본 연구는 도로 노면의 결빙을 방지하기 위해 열적 특성을 갖는 콘크리트를 개발했습니다. 팽창 점 토에 상변화 물질(PCM)을 함침 시키고, 고열 전도성 에폭시와 실리카 흄으로 이중코팅을 하여 PCM 물질의 유출 방지, 골재의 부착성 개선, 열적 성능 개선을 하였으며 이를 DSC를 통해 열적 성능 평가 를 진행하여 확인했습니다. 또한 상변화 물질과 경량골재의 사용으로 인한 강도 감소 개선을 위한 CNT 혼합으로 강도 감소를 25% 개선하였습니다.

상변화 물질(PCM)은 상전이 동안 에너지를 흡수하거나 방출할 수 있는 잠열 저장 물질로 활용된다. 최근 수십 년 동 안, 연구자들은 다양한 온도 적용을 위한 건설 물질로의 다양한 PCM의 통합을 탐구해 왔다. 그러나, PCM을 통합하는 콘크리트 의 기계적 및 열적 반응은 통합 방법에 의해 영향을 받는다. PCM을 콘크리트에 추가하기 위한 여러 기술이 제안되었다. 그럼 에도 불구하고, 콘크리트에 마이크로 캡슐화 PCM(m-PCM)의 통합은 종종 기계적 강도의 상당한 감소를 초래한다. 기존 콘크리 트에 m-PCM의 추가와 관련된 한계를 극복하기 위해, 예외적인 강도 및 내구성 특성으로 인해 초고성능 시멘트 복합체(UHPCC) 가 선호된다. 따라서, 본 연구에서는 기존 기술의 단점을 해결하기 위해 PCM을 통합한 신규 나노 엔지니어링 UHPCC를 개발하 였다. 또한, 시멘트 복합체의 기계적 및 열적 성능을 향상시키기 위해 다중 벽 탄소 나노튜브(MWCNT)를 추가하였다. 결과는 MWCNT의 포함이 기계적 성능을 향상시켰을 뿐만 아니라 시멘트 복합체의 열적 성능을 향상시켰다는 것을 보여 주었다.

Yttria-stabilized zirconia (YSZ) has a low thermal conductivity, high thermal expansion coefficient, and excellent mechanical properties; thus, it is used as a thermal barrier coating material for gas turbines. However, during long-time exposure of YSZ to temperatures of 1200oC or higher, a phase transformation accompanied by a volume change occurs, causing the YSZ coating layer to peel off. To solve this problem, YSZ has been doped with trivalent and tetravalent oxides to obtain coating materials with low thermal conductivity and suppressed phase transformation of zirconia. In this study, YSZ is doped with trivalent oxides, Nd2O3, Yb2O3, Al2O3, and tetravalent oxide, TiO2, and the thermal conductivity of the obtained materials is analyzed according to the composition; furthermore, the relative density change, microstructure change, and m-phase formation behavior are analyzed during long-time heat treatment at high temperatures.

This study reassess safety margin of the current Peak Cladding Temperature (PCT) limit of dry storage in terms of hydrogen migration by predicting axial hydrogen diffusion throughout dry storage with respect to wet storage time and average burnup. Applying the hydride nucleation, growth, and dissolution model, an axial finite difference method code for thermal diffusion of hydrogen in zirconium alloy was developed and validated against past experiments. The developed model has been implemented in GIFT – a nuclear fuel analysis code developed by Seoul National University. Various discharge burnups and wet storage time relevant to spent fuel characteristics of Korea were simulated. The result shows that that the amount of hydrogen migrated towards the axial end during dry storage for reference PWR spent fuel is limited to ~50 wppm. This result demonstrates that the current PCT margin is sufficient in terms of hydrogen migration.

PURPOSES : This study aims to determine the type (e.g., melting point, freezing point, latent heat fusion) and optimal content of phase change material (PCM) based on the numerical and experimental analyses evaluating the effects of heat transfer in PCM-modified asphalt pavement systems. METHODS : The effect of PCM on the thermophysical properties of PCM-modified asphalt concrete can be taken as an effective volumetric heat capacity. The volumetric fraction of PCM was calculated using an iterative method. The numerical model was established and computed using the MATLAB 2020 software. The optimum PCM design tool was developed to select the type and contents of the PCM. The PCM was chosen based on the following criteria: black-ice-formation delay time, minimize temperature increase, and increase temperature area. To validate the numerical model, asphalt mixtures were modified with varying PCM contents, and the temperature response of the PCMmodified asphalt samples was examined via temperature test. RESULTS : The numerical results showed that incorporating PCM into the asphalt mixture can slow the cooling rate of the pavement system. The predicted results from the optimum PCM design tool were highly consistent with the measured values from the laboratory temperature test. CONCLUSIONS : The temperature of PCM-modified asphalt pavement can be predicted via numerical method. The effect of PCM on the thermophysical properties can be considered as effective volumetric heat capacity; while the volume fraction of PCM can be calculated via an iterative method. The accuracy of the numerical model was confirmed by a high agreement between the measured and predicted values.

