In order to analyze the sensitivity of carbon dioxide flux by soil temperature in the grassplot, carbon dioxide flux and soil temperature were observed 24 times from March, 2010 to March, 2011 at nine sites in the grassplot. The average of CO2 in the grassplot is 2.2~36.7℃, the highest in August, the lowest in January, and the average of carbon dioxide flux is 12~1479 mgCO2·m-2·hr-1, and the carbon dioxide emission from the grassplot to the atmosphere was 10 times higher in summer than in winter. The temperature response coefficient estimated by the exponential function of carbon dioxide flux according to soil temperature was ranged from 0.1065 to 0.1274, and the increase tendency of CO2 flux with soil temperature was linear at 0~2 0℃and exponential at 20~40℃. The Q10 values for each of nine observation sites on the grassplot was in the range of 2.901 ~ 3.575, and the Q10 value using the total data observed in the lawn was estimated to be 3.374. In the homogeneous grassplot area, the average of Q10 values by observation point and the Q10 value by the total data were estimated similarly.

하수슬러지의 발생량은 산업발달 및 인구증가로 꾸준히 증가하고 있으나, 하수슬러지의 해양투기 금지로 대체 할 수 있는 새로운 처리 방법이 요구되고 있다. 특히, 최근에는 건조슬러지를 재이용하는 다양한 방안들이 제기되고 있으며, 그 중 활성탄을 제조하여 이용하는 방법이 있다. 활성탄은 일반적으로 석탄이나 목재와 같은 탄소질 물질을 이용하여 제조된다. 또한 활성탄의 제조는 탄화와 활성화 공정으로 이루어지며, 탄화와 활성화 공정의 인자들의 변화를 통해 활성탄의 특성이 달라진다. 따라서 본 연구에서는 국내 건조 하수처리장에서 발생한 건조슬러지를 이용하여 활성탄을 제조하였다. 탄화시간, 탄화온도, 활성화시간, 활성화온도, 수증기 주입량과 같은 여러 인자들의 변화에 따른 활성탄의 비표면적, 기공분포도의 분석을 통해 활성탄의 최적조건을 도출하여 활성탄을 제조하고자 하였다.

Adsorption of phenol on activated carbon in a fixed bed was studied. The effects of fixed-bed length, superficial velocity (flow rate) and particle size of adsorbent on fixed-bed performance were investigated. Some characteristic parameters such as the breakthrough time (t0.05), saturation time (t0.95), length of mass transfer zone (LMTZ), adsorptive capacity (W), and adsorption rate constant (Ka) were derived from the breakthrough curves. Adsorbent particle sizes significantly affected the shape of the breakthrough curve. Larger particle sizes resulted in an earlier breakthrough, a longer LMTZ and a lower adsorption rate. Superficial velocity was a critical factor for the external mass transfer during fixed-bed adsorption process. The external mass transfer resistance was dominant as increasing superficial velocity.

It is expected that construction waste include a waste concrete is continuously increase each year in the future. Theamount of construction waste is a lot and according to the nature of construction waste, it does not have a seriousenvironmental pollution and hazards. Therefore it is used as recycled aggregate directly or through a simple intermediatetreatment. The purpose of this study, recycled aggregate concrete used in a building structure system. Thus this studyfigure out which physical and mechanical characteristics of recycled aggregates concrete. According to replacement levelof recycled aggregates compared with natural aggregate, examine a life cycle CO2 emission and review cost efficiencyfor the practical use of recycled aggregate concrete. The result of this study that recycled aggregate concrete decline aCO2 emission and decrease material cost when a replacement level is increase. Carbon dioxide emissions per unit volumein aggregate by dry process according to substitution ratio compared with 0%, in 30% is 0.10%, in 50% is 0.34%, in100% is 0.58% reduce. Aggregate by wet process according to substitution ratio compared with 0%, in 30% is 0.02%,in 50% is 0.20%, in 100% is 0.35% reduce.

The purpose of this paper is to verify the seismic strengthening effect of R/C buildings strengthened with the Carbon Fiber Composite Cable (CFCC) In this study, a three-story R/C building that constructed in the 1980s was selected, and its seismic performance before and after strengthening was evaluated based on the nonlinear dynamic analyses of members levels. The result indicated that the seismic strengthening effect of the proposed CFCC method was verified in terms of both strength and ductility demands, compared to the building before strengthening.

The concentration of organic compounds was analyzed at each step of BAC process though BDOCtotal/rapid/slow. Further, bacteria communities and biomass concentrations measured FISH and ATP methods were analyzed. The bed volume (BV) of steady state is different from that of based on assessment of organic compounds removal. Bed volumes in DOC, BDOCrapid and BDOCtotal/slow removal at steady state were around 27,500 (185.8 day), 15,000 (101.4 day) and 32,000 (216.2 day), respectively. A biomass didn't change after the bed volume reached 22,500 (152.0 day) according to analyzing ATP concentration of bacteria. The concentration of ATP was 2.14 μg/g in BV 22,500 (152.0 day). The total bacterial number was 4.01±0.4×107 cells/g at the bed volume 1,150 (7.8 day) (the initial operation) and the number of bacteria was 9.27±0.2×109 at the bed volume 58,560 395.7 day) that increased more than 200 times. Bacterial uptrend was reduced and bacterial communities were stabilized since BV 18,720 (126.5 day). When BV were 1,150 (7.8 day), 8,916 (60.2 day), 18,720 (126.5 day), 31,005 (209.5 day), 49,632 (335.3 day), 58,560 (395.7 day), a proportion of total bacteria for the Eubacteria were 60.1%, 66.0%, 78.4%, 82.0%, 81.3% respectively. γ-Proteobacteria group was the most population throughout the entire range. The correlation coefficient (r2) between Eubacteria biomass and ATP concentration was 0.9448.

