WAAM(Wire Arc Additive Manufacturing) has gained attention as an innovative technology in small-batch, multi-product production due to its advantages of low production costs, rapid build rates, and design flexibility. However, challenges such as relatively low geometric accuracy, surface finish defects, residual stresses, and distortion due to high heat input persist and require improvement. This study analyzes the influence of deposition path angles on deposition performance in the WAAM process. Experiments were conducted using stainless steel (STS309MoL) wire, known for its excellent heat resistance and corrosion resistance due to its relatively high ferrite content within the austenitic structure. To mitigate residual stresses and distortion caused by high heat input, the CMT(Cold Metal Transfer) process was employed for five layers of deposition. Five different deposition path angles were selected as process variables, and the impact of deposition path angles on deposition performance was evaluated based on experimental results.

PURPOSES : The current research aims to evaluate the impact of coating materials and temperature on the percentage of bead loss in pavement markings. METHODS : Five mixtures with varying numbers of coating layers (C0, C1, C2, C3, and C4) were prepared to assess the effect of coating layers on bead loss. The effect of stripping was simulated using a modified Hamburg Wheel Tracking test. Furthermore, the influence of temperature and coating material on bead loss was examined using control mixture (without coating), YR, and SY coating mixtures. The percentage bead loss was evaluated by a developed image analysis program. RESULTS : The results demonstrated a substantial reduction in bead loss as the number of coating layers increased, with the C4 mixture showing an impressive 4.3% bead loss after 500 HWT braking cycles compared to 27.4% for the C0 mixture. Higher testing temperatures resulted in increased bead loss, with the control mixture exhibiting the highest percentage loss at 7,500 HWT rolling cycles. Conversely, the YR and SY coating mixtures displayed superior resistance to bead loss. Statistical analysis confirmed the significance of coating layers in reducing bead loss, further supporting the effectiveness of coatings in preserving bead adhesion during HWT cycles. CONCLUSIONS : The findings highlight the potential of coating materials as a key protective measure for enhancing the longevity and performance of pavement markings.

PURPOSES : The purpose of this study is to verify the effect of improving the retroreflectivity of pavement marking by increasing the refractive index of glass bead. METHODS : Pavement marking test-beds has been installed in National Highway 19, 42 and KICT Yeoncheon SOC Center. In testbeds several marking sections were installed for each type of marking materials and glass beads. In this test-beds initial dry and wet retroreflectivity were measured and analyzed. RESULTS : When the refractive index of glass bead was adjusted upward in water based paint(glass bead No.1→ No.2), dry retroreflectivity increased by about 30 to 70%, and wet retroreflectivity slightly increased by about 10 to 40%. When using glass bead No. 2 in water based paint, it was found to meet the standards of the Road Traffic Act. However, since wet retroreflectivity of water based paint slightly exceeds the standard value, a follow-up investigation is needed to determine how long this performance can be maintained. When using glass bead No.1 in MMA(methyl methacrylate), the average wet retroreflectivity was evaluated to be 128 to 150 mcd/lx/m2, and when using glass bead No.2, the average wet retroreflectivity was evaluated to be about 200 to 270 mcd/lx/m2. Accordingly, MMA showed the best performance compared to other paints. CONCLUSIONS : When using glass bead No.1 in water-soluble paints and thermoplastic, it did not meet the wet retroreflectivity standards of the Road Traffic Act. But when using glass bead No.2, it met the wet retroreflectivity standards. As a result of analyzing the road marking budget according to the upward adjustment of the refractive index of glass bead, it was analyzed that if only the material class was adjusted upward, the cost would increase by more than twice the current budget. In order to decrease this budget increase rate(to increase service life), it is necessary to strengthen quality control standards for pavement marking and develop scientific-systematic quality control techniques.

