Molten salt immersion technique has been tested with several Sr oxides, SrZrO3, SrMoO4 and U2SrOy, and MgCl2 based molten salts for the Sr nuclide separation. Reaction time, temperature, and salt composition were varied to effectively separate Sr in chloride forms. ICP-OES, XRD, and SEM analysis were conducted for the conversion efficiency and structure and morphology analysis. It is confirmed that all experiments of SrZrO3 with MgCl2 at 800°C for reaction time 5, 10, 20 hours showed higher conversion efficiency than 99% and in LiCl-KCl-MgCl2 and NaCl-MgCl2 molten salts at 500°C or 600°C, conversion efficiency higher than 97% was obtained. SrMoO4 in MgCl2 immersion experiments for 10 hours showed higher conversion efficiency than 99% when the molar ratio of salt/oxide powder is 7. U2SrOy was also tested with MgCl2 molten salt at 800°C and higher efficiency than 99% and mainly MgUO4 were produced as a reaction product.

An accumulation of spent nuclear fuel (SNF) has brought a considerable interest due to its energy and environmental issue. To effectively manage SNF, a pyroprocessing is introduced to separate useful resources from the spent fuels and to manufacture suitable fuels. In head-end process of pyroprocessing, spent fuels are thermally treated to prepare UO2 pellets, where various radioactive gases from SNFs are released during thermal treatment. Within these gases, C-14 as CO2 form is a radioactive fission product which had a long half-life of 5,730 years and emits beta radiation of 0.156 MeV. Generally, current CO2 capturing technologies include adsorption by solid materials, absorption by aqueous solutions, and membrane separation. Among these methods, absorption is an effective approach which traps CO2 effectively and and it is easy to operate at room temperature. In addition, it is highly recommended as immobilizing 14CO2 as CaCO3 formation due to the high thermal and chemical stability, and the relatively low solubility in water. Generally, a double alkali method has been proposed to capture low concentrated 14CO2 from the stream. This method for CO2 capture includes absorption process with NaOH solution and causticization using Ca(OH)2. In this study, CO2 emitted from SNF is captured using double alkali method, and the effects of operating conditions on capturing efficiency were investigated. Furthermore, considering the two-film theory, the effects of trapping conditions on the CO2 absorption performance were examined. The recovered CaCO3 from causticization was collected from the absorbing solution and analyzed.

This paper intends to present considerations on the question of what is the “load standard” or “design load” for integrity evaluation under normal transportation conditions and what type of design load is good for users. This suggests a direction for subsequent research on producing design loads that transport business companies can utilize without difficulty. Several studies have been conducted to evaluate the integrity of spent nuclear fuel during normal transportation. A representative study recently conducted is the Multi-modal Transportation Test (MMTT) conducted using a commercial spent nuclear fuel cask by US DOE in 2017. In Korea, additional transport tests were planned to acquire sufficient test data under the conditions of road and sea transport considering the Korean situation. As a result, road transport tests were carried out in 2020 and sea transport tests were carried out in 2021. In the road transport test, a driving test that simulates various road conditions and a test that cycled a 4.5 km road eight times were performed. In most cases, the maximum acceleration of less than 1 g occurred, and the maximum strain was less than 48 με. For the sea transport test, the magnitude of both the maximum acceleration and the maximum strain were lower than those in the road transport test. We concluded tentatively that the integrity of spent fuel under normal conditions of transport was satisfactory with a large margin. However, when the storage business is realized and the transport of spent fuel becomes visible, the storage and transport business companies will have to prove the maintenance of the integrity of the spent fuel under normal transport conditions at the request of the regulatory agency. The transport business companies can transport the spent nuclear fuel by using different types of transport casks and different types of trucks and ships from those used in the tests mentioned above. However, it is absurd to have to prove the integrity of spent nuclear fuel by performing expensive tests again. Therefore, in this study, the design load that can be used by transport business companies is to be presented. The design load to be presented should satisfy the following requirements. The design load should be applicable including some differences in the transport cask or transport system, or different design loads should be presented according to the differences. The location where this design load is applied is to be specified (e.g. fuel rod, basket, internal structure). Requirements according to the operating speed of the transport system should be presented together. The type of design load is to be presented (e.g. PSD, SRS, FDS etc.). Other types of standards may be presented. For example, a speed limit for a vehicle carrying spent nuclear fuel may be suggested, or a speed limit for a vehicle passing through a speed bump may be suggested. In order to present such a reliable design load, a multi-axis vibration excitation shaker table test will be carried out. Though this shaker table test, the behavior of the nuclear fuel assembly is closely evaluated by applying the data obtained from the road and sea transport tests previously performed as an input load. In addition, FDS (Fatigue Damage Spectrum) will be produced and applied to experimentally evaluate the durability of fuel assemblies under normal transport conditions.

