The atmospheric pressure plasma treatments (Ar/O2 and Ar/N2) of activated carbon fibers (ACFs) were carried out to introduce hydrophilic functional groups on carbon surfaces in order to enhance the hydrogen chloride gas (HCl) adsorption. Surface properties of the ACFs were determined by XPS and SEM. N2/77 K adsorption isotherms were investigated by BET and D-R (Dubinin-Radushkevich) plot methods. The HCl removal efficiency was confirmed by HCl detecting tubes (range:1~40 or 40~1000 ppm). As experimental results, it was found that all plasma-treated ACFs showed the decrease in the pore volume, but the HCl removal efficiency showed higher level than that of the untreated ACFs. This result indicated that the plasma treatments led to the conformation of hydrophilic functional groups on the carbon surfaces, resulting in the increase of the interaction between the ACFs and HCl gas.

Antibacterial behaviors of PAN-based activated carbon fibers (ACFs) containing silver metal were investigated. The effects of surface and pore structures of the ACFs were studied by N2/77 K adsorption and D-R plot as a function of silver loading content. The antibacterial activities were investigated by a dilution test against Staphylococcus aureus (S. aureus; gram positive) and Klebsiella pnemoniae (K. pnumoniae; gram negative). As experimental results, the ACFs showed some decreases in specific surface areas, micropore volumes, and total pore volume with an increase of silver content. However, the antibacterial activities of the ACFs were strongly increased against S. aureus as well as K. pnumoniae, which could be attributed to the presence of antibacterial metal in the ACFs system.

In this work, the effect of a direct oxyfluorination on surface and mechanical interfacial properties of PAN-based carbon fibers is investigated. The changes of surface functional groups and chemical composition of the oxyfluorinated carbon fibers are determined by FT-IR and XPS measurements, respectively. ILSS of the composites is also studied in terms of oxyfluorination conditions. As a result, FT-IR exhibits that the carboxyl/ester groups (C=O) at 1632 cm-1 and hydroxyl group (O-H) at 3450 cm-1 are observed in the oxyfluorinated carbon fibers. Especially, the oxyfluorinated carbon fibers have a higher O-H peak intensity than that of the fluorinated ones. XPS result also shows that the surface functional groups, including C-O, C=O, HO-C=O, and C-Fx after oxyfluorination are formed on the carbon fiber surfaces, which are more efficient and reactive to undergo an interfacial reaction to matrix materials. Moreover, the formation of C-Fx physical bonding of the carbon fibers with fluorine increases the surface polarity of the fibers, resulting in increasing ILSS of the composites. This is probably due to the improvement of interfacial adhesion between fibers and matrix resins.

The specific adsorption behaviors of activated carbons (ACs) treated with 30 wt% H3PO4 or NaOH were investigated in the removals of NO or NH3. The acid and base values were determined by Boehm's titration method. And, the surface properties of ACs were studied by FT-IR and XPS analyses. Also, N2/77K adsorption isotherm characteristics, including the specific surface area and micropore volume were studied by BET and t-plot methods, respectively. From the adsorption tests of NO and NH3, it was revealed in the case of acidic treatment on ACs that the NH3 removal was more effective due to the increase of acidic functional groups in carbon surfaces. Also, the NO removal was increased, in the case of basic treatment, due to the improvement of basic functional groups, in spite of significant decreases of BET's specific surface area and total pore volume. It was found that the adsorption capacity of ACs was not only determined by the textural characteristics but also correlated with the surface functional groups in the acid-base intermolecular interactions.

In this work, the effect of anodic oxidation treatment on Cr(VI) ion adsorption behaviors of activated carbon fibers (ACFs) was investigated. The aqueous solutions of 10 wt% H3PO4 and NH4OH were used for acidic and basic electrolytes, respectively. Surface characteristics and textural properties of ACFs were determined by XPS and N2 adsorption at 77 K. The heavy metal adsorption of ACFs was conducted by ICP. As a result, the adsorption amount of the anodized ACFs was improved in order of B-ACFs 〉 A-ACFs 〉 pristine-ACFs. In case of the anodized treated ACFs, the specific surface area was decreased due to the pore blocking or pore destroying by acidic electrolyte. However, the anodic oxidation led to an increase of the Cr(VI) adsorption, which can be attributed to an increase of oxygen-containing functional groups, such as, carboxylic, lactonic, and phenolic groups. It was clearly found that the Cr(VI) adsorption was largely influenced by the surface functional groups, in spite of the reduced specific surface area of the ACFs.