본 연구의 목적은 구슬 문양 디자인의 상징성과 의미 및 신라문화와의 연관성, 유리구슬 제조의 제반 여건을 조사 하여 예술성과 기술성이 뛰어난 신라 인면 상감 유리구슬의 신라 자체 제작설을 검증하는 것이다. 연구방법으로는 디자인 분석 이외에 고문헌과 신화, 유리 유물, 유리 및 금속의 생산기술, 실크로드 교차로의 특성 등을 조사하였으 며 홍산문화 유물, 다른 상감 유리구슬의 사례들을 수집하였다. 마한, 부여, 신라인은 구슬을 보배로 삼고 장신구에 애용하였는데, 구슬 속의 인면상 상투와 금관장식, 새와 꽃나무의 모든 디자인 요소가 김알지, 김수로, 박혁거세, 주 몽 등 위인들의 난생설화, 북방의 새 및 신수 숭상 등과 밀접하였고, 디자인 요소와 배치가 신라의 다른 유물에서도 동일하게 표현되고 있음을 확인하였다. 구슬과 인면상의 기원은 홍산문화였으며 하가점하층문화의 고조선 북표에서 는 구슬용 석범이 발견되었다. 또 경주 식리총의 상감 유리구슬과 일본 토간모리 고분의 인면 상감 유리구슬의 출토 는 신라 자체 제작설을 확증시켜주는 것이다. 백제인이 5세기 일본에 유리구슬 제작소를 둔 사실은 신라인이 인도네 시아 자바에도 제작소를 두었음을 의미한다. 신라와 밀접한 관계였던 인도네시아 자바는 신라의 해상실크로드 교차 로, 원석 및 노동력 제공지이고 유리구슬의 소비 지역이나 기원지는 아니었다. 이에 구슬에 대한 신화와 전통을 보유 하고 머리에 상투와 금관을 착용하였으며, 금속 및 상감 기술 등 난이도 높은 기술을 보유했던 신라가 자체 제작한 것이 틀림없다.

The removal of cesium (Cs) from contaminated clay minerals is still a challenge due to the limited efficiency of the process. Thus, this study aimed to enhance the removal for Cs+ ions during the conventional acid washing process by incorporating a bead-type adsorbent. Polyacrylonitrile-based nickel potassium hexacyanoferrate (NiFC-PAN) was utilized as the Cs adsorbent to selectively adsorb Cs+ ions in a strongly acidic solution that contained competing ions. To enable easy separation of clay particles and protect the adsorbent from harsh environmental conditions, PAN was deliberately constructed as large beads. The synthesized adsorbent (NiFC/PAN in a 2:1 ratio) displayed high selectivity for Cs+ ions and had a maximum capacity of 162.78 mg/g for Cs+ adsorption in 0.5 M HNO3 solution. Since NiFC-PAN exhibited greater Cs selectivity than the clay mineral (hydrobiotite, HBT), adding NiFC-PAN during the acid washing substantially increased Cs desorption (73.3%) by preventing the re-adsorption for Cs+ ions on the HBT. The acid treatment in the presence of NiFCPAN also significantly decreased the radioactivity of 137Cs-HBT from 209 to 27 Bq/g, resulting in a desorption efficiency of 87.1%. Therefore, these findings suggest that the proposed technique is a potentially useful and effective method for decontaminating radioactive clay.

The Ag0-containing sorbents synthesized by Na, Al, and Si alkoxides have higher maximum iodine capture capacity and textural properties than zeolite-based Ag0-containing sorbents. However, these sorbents were prepared in the form of granules via a step for cutting cylindrical alcogels. Since asmade sorbents decreased packing density, they must be additionally crushed and then classified into an appropriate size for increasing packing density. The bead formation in the step of sol-gelation could bring about the simplification of sorbent preparation process and an improvement of packing density. In the Na, Al, and Si alkoxides as starting materials, sol solution was hydrophilic and lower density than vegetable oil, which transformed sol droplets to sol-gel beads. Thus, in these precursors, sol droplets, which must be sprayed by single nozzle placed at bottom side of oil column, can rise up through oil column. Acetic acid (HOAc) was used as the catalyst for the hydrolysis of Na alkoxide (TEOS) and gelation of the Na+AlSi-OH alcosol. For obtaining sol-gel beads, experiments were performed by the flowrate change of sol solution and HOAc at different nozzle sizes using soybean oil column of 1 m in length. At a sol/HOAc flowrate ratio of 3.85, some Na+AlSi-OH alcogel beads were obtained. After the Ag/Na ion-exchange, Ag content in Ag+AlSi-OH hydrogel was low due to reaction between Na+ and HOAc during sol-gelation and aging step. The Ag+AlSi-OH hydrogel with high Ag content could be prepared by Na addition. After the solvent exchange and drying at ambient pressure, the bead sorbents had higher Ag0 content and larger pore size than granular sorbents. However, further experiments are needed to increase yield rate in bead sorbent.

