Nuclide separation of commercial nanofiltration (NF) & reverse osmosis (RO) membranes is investigated to elucidate the permeation mechanism and possibility on applying treatment of wastewater from nuclear facility. Since wastewater from nuclear facility contains significant amount of dangerous nuclides, their treatment for recycle or clearance is necessary. Polyamide based commercial membranes are prepared to investigate their separation performance on single- & multi-component nuclide aqueous solutions. Similar to their desalination performance, NF shows higher flux, but RO has high rejection. With respect to rejection, NF and RO membranes have better performance comparing to desalination. This study indicates that NF and RO membranes can be potential candidate for nuclide separation.

Radioactive liquid waste has given soil & water pollution and further congenital defect to the humanity. With this regard, there are lots of interests in reducing concentration of radioactive material even if it is in low level (ppm). There are filtration driven by pressure such as ultra-filtration, nano-filtration, and reverse osmosis to separate radioactive liquid waste. Among them, Nano-Filtration membrane shows promising performance in both permeability and selectivity. Commercial nanofiltration membrane were applied to separate model solutions. Model seawater was desalinated to 6,100 ppm with flux of 90 L/ ㎡h. On the other hands, Model nuclides (Co, Cs, and Sr) solutions are separated from 10 ppm to 2 ppm, 0.23 ppm, and 0.13 ppm. Commercial nanofiltration membranes show the trade-off property between selectivity and flux.

In the decommissioning site of Korean Research Reactor 1&2 (KRR-1&2), according to Low and Intermediate-level Radioactive Waste Disposal Acceptance Criteria of the Korea Radioactive Waste Agency (WAC-SIL-2022-1), characteristics of radioactive waste was conducted on approximately 550 drums of concrete and soil waste for a year starting from 2021. Among them, 50 drums of concrete waste transported and disposed to Gyeongju LILW disposal facility at the end of 2022. For the remaining approximately 500 drums of concrete and soil waste stored on-site, they were reclassified into two categories: permanent disposal grade and clearance grade. This classification was based on calculating the sum of fractions (SOF) per drum for each radionuclides. The plan is to dispose of around 200 drums in the permanent disposal grade and about 300 drums in the clearance grade by the end of 2023. Since concrete and soil decommissioning wastes are generated in large quantities over a short period with similar origins, they were grouped within five drums as suggested by the acceptance criteria. Mixed samples were collected from each group and used for radionuclide analysis. When utilizing mixed samples, three distinct samples are collected and analyzed for each group. The maximum value among these three radionuclide analysis results is then uniformly applied as the radionuclide concentration value for all drums within that group. Radioactive nuclides contained in similar types of radioactive waste with similar origins can be expected to have some statistical distribution. However, There has been no verification as to whether the maximum value among the three mixed samples exists within the statistical distribution or if it deviates from this distribution to represent a different value. In this study, we confirmed characteristics of radionuclide concentration distribution by examining and comparing radionuclide concentration distributions for radioactive wastes drum grouped for nuclear characteristic among 50 concrete wastes drum disposed in year 2022 and 500 concretes & soils drum scheduled for disposal (clearance or permanent disposal) in year 2023. In particular, when comparing tritium to other nuclides, it was observed that the standard deviation for the distribution of maximum values was approximately 318 times larger.

The safety of deep geological disposal systems has to be ensured to guarantee the isolation of radionuclides from human and related environments for over a million years. Over such a long timeframe, disposal systems can be influenced by climate change, leading to significant long-term impacts on the hydrogeological condition, including changes in temperature, precipitation and sea levels. These changes can affect groundwater flow, alter geochemical conditions, and directly/ indirectly impact the stability of the repository. Hence, it is essential to conduct a safety assessment that considers the long-term evolution induced by climate change. In this context, the Korea Atomic Energy Research Institute (KAERI) is developing the Adaptive Process-based total system performance assessment framework for a geological disposal system (APro). Currently, numerical modules for APro are under development to account for the longterm evolution that can influence groundwater flow and radionuclide transport in the far-field of the disposal system. This study focuses on the development of two numerical modules designed to model permafrost formation and buoyance force due to relative density changes. Permafrost is defined as a ground in which temperature remains below zero-isotherm (0°C) continuously for more than two consecutive years. In regions where permafrost forms, the relative permeability of porous media is significantly reduced. The changes in permeability due to permafrost formation are modelled by calculating the unfrozen fluid content within a porous medium. Meanwhile, buoyancy force can occur when there is a difference in density at the boundary of two distinct water groups, such as seawater (salt water) and freshwater. Sea level change associated with climate change can alter the boundary between seawater and freshwater, resulting in changes in groundwater flow. The buoyancy force due to relative density is modelled by adjusting concentration boundary conditions. Using the developed numerical modules, we evaluated the long-term evolution’s effects by analyzing radionuclide transport in the far-field of the disposal system. Incorporating permafrost and buoyancy force modelling into the APro framework will contribute valuable insights into the complex interactions between geological and climatic factors, enhancing our ability to ensure the secure isolation of radionuclides for extended periods.