In order to effectively utilize thermal energy, we analyzed the performance of the high efficiency latent heat storage system which can be used for greenhouse heating by using the developed phase change material. The system consists of hot water boiler, heat storage material, heat storage box, heat storage tank, circulation pump, control panel, and storage material. As a result, the latent heat and latent heat temperature of sodium acetate hydrate as latent heat storage material are 231.6 ~ 264.8kJ/kg, 54.95 ~ 55.48℃. As the number of cooling and heating increased, the latent heat temperature showed a slight change, but the latent heat decreased 33.1kJ/kg as the number of repetition increased. In the case of sodium acetate hydrate, large supercooling phenomenon was observed, and it was found that mixing of additives such as nucleating agent, thickener and supercooling agent can control the supercooling more effectively. The consumption of kerosene decreased until the temperature of the heat storage tank was raised to the set temperature by the closed circuit for 4 hours in the initial stage of the boiler operation. The heat exchange rate according to the change of the flow rate was maintained at the set temperature inside the heat storage tank after 4 hours of operation, Consumption was high. As the flow rate increased, the inlet and outlet temperature difference decreased, the heat exchange rate increased, and the heat exchange efficiency was in the range of 57.4 ~ 60.5%.

이 연구의 목적은 초등학교 6학년 학생들의 달의 위상 변화에 대한 학습 발달과정을 천문학적 시스템 사고를 기반으로 탐색하는 것이다. 선행 연구 결과 분석을 통해 서답형 문항을 개발하고 가설적 학습 발달과정을 설정하였으며, 이를 토대로 문항 분석틀을 개발하였다. 달의 위상 변화에 대한 수업을 실시하기 전과 후에 서답형 문항을 이용한 검 사 자료를 수집하였으며, 평가 결과를 이용하여 가설적 학습 발달과정의 타당성을 검증하였다. 이를 통하여, 상향식으로 지구-달계에 대한 학습 발달과정을 탐색할 수 있었다. 연구 결과, 초등학생들은 지구 기반 관점과 우주 기반 관점 사 이의 사고 전환에 어려움을 겪는 것으로 보인다. 또한, 달의 위상 변화에 대한 초등학생들의 학습 발달과정을 근거로 할 때, 달의 위상 변화의 개념은 교육과정 상에서 초등학교의 학습 내용으로 다소 높은 수준인 것으로 판단된다.

본 논문은 육해상의 운송장치에 축냉시스템을 적용시키기 위한 기초 연구이다. 또한, 축냉재의 고액상변화에 대한 수치해석을 수행한 연구이다. 수치해석법으로는 유한차분법(Finite-Difference Method)을 이용하였으며, 1차원 비정상의 상태를 가정하여 계산하였다. 또한 용기는 직사각형의 구형용기로 가정하여 대칭의 조건을 이용하였다. 축냉을 목적으로 사용하는 열매체는 염화칼슘 수용액(CaCl₂) 30wt%의 물성치를 사용하여 계산을 수행하였다. 계산에 영향을 미치는 요소로는 냉동고의 냉기 온도 및 냉기 유속이 있으며, 축냉재를 싸고 있는 용기는 플라스틱으로 가정하였다. 본 수치해석에서 경계층의 두께는 냉기의 속도 증가와 함께 얇게 되고 축열시간도 짧아지는 것을 확인할 수 있었다. 그리고 냉기의 유속이 빨라질수록 열전달이 촉진되어 축냉용기 전면부에서의 온도가 낮아짐을 알았다. 축냉용기의 후면부에서는 경계층이 두꺼워져 열전달이 전면부에 비해 작아짐을 알았다.

The environment and requirements of modern war fields have been affected and thus changed by a variety of issues. To this end, the development of safety-critical weapon systems frequently need to meet those changes even in the operational phase. The necessity of the changes may be due to the preparation for mass-production or the request originated from the user military forces. To meet such a need can be even tougher in the development of safety-critical weapon systems since the integration of the requirements for both systems design and systems safety would make it troublesome. To handel the matter in this paper, utilization of architecture DB is proposed. Specifically, the situation in demand has first been analyzed and then a problem-solving process to accommodate the design changes has been constructed. In doing so, the concept of the aforementioned integration is particularly focused on the functional architecture, which could be a core concept of our approach to solving the problem. The result of a case study demonstrating the method studied using a computer-aided systems engineering tool is also presented.

