Exploring cheap and efficient oxygen evolution reaction (OER) catalysts is extremely vital for the commercial application of advanced energy storage and conversion systems. Herein, a self-supporting Co3S4/ S-doped reduced graphene oxide ( Co3S4/S-rGO) film catalyst is successfully prepared by a blade coating coupled with high-temperature annealing strategy, and its morphology, structure and composition are measured and analyzed. It is substantiated that the as-synthesized Co3S4/ S-rGO film possesses unique self-supporting structure, and is composed of uniformly dispersed Co3S4 nanoparticles and highly conductive S-rGO, which benefit the exposure of catalytic sites and electron transfer. By reason of the synergistic effect of the two individual components, the self-supporting Co3S4/ S-rGO film catalyst displays outstanding catalytic performance towards OER. As a consequence, the Co3S4/ S-rGO film catalyst delivers an overpotential of 341 mV at 10 mA cm-2, and the current attenuation rate is only 2.6% after continuous operation for 4 h, verifying excellent catalytic activity and durability. Clearly, our results offers a good example for the construction of high-performance self-supporting carbon-based composite film catalysts for critical electrocatalytic reactions.

A novel kind of self-assembled graphene quantum dots-Co3O4 (GQDs-Co3O4) nanocomposite was successfully manufactured through a hydrothermal approach and used as an extremely effectual oxygen evolution reaction (OER) electrocatalyst. The characterization of morphology with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that Co3O4 nanosheets combined with graphene quantum dots (GQDs) had a new type of hexagonal lamellar selfassembly structure. The GQDs-Co3O4 electrocatalyst showed enhanced electrochemical catalytic properties in an alkaline solution. The start potential of the OER was 0.543 V (vs SCE) in 1 M KOH solution, and 0.577 V (vs SCE) in 0.1 M KOH solution correspondingly. The current density of 10 mA cm− 2 had been attained at the overpotential of 321 mV in 1 M KOH solution and 450 mV in 0.1 M KOH solution. Furthermore, the current density can reach 171 mA cm− 2 in 1 M KOH solution and 21.4 mA cm− 2 in 0.1 M KOH solution at 0.8 V. Moreover, the GQDs-Co3O4 nanocomposite also maintained an ideal constancy in an alkaline solution with only a small deterioration of the activity (7%) compared with the original value after repeating potential cycling for 1000 cycles.

Amorphous molybdenum sulfide ( MoSx) has been regarded as a promising hydrogen evolution reaction (HER) catalyst due to its mild preparation conditions and low-cost precursor materials. In this work, we report a simple strategy combining the growth of amorphous MoSx on the surface of metal organic frameworks (ZIF-67) and annealing treatment to prepare Co-doped MoSx nanopolyhedrons (denoted as CoMoSx NPs). The CoMoSx NPs exhibit excellent HER activity in acid condition with an overpotential of 188 mV at a current density of 10 mA cm− 2 (η10), and a relatively stable overpotential after 2000 cyclic voltammetry (CV) cycles testing. The excellent HER performance of the CoMoSx NPs can be attributed to the doping of Co element adjust the electronic structure and increase the conductivity of catalyst, and the nanopolyhedrons structure which can expose more active sites for HER electrocatalytic. This study offers a low-cost and simple strategy to prepare high-activity HER catalyst, which holds great promises in developing advanced electrocatalysts for energy storage.

하와이는 깨끗한 휴양지와 현대적 경관이 어우러진 세계적인 관광지로 써 많은 여행객들의 발걸음을 이끌어왔다. 이뿐 아니라 19세기 중반 이 후 사탕수수 산업의 호황으로 가속화되어온 세계 여러 지역으로부터의 하와이로의 노동이주 물결은 동서문명 조우의 공간이자 다문화주의의 중 심지로서의 발전을 추동케 했다. 이처럼 하와이는 주민들의 상대에 대한 포용과 이해를 바탕으로 한 환대정신과 하와이 관광 산업의 중심축을 구 성하는 환대산업과 더불어 하와이 특유의 문화다양성이 잘 어우러져 세 계적인 환대도시로서의 입지를 공고히 해 왔다. 본 연구는 이러한 하와 이의 관광·다문화를 중심으로 한 환대성의 이면에 교묘한 군사주의와 식 민주의로 대변되는 적대성이 존재한다는 사실을 비판적으로 성찰하였다. 미국은 1893년 하와이를 점령하였으며, 1941년 진주만 피습 이후 이 사 건을 하와이 역사의 중추적 내러티브로 재구성하며 진주만, 특히 USS Arizona 기념관이 하와이의 주력 관광상품으로 발돋움하게 되었다. 이를 통해 그 이면에 은폐된 미국의 군사주의와 원주민의 주권 상실의 역사를 교묘하게 감추어왔다. 또한 본 연구는 하와이를 표상하는 다문화주의의 배경을 환태평양 지역의 제국주의와 식민주의적 맥락에서 고찰하였다. 하와이 왕국을 전복시킨 미국 본토에서 넘어온 백인들은 하와이 사탕수 수 산업을 장악하였고, 이에 따라 값싼 아시아계 노동이민자들의 원활한 정착을 위해 다문화주의를 의도적으로 전파한 정착형 식민주의를 주목할 필요가 있다.