Nuclear power is responsible for a large portion of electricity generation worldwide, and various studies are underway, including the design of permanent deep geological disposal facilities to safely isolate spent nuclear fuel generated as a result. However, through the gradual development of drilling technology, various disposal option concepts are being studied in addition to deep geological disposal, which is considered the safest in the world. So other efforts are also being made to reduce the disposal area and achieve economic feasibility, which requires procedures to appropriately match the waste forms generated from separation process of spent nuclear fuel with disposal option systems according to their characteristics. And safety issue of individual disposal options is performed through comparison of nuclide transport. This study briefly introduces the pre-disposal nuclide management process and waste forms, and also introduces the characteristics of potential disposal options other than deep geological disposal. And environmental conditions and possible pathways for nuclide migration are reviewed to establish transport scenarios for each disposal option. As such, under this comprehensive understanding, this study finally seeks to explore various management methods for high-level radioactive waste to reduce the environmental burden.

The separation efficiency of nuclides in molten salt systems was investigated, with a focus on the influence of apparatus configuration and experimental conditions. A prior study revealed that achieving effective Sr separation from simulated oxide fuel required up to 96 hours, reaching a separation efficiency of approximately 90% using a static dissolution reaction in a porous alumina basket. In this study, we explored the impact of agitation on improving Sr separation efficiency and dissolution rates. The simulated oxide fuel composition consisted of 2wt% Sr, 3wt% Ba, 2wt% Ce, 3wt% Nd, 3wt% Zr, 2wt% Mo, and 89wt% U. To quantify the Sr concentration in the salt, we utilized ICP analysis after salt sampling via a dip-stick technique. Furthermore, we conducted ICPOES analysis over a 55-hour duration to assess the separated nuclides. Complementing these analyses, SEM and XRD investigations were performed to validate the crystal structure and morphology of the oxide products.

Spent nuclear fuel continues to be generated domestically and abroad, and various studies are actively being conducted for interim dry storage and disposal of spent nuclear fuel. The characteristics vary depending on the type of spent nuclear fuel and the initial specifications, and based on these characteristics, it is essential to estimate the burnup and enrichment of spent nuclear fuel as a nondestructive assay. In particular, it is important to estimate the characteristics of spent nuclear fuel with non-destructive tests because destructive tests cannot be performed on all encapsulated spent nuclear fuel in case of intrusion traces in safeguards. Data is made by measuring spent nuclear fuel directly to evaluate burnup of spent nuclear fuel, but computer simulation research is also important to understand its characteristics because past burnup history is not accurately written, and destructive testing is difficult. In Sweden, the dependency of the burnup history in source strength and mass of light-water reactor-type spent nuclear fuel was evaluated, and this part was also applied to MAGNOX in consideration of the possibility of being used to verify DPRK’s denuclearization. SCALE 6.2 TRITON modeling was performed based on public information on DPRK’s 5 MWe Yongbyon reactor, and the source strength of Nb-95, Zr-95, Ru-106, Cs-134, Cs-137, Ce-141, Ce- 144, Eu-154 nuclides were evaluated. Since the burnup of MAGNOX is lower than that of lightwater reactors, major nuclides in decay heat were not considered. The cooling period was evaluated based on 0, 5, 10, and 20 years. In case the discharge timing was different, the total period of discharge and reloading was the same, and the end-cycle burnup was the same, calculations showed that the source strength emitted from major nuclides was evaluated within 2-3% except for Ru-106 and Ce-144 nuclides. Even the burnup step of nuclear fuel is the same, and the reloaded length after discharge is different, i.e., the cooling period between is different at 5, 10, and 20, the source strength of Nb-95, Zr-95, Ce-144, and Cs-137 was evaluated as an error of 1%. Except for Ru-106 and Ce-144, nuclides are highly dependent on burnup. Compared to the case of light-water reactors, the possibility of a decrease in error needs to be considered later because the specific power is low. As a result, radionuclides in released fuel depend on the effects of burnup, discharged and reloaded period, and a cooling period after release, and research is needed to correct the cooling period within the future burnup history. In addition, in this study, it is necessary to select a scenario -based burnup because the standard burnup due to the statistical treatment of discharged fuels was not considered as conducted in previous studies.

