Large-area graphene of the order of centimeters was deposited on copper substrates by low-pressure chemical vapor deposition (LPCVD) using hexane as the carbon source. The effect of temperature and the carrier gas flowrates on the quality and uniformity of the as-deposited graphene was investigated using the Raman analysis. The film deposited at 870 °C with a total carrier gas flowrate of 50 sccm is predominantly single-layer with very low defects according to the Raman spectra. The 2D/G peak intensity ratios obtained from the Raman spectra of samples from three different locations of graphene deposited on a whole copper catalyst was used to calculate the large-area uniformity. Based on the results, a very high uniformity of 89.6% was calculated for the graphene deposited at 870 °C. The uniformity was observed to decrease with increasing temperature. Similar to the thickness uniformity, the electrical conductivity values obtained as a result of I–V measurements and water contact angle measurements were found to be close to each other for the graphene deposited under the same deposition conditions.
The purpose of this study is to experimentally figure out thermal performances of a newly developed wavy patterned heat plates(first heat plates) which are known to have better thermal performances than the conventional heat plates. Three types of products were made with high and low chevron angled plates. The test results show that overall heat transfer coefficients and pressure drops increased with flow rates and chevron angles just like other studies. Another purpose of this study is to find a way to reduce pressure drops while maintaining or even improving the heat transfer characteristics of the first heat plates. Research on optimization of the distribution area on the heat plate to achieve the even fluid distribution was conducted, and then the second heat plates were developed to reflect the research results. Another new three types of products with the second heat plates were manufactured and tested, too. The test results of the second heat plates were compared with those of the first heat plates to find out how the distribution area contributed to the thermal performances of the heat plates. The comparison showed that distribution area optimization could affect thermal performances of the high chevron angled plate positively, but the low chevron angled plate had little effect from the optimization. This is considered to be because the low chevron angled plate itself has a characteristic that the pressure drop is small.
본 연구는 전남 광양시 백운산의 조릿대 개화지에서 외적 환경인자가 개화원인으로 작용하는가를 조사했다. 이를 토대로 조릿대의 개화원인, 개화양식 및 생활사 전략을 고찰했다. 조릿대 개화지와 비개화지 사이의 토양・물리적 조건・광량 차이는 없었다. 2014~17년 사이에 조릿대가 개화했던 한국과 일본 개화지의 강수량・기온은 평년치(과거 30년)와 다른 특이점을 찾을 수 없었다. 또한 대면적으로 조릿대가 꽃을 피운 후에 대부분 죽었으나 일부 조릿대 간이 다시 발생하기도 하고 일부는 죽지 않았다. 즉, 조릿대는 외적 환경인자와 상관없이 일제히 개화했으며, 대부분의 조릿대 간은 죽지만 일부는 살아남았다. 이는 조릿대 개화원인은 외적 환경인자 영향보다 생물시계에 따라 주기적으로 발현하는 특정 유전자(일명, 유전자 시계)로 촉발된다고 본다. 한편, 멀리 떨어져 있는 조릿대 개체와 동조해 꽃을 대규모로 피우며, 소규모 단독으로 여러 번 개화하기도 한다. 이것은 평생 한 번 개화하는 조릿대의 유성번식 실패 리스크를 분산하기 위한 일종의 보험시스템이라고 판단된다. 열대성 대나무・조릿대류가 온대로 분포를 넓히면서 환경 의 불확실성 증가에 따른 유성번식의 최적화를 위해 장주기 단개화성이 강화된 것으로 추정된다.
When taking X-ray, Some of them are not only absorbed as they pass through the body, but some are scattered and blurred. To prevent this problem, 'X-Ray Grid' was placed between the body and the film. Conventionally, in order to manufacture an X-ray grid, a lead sheet and an aluminum sheet were adhered with epoxy or the like, cut to a predetermined thickness, and formed in a line at a predetermined angle. New grids are actively being developed to solve this problem. In this study, Laser beam was irradiated on a photosensitive glass having high X-ray transmittance to form an oblique lattice type channel. When the photosensitive glass is exposed to Laser beam, Previous studies have shown that laser exposure to photosensitive glass reacts with UV-Laserto form high-precision microstructures. The photosensitive glass exposed by the laser is heat-treated at a high temperature to crystallize the exposed part. When the crystallized patterns are etched with a hydrofluoric acid liquid solution, a structure having a depth is completed. The completed structure is filled with metals with X-ray shielding properties. The angle of incidence can be processed up to 18, which is the angle of incidence of ordinary X-ray, The upper surface line width of theetched pattern is 20um or less and The depth of processing after etching was found to be more than 100um, which means 'the filler can be deposited sufficiently'.
Graphene-based derivatives such as graphene oxide(GO) have great potential as membrane material due to their controllable d-spacing, extremely large surface area and tunability of multifunctional groups. GO, highly oxidized graphene, has especially good affinity to CO2 arose from its oxide functional groups(e.g. carboxylic acid, hydroxyl groups) on 2-D nanosheet plane. Here, we synthesized GO/polymer composite materials and fabricated large-area thin film composite(TFC) membrane for CO2 separation using polymeric porous support. Further, we have produced flat-sheet membrane modules with the TFC membranes and tested the performance of the module under CO2/N2 mixed gas and flue gas conditions. The membrane module exhibited high CO2 separation performance as 74% of purity and 22% of recovery under flue gas condition including CO2, O2 and N2.