극저온 액체 상태의 LNG는 주거용과 산업용으로 공급되기 전에 가스 상태로 변환된다. 이러한 재가스화 과정 중에 LNG는 83.7×104 kJ/kg 정도의 많은 냉열에너지를 제공한다. 이 냉열에너지를 일부 선진국들에서는 질소, 수소, 헬륨과 같은 극저온 유체들의 액화, 제빙 및 냉방시스템에 이용하고 있다. 따라서 우리나라에서도 인천, 평택 및 통영 LNG 인수기지 주변에 LNG의 냉열에너지를 이용한 냉열에너지 회수시스템을 설립할 필요가 있다. 여기서는 저열유속상태에서 상변화를 동반하는 LNG의 유동거동 특성을 파악하기 위해 LNG의 85 %를 차지하는 메탄을 작동유체로 사용하였다. 또한 본 논문은 극저온 열교환기 내부를 흐르는 메탄과 질소, 프로판, R11 및 R134a의 유동경계에 영향을 주는 관 직경, 관의 경사각도 및 포화압력의 효과를 보여준다. 또한 여기서 얻어진 이론적 연구결과와 기존의 실험 데이터와도 비교 되었다. 그리고 메탄의 유동경계에 주는 파이프의 경사각도의 영향은 매우 큼을 알 수 있었다.

SnxSe100-X (15|X|30) alloys have been studied to explore their suitability as phase change materials for nonvolatile memory applications. The phase change characteristics of thin films prepared by a Radio Frequency (RF) magnetron co-sputtering system were analyzed by an X-ray diffractometer and 4-point probe measurement. A phase change static tester was also used to determine their crystallization under the pulsed laser irradiation. X-ray diffraction measurements show that the transition in sheet resistance is accompanied by crystallization. The amorphous state showed sheet resistances five orders of magnitude higher than that of the crystalline state in SnxSe100-X (x = 15, 20, 25, 30) films. In the optimum composition, the minimum time of SnxSe100-X alloys for crystallization was 160, 140, 150, and 30ns at 15mW, respectively. The crystallization temperature and the minimum time for crystallization of thin films were increased by increasing the amount of Sn, which is correlated with the activation energy for crystallization.

Electrical optical switching and structural transformation of Ge15Sb85, Sb65Se35 and N2.0 sccm doped Sb83Si17 were studied to investigate the phase change characteristics for PRAM application. Sb-based materials were deposited by a RF magnetron co-sputtering system and the phase change characteristics were analyzed using an X-ray diffractometer (XRD), a static tester and a four-point probe. Doping Ge, Se or Si atoms reinforced the amorphous stability of the Sb-based materials, which affected the switching characteristics. The crystallization temperature of the Sb-based materials increased as the concentration of the Ge, Se or Si increased. The minimum time of Ge15Sb85, Sb65Se35 and N2.0 sccm doped Sb83Si17 for crystallization was 120, 50 and 90 ns at 12 mW, respectively. Sb65Se35 was crystallized at 170˚C. In addition, the difference in the sheet resistances between amorphous and crystalline states was higher than 104Ω/γ.

Various kinds of Mg-Zn-Ca base alloys were rapidly quenched via melt spinning process. The meltspun ternary and quaternary alloy ribbons were heat-treated, and then the effects of additional elements on age hardening behavior and phase change of precipitates were investigated using Vickers hardness tester, XRD, and TEM equipped with EDS system. In ternary alloys, age hardening was mostly due to the distribution of and . The stable phases of precipitates were varied according to the aging temperature and the alloy composition. With the increase of Ca content, precipitates were detected more than precipitates. In quaternary alloys, the precipitates taken from Mg-Zn-Ca-Co were identified as new quaternary phase, whereas those taken from Mg-Zn-Ca-Zr as MgZnCa containing Zr. In general, the ternary alloy showed higher peak hardness and thermal stability than the quaternary considering the total amounts of the solutes. It implies that the structure of precipitate should be controlled to have the coherent interface with the Mg matrix.

Nanosized WC and WC-Co powders were synthesised by chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl(W(CO)) and cobalt octacarbonyl(Co(CO)). The microstructural changes and phase evolution of the CVC powders during post heat-treatment were studied using the XRD, FE-SEM, TEM, and ICP-MS. CVC powders were consisted of the loosely agglomerated sub-stoichimetric WC and the long-chain Co nanopowders. The sub-stochiometric CVC WC and WC-Co powders were carburized using the mixture gas of CH-H in the temperature range of 730-85. Carbon content of CVC powder controlled by the gas phase carburization at 85 was well matched with the theoretical carbon sioichiometry of WC, 6.13 wt％. During the gas phase carburization, the particle size of WC increased from 20 nm to 40 nm and the long chain structure of Co powders disappeared.