본 연구의 목적은 고준위폐기물 처분기술 개발과 관련하여 현장실증 연구를 위해 사용될 공학규모 이상의 균질 완충재 블록 을 제작하기 위한 새로운 방법론을 제시하는 것이다. 이와 관련하여 플롯팅 다이(floating die) 방식의 프레스 재하 및 냉간 등방압프레스(CIP; Cold Isostatic Press) 기법을 국내 최초로 완충재 제작에 적용하였다. 또한 소요 밀도기준을 충족하는 완충재 블록을 생산하기 위한 최적의 제작조건(프레스 및 CIP의 소요 압력)과 현장 적용성을 분석하였다. 상기 기법의 적용을 통해 완충재 블록 내 밀도분포 편차가 현저히 감소하였으며, 이와 동시에 평균 건조밀도가 소폭 상승하고 약 5%의 크기가 감소하였다. 또한 CIP 적용을 통해 응력이완(stress release) 현상이 감소하고, 이로 인해 시간 경과에 따른 표면균열 발생이 현저히 저감됨을 시험제작을 통해 확인하였다. 본 연구에서 제시된 방법론은 공학규모 이상의 균질한 완충재 블럭을 성형할 수 있으며, 또한 이는 선진핵주기 고준위폐기물처분시스템(AKRS; Advanced Korea Reference Disposal System of HLW)의 완충재 소요 밀도기준을 충족하는 것으로 분석되었다.

A series of amphiphilic block copolymers consisting of hydrophobic poly(methyl methacrylate) (PMMA) and poly(polyethylene glycol methyl ether methacrylate) (PPEGEMA) were synthesized by Cu based ATRP and utilized as an additive to prepare asymmetric ultrafiltration (UF) membranes by non-solvent induced phase separation (NIPS) with PVDF. Obtained PVDF based UF membranes gave in-situ hydrophilic surfaces on the hydrophobic PVDF matrix because of strong compatibility PMMA block segment to PVDF and the hydrophilicty of PPEGMA block segment to the non-solvent (water), which showed improved water flux in comparison to neat PVDF UF membrane.

The heat transfer characteristics of forced convection according to the geometric shapes with four rectangular blocks in a horizontal PCB channel was analyzed numerically using SST (Shear Stress Transport) turbulence model. As the boundary condition for CFD (Computational Fluid Dynamics) analysis, the inlet temperature and air velocity were respectively 300 K and 3.84 m/s and the heat flux of the block surface was 358 W/㎡. The shape factors of block were width, height, spacing and channel entrance height. As the results, the heat transfer rate was decreased as the width ratio (x/h) was increased, while it was increased as the height ratio (h/x) is increased. Also as the block spacing ratio (s/x) was increased, the heat transfer effects was not significantly affected. And as the channel entrance height ratio (H/x) was increased, the heat transfer performance was decreased.

PURPOSES :In this study, we analyzed the road crossing behavior of older pedestrians on a mid-block signalized crosswalk, and compared it to that of younger pedestrians. In addition, we analyzed the correlation between accidents involving older pedestrians while crossing roads and their behavioral characteristics. Finally, we confirmed the reasons for an increase in accidents involving older pedestrians.METHODS :First, 30 areas with the highest incidence of accidents involving older pedestrians while crossing roads were selected as target areas for analysis. Next, we measured the start-up delay (the time elapsed from the moment the signal turns green to the moment the pedestrian starts walking) and head movement (the number of head turns during crossing a road) of 900 (450 older and 450 younger) pedestrians. The next step was to conduct a survey and confirm the differences in judgment between older and younger pedestrians about approaching vehicles. Finally, we analyzed the correlation between the survey results and traffic accidents.RESULTS :The average start-up delay and head movement of the older pedestrians was 1.58 seconds and 3.15 times, respectively. A definite correlation was obtained between head movement and the frequency of pedestrian traffic accidents. The results of our survey indicate that 17.3% of the older pedestrians and 7.8% of the younger pedestrians have a high crash risk.CONCLUSIONS :Behavioral characteristics of older pedestrians were closely correlated with accidents involving older pedestrians while crossing roads in mid-block signalized crosswalks. Our study indicates that in order to reduce the number of accidents involving older pedestrians, it is necessary to develop an improvement plan including measures such as installation of safety facilities taking the behavioral characteristics of older pedestrians into consideration and their safety education.

A class of phenolphthalein anilide based poly(ethersulfone) (PES) block copolymers containing pendent quaternary ammonium (QA) groups was prepared as anion exchange membranes by reaction involving nucleophilic substitution, benzylic bromination, quaternization and anion exchange with hydroxide ions. Hexafluorobenzene (HFB) was utilized as a linkage group between the hydrophobic and hydrophilic oligomer blocks. Nano-phase separated membrane morphology due to block structure of poly (ethersulfone) serves for better management of absorbed water for higher hydroxide conductivity with good thermal, and dimensional stability. The water uptake, swelling ratio, conductivity, and chemical stability of the copolymer membranes were comparatively investigated.

