In this study, defects generated in the YSZ coating layer of the IN738LC turbine blade are investigated using an optical microscope and SEM/EDS. The blade YSZ coating layer is composed of a Y-Zr component top coat layer and a Co component bond coat layer. A large amount of Cr/Ni component that diffused from the base is also measured in the bond coat. The blade hot corrosion is concentrated on the surface of the concave part, accompanied by separation of the coating layer due to the concentration of combustion gas collisions here. In the top coating layer of the blade, cracks occur in the vertical and horizontal directions, along with pits in the top coating layer. Combustion gas components such as Na and S are contained inside the pits and cracks, so it is considered that the pits/cracks are caused by the corrosion of the combustion gases. Also, a thermally grown oxide (TGO) layer of several μm thick composed of Al oxide is observed between the top coat and the bond coat, and a similar inner TGO with a thickness of several μm is also observed between the bond coat and the matrix. A PFZ (precipitate free zone) deficient in γ' (Ni3Al) forms as a band around the TGO, in which the Al component is integrated. Although TGO can resist high temperature corrosion of the top coat, it should also be considered that if its shape is irregular and contains pore defects, it may degrade the blade high temperature creep properties. Compositional and microstructural analysis results for hightemperature corrosion and TGO defects in the blade coating layer used at high temperatures are expected to be applied to sound YSZ coating and blade design technology.
한국원자력연구원 처분시스템개발과제에서는 처분용기 재료로 개발중인 저온분사코팅 구리에 대한 틈새부식(Crevice Corrosion) 시험을 실시하였다. 본 시험을 통하여 틈새에서의 부식의 발생여부와 발생되는 시점인 재부동태 전위(Repassivation Potential)를 측정하고자 하였다. 틈새부식 시험 방법으로 (1) ASTM G61-86 : Cyclic Potentiodynamic Polarization Measurements, (2) SWRI의 PotentiodynamicPolarization plus intermediate Potentiostatic Hold method, 그리고 (3) ASTM G192-08 (THE method) :Potentiodynamic- Galvanostatic -Potentiostatic Method 등의 3가지 방법을 소개하였다. 실제 저온분사코팅구리의 부식시험에서는 ASTM G61-86에 따라서 틈새부식장치를 설치하고, 저온분사 코팅구리가 KURT 지하수를 모사한 용액에서 어떻게 틈새부식이 일어나는지 살펴보았다. 전기적 부식조건으로는 Cyclic Polarization Test, Potentiostatic Polarization Test, 및 Electrochemical Impedance Spectroscopy등을 사용하였다. 그리고 부식이 된 시편에 대해 Profilometer Measurement를 통해 실제 부식표면의 높낮이를 조사하여 틈새부식 유무를 관찰하였다. 최종적인 결론에서는 저온분사코팅구리는 틈새부식을 나타나지 않는다는 것을 확인할 수 있었다. 그리고 시험에 사용된 세종류의 구리에 대한 상대적인 부식평가를 한 결과, 부식전위를 나타내는 개방회로(Open Cell)에서의 전위는 구리의 제조방식과 상관없이 구리의 순도가 높을수록 높은 값을 보이는 것을 확인할 수 있었다. 결론적으로 KURT 심층지하수 조건에서는 구리는 틈새부식이 발생되지 않는다고 결론지었다.
Chromium nitride (CrN) samples with two different layer structures (multilayer and single layer) were coated on bipolar plates of polymer electrolyte membrane fuel cells (PEMFC) using the reactive sputtering method. The effects with respect to layer structure on corrosion resistance and overall cell performance were investigated. A continuous and thin chromium nitride layer (Cr0.48 N0.52) was formed on the surface of the SUS 316L when the nitrogen flow rate was 10 sccm. The electrochemical stability of the coated layers was examined using the potentiodynamic and potentiostatic methods in the simulated corrosive circumstances of the PEMFC under 80˚C. Interfacial contact resistance (ICR) between the CrN coated sample and the gas diffusion layer was measured by using Wang's method. A single cell performance test was also conducted. The test results showed that CrN coated SUS316L with multilayer structure had excellent corrosion resistance compared to single layer structures and single cell performance results with 25 cm2 in effective area also showed the same tendency. The difference of the electrochemical properties between the single and multilayer samples was attributed to the Cr interlayer layer, which improved the corrosion resistance. Because the coating layer was damaged by pinholes, the Cr layer prevented the penetration of corrosive media into the substrate. Therefore, the CrN with a multilayer structure is an effective coating method to increase the corrosion resistance and to decrease the ICR for metallic bipolar plates in PEMFC.
산화물 사용 후 핵연료를 처리하는 전해환원공정에서는 LiCl 용융염계에서 산소가 생성되는 반응을 수반하게 되 며, 생성된 산소로 인해 반응기의 구조재료를 상당히 부식시킬 수 있는, 화학적으로 심각한 반응환경을 조성한다. 따라서, 고온 용융염을 다루는 전해환원 공정장치를 위해서는 최적의 재료를 선택하는 것이 필수적이다. 본 연구에 서는 리튬용융염, 675℃, 216시간동안 산화분위기에서 코팅이 안 된 초합금과 코팅된 초합금 시편의 고온 부식연구 를 수행하였다. IN713LC 초합금 시편에 aluminized NiCrAlY bond 코팅 후 Y2O3 top 코팅을 하였다. 코팅이 안 된 초 합금은 부식층의 빠른 성장응력과 열적응력에 의한 부식층의 박리로 명확한 무게손실을 보인다. 탑 코팅의 화학적 및 열적 안정성으로 인해 고온 리튬용융염을 다루는 구조재료의 부식 저항성이 증가함을 확인할 수 있었다