Many radionuclides emit two or more gamma rays in a cascade once they decay. At this time, gamma rays are detected at the same time, and the signals are overlapped and measured as one added signal. This is called the summing coincidence effect, and it causes an error of more than 10% depending on the detection efficiency, measurement conditions, and target nuclide. It is known to be greater as the efficiency of the detector increases and as the distance between the source and the detector decreases. It is necessary to consider the summing coincidence effect since the efficiency of the HPGe detector owned by the KHNP CRI is as high as 65%. In this study, We would like to propose an appropriate gamma nuclide analysis method for radioactive waste generated from NPP by evaluating the influence on the summing coincidence effect.

The segmentation of activated components is considered as a one of the most important processes in decommissioning. The activated components, such as reactor vessel and reactor vessel internals, are exposed to neutron from the nuclear fuel and classified to intermediate, low, and very low-level wastes. As it is expected, the components, which are closed to nuclear fuel, exhibit higher degree of specific activity. After the materials were exposed to neutrons, their original elements transform to other nuclides. The primary nuclides in activated stainless steel are 55Fe, 63,59Ni, 60Co, 54Mn, etc. The previous study indicates that the specific activity of individual nuclide is strongly depends on the material compositions and impurities of the original materials. The 59Co is the one of the most important impurities in stainless steel and carbon steel. In this paper, the relationship between individual nuclides in activation analysis of activated components was studied. The systematic study on specific activity of primary nuclides will be discussed in this paper to understand the activation tendency of the components.

With the increasing demand for a repository to safely dispose of high-level radioactive waste (HLW), it is imperative to conduct a safety assessment for HLW disposal facilities for ensuring the permanent isolation of radionuclides. For this purpose, the Korea Atomic Energy Research Institute (KAERI) is currently developing the Adaptive Process-based total system performance assessment framework for a geological disposal system (APro). A far-field module, which specifically focuses on fluid flow and radionuclide transport in the host rock, is one of several modules comprising APro. In Korea, crystalline rock is considered the host rock for deep geological disposal facilities due to its high thermal conductivity and extremely low permeability. However, the presence of complex fracture system in crystalline rock poses a significant challenge for managing fluid flow and nuclide transport. To address this challenge, KAERI is participating in DECOVALEX-2023 Task F1, which seeks to compare and verify modeling results using various levels of performance assessment models developed by each country for reference disposal systems. Through the benchmark problems suggested by DECOVALEX-2023 Task F1, KAERI adopts the Discrete Fracture-Matrix (DFM) as the primary fracture modeling approach. In this study, the transport processes of reactive tracers in fractured rock, modeled with DFM, are simulated. Specifically, three different tracers (conservative, decaying, adsorbing) are introduced through the fracture under identical injecting conditions. Thereafter, the breakthrough curves of each tracer are compared to observe the impact of reactive tracers on nuclide transport. The results of this study will contribute to a better understanding of nuclide behavior in subsurface fractured rock under various conditions.

The design of a radioactive waste disposal system should include both natural and engineered barriers to prevent radionuclide leakage and groundwater contamination. Colloids and gases can accelerate the movement of radionuclides and affect their behavior. It is important to consider these factors in the long-term stability evaluation of a deep geological repository. An experimental setup was designed to observe the acceleration of nuclide behavior caused by gas-mediated transport in a simulated high temperature and pressure environment, similar to a deep disposal repository. The study used specimens to simulate gas flow in engineered barriers, based on conditions 1000 years after repository closure. In the experiment, bentonite WRK with a dry density of 1.61 g/cm3 was used after compaction. Measurements were taken of the saturation time and gas permeability of compacted bentonite. In this study, gas was injected into saturated buffer materials at various pressures to evaluate the penetration phenomenon of the buffer material according to the gas pressure. It was observed that gas penetrated the buffer material and moved upward in the form of gas bubbles at a specific pressure. Furthermore, when a flow was continuously induced to penetrate the buffer material, erosion occurred, and the eroded particles were found to be able to float upward or be transported by gas bubbles. In future studies, analysis will be conducted on the transport rate of fine particles according to the size of gas bubbles and the characteristics of the nuclides adsorbed on the fine particles.

Separating nuclides from spent nuclear fuel is crucial to reduce the final disposal area. The use of molten salt offers a potential method for nuclide separation without requiring electricity, similar to the oxide reduction process in pyroprocessing. In this study, a molten salt leaching technique was evaluated for its ability to separate nuclides from simulated oxide fuel in MgCl2 molten salts at 800°C. The simulated oxide fuel contained 2wt% Sr, 3wt% Ba, 2wt% Ce, 3wt% Nd, 3wt% Zr, 2wt% Mo, and 89wt% U. The separation of Sr from the simulated oxide fuel was achieved by loading it into a porous alumina basket and immersing it in the molten salt. The concentration of Sr in the salt was measured using ICP analysis after sampling the salt outside the basket with a dip-stick technique. The separated nuclides were analyzed with ICP-OES up to a duration of 156 hours. The results indicate that Ba and Sr can be successfully separated from the simulated fuel in MgCl2, while Ce, Nd, and U were not effectively separated.