In this study, the heating block for 3D printer has a problem that heat is transferred to the filament guide portion to dissolve the filament, thereby preventing the filament from being discharged quickly out of the nozzle. In order to solve these problems, the cladding with different thermal conductivity was fabricated and the heating block was manufactured. The properties of the fabricated clad material and the surface temperature of the fabricated heating block were measured and the following conclusions were obtained. As a result of modeling thermal analysis of the heating block made of the clad material developed in this study rather than the existing heating block, the surface temperature of the filament guide portion was predicted to be lower than the surface temperature of the heating portion. The shear strength of the clad material developed in this study was measured and the average value of 82.8 MPa was obtained. The thermal conductivity of the existing heating block was 237W/m K at 300K. The thermal conductivity of the heating block made of the clad material ⋅ developed in this study was 81.416W/m K, which is lower than the conventional thermal conductivity. The ⋅ surface temperature of the heating block made of the clad material developed in this study is 172.3℃, which is lower than that of the conventional heating block. Future research is to evaluate the thermal distribution by using a metal with a lower thermal conductivity than carbon steel and by cladding pressure, evaluating the physical properties of the clad material, and fabricating it as a heating block.

최근 콘크리트 궤도 슬래브 하면과 교량 바닥판 사이에 저마찰 슬라이드층을 형성하는 궤도 시스템인 슬라이딩 궤도와 관 련된 연구가 활발히 진행되고 있다. 본 연구에서는 슬라이딩 궤도에서 열차 주행에 따른 횡방향 하중을 저항하기 위해 설치 되는 횡방향 지지 콘크리트 블록의 전단 내하력에 대한 연구를 수행하였다. 횡방향 지지 콘크리트 블록의 전단 내하력 산정 을 위해 타설경계면에서의 콘크리트 마찰 및 철근의 다월 거동을 고려한 산정 기법을 개발하다. 제안된 산정 기법은 기존의 실험에서 측정된 전단 내하력을 13∼23% 정도 보수적으로 예측하는 것으로 나타났다. 이는 균열면 골재 맞물림 효과를 무 시한 것에 따른 것으로, 현장에서의 타설경계면 상태가 불확실한 것을 고려할 때 횡방향 지지 콘크리트 블록에 대한 안전측 설계를 위해 제안된 산정 기법이 합리적인 것으로 판단된다. 제안된 전단 내하력 산정 기법을 토대로 횡방향 지지 콘크리트 블록에 대한 설계 방안을 마련하였다

Hospital costing has generally been using ABC costing method. However, based on increase of expensive equipment, the fixed cost is increased in the hospital industry. The most common equipment industry are using building block costing method for depreciation and equipment management costing elements. Additionally it presents three options that may be considered to be supported by the IT system to find the most appropriate alternative.

OBJECTIVES : The objective of this study is to analyze the nonlinear behavior of block pavements using multi-load level falling weight deflectometer (FWD) deflections. METHODS: Recently, block pavements are employed not only in sidewalks, but also in roadways. For the application of block pavements in roadways, the structural capacities of subbase and subgrade are important factors that support the carry traffic load. Multi-load level FWD testing was conducted on block pavements to analyze their nonlinear behavior. The deflection ratio due to the increase in load was analyzed to estimate the nonlinearity of block pavements. Finite element method with nonlinear soil model was applied to simulate the actual nonlinear behavior of the block pavement under different levels of load. RESULTS: The results of the FWD testing show that the center deflections in block pavements are approximately ten times greater than that in asphalt pavements. The deflection ratios of the block pavement due to the increase in the load range from 1.2 to 1.5, indicating that the deflection increased by 20~50%. The material coefficients of the nonlinear soil model were determined by comparing the measured deflections with the predicted deflections using the finite element method. CONCLUSIONS: In this study, the nonlinear behavior of block pavements was reviewed using multi-load level FWD testing. The deflection ratio proposed in this study can estimate the nonlinearity of block pavements. The use of nonlinear soil model in subbase and subgrade increases the accuracy of predicting deflections in finite element method.

연료로부터 벤젠 또는 톨루엔과 같은 유독한 방향족 성분의 제거 및 분리는 최대 허용 농도의 감소로 인해 점점 더 많이 주목 받고 있다. 그 중에서도 가솔 린의 벤젠 함량은 지금 법률상으로 유럽에서 1% 이하로 제한되고 있다. 이러한 분리공정에 있어서 에너지의 소모를 줄이고 분리효율을 높일 수 있는 투과증발 공정이 각광을 받고 있다. 본 연구에서는 벤젠에 대한 고선택성을 나타내는 sulfonated SEBS 공중합체를 합성하였고, 1H-NMR과 FT-IR 분석을 통해 술폰화 가 되었음을 확인하였다. 혼합물 분리를 위한 투과증발 실험 장치를 제작하여 sulfonated SEBS막을 제조하여 벤젠 조성 변화에 따른 투과증발 실험을 실시하 였으며, 그에 따른 투과유량 및 투과도를 계산하여 투과특성을 확인하였다.

