The untreated effluent dropping into the environment from various textile industries is a major issue. To solve this problem, development of an efficient catalyst for the degradation of macro dye molecules has attracted extensive attention. This work is mainly focused on the synthesis of nickel–manganese sulfide decorated with rGO nanocomposite (Ni–Mn-S/rGO) as an effective visible photocatalyst for degradation of textile toxic macro molecule dye. A simple hydrothermal method was used to synthesize Ni–Mn-S wrapped with rGO. The prepared composites were characterized using various techniques such as X-ray diffraction (XRD), high-resolution scanning electron microscopy (HR-SEM), high-resolution transmission electron microscopy (HR-TEM), Fourier transform infra-red spectrometer (FTIR), and ultra violet–visible (UV–Vis) spectroscopy. The photocatalytic performance of nickel sulfide (NiS), manganese sulfide (MnS), nickel–manganese sulfide (Ni–Mn-S), and Ni–Mn-S/rGO nanocomposite was assessed by analyzing the removal of acid yellow (AY) and rose bengal (RB) dyes under natural sun light. Among these, the Ni–Mn-S/rGO nanocomposite showed the high photocatalytic degradation efficiency of AY and RB dyes (20 ppm concentration) with efficiency at 96.1 and 93.2%, respectively, within 150-min natural sunlight irradiation. The stability of photocatalyst was confirmed by cycle test; it showed stable degradation efficiency even after five cycles. This work confirms that it is an efficient approach for the dye degradation of textile dyes using sulfide-based Ni–Mn-S/rGO nanocomposite.
The normal feeding approach of goats might be due to their precise anatomical and physiological characteristics of entity, which permit them to be highly selective, to eat legume silages and wild green grass. This review has been designed to consider the grazing behavior, fodder selection, and feed composition of goats. Various herbs and corns consumed by goats have numerous nutritive resources. Based on the general herbaceous intake activities and behavior of goats, they prefer wild grass such as grass grown in the steep hills than soft grass. Because the digestion capacity of cellulose feed has higher digestion level compared to other non-ruminants within rumen and it is advantageous to use wild forest or mountain grass which comprises high proportion of cellulose feed for goat. In South Korea, there are abundant feed resources for goats because of occupying large areas of mountains. Thus, goat production and feeding costs could be reduced if plants are used from the wild forest as a feed for goats relative to grassland grazing. Also, it is expected to contribute in improvement of goat farming with harmonious relationship between the grassland and wild forest while satisfying animal welfare and physiological desires of livestock.
Researchers have yet to investigate whether it is beneficial for exporters to engage in greater levels of product adaptation in their export operations, or whether there is some limit to the amount of adaptation exporters should engage in. We posit that customer value creation, a central marketing concept and a mechanism to achieving market and financial goals in business to business markets, is a core outcome of export product adaptation activities. In order to explore the routes by which adaptation may shape export customer value creation, we adopt a multi-faceted conceptualization of firm-level product adaptation, comprising export product adaptation (i) quantity, (ii) intensity and (iii) novelty. Drawing on survey data from 249 Finnish exporters involved in business-to-business activities, we find evidence to support the claim that the impact of export product adaptation on export customer value creation is contingent on various factors, and we identify instances where greater adaptation is beneficial for export customer value creation, and instances where greater export product adaptation is potentially harmful for export customer value creation.
Polycyclic aromatic hydrocarbons (PAHs) are considered to be carriers of the unidentified infrared bands, which are ubiquitously observed in the Universe. PAHs are mainly formed around evolved carbon-rich stars and injected into interstellar space. Planetary nebulae (PNe), a late stage of low- and intermediate stellar mass evolution, are suitable objects to investigate the formation and evolution of PAHs. The shortest PAH feature is located in 3.3 μm, which is important to examine the excitation and size distribution of PAHs. While the number of samples had been limited before, the high sensitivity of AKARI/IRC has drastically increased the number of samples. We obtained the 2-5 μm spectra of Galactic PNe with AKARI/IRC and compiled a near-infrared spectral catalog, containing 73 PNe. We investigate the detection rate and the evolution of the PAH features. The characteristics of the catalog are illustrated and the origin of the evolution of the PAH features is discussed.
