The most general photocatalyst, TiO2 and WO3, are acknowledged to be ineffective in range of visible light. Therefore, many efforts have been directed at improving their activity such as: band-gap narrowing with non-metal element doping and making composites with high specific surface area to effectively separate electrons and holes. In this paper, the method was introduced to prepare a photo-active catalyst to visible irradiation by making a mixture with TiO2 and WO3. In the TiO2-WO3 composite, WO3 absorbs visible light creating excited electrons and holes while some of the excited electrons move to TiO2 and the holes remain in WO3. This charge separation reduces electron-hole recombination resulting in an enhancement of photocatalytic activity. Added Ag plays the role of electron acceptor, retarding the recombination rate of excited electrons and holes. In making a mixture of TiO2-WO3 composite, the mixing route affects the photocatalytic activity. The planetary ball-mill method is more effective than magnetic stirring route, owing to a more effective dispersion of aggregated powders. The volume ratio of TiO2(4) and WO3(6) shows the most effective photocatalytic activity in the range of visible light in the view point of effective separation of electrons and holes.

PURPOSES: This research investigates traffic noise characteristics as change the transverse rumble strips shape from rectangular to cylinder at toll plaza of highway. METHODS : The traffic noise was investigated at two different places at toll plaza of highway. One is modified grooving, another is employed cylinder shape of TRS instead of rectangular shape of TRS. A measurement of traffic noise was conducted at same location and time period. The traffic volume information was gotten from office of highway office and vehicle speed was measured by speed measuring device. The traffic noise measurement was conducted from 13:00 to 23:00 and by pass-by method. Also, the traffic noise was measured behind noise barrier. Various distance from noise barrier(7.5m, 30m, 50m) and different heights(1.2m, 3m, and 5m) were parameter for measurement of traffic noise in this study. RESULTS : The class 1 vehicle was contributed from traffic volume which was increased 1,500. However, the distribution of traffic speed didn’t change compare to previous investigated period. From this study, It was found that the external traffic noise was changed as function of geometric shape of TRS. The external noise from modified grooving was less than 1.2dB(A) of the current TRS. A difference of traffic noise was 20dB(A) before and after barrier. It came from a noise barrier effect as reduction of traffic noise. According to investigate a traffic noise distribution near barrier, there is similar noise characteristic as function of height at 7.5m distance from noise barrier. Also, There is no different traffic noise between 30m and 50m from source of the noise of sound barrier. CONCLUSIONS: Based on this traffic noise investigation result, there is a clear characteristic difference as changed TRS shape. The traffic noise was reduced by changed TRS shape. Specially, traffic noise was decreased although the traffic volume was increase for same investigation time and period. It is implied that cylinder type of TRS significantly reduces the traffic noise. The specification of various TRS will be studied in the future.

Cu2ZnSn(Sx,Se1-x)4 (CZTSSe) thin films were prepared by sulfurization of evaporated precursor thin films. Precursor was prepared using evaporation method at room temperature. The sulfurization was carried out in a graphite box with S powder at different temperatures. The temperatures were varied in a four step process from 520˚C to 580˚C. The effects of the sulfurization temperature on the micro-structural, morphological, and compositional properties of the CZTSSe thin films were investigated using X-ray diffraction (XRD), Raman spectra, field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The XRD and Raman results showed that the sulfurized thin films had a single kesterite crystal CZTSSe. From the FE-SEM and TEM results, the Mo(Sx,Se1-x)2 (MoSSe) interfacial layers of the sulfurized CZTS thin films were observed and their thickness was seen to increase with increasing sulfurization temperature. The microstructures of the CZTSSe thin films were strongly related to the sulfurization temperatures. The voids in the CZTSSe thin films increased with the increasing sulfurization temperature.

본 연구에서는 ALBC3 합금에 Ni기 자용성 합금으로 내마모성 및 내캐비테이션 특성을 향상시키기 위하여 용사코팅 후 열처리를 실시하여 캐비테이션 특성을 평가하였다. 본 연구 결과, 자용성 합금 코팅층이 높은 경도를 나타내어 내마모성이 우수할 것으로 판단되나, 다공질의 조직으로 인해 열악한 내캐비테이션 특성을 나타냈다. 따라서 열처리 조건의 최적화가 중요하며, 본 조건에서는 열처리온도를 높여 자용성 합금 내 B와 Si의 유동성을 증가시킴으로써 기공이나 결함을 제거하여 특성개선 효과를 기대할 수 있을 것으로 판단된다.