Aluminum material, which has excellent corrosion resistance, durability, and light weight, is widely used in the field of shipbuilding, and welding is an essential technology in shipbuilding. currently, welding is efficiently used to assemble structures of various sizes in the shipbuilding process, but aluminum is a very sensitive material at high temperatures and in a molten state, so appropriate process control is essential. research on aluminum welding has been continuously conducted, but most of the research is on the butt welding method. therefore, in this study fillet welding experiments, which are essentially applied to the internal structure of aluminum ships, were performed and the correlation between welding beads and process variables was identified. for the welding experiment GMA fillet welding was performed on Al5083 material used in the shipbuilding industry, and the influence of the process variable was confirmed by analyzing the correlation through the analysis of the etched fillet weld bead cross section for the test result according to the process variable.

PURPOSES : The aim of this study is to evaluate the stripping resistance of a bead coating via the Hamburg wheel tracking test and image analysis. METHODS : First, the stripping resistance of the bead coating was evaluated via the Hamburg wheel tracking test. A pneumatic wheel with a load of 175±2 N was used to simulate repeated skid cycles. Several bead coating mixtures with different numbers of coating layers, i.e., zero, one, two, three, and four layers, i.e., zero, one, two, three, and four layers,were conducted. Finally, an image analysis program was developed to analyze surface images captured from the Hamburg wheel tracking test. RESULTS : The results show that the samples with more coating layers exhibit higher stripping resistance. After 500 stripping cycles, the percentage of bead loss is 4% to 28%. At 80% bead loss, the mixture with one coating layer presents more skid cycles than the control sample without a coating layer. CONCLUSIONS : Incorporating a coating layer can improve the stripping resistance of glass beads under repeated skid cycles. Additionally, an image analysis program is established in this study to determine the percentage of bead loss caused by the stripping test.

Environmental regulations of the International Maritime Organization (IMO) are getting stricter, and the demand for replacing the fuel of ships with eco-friendly fuels instead of heavy oil in the shipbuilding and marine industries is increasing. Among eco-friendly fuels, LNG (liquefied natural gas) is currently the most popular fuel. This is because it is an alternative that can avoid the IMO's environmental regulations by replacing fuel. In PART 1, as a basic study of laser welding of high manganese steel materials, a fiber laser bead-on-plate experiment was conducted using nitrogen protective gas, and the effect of each factor on the penetration shape was analyzed through cross-sectional observation. In PART II, argon and helium shielding gases, not the nitrogen shielding gas used in PART I, were tested under the same experimental conditions and the effect of the shielding gas on penetration during laser welding was conducted.

Environmental regulations of the IMO (International Maritime Organization) are becoming more and more conservative. In order to respond to IMO, the demand for replacing the fuel of ships with eco-friendly fuels instead of conventional heavy oil is increasing in the shipbuilding and offshore industries. Among eco-friendly fuels, LNG (Liquefied Natural Gas) is currently the most popular fuel. LNG is characteristically liquefied at -163 degrees, and at this time, its volume is reduced to 1/600, so it is transported in a cryogenic liquefied state for transport efficiency. A tank for storing this should have sufficient mechanical/thermal performance at cryogenic temperatures, and among them, high manganese steel is known as a material with high price competitiveness and satisfying these performance. However, high manganese steel has a limitation in that the mechanical performance of the filler metal is lower than that of the base metal called ‘under matching’. In this study, to overcome this limitation, a basic study was conducted to apply the fiber laser welding method without filler metal to high manganese steel. To obtain efficient welding conditions, in this study, bead-on-plate welding was performed by changing the fiber laser welding speed and output using helium shielding gas, and the effect of each factor on the penetration shape was analyzed through cross-sectional observation.