Polycyclic aromatic hydrocarbons (PAHs) in Galactic planetary nebulae (PNe) are investigated by means of the unidentified infrared (UIR) bands. Continuous near- to mid-infrared spectra of PNe are obtained with the AKARI/IRC and the Spitzer/IRS. All 19 PNe in the present study show prominent dust emissions and we investigate the variation in the intensity ratios among the UIR bands. The ionization fraction and the size distribution of PAHs in PNe are derived using the UIR band ratios. We find that the ionization fraction of PAHs in PNe is around 0.0-0.6 and that small PAHs are scarce. The present result indicates a systematic trend of the 3.4 μm aliphatic feature to become weak as the PAH ionization fraction increases.
We show how the rotation emission from isolated interstellar Polycyclic Aromatic Hydrocarbons (PAHs) can explain the so-called anomalous microwave emission (AME). AME has been discovered in the last decade as microwave interstellar emission (10 to 70 GHz) that is in excess compared to the classical emission processes: thermal dust, free-free and synchrotron. The PAHs are the interstellar planar nano-carbons responsible for the near infrared emission bands in the 3 to 15 micron range. Theoretical studies show that under the physical conditions of the interstellar medium (radiation and density) the PAHs adopt supra-thermal rotation velocities, and consequently they are responsible for emission in the microwave range. The first results from the PLANCK mission unexpectedly showed that the AME is not only emitted by specific galactic interstellar clouds, but it is present throughout the galactic plane, and is particularly strong in the cold molecular gas. The comparison of theory and observations shows that the measured emission is fully consistent with rotation emission from interstellar PAHs. We draw the main lines of our PLANCK-AKARI collaborative program which intends to progress on this question by direct comparison of the near infrared (AKARI) and microwave (PLANCK) emissions of the galactic plane.
본 연구는 도매상에서 판매하고 있는 염소육의 영양학적 및 미생물학적 품질을 평가하기 위하여 수행하였다. 시료는 1년생, 2년생, 3년생 염소육을 대상으로 수행하였으며, 각 연령별에서 3마리씩 4부분의 다른 부위(어깨, 목, 허리, 다리)를 선정하여 총 36점을 대상으로 본 실험을 수행하였다. 염소육의 품질을 평가하기 위하여 각 시료의 외형, 색, 냄새, 육즙, 일반조성분, pH, 총균수, 대장균군과 효모수를 측정하였다. 각 부위별 염소육의 pH는 평균적으로 5.647- 5.692로 나타내어 각 부위별 염소육의 pH는 유의적 차이가 나타나지 않은 반면 연령별 염소육의 pH는 5.585-5.743로 유의적 차이(p < 0.01)를 나타냈다. 각 연령별 염소육의 육즙함량은 32.24-42.10%로 유의적인 차이(p < 0.01)를 나타내었으며, 마블링은 다른 부위보다 목살부위에서 더 명확하게 확인할 수 있었다. 염소육의 단백질 함량은 20.78-27.71% 의 결과로 유의적 차이(p < 0.01)를 나타내었고, 다리부위는 다른 부위에 비하여 높은 단백질 함량을 나타내었으며 각 부위별 염소육의 지방 함량은 2.657-11.469%로 유의적인 차이(P < 0.01)를 나타냈다. 염소육의 수분함량은 69.20- 73.31%, 1년생 염소육의 회분함량은0.989 ± 0.129%로 다른 연령대의 염소육보다 높은 것으로 나타났으며 이 결과 또한 유의적인 차이(P < 0.01)를 나타내었다. 칼슘의 함량은 유의적인 차이를 나타내지 않은 반면 1년생 염소육의 인의 함량은 0.149 ± 0.0251%로 다른 년생의 염소고기에 비하여 높은 것으로 나타냈다. 연령별 염소육의 총균수 수준은 5.05- 5.15 log cfu/g으로써 유의적 차이를 나타내지 않은 반면 각 부위별 염소육의 대장균군의 오염수준은 2.56-3.05 log cfu/g 으로 유의적인 차이(P < 0.01)를 나타냈다. 연령별 염소육 또한 대장균군 오염수준은 2.79-2.84 log cfu/g 으로써 유의적인 차이(P < 0.05) 를 나타냈으며 1년생 염소육의 대장균 오염수준은 다른 연령의 염소육에 비해 높은 것으로 나타났다. 효모의 오염수준 또한 각 부위별(P < 0.01), 연령별(P < 0.05) 로 유의적인 차이를 나타내었다. 결론적으로 염소육의 영양학적, 미생물학적 품질은 염소의 연령과 판매 부위에직접적인 영향을 받는 것으로 사료된다.