A thermal-optical transmittance carbon analyzer has been developed to determine particulate organic (OC) and elemental (EC) carbon. Several analysis factors affecting the sensitivity of OC and EC determination were investigated for the carbon analyzer. Although total carbon (TC) is usually consistent in the determination, OC and EC split is sensitive to adopted analysis protocol. In this study the maximum temperature in oxygen-free He in the analysis was examined as a main cause of the uncertainty. Prior to the sensitivity analysis consistency in OC-EC determination of the carbon analyzer and the uniformity of carbonaceous aerosol loading on a sampled filter were checked to be in acceptable range. EC/TC ratios were slightly decreased with increasing the maximum temperature between 550-800oC. For the increase of maximum temperature from 500oC to 800oC, the EC/TC ratio was lowered by 4.65-5.61% for TC loading of 13-44 μg/cm2 with more decrease at higher loading. OC and EC determination was not influenced by trace amount of oxygen in pure He (>99.999%), which is typically used in OC and EC analysis. The facing of sample loaded surface to incident laser beam showed negligible influence in the OC-EC split, but it caused elevated PC fraction in OC for forward facing relative to backward facing.

본 연구의 목적은 CFRP판을 다양한 방법으로 보강한 RC보의 휨거동을 실험적으로 비교․분석하고, 프리스트레싱을 도입하여 보강된 콘크리트 구조물의 성능개선 효과와 구조거동을 예측할 수 있는 해석모델을 개발하는 것이다. 이를 위하여 프리스트레싱이 도입된 CFRP판의 부착 및 휨거동 특성을 분석하고, CFRP 및 Epoxy 수지의 거동특성을 규명하였다. 또한 CFRP판의 보강방법과 프리스트레싱 수준 등을 실험변수로 설정하여 콘크리트 보의 휨실험을 수행하고, 개발된 해석모델의 결과와 비교․검증하였다. 연구결과 본 해석기법은 충분한 신뢰도를 가지고 있으므로 CFRP를 사용한 보강설계에 효과적으로 적용이 가능하다고 판단된다.

The bacterial community structure in biological activated carbon (BAC) process in drinking water treatment plant was investigated by Fluorescent in situ Hybridization (FISH) with rRNA-targeted oligonucleotide probe. Samples were collected at different three points in BAC process every month for one year. They were hybridized with a probe specific for the alpha, beta, gamma subclass of the class Proteobacteria, Cytophaga- Flavobacteria group and Gram-positive high G+C content (HGC) group. Total numbers of bacteria in BAC process counted by 4',6-diamidino-2-phenylindole (DAPI) staining were 5.4×1010 (top), 4.0×1010 (middle) and 2.8×1010 cells/ml (bottom). The number of the culturable bacteria was from 1.0×107 to 3.6×107 cells/ml and the culturability was about 0.05%. The faction of bacteria detectable by FISH with the probe EUB338 was about 83% of DAPI counts. Gamma and alpha subclass of the class Proteobacteria were predominant in BAC process and their ratios were over 20% respectively. In top and middle, alpha, beta and gamma subclass of the class Proteobacteria competed with each other and their percentages was changed according to the season. In bottom, gamma subclass of the class Proteobacteria was predominant all through the year. It could be successfully observed the seasonal distribution of bacterial community in biological activated carbon process using FISH.

A bismuth-coated carbon fiber microelectrode was prepared using cyclic voltammetry (CV). An analytical application was performed for the copper analysis with Square Wave Stripping Voltammetry (SWSV). Gallic acid n-propyl ester (PG) was used for the complex formation with a copper ion, and electrochemical measurements were performed with a pre-amplifier of a low-current module for nano amper detection. The effects of various parameters on the response were optimized. Analytical working ranges of 0.03-25.9 μgl-1 and 0-25 mgl-1 Cu(II) were obtained. The relative standard deviation at 13 mgl-1 Cu was 0.9% (n = 12) in optimum conditions. The detection limit was found to have been 0.019 μgl-1, with a 30-sec accumulation time. The developed methods were applied to a copper assay in water samples.

본 연구의 목적은 CFRP판을 다양한 방법으로 보강한 RC보의 휨거동을 실험적으로 비교․분석하고, 프리스트레싱 보강공법의 실용화를 목적으로 프리스트레싱 보강 RC부재의 휨성능 평가식을 제안하는 것이다. 실험변수로는 CFRP판의 보강방법, 콘크리트 압축강도, 인장철근비 그리고 프리스트레싱 수준 등을 고려하였다. 실험결과 프리스트레싱이 도입되지 않은 실험체는 조기 부착파괴로 인해 탄소판이 콘크리트로부터 탈락하면서 파괴된 반면, 프리스트레싱을 가한 대부분의 실험체는 CFRP판의 파단으로 파괴되었다. 프리스트레싱 보강된 부재의 휨강도를 예측할 수 있는 식을 제안하였으며, 실험결과와의 비교를 통하여 제안식은 휨강도 예측에 있어 충분한 정확도를 확보하고 있음을 확인하였다.

The adsorption experiment of phenol(Ph) from aqueous solution on granular activated carbon was studied in order to design the fixed-bed adsorption column. The experimental data were analyzed by unsteady-state, one-dimensional heterogeneous model. Finite element method(FEM) was applied to analyze the sensitivity of parameter and to predict the fixed-bed adsorption column performance on operation variable changes. The prediction model showed similar effect to mass transfer and intraparticle diffusion coefficient changes suggesting that both parameter present mass transfer rate limits for GAC-phenol system. The Freundlich constants had a greater effect than kinetic parameters for the performance of fixedbed adsorption column. FEM solution facilitated prediction of concentration history in solution and within adsorbent particle.