The Na, Al, and Si akoxides-based sorbents for iodine capture have higher maximum iodine capture capacity and pore properties than zeolite-based sorbents. However, these sorbents were prepared in the form of granules via a step for cutting cylindrical alcogels. Since as-made sorbents decreased packing density, they must be additionally crushed and then classified into an appropriate size for increasing packing density. The bead formation in the step of sol-gelation could bring about the simplification of sorbent fabrication process and an improvement of packing density. For the formation of gel bead, characteristics such as hydrophilic or hydrophobic property and density of sol solution were investigated to design sol-gelation equipment. The sol-gel bead preparation equipment in the reflection of sol solution characteristics was fabricated through selection of oil for formation of sol bead, solvent for collection of gel bead, and nozzle for spray of sol droplet formation. The continuous or discontinuous formation of sol beads from NaAlSi-OH sol solution were observed according to flow rates of 6 to 8 mL·min−1 and nozzle diameters of 0.4 to 0.8 mm. In the sphericity of sol bead, the best sol beads were obtained from 0.5 mm nozzle without clogging by sol solution in the flow rate range of 6–8·min−1.

During normal and off-normal conditions, the concrete structures of dry storage system for spent nuclear fuel must maintain structural integrity. A stress-strain curve is the most important key factor for structural integrity evaluation. The ASTM C39 specifies the concrete specimen geometry for the static compression test. However, there is no standard specimen size for intermediate stain rate, and it is not easy to maintain consistency among all test results because the failure tendency is different from each other. In order to account for the strain rate effects on concrete, the dynamic increase factor (DIF) is conventionally addressed by dividing dynamic strength by static strength. However, the DIF value considers only the strength of concrete and does not describe the overall behavior of concrete, such as a stress-strain relation. The objective of this study is to propose proper specimen geometry for the concrete dynamic compression test by several parametric study. The static compression simulation results with the specimen specified in ASTM C39 showed the constant strain distribution in a cylindrical specimen. However, as the strain rate increases, the strain state in specimen showed a nonuniform with the same geometry of ASTM C39. The non-uniform strain state in the specimen deteriorates the consistency and accuracy of the compression test. Therefore, we presented the specimen shape and size to form a uniform strain state through radial direction by drilling a hole in the axial direction. We analyzed two specimens using ABAQUS with the concrete damaged plasticity model, one with a hole at the center and the other without the hole. As a result, the strain distribution became more uniform than the specimen without the hole. Based on the results, we proposed the specimen shape and size for the intermediate strain rate compression test.

Laboratory testing to simulate the drying of spent fuel is most often done using a cooling rate of approximately 5°C per hour because there are so many restricted test conditions like R&D project duration limit, budget and temporary electronic supply blackout at laboratory building. However, in a real dry cask storage system, the fuel cools much slower. Early data from KAERI on unirradiated, pre-hydrided cladding has shown that slower cooling may result in more brittle behavior than is currently observed based on these short-term tests. Given the potential safety and future handling implications of failed fuel, it is important to determine if the material properties of spent fuel cladding measured in these laboratory tests are the same as would be observed on fuel that has undergone a much longer, slower cooling, which may provide more time for hydrides to precipitate in the radial direction. KAERI and PNNL have started a collaborative I-NERI R&D project on this topic and each organization will perform tests on unirradiated & irradiated cladding under various hoop stress and cooling rate combinations. Scope of collaborative work is to evaluate long-term cooling (slow cooling rate) on hydride reorientation and subsequent material properties of cladding to determine if past and current research activities on spent nuclear fuel are bounding. The results will be used to direct future testing and help predict cladding performance over a wide range of burnups during extended storage and transportation.