PURPOSES : This study is to develop a method to evaluate lubrication of asphalt binder using WMA additives and compare their lubrication effects on two types of WMA additives and three types of asphalt film thicknesses. METHODS : This study is based on laboratory experiments and rheological analysis of the experimental results. Testing materials are aggregate diskes, asphalt, and WMA additives. The main testing method is stress sweep test by using dynamic shear rheometer (DSR). RESULTS : Sasobit gives more lubrication effects on film thicknesses 0.2mm and under but LEADCAP does on film thicknesses over 0.3mm. CONCLUSIONS : LVE-Limit is a better parameter to discern the lubrication effects on the thin film asphalt thickness. Both Sasobit and LEADCAP WMA additives provide effective lubrication at the compaction temperature.

골재의 다짐모형(Packing Density Model)은 다양한 최적다짐밀도를 통하여 혼합물 내에서 골재의 역 할을 최대화하거나 다른 고가의 재료를 절감하기 위하여 다양한 건설분야에서 연구되고 있다. 다짐밀도모형은 1929년에 Furnas에 의하여 제시된 단순한 모형으로부터, Aim and Goff 모형, Toufar 모형, Linear Packing Density 모형 등 다양한 연구자들에 의하여 그 형태가 제시되고 발전되어 왔으나, 기본 적으로 굵은골재에 잔골재가 포함되는 경우와 잔골재에 굵은골재가 포함되는 경우로 단순화될 수 있으며, 모형의 정밀도를 향상시키거나 물리적 현상을 반영하기 위한 함수 또는 계수의 조합으로 보완되는 것이 일반적이다. 본 연구에서는 다양한 다짐밀도모형을 고찰하여 잔골재와 굵은골재의 부피비에 따른 다짐밀도예측결과 를 평가하였으며, 향후 이산요소법(Discrete Element Method, DEM)을 이용하여 개발될 골재배합설계법에 필요한 변수를 고려한 모형의 형태를 제시하였다. 다짐밀도모형의 재해석을 통하여 확인된 다짐밀도 모형의 주요변수는 개별 골재의 단위중량, 지름 및 개별골재더미의 다짐밀도이며, 다짐의 최적화를 저해하는 Wall Effect와 Loosening Effect를 고려하기 위하여 통계적함수를 적용하거나 다짐에너지를 고려 하기 위한 변수도 조건에 따라 적용될 수 있음을 확인하였다. 또한 대부분의 이론적 다짐밀도모형에서 개별 골재더미의 다짐밀도는 골재 혼합물의 다짐밀도에 큰 영향을 미치는 변수이지만, 그 영향이 작지 않을 것으로 예측되는 개별골재더미 사이의 물리적 상호작용은 대부분의 기존다짐밀도모형에 고려되어 있지 못한 것으로 확인되었다. 이상의 기존 수학적 다짐모형의 검토를 통하여 DEM을 활용하여 개발될 다짐밀도예측모형의 형태를 제안하였다.

상온 아스팔트는 70년대 초반 석유위기 인하여 아스팔트 가격이 상승하여 대안으로 발전을 맞이 하였으나 이후 가열 아스팔트에 밀려 크게 활성화 되지 못하였다. 활성화 되지 못했던 중요한 이유 중에 하나는 상온 아스팔트는 양생시간이 필요하고 양생 후에도 가열 아스팔트에 비하여 공학적 성능이 우수하지 않았기 때문이다. 이산화탄소 배출을 억제하고 새로운 상온 화학 기술이 진보하고 아스팔트 재활용에 대한 관심이 고조 되면서 새로운 상온 아스팔트 공법이 개발되고 있다. 본 연구는 중속 경화(Medium setting: MS) 상온 아스팔트를 사용하여 혼합물을 제조하여 관련 시험을 수행하였다. 시험 결과 기존 상온 아스팔트에 비하여 양생 속도가 신속하고 성능이 향상되어 새로운 포장공법으로 기대된다.

고속도로 영업소 진입로에는 운전자에게 주의환기를 주기 위해 횡방향 럼블스트립이 설치되어 있다. 이러한 럼블스트립은 대부분 직사각형 형상을 갖고 있다. 럼블스트립의 형상에 따라 소음의 특성이 다르게 나타나는 것으로 알려져 있다. 본 연구에서는 직사각형 형태의 럼블스트립을 원형의 럼블스트립으로 개선함에 따른 소음특성 변화에 대한 연구를 수행하였다. 서울외곽순환고속도로 영업소 광장에 개선된 원형 형상의 럼블스트립을 적용하고, 사후 모니터링을 실시하여 개선 전·후의 소음특성에 대해 분석하였다. 본 연구 결과, 럼블스트립의 개선 전·후 소음특성은 개선후의 교통량이 증가했음에도 소음은 감소하는 것을 알 수 있었다. 차량주행속도는 개선 전·후 모두 약 58km/h로 거의 유사하게 나타났다. 원형의 럼블 스트립이 직사각형 형상의 럼블스트립보다 시간대별로 약 1~3dB(A)의 소음저감 효과가 나타났다. 이런 현장적용의 결과를 볼 때, 횡방향 럼블스트립의 다양한 규격(럼블스트립의 간격, 깊이, 형상 등)에 대한 추가적인 연구를 진행하면 더 우수한 성능의 럼블스트립 규격을 개발할 수 있을 것으로 사료된다.

SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is charac- terized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. The CNTs was good additives to improve the mechanical properties of metal. In this study, 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. The SKD11+ CNT hybrid nanocomposites were investigated by FE-SEM, particle size distribution, hardness and wear resistance. The CNT was well dispersed in the SKD11 matrix and the mechanical properties of the composite were improved by CNTs addition. It shows good fea- sibility as cold work die tool.

Nickel-based superalloy IN 713C powders have been consolidated by hot isostatic pressing (HIPing). The microstructure and mechanical properties of the superalloys were investigated at the HIPing temperature ranging from 1030o C to 1230o C. When the IN 713C powder was heated above γ' solvus temperature (about 1180o C), the microstruc- ture was composed of the austenitic FCC matrix phase γ plus a variety of secondary phases, such as γ' precipitates in γ matrix and MC carbides at grain boundaries. The yield and tensile strengths of HIPed specimens at room temperature were decreased while the elongation and reduction of area were increased as the processing temperature increased. At 700o C, the strength was similar regardless of HIPing temperature; however, the ductility was drastically increased with increasing the temperature. It is considered that these properties compared to those of cast products are originated from the homogeneity of microstructure obtained from a PM process.

PURPOSES : The purpose of this study is to evaluate of field application and laboratory performance of warm-mix asphalt (WMA) according to the dosage rate of organic-based WMA additive. METHODS: Three asphalt mixtures, i.e., hot mix asphalt (HMA), WMA with the dosage rate of 1.5%, WMA with the dosage rate of 1.0%, were sampled from the asphalt plant when the field trial project were constructed. With these mixtures, the laboratory testings were performed to evaluate the linear viscoelastic characteristics and the resistance to moisture, rutting and fatigue damage. RESULTS : From the laboratory test results, it was found that the WMA with the reduced dosage rate of additive would be comparable to HMA and WMA with the original dosage rate in terms of the dynamic modulus, tensile strength ratio, rutting resistance. However, the fatigue reisistance of WMA with the reduced dosage rate was slightly worse but it should be noted that the fatigue performance is necessarily predicted by combining the material properties and pavement structure. CONCLUSIONS: Through the field construction and laboratory testings, the dosage rate of organic-based WMA additive could be reduced from 1.5% to 1.0% without the significant decrease of compactability and laboratory performance. The long-term performance of the constructed pavement will be periodically monitored to support the findings from this study.

This study for add functional nutrition ginseng to make consommé soup of beef. consommé soup of beef added to the supplementary materials, the moisture content of ginseng (75.34%), crude protein 2.78%, crude fat 0.53%, ash 0.018%, respectively. Consommé soup beef cone with the addition of solid content and viscosity measurements, the results showed BCG0 3.34% viscosity ginseng 0% 2.26 acid group most were lower. The sweetness of the control group, 0% added ginseng lowest measured pH is 6.53, and 4.13 BCG12 the lowest amount was measured. Consommé soup beef cone with the addition of lightness was lower as the control group BCG0 34.21, redness BCG0 14.44 as the highest value, respectively. Yellowness decreased significantly (p<0.001) between the amount of ginseng have more and more each sample. Turbidity was decreased with increasing the amount of ginseng. Ginseng added 6% BCG6 symbols from color BCG9 5.10 the highest rating, and flavor 5.40 as the highest rating was 9% added BCG9 5.70 overall acceptability overall acceptance was rated the highest. Strength ginseng 0% added in the control group showed the highest intensity of 6.4, dark brown. Savory flavor 0% added ginseng BCG0 showed the lowest intensity to 4.4. Consommé soup when you try to synthesize the results of all the experiments, the addition of ginseng considered the best addition to the 9%, and the addition of more than 12% of ginseng reducing rather symbols that suggest.