The Na, Al, and Si akoxides-based sorbents for iodine capture have higher maximum iodine capture capacity and pore properties than zeolite-based sorbents. However, these sorbents were prepared in the form of granules via a step for cutting cylindrical alcogels. Since as-made sorbents decreased packing density, they must be additionally crushed and then classified into an appropriate size for increasing packing density. The bead formation in the step of sol-gelation could bring about the simplification of sorbent fabrication process and an improvement of packing density. For the formation of gel bead, characteristics such as hydrophilic or hydrophobic property and density of sol solution were investigated to design sol-gelation equipment. The sol-gel bead preparation equipment in the reflection of sol solution characteristics was fabricated through selection of oil for formation of sol bead, solvent for collection of gel bead, and nozzle for spray of sol droplet formation. The continuous or discontinuous formation of sol beads from NaAlSi-OH sol solution were observed according to flow rates of 6 to 8 mL·min−1 and nozzle diameters of 0.4 to 0.8 mm. In the sphericity of sol bead, the best sol beads were obtained from 0.5 mm nozzle without clogging by sol solution in the flow rate range of 6–8·min−1.

Due to environmental pollution, regulations on existing petroleum-based fuels are increasing day by day. LNG is in the spotlight as an eco-friendly fuel that does not emit NOx or SOx, but its boiling point is -163°C, so it needs to be handled with care. Materials that can be used at the above temperature are defined by IMO through the IGC Code. Among them, 9% nickel steel has great advantages in yield strength and tensile strength under cryogenic conditions, but it is difficult to use in arc welding such as FCAW for various reasons. This study is a study to apply fiber laser welding to solve this problem. As a previous study, this study conducted a study to find a welding heat source. After performing bead on plate welding, the optimal heat source was derived by analyzing the shape of the bead and adjusting the parameters of the heat source model. In this case, by applying the multi-island genetic algorithm, which is a global optimization algorithm, not the intuition of the researcher, accurate results could be derived in a wide range.

Due to stricter environmental regulations of the International Maritime Organization (IMO), the number of ships fueled by Liquefied Natural Gas (LNG) is rapidly increasing. The International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk (IGC Code) limits the material of tanks that can store cryogenic substances such as LNG. Among the materials listed in the IGC Code, ASTM A553M-17 has been recently adopted as a material for LNG fuel tank projects because of its excellent mechanical properties at cryogenic temperatures. In shipyards, this material is being used to build tanks through Flux Cored Arc Welding (FCAW). However, there is a problem that magnetization occurs during welding and there is a big difference in welding quality depending on the welding position. In order to overcome this problem, this study intends to conduct basic research to apply laser welding to ASTM A553M-17 material. As a result of analyzing the bead shape according to laser BOP speed and Energy density performed in this study, it was confirmed that the penetration and energy density are proportional but the penetration and BOP speed are inverse proportional to some extent. In addition, a range of suitable welding speed and energy density were proposed for the 6.1mm thickness material performed in this study.

Due to stricter environmental regulations of the International Maritime Organization (IMO), the number of ships fueled by Liquefied Natural Gas (LNG) is rapidly increasing. The International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk (IGC Code) limits the material of tanks that can store cryogenic substances such as LNG. Among the materials listed in the IGC Code, ASTM A553M-17 has been recently adopted as a material for LNG fuel tank projects because of its excellent mechanical properties at cryogenic temperatures. In shipyards, this material is being used to build tanks through Flux Cored Arc Welding (FCAW). However, there is a problem that magnetization occurs during welding and there is a big difference in welding quality depending on the welding position. In order to overcome this problem, this study intends to conduct basic research to apply laser welding to ASTM A553M-17 material. In Part I, the bead shape according to the welding output was analyzed and in PART II, ​​the penetration phenomenon according to the welding speed was analyzed after Bead on Plate (BOP) test. As a result of analyzing the bead shape according to laser power performed in this study, it was confirmed that the laser power and penetration depth are proportional to some extent. In addition, a range of suitable welding power was proposed for the 6.1mm thickness material performed in this study.