In this study, the effects of carbon black (CB) content and anodic oxidation treatment with AgNO3 on positive temperature coefficient (PTC) behavior of CB/HDPE nanocomposites were investigated. Also, the addition of elastomer as a toughing agent was studied. The 20~50 wt% of CB, 0~5 wtt% of elastomer, and 1 wt% of AgNO3-filled HDPE nanocomposites were prepared using the internal mixer in 60 rpm at 160˚C and the compression-molded at 180˚C for 10 min. As a result, the room temperature resistivity and PTC intensity of the composites were dependent, to a large extent, on the content of CB, addition of elastomer, and surface chemical properties that were controlled in the relative arrangements of the carbon black aggregates in a polymeric matrix. Moreover, the composites with relatively low room temperature resistivity and suitable PTC intensity could be achieved by treatment of AgNO3. Consequently, it was noted that PTC effect was due to the deagglomeration or the breakage of the conductive networks caused by thermal expansion or crystalline melting of the polymeric matrix.

In this work, the activated carbons (ACs) with high micropores were synthesized from the polystyrene (PS) with KOH as activating agent. And the influence of activation temperature on porosity of the ACs studied was investigated. The porous structures of ACs were characterized by nitrogen adsorption at 77K using BET and D-R equations, and MP and BJH methods. The weight loss behaviors of the samples impregnated with KOH were also monitored using thermogravimetric analyzer (TGA). As a result, it was found that the samples could be successfully converted into ACs with well-developed micropores. From the results of pore size analysis, it was confirmed that elevated activation temperature does lead to the formation and deepening of microstructures without significant change in mesostructures. A thermogravimetric study showed that KOH could suppress the thermal decomposition of the sample, resulting in the increase of carbon yields.

In this work, activated carbon fibers (ACFs) were plated with copper metal using electroless plating method and the effects of surface properties and pore structures on chromium adsorption properties were investigated. Surface properties of ACFs have been characterized using pH and acid/base values. BET data with N2 adsorption were used to obtain the structural parameters of ACFs. The electroless copper plating did significantly lead to a decrease in the surface acidity or to an increase in the surface basicity of ACFs. However, all of the samples possessed a well-developed micropore. The adsorption capacity of Cr(III) for the electroless Cu-plated ACFs was higher than that of the as-received, whereas the adsorption capacity of Cr(VI) for the former was lower than that of the latter. The adsorption rate constants (K1, K2, and K3) were also evaluated from chromium adsorption isotherms. It was found that K1 constant for Cr(III) adsorption depended largely on surface basicity. The increase of Cr(III) adsorption and the decrease of Cr(VI) adsorption were attributed to the formation of metal oxides on ACFs, resulting in increasing the surface basicity.

The effect of electrochemical surface treatments in KOH chemical solution on microstructures of carbon blacks was investigated in terms of surface functional values and XRD measurements. And their mechanical interfacial properties of the carbon blacks/rubber composites were studied by the composite tearing energy (GIIIC). It was found that the development of basic-surface functional groups lead to the significant physical changes of carbon blacks, such as, decrease of the interlayer spacing (d002), increase of the crystalline size along c-axis (Lc), and increase of degree of crystalline (χc). This treatment is possibly suitable for carbon blacks to be incorporated in a hydrocarbon rubber matrix, resulting in improving the hardness and tearing energy of the resulting composites.

