH and their mixture, it is expected to be monitored and controlled.
The seasonal occurrence of two Tortricinae species, Adoxophyes honmai (Yasuda) and Homona magnanima Diakonoff, was monitored at persimmon orchard in Changwon city, Gyeongnam, using sex attractant traps in 2012 and 2013. During the monitoring, a number of Neocalyptis angustilineata (Walsingham) was attracted to sex pheromone traps of H. magnanima. For A. honmai, a blend of Z9-14Ac, Z11-14Ac, E11-14Ac, 10me-12Ac with the ration of 314, 623, 55, and 9 ㎍ respectively, was used. A blend of Z11-14Ac and Z9-12Ac in the ratio of 900+100 ㎍ was used for H. magnanima. A 1:1 blend of Z11-14Ac and Z9-12Ac (500+500 ㎍) was also used for N. angustilineata. The two-years’ monitoring revealed that A. honmai and H. magnanima occurred four times a year, and N. angustilineata did three times. The peak occurrence of each generation for A. honmai was the 2nd or 3rd week of May, the 1st to 2nd week of July, and 5th week of July to 1st week of August, and 2nd to 4th week of September for the 1st, 2nd, 3rd, and 4th generation, respectively. The peak occurrence of each generation for H. magnanima was the 3rd to 4th week of May, the 2nd to 3rd week of July, and 4th week of August to 1st week of September, and 4th week of September to 3rd week of October for the 1st, 2nd, 3rd, and 4th generation, respectively. N. angustilineata showed clear three peaks of the 5thweek of May to 1st week of June, from 4th to 5th week of July, and 1st to 3rd week of September for the 1st, 2nd, and 3rd generation, respectively.
A significantly higher number of N. angustilineata was attracted to sex pheromone traps of H. magnanima for the two years than H. magnanima was. H. magnanima was attracted only to the 9:1 blending ratio. However, N. angustilineata was attracted equally to both of the blending ratios.
본 연구에서는 poly(vinyl chloride) (PVC)가지형 공중합체 전해질과 헤테로폴리산(HPA)을 이용하여 유무기 합성 전해질막을 제조하였다. poly(vinyl chloride)-g-poly(styrene sulfonic acid) (PVC-g-PSSA)는 PVC의 이차 염소의 직접적인 개시를 이용한 atom transfer radical polymerization (ATRP)로 합성하였다. 이때, HPA 나노입자는 수소 결합을 통해 PVC-g-PSSA 가지형 공중합체와 결합하는 것을 FT-IR spectroscopy를 통하여 확인하였다. 전해질막의 수소이온 전도도는 HPA의 질량 분율이 0.3이 될 때까지 상온에서 0.049에서 0.068 S/cm로 증가하였다. 이것은 HPA 나노입자 고유의 전도도와 가지형 공중합체가 가지고 있는 술폰산의 강화된 산도 때문이라고 추정된다. 합습률은 HPA의 질량 분율이 0.45까지 증가할수록 130에서 84%로 감소하였다. 이것은 HPA나노입자와 고분자 메트릭스 사이의 수소 결합의 상호작용 때문에 물을 흡수하는 site의 수가 감소한 결과라고 볼 수 있다. 열중량 분석결과 HPA의 농도가 증가할수록 전해질막의 열적 안정성이 강화된다는 것을 알 수 있었다.
Bicuculline is one of the most commonly used GABAд eceptor antagonists in electrophysiological research. Because of its poor water solubility, bicuculline quaternary ammonium salts such as bicuculline methiodide (BMI) and bicuculline methbromide are preferred. However, a number of studies have shown that BMI has non-GABAд eceptor-mediated effects. The substantia gelatinosa (SG) of the trigeminal subnucleus caudalis (Vc) is implicated in the processing of nociceptive signaling. In this study, we investigated whether BMI has non-GABA receptor-mediated activity in Vc SG neurons using a whole cell patch clamp technique. SG neurons were depolarized by application of BMI (20M) using a high Cℓ⁻ipette solution. GABA ( 30-100μM) also induced membrane depolarization of SG neuron. Although BMI is known to be a GABAд receptor antagonist, GABA-induced membrane depolarization was enhanced by co-application with BMI. However, free base bicuculline (fBIC) and picrotoxin (PTX), a GABAд and GABAс receptor antagonist, blocked the GABA-induced response. Furthermore, BMI-induced membrane depolarization persisted in the presence of PTX or an antagonist cocktail consisting of tetrodotoxin (Nα+ nnel blocker),AP-5 (NMDA receptor antagonist), CNQX (non-NMDA receptor antagonist), and strychnine (glycine receptor antagonist). Thus BMI induces membrane depolarization by directly acting on postsynaptic Vc SG neurons in a manner which is independent of GABAд receptors. These results suggest that other unknown mechanisms may be involved in BMI-induced membrane depolarization.
본 논문에서는 지진하중을 받는 사장교의 진동제어 기법 개발을 위해 제공된 벤치마크 사장교에 복합제어 기법을 적용하였다. 이 벤치마크 문제는 2003년 완공 예정으로 미국 Missouri 주에 건설중인 Cape Girardeau 교를 대상 구조물로 고려하였다. Cape Girardeau 교는 New Madrid 지진구역에 위치하고 Mississippi 강을 횡단하는 주요 교량이라는 점 때문에 설계 단계에서부터 내진 문제를 중요하게 고려하였다. 벤치마크 문제에는 사장교의 상세한 설계도면에 기초해 교량의 복잡한 거동을 나타낼 수 있는 3자원 선형모델과 각 제어기법의 성능을 평가하기 위한 18개의 평가기준이 제시되어 있다. 본 연구에서 적용한 복합제어 기법은 지진하중으로 인해 구조물에 발생되는 하중을 줄이기 위한 수동제어 기법과 상판변위와 같은 구조물의 응답을 추가적으로 제어하기 위한 능동제어 기법이 결합된 제어 방법이다. 수동제어 장지로는 납고무받침을 사용하였고 Bouc-Wen 모델을 사용하여 비선형 거동을 고려 할 수 있도륵 모델링 하였다. 능동제어 장치로는 이상적인 hydraulic actuators 가 사용되었으며 제어 알고리듬은 H_2/LQG 를 적용하였다. 수치해석 결과 제안방법의 성능은 수동제어 방법에 비해 매우 효과적이며, 능동제어 방법에 비해서는 약간 좋은 제어성능을 나타내었다. 복합제어 방법은 수동제어 부분 때문에 능동제어 방법에 비해 보다 신뢰할 수 있는 제어 방법이다. 따라서 제안된 제어방법은 지진하중을 받는 사장교의 제어를 위해 효과적으로 사용될 수 있다.
The correlation between meteorological data collected at the optical wide-field patrol network (OWL-Net) Station No. 1 and the seeing of satellite optical observation data was analyzed. Meteorological data and satellite optical observation data from June 2014 to November 2015 were analyzed. The analyzed meteorological data were the outdoor air temperature, relative humidity, wind speed, and cloud index data, and the analyzed satellite optical observation data were the seeing full-width at half-maximum (FWHM) data. The annual meteorological pattern for Mongolia was analyzed by collecting meteorological data over four seasons, with data collection beginning after the installation and initial set-up of the OWL-Net Station No. 1 in Mongolia. A comparison of the meteorological data and the seeing of the satellite optical observation data showed that the seeing degrades as the wind strength increases and as the cloud cover decreases. This finding is explained by the bias effect, which is caused by the fact that the number of images taken on the less cloudy days was relatively small. The seeing FWHM showed no clear correlation with either temperature or relative humidity.