Chitosan, natural organic polymer, has been applied in water treatment as adsorbent due to non-toxic for human being. The amino group as functional group, can interacts with cation and anion at the same time. The prepared chitosan bead (HCB) was crosslinked to increase chemical stability (HCB-G) and both HCB and HCB-G were prepared to increase physical strength by drying referred to DCB and DCB-G, respectively. The adsorption effect for crosslinking and drying for four types of chitosan bead was tested using pseudo fist order (PFO), pseudo second order (PSO), and intraparticle diffusion model (ID). Regardless of PFO and PSO, the order of K, rate constant, is as followed: HCB > HCB-G > DCB > DCB-G for Cu(II) and phosphate. Drying leading to contraction of bead significantly reduced adsorption rate due to reduce the porosity of chitosan. In addition, crosslingking also negatively effect on adsorption rate. When compared with Cu(II) using hydrogel bead, phosphate showed higher value than Cu(II) for PFO and PSO. The application of ID showed that both hydrogel beads (HCB and HCB-G) obtained a very low R2 ranging to 0.37 to 0.81, while R2 can be obtained to over 0.9 for DCB and DCB-G, indicting ID is appropriate for low adsorption rate.

Because of the International Maritime Organization(IMO)'s regulation to regulate emissions of ships, a change is taking place to replace ship fuels from Heavy Fule Oil(HFO) to Liquefied Natural Gas(LNG). In the case of LNG, it is a material obtained by liquefying Natural Gas(NG), and it is -163 degrees below zero, and the volume is reduced to 1/600 level. The material of the tank that can store LNG must be a material that can safely store LNG in a cryogenic environment, and the materials of the tank that can store LNG are limited in the International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code). Among the materials listed in the IGC Code, 9% nickel steel is used as a material for LNG fuel propulsion tanks that are recently ordered because of relatively high mechanical properties under cryogenic environments. In this study, the mechanical properties of butt welds were measured following the weld reliability evaluation of Flux Cored Arc Welding(FCAW) butt welds made of 9% nickel steel by PARTI. The measured mechanical properties are tensile strength, bending strength, hardness, and cryogenic impact test required by the classification for Welding Procedure Specification(WPS) approval.

Because of the International Maritime Organization(IMO)'s regulation to regulate emissions of ships, a change is taking place to replace ship fuels from Heavy Fule Oil(HFO) to Liquefied Natural Gas(LNG). In the case of LNG, it is a material obtained by liquefying Natural Gas(NG), and it is -163 degrees below zero, and the volume is reduced to 1/600 level. The material of the tank that can store LNG must be a material that can safely store LNG in a cryogenic environment, and the materials of the tank that can store LNG are limited in the International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code). Among the materials listed in the IGC Code, 9% nickel steel is used as a material for LNG fuel propulsion tanks that are recently ordered because of relatively high mechanical properties under cryogenic environments. In this study, butt welding was performed on a 9% nickel steel material using Flux Cored Arc Welding(FCAW), the most widely used welding method in shipyards. In PARTI, after securing the welding conditions, cross-sectional observation results analysis, liquid penetrating test, and radiographic test were performed to verify the reliability of the weld.

The bead geometry according to the welding conditions was analyzed through the laser fillet welding experiment of 9% Ni steel, and the relationship between the shear strength and the five bead geometry measured by selecting the main bead geometry of the fillet weld was analyzed. Among the welding conditions, the welding conditions that directly affect the penetration depth are welding speed and laser power, and the working angle and beam position have a great influence on the formation of leg of vertical and horizontal members. The bead shape, which greatly affects the shear strength, is the horizontal member length, neck thickness, and weld length, and has a proportional relationship with the shear strength. As a result of confirming the relationship between shear strength and bead shape through the derivation of the trend line, it was confirmed that the length of the vertical member, whose R2 value was 0.92, was most closely related to the shear strength.