From Fukushima nuclear disaster, as the water which is supplied by rain and groundwater flow into reactor building, contaminated water which contains radioactive nuclides is occurred. Although about 600 tons of contaminated water was generated at the early of accident, as the groundwater management system is developing, about 150 tons of contaminated water is generated now. Tokyo Electric Power Holdings (TEPCO) operate a multi-nuclide removal equipment which is called ‘ALPS’ and store purified water (ALPS treated water) in the Fukushima NPP site by tank. From 2023, the Japanese government decided to dilute the stored ALPS treated water and discharge it into the ocean to secure space on the site. In this study, based on the data opened to the public by TEPCO, the current status of ALPS is investigated. The dilution and discharge process under conceptual design was investigated. In addition, the treatment capacity of ALPS was analyzed based on the radioactivity concentration data of 7 nuclides. And then, two points to be checked found. First, it was confirmed that the performance of ALPS temporarily decreased between 2015 and 2018 due to reduced replacement cycle of filter and absorbent. Second, it was confirmed that the ALPS treated water from specific ALPS still haven’t satisfied the discharge limit for I-129, Sr-90, and Cs-137. In the case of Cs-137, about 1.7 times the radioactivity concentration was detected compared to the discharge limit. For I-129 and Sr-90, about 2.4 times and 2.1 times of radioactivity concentration was detected compared to the discharge limit. From this study, some of the ALPS treated water are confirmed that the radioactivity concentration exceeds the discharge limit, and the treatment capacity of ALPS might be unstable depend on the ALPS operation such as replacement cycle. Therefore, before the discharging of contaminated water on 2023, it is necessary to inspect ALPS if it purifies contaminated water with reliability or not, and to secure the reliable evaluation method to measure radioactivity concentration.

To minimize the short-term thermal load on the repository facility, heat generating nuclides such as Cs-137 and Sr-90 should be separated from the spent nuclear fuel for efficiency of repository facility. In particular, Sr-90 must be separated because it generates high heat during the decay process. Recently, Korea Atomic Energy Research Institute (KEARI) is developing a waste burden minimization technology to reduce the environmental burden caused by the disposal of spent nuclear fuel and maximize the utilization of the disposal facility. The technology includes a nuclide management process that can maximize disposal efficiency by selectively separating and collecting major nuclides such as Cs, Sr, I, TRU/RE, and Tc/Se from spent nuclear fuel. Among the major nuclides, Sr nuclides dissolve in chloride phase during the chlorination process of spent nuclear fuel and recovered in the form of carbonate or oxide via reactive distillation. In this process, Ba nuclides are also recovered along with Sr nuclides due to their chemical similarity. In this study, we prepared group II nuclide ceramic waste form, Ba(x)Sr(1-x)TiO3 (x=0, 0.25, 0.5, 0.75, 1), using the solid-state reaction method by considering the various ratio of Sr/Ba nuclides generated from nuclide management process. The established waste form fabrication process was able to produce a stable waste form regardless of the ratio of Sr/Ba nuclides. To evaluate the stability of group II waste form, physicochemical properties such as leaching and thermal properties were evaluated. Also, the radiological properties of the Ba(x)Sr(1-x)TiO3 waste forms with various Sr/Ba ratios were evaluated, and the estimation of centerline temperature was carried out using the experimental thermal property data. These results provided fundamental data for long-term storage and management of group II nuclides waste form.

The nuclide management technology for separating high-heat generating/high-mobility/long-lived nuclides from high-level wastes based on the chemical reactions is under development. In order to secure the reliability of nuclear non-proliferation and to implement the effective safeguards, it is necessary to consider the safeguards from the conceptual design phase of the novel technologies. However, there was no experience and research on safeguards for the chemical reaction based nuclide management technology. In order to development the available monitoring techniques for the safeguards of nuclide management technology, the possible diversion scenarios were developed and the material flows of major nuclear materials were analyzed according to the various diversion strategies for each unit process in this study. The diversion strategies in this study is limited to the diversion of nuclear materials according to the change of operational parameters (temperature, chemical reagents, pressures, etc). The nuclear material distribution behaviors under the abnormal conditions were analyzed and compared with normal conditions using the HSC Chemistry. The results will be used to determine the proper signals and feasible techniques to monitor the abnormal operations.