Carbonates are inorganic ligands that are abundant in natural groundwater. They strongly influence radionuclide mobility by forming strong complexes, thereby increasing solubility and reducing soil absorption rates. We characterized the spectroscopic properties of Am(III)-carbonate species using UV-Vis absorption and time-resolved laser-induced fluorescence spectroscopy. The deconvoluted absorption spectra of aqueous Am(CO3)2 − and Am(CO3)3 3− species were identified at redshifted positions with lower molar absorption coefficients compared to the absorption spectrum of aqua Am3+. The luminescence spectrum of Am(CO3)3 3− was red-shifted from 688 nm for Am3+ to 695 nm with enhanced intensity and an extended lifetime. Colloidal Am(III)-carbonate compounds exhibited absorption at approximately 506 nm but had non-luminescent properties. Slow formation of colloidal particles was monitored based on the absorption spectral changes over the sample aging time. The experimental results showed that the solubility of Am(III) in carbonate solutions was higher than the predicted values from the thermodynamic constants in OECD-NEA reviews. These results emphasize the importance of kinetic parameters as well as thermodynamic constants to predict radionuclide migration. The identified spectroscopic properties of Am(III)-carbonate species enable monitoring time-dependent species evolution in addition to determining the thermodynamics of Am(III) in carbonate systems.

본 연구는 반도체 제품과 설비기술을 대상으로 제품-공정기술 공진화를 교차영향분석(cross impact analysis)을 통해 구체화하고, 공진화 관계를 기술 인텔리전스의 대표적 도구 중 하나인 기술레이더에 통합하는 방법을 제시한다. 교차영향분석을 통해 공정기술 발전과 제품특성 개선이 반복되는 공진화 경로와 축이 되는 세부기술들을 파악했다. 또한 공진화 관계를 기술레이더의 기술가치평가 프로세스에 반영 해 가치평가와 연구개발 포트폴리오의 신뢰성을 제고했다. 학술적 측면에서 기술간 공진화를 세부기술 단위에서 구체화했으며, 기술 공진화 이론과 기술 인텔리전스의 접점을 제시했다는 의미가 있다. 실무적 측면에서는 반도체 관통전극-하이브리드 패키지 제품과 주요 후공정 기술간 공진화 및 기술레이더 분석 실례를 제시하고, 이를 통해 기술간 공진화 관계를 기존 기술전략 및 기획도구에 반영 해 기업의 미래준비역량과 전략기획의 신뢰성을 제고하는 방법을 구체화했다는 점에서 가치가 있다.

In the Ti(CN)-Co/Ni cermet, WC is an effective additive for increasing sinterability and mechanical properties such as toughness and hardness. In this work, WC, (WTi)C and (WTi)(CN) were used as the source of WC and their effects were investigated in the respect of microstructural evolution and mechanical properties. Regardless of the kinds of WC sources, the hard phase with dark core and bright rim structure was observed in the Ti(CN)-Co/Ni cermet under the incorporation of relatively small amount of WC. However, hard phases with bright core began to appear and their frequency increased with the increase of all kinds of WC source addition. The ratio of bright core to dark one in the (TiW)(CN)-Co/Ni cermet was greatest under the incorporation of (WTi)C compared at the same equivalent amount of WC. The mechanical properties were improved with the addition of WC irrespective of the kinds of sources, but the addition of (WTi)(CN) was less effective for the increase of fracture toughness.

The microstructure evolution during sintering of a compact being composed of three layers of (WC-15%Co)/Fe powder mixture with different Fe contents has been observed. The Fe contents in the respective (WC-15%Co)/Fe layers were varied by 20%. 50%, and 90% in sequence by volume from a top layer to a bot- tom layer. The sintering temperatures and times were varied from 110 to 125 and from 1 h to 4 h, The compact layer was not densified below 120 in 4 h. Appropriate sintering temperature and time conditions for making a multi-layered hard metal compact were determined as 125 and 3 h, respectively.