This study was performed to investigate the distribution of indoor air pollutants in medical facility in Gyeonggi-do area from February to November, 2012, and to conduct the health risk assessment from obtained data. PM10, CO₂, formaldehyde, CO, and total bacteria count(TBC) did not exceed the maintained standards, but mean concentration of TVOC was 402.3 ㎍/㎥ and thirteen of them exceeded the recommended standard. In the concentration distribution of pollutants for the monthly samples, CO₂, formaldehyde, TVOC, TBC were the highest level in August. From the factor analysis of indoor air pollution provided three factors; the first factor was seasonal factor (indoor temperature and humidity, TBC and formaldehyde), the second factor was ventilation factor (CO₂, PM10 and CO), and the third factor was building(or interior) factor (TVOCs). In the health risk assessment results, the excess carcinogenesis of formaldehyde for resonable maximum exposure worker was 1.21×10-⁴ which means exceeding the cancer criteria(1.0×10-⁴). We confirmed the probability of health effect caused by TVOC. The lifetime excess cancer risk of carcinogens(benzene, formaldehyde) and hazard quotient of non-carcinogens(toluene, ethylbenzene, xylene, styrene), and risk of regulation substances(PM10, CO₂) were safety level for inpatients and out patients.

본 연구에서는 2007년의 금강 중∙하류부의 백마강의 상류에서 하류에 이르는 5개 지점에서 이∙화학적 수질특성을 분석하였고, 그 곳에 서식하는 어류군집의 어종분포 및 길드분석을 통해 군집구조 및 생태건강도 특성을 평가하였다. 전형적인 하류하천인 백마강의 BOD, COD농도는 각각 평균 2.8 mg L-1, 4.0 mg L-1였고, TN, TP의 농도는 각각 5.0 mg L-1, 158 μg L-1로서 이미 부영양 상태로 판정되었으며, 특히 하류 지점에서는 유기물오염 및 부영양화 현상이 뚜렷했다. 5개 지점에서 출현한 어종은 총 19종으로 나타났고, 내성종인 끄리는 가장 높은 상대 풍부도(48%)를 보였다. 백마강에서 민감종의 비율(2.3%)은 낮은 반면 내성종 비율(71.8%)은 높게 나타나 중∙하류 하천에서의 전형적인 길드 변화 현상이 확연히 나타났다. 하천 생태건강도 평가 (IBI)에 따르면, 백마강에서 생물보전지수는 14.8로서 악화상태인 것으로 나타났고, 수질에서 보여준 바와 같이 하류부에서는 극명하게 악화된 것으로 나타났다. 특히 하류구간 (S3~S5)의 낮은 건강도 지수값은 하수종말처리장으로부터 나온 배출수의 화학적 영향이 큰 것으로 사료되었다. 이는 생태건강도 모델값이 수질 특성을 잘 반영하는 객관성 있는 평가기법으로 활용 될 수 있음을 제시하였다. 따라서 백마강의 생태계 보존을 위해서는 향후 이 구간에 대한 하천복원 및 지속적인 생태모니터링이 중요하다고 판단된다.

In this study, an HP-mod. type(KHR-45A), which is used as a heater tube material in the pyrolysis process, was evaluated for its carburizing properties. It was confirmed from the microstructural observation of the tubes that the volume fraction of carbide increased and that the coarsening of Cr-carbide generated as a degree of carburization increased. The depth of the hardened layer, which is similar to the thickness of the carburized region of each specimen, due to carburization is confirmed by measurement of the micro-Vickers hardness of the cross section tube, which thickness is similar to that of the carburized region of each specimen. Two types of chromium carbides were identified from the EBSD (electron back-scattered diffraction) image and the EDS (energy-dispersive spectroscopy) analysis: Cr-rich M23C6 in the outer region and Cr-rich M7C3 in the inner region of tubes. The EDS analysis revealed a correlation between the ferromagnetic behavior of the tubes and the chromium depletion in the matrix. The chromium depletion in the austenite matrix is the main cause of the magnetization of the carburized tube. The method used currently for the measurement of the carburization of the tubes is confirmed; carburizing evaluation is useful for magnetic flux density measurement. The volume fraction of the carbide increased as the measuring point moved into the carburized side; this was determined from the calculation of the volume fraction in the cross-section image of the tubes. These results are similar to the trends of carburization measurement when those trends were evaluated by measurement of the magnetic flux density.

In this paper, the vibrational characteristic of electronic solenoid structure for vehicle is analyzed by using ADAMS as commercial multi-body dynamics analysis program. This study model is made with CATIA V5R18 as 3D computer-aided design program and analyzed with rigid body mode in ADAMS. To fulfill the vibration analysis, the result value of solenoid structure is suggested.