This paper presents a computational fluid dynamics (CFD) analysis to investiagate the effect of expansion chamber on overpressure reduction in protective tunnels subjected to detonation of high explosives. A commercial CFD code, Viper::Blast, was used to model the blast waves in a protective tunnel with a length of 160 m, width of 8.9 m and height of 7.2 m. Blast scenarios and simulation matrix were establihsed in consideration of the design parameters of expansion chamber, including the chamber lengths of 6.1 m to 12.1 m, widths of 10.7 m to 97 m, length to width ratios of 0.0 to 5.0, heights of 8.0 m and 14.9 m, and ratios of chamber to tunnel width of 1.2 to 10.9 m. A charge weight of TNT of 1000 kg was used. The mesh sizes of the numerical model of the protective tunnel were determined based on a mesh convergence study. A parametric study based on the simulation matrix was performed using the proposed CFD tunnel model and the optimized shape of expansion chamber of the considered tunnel was then proposed based on the numerical results. Design recommendations for the use of expansion chamber in protective tunnel under blast loads to reduce the internal overpressures were finally provided.

Hispidin is a secondary metabolite found in numerous medicinal mushrooms that has attracted significant attention, owing to its distinct biological effects, including antioxidant, anti-inflammatory, antitumor, and cytoprotective properties. Experiments are being carried out to study the interaction of detonation nanodiamonds (DNDs) with synthetic and natural hispidin sourced from extracts of Pholiota sp. fungus. The bioluminescence method is used to determine the adsorption/ desorption properties of DNDs toward hispidin. It is found that hispidin forms strong conjugates with DNDs, and the use of various eluents does not result in a significant release of the adsorbed hispidin molecules. DND-bovine serum albumin (BSA) complex, where DNDs serve as a carrier for the protein and the latter acts as a hispidin sorbent, has been developed and applied in hispidin adsorption/desorption tests. The results support the use of the DNDs as a carrier for hispidin in medical applications. They also advocate the application of the DND-BSA complex for isolating the substance from fungal extracts.

압력용기의 내압은 압력용기 설계의 중요한 인자이며 이를 바탕으로 관련 설계기준 및 구조해석결과에 따라 압력용기의 두께 및 직경과 같은 기하학적 형상이 결정된다. 그러나 압력용기 내부에서 폭굉이 일어날 경우 이 폭굉압력을 적절히 고려 하여 압력용기를 설계할 수 있는 설계기준은 미흡한 실정이다. 일반적으로 폭굉이 발생할 경우, 초기 폭굉압력이 용기 벽면에 도달하여 반사하는 반사압력은 초기압력의 2배 이상이라고 알려진다. 그러나 폭굉압력은 구조물의 고유주기보다도 짧은 시간 안에 최대치에 도달한 후 급격하게 감소하는 경향을 보이며, 이 경우 실제 용기벽면이 받게 되는 압력은 반사압력에 비해 매우 작을 수 있다. 따라서 본 연구에서는 이러한 폭굉의 특성을 고려하여 압력용기가 견뎌야 하는 적절한 등가의 폭굉압 력을 산정하는 방법을 제안함으로써 폭굉을 고려한 효율적인 압력용기 설계기준을 제시하고자 하였다.

In the present work, physicochemical treatments were introduced for de-aggregation and stable dispersion of detonation nanodiamonds (DND) in polar solvents. The DNDs in water exhibited a particle size of 138 nm and high dispersion stability without particular treatment. However, the DNDs in ethanol were severely aggregated to several micrometers in size and showed poor dispersion stability with time. To break down aggregates of DNDs and enhance the dispersion stability of them in ethanol, mechanical force and chemical surfactant were introduced as functions of zirconia ball size, kind of surfactant and amount of surfactant added. From the analyses of average particle size and Turbiscan results, it was suggested that the size of DNDs in ethanol can be reduced by only mechanical force; however, the DNDs were re-aggregated due to high surface activity. The long-term dispersion stability can be achieved by applying mechanical force to break down the aggregates of DNDs and by preventing re-aggregation of them using proper surfactant.

Colloidal stability is one of crucial factors for many applications of nanodiamond. Despite recent development, nanodiamonds available on the market often exhibit a high impurity content, wide size distribution of aggregates and low resistance to sedimentation. In the current study, four commercial nanodiamond powders synthesized by detonation synthesis were surface modified and then separated with respect to the size into six fractions by centrifugation. The fractions were evaluated by zeta potential, particle size distribution and elemental composition. The results showed that the modified nanodiamonds form stable colloidal suspensions without sedimentation for a long time.

본 연구에서는 다양한 RC 슬래브의 접촉 발파 실험을 수행하여 내폭 성능을 평가하였다. RC 슬래브의 내폭 성능 향상을 위해 섬유 보강과 외부 CFRP 시트 보강을 도입하였다. 폭발하중 실험은 2,000×1,000×100mm RC 슬래브를 제작하였고, 일반 콘크리트와 강섬유 보강 콘크리트, 하이브리드 PVA 섬유 보강 시멘트 복합체, 초고성능 콘크리트를 적용하였다. 접촉 발파로 생긴 RC 슬래브의 손상 정도를 크레틀, 스폴과 브리치의 직경과 깊이로 평가하였다. 실험 결과를 LS-DYNA 유한요소해석 프로그램과 Morishita 등의 예측식으로 검증하고 비교분석하였다. 분석 결과, LS-DYNA 프로그램을 이용하여 크레틀, 스폴, 브리치의 직경 및 깊이에 대한 개략적인 예측이 가능하며, 폭발하중 하에서 손상부의 거시적 거동을 모사함으로써 부재의 파괴 이력을 나타낼 수 있었다. 국부 손상에 대한 세가지 예측식이 소개되어 있으나 경험식으로써의 한계가 존재하며, 이에 대한 추가 연구가 필요하다고 판단된다.