The anion exchange membrane fuel cells (AEMFCs) have been noticed as the promising power sources. One of the most important components in AEMFC is the anion exchange membranes(AEMs). Recently various materials for AEMs have been investigated for fuel cell applications. Imidazolium-based long alkyl chain multiblock copolymers have drawn much interest due to their well-defined phase separation between hydrophilic and hydrophobic blocks. We report herein the investigation of the effect of block ratio on the phase separation as well as mechanical and electrical properties of the corresponding membranes.

Polyimides (PI) have the high mechanical, thermal, and chemical stability. However, they have low permeability resulting from rigid chain structure. On the other hand, PDMS is a highly CO2 permeable soft polymer. To overcome low permeability of polyimide, we developed PDMS-based polyimide block copolymer. The effect of PDMS contents on the gas separation properties will be discussed in detail.

Polymer electrolyte membrane fuel cells (PEMFC) are considered as prospective energy conversion systems because of high efficiency and environmental advantage. However, the current PEMFC technology uses commercialized perfluorosulfonic acid (PFSA) polymers as a proton exchange membrane, which has the issues of high production cost, poor recyclability at intermediate temperature. In this study, We have synthesized a non-fluorinated hydrocarbon membrane. Also, non-fluorinated membrane has a symmetric chemical structure and sulfonated block copolymer was prepared and characterized using 1H-NMR, and the proton conductivity, ion exchange capacity (IEC), and water uptake. properties were evaluated. The synthesis, characteristic and fuel cell performance and newly prepared membrane will be discussed.

Novel sulfonated poly(arylene ether sulfone)s multi-block copolymer membranes containing highly sulfonated hydrophilic blocks were synthesized. Different local concentration of sulfonic acid in their hydrophilic blocks affected chemical and physical properties of the SPAES. To investigate the effects of chemical composition on their membrane properties, different hydrophilic oligomers sharing same hydrophobic blocks gave us exact comparison of effect of hydrophilic blocks. The higher concentration of sulfonic acid groups resulted in higher proton conductivity under certain relative humidity conditions than that of the state-of-the-art perfluorinated sulfonic acid membrane and showed that the well-developed phase separation of SPAES.

목판본 ｢탐라지도｣는 여타의 제주도 지도와는 달리 격자 형태의 방격과 한라산을 중심으로 하는 방사상의 방위선이 그려져 있어서 일찍부터 학계의 관심을 끌었다. ｢탐라지도｣는 지도에 기재된 내용으로 볼 때, 1706년에서 1716년 사이에 제작된 것으로 추정된다. 전체적인 해안선의 윤곽과 표현 기법 등은 1709년의 ｢탐라지도병서｣와 유사하여 같은 계열의 지도로 평가된다. 지도는 텍스트인 주기문을 같이 수록하고 있는데 제주도의 위치관계, 도서, 명소 등에 대한 내용으로 이루어져 있다. ｢탐라지도｣는 방격법과 방위선법을 사용하고 있다. 방격법은 중국에서 전래된 것으로 거리 관계를 명확히 하려는 목적을 지니고 있고, 방위선법은 주변국과의 위치관계를 정확하게 표현하려는 의도를 지니고 있다. 방위선법은 서양의 포르톨라노 지도와 유사하나 실제 항해용으로 사용하지는 못했던 것으로 보인다.

연료로부터 벤젠 또는 톨루엔과 같은 유독한 방향족 성분의 제거 및 분리는 최대 허용 농도의 감소로 인해 점점 더 많이 주목 받고 있다. 그 중에서도 가솔린의 벤젠 함량은 지금 법률상으로 유럽에서 1% 이하로 제한되고 있다. 이러한 분리공정에 있어서 에너지의 소모를 줄이고 분리효율을 높일 수 있는 투과증발 공정이 각광을 받고 있다. 본 연구에서는 벤젠에 대한 고선택성을 나타내는 sulfonated SEBS 공중합체를 합성하였고, 1H-NMR과 FT-IR 분석을 통해 술폰화가 되었음을 확인 하였다. 혼합물 분리를 위한 투과증발 실험 장치를 제작하여 sulfonated SEBS막을 제조하여 벤젠 조성 변화에 따른 투과증발 실험을 실시하였으며, 그에 따른 투과유량 및 투과도를 계산하여 투과특성을 확인하였다.