In this work, the carbon fibers-reinforced carbon matrix composites made with different carbon char yields of phenolic resin matrix have been characterized by mechanical flexural tests for acoustic emission properties. The composites had been fabricated in the form of two-dimensional polyacrylonitrile based carbon fibers during the carbonization process. It was found that the composites made with the carbon char yield-rich of resin matrix result in better mechanical interfacial properties, i.e., the interlaminar shear strength (ILSS) of the composites. The data obtained from the acoustic emission monitored appeared to show that the composites made with carbon char yield-rich were also more ductile. From the acoustic emission results, the primary composite failure was largely depended on the debonding at interfaces between fibers and matrix. The interlaminar shear strengths of the composites were correlated with the acoustic emission results.

The effect of surface free energy on the positive temperature coefficient (PTC) of carbon black/thermoplastic resin composites was investigated. The thermoplastic resins such as EVA, LDPE, LLDPE and HDPE were used with the addition of 30 wt.% of the carbon black. The surface free energy of the composites was studied in the context of two-liquid contact angle measurements, i.e., deionized water and diiodomethane. It was observed that the resistivity on PTC composites Was greatly increased near the crystalline melting temperature, due to the thermal expansion of polymeric matrix. From the experimental results, it was proposed that the decrease of surface free energy induced by interactions between carbon black surfaces and polymer chains is an important factor to the fabrication of a PTC composite made of carbon black and polymeric matrix.

Climate data were obtained over an eight-year period (July 2013 to June 2021) using an automatic weather observation system (AWS) installed at the foot of Mt. Geumo in Chilgok, Gyeongbuk. Using climate data, the statistical and meteorological characteristics of the local circulation between the Nakdong River and Mt. Geumo were analyzed. This study is based on automatic weather observation system data for Dongyeong, along with comparative climate data from the Korea Meteorological Administration (Chilgok) and the Gumi meteorological observatory. Over the eight- years, mountain and valley winds have occurred 48 times a year on average, with the highest occurring in May and the weakest winds in June and December. When mountain winds occurred, the temperature in the nearby lowland region more strongly decreased than when valley winds blew. However, the potential to use mountain winds to improve urban thermal environments is limited because mountain winds occur infrequently in summer when a drop in nighttime temperature is required.

Eight years (2014–2021) of climate data were collected from an automatic weather observation system installed at the foot of Mt. Geumo in Chilgok, Gyeongbuk. Using these data, we investigated local bio-climatological indices (warmth index, WI; coldness index, CI; and effective accumulated temperature, EAT) of the mountain region adjacent to the Keimyung Dongyeong forest. The study area’s WI and CI were 109.3℃ and –11.3℃ per month, respectively, averaged across 8 years. These values are indicative of an evergreen broad-leaved forest in the warm temperate climate zone, suitable for cultivating sweet persimmons and figs. Additionally, EAT in Dongyeong was 2,113.7℃, averaged across 8 years, suitable for growing crops such as corn, soybean, and potato.

스마트 학습법을 적용한 학생과 적용하지 않은 학생들을 대상으로 자기주도적 학습능력 및 학업적 자기 효능감이 효과적으로 적용되었는지 알아보고 향 후 보건 계열 방사선과 전공과목에 스마트 학습법을 적용 한 효과에 대해 논의 및 향 후 발전적인 방향에 대해 제언하고자 한다. 2016년 3월부터 6월까지 한 학기동 안 스마트 학습법으로 강의를 받은 학생과 스마트 학습법을 적용하지 않은 학생 두 분류로 나누었고 자료 수집방법은 자가 보고형 질문지 방식으로 진행하였다. 스마트 학습법으로 강의를 받은 교육군이 비교육군 에 비해 자기주도 학습능력를 검정한 결과, 5점 만점에 교육군이 3.46점, 비교육군이 2.63점으로 통계적으 로 유의한 차이가 있는 것으로 나타났고(t=9.721, p=.000), 성취목표지향성을 검정한 결과, 교육군이 3.12점, 비교육군이 2.92점으로 통계적으로 유의한 차이가 있는 것으로 나타났다(t=4.544, p=.000). 위의 결과로 스 마트학습법이 자기주도학습, 학업적 자기효능감 및 학습 만족도에 대해 긍정적인 영향을 보여줬으며, 향 후 보건 계열 학과에서도 교수자는 학습자와 쌍방향 커뮤니케이션을 통해 강의의 질적 향상을 위해 학습 변화가 필요하다.