Detailed temperature distributions of the spent fuel are required to evaluate the long-term integrity of the dry storage system. In this study, a subchannel analysis method was established to obtain the detailed temperatures of a spent fuel using the COBRA-SFS code. The SAHTT (Single Assembly Heat Transfer Test) model was selected as the subchannel analysis. It was developed at the PNL to investigate heat transfer characteristics of spent PWR fuel under dry storage conditions. The SAHTT has a 15×15 rod array with simulated rods 0.42 in. (10.7 mm) in diameter. Control rod thimbles were modeled with unheated rods. The COBRA-SFS input consists a detailed subchannel model with 256 subchannels, 225 rods, and 8 slab nodes. The heat generation rate was axially uniform with total power of 1.0 kW. Subchannel analyses were performed for the vertical orientation under three different backfills of air, helium, and vacuum. For the vacuum backfill, the peak temperature was the highest and temperature gradients the sharpest only due to the radiation heat transfer effect. For the helium backfill, peak temperature was lowest and the axial profiles flattest due to the higher conductivity and lower density of helium. Subchannel analyses were also performed to evaluate the effect of thermal parameters such as surface emissivity, convective heat transfer coefficients, and flow resistance coefficients on the PCT (Peak Cladding Temperature). The PCT was affected by the emissivity of the fuel rod and the basket, and in particular, the basket emissivity had a greater effect. The PCT was affected by the Nusselt number, but the range of the Nusselt number is around 3.66. Therefore, the effect of the Nusselt number on the PCT will not be significant. As a result of the analysis according to the flow resistance coefficients, the PCT was affected by the wall friction factor, but the loss coefficients from the space grid had little effect. Subchannel technique obtained from this work can be used to predict the detailed temperature distributions of spent fuel assembly.

When disposing of spent nuclear fuel, there is a risk of exposure that could exceed the annual allowable dose due to human intrusion after the institutional control period. Therefore, it can be treated with the pyroprocess, but the decontamination factor is not sufficient, and an additional actinide recovery is required because molten waste salt-containing actinide is generated. In the case of reducing the element in the spent molten salt through an electrochemical method using a liquid Bi electrode, it is difficult to separate only the actinide element because the two-element groups are reduced together due to the large concentration difference between the actinide and the rare earth element. Therefore, a process of forming a Bi intermetallic compound using a liquid Bi electrode, which has higher element separation efficiency than a liquid Cd electrode, and physically separating the Bi intermetallic compound using the difference in density of the produced compound has been proposed. For this, it is necessary to understand the properties and density separation of the intermetallic compound to be produced, and experiments were planned and conducted for this purpose. Various metals were added to the molten Bi to form an intermetallic compound, and an analysis device such as SEM was used to determine the intermetallics distribution, composition, and internal structure. As the added metal, Ce is a representative element for lanthanide, and Hf with the most similar intermetallic density, decomposition temperature, and standard reduction potential to U, and U as a substitute element for actinide was adopted. As a result of SEM and EDS analysis, it was confirmed that the separation was made in Bi due to the density difference between the produced intermetallic compounds. A Ce-Bi intermetallic compound was observed in the upper part, Hf at a concentration smaller than the error range was detected, and a Hf-Bi intermetallic compound which containing high concentration of Ce was observed in the lower part. Separation of high-purity Ce seems to be possible in the upper part, and it seems difficult to separate high-purity Hf in the lower part. Therefore, to separate highpurity Hf, an additional process suitable for it seems to be necessary.

Some Spent Fuel Pools (SFPs) will be full of Spent Nuclear Fuels (SNFs) within several years. Because of this reason, transporting the SNF from SFP to interim storage facilities or permanent disposal facilities should be considered. There are two ways to transport the SNF from a site to other site, one is the land transportation with truck or train, and the other is the maritime transportation with ship. The maritime transportation has some advantages compared with the land transportation. The maritime transportation method uses safer route which is far from populated area than land transportation method, and transport more weight than land transportation method. However, the cask should be loaded into the ship for the maritime transportation, and there is a possibility of a drop accident of the cask onto the ship. Therefore, it is necessary to evaluate the structural integrity of the cask and ship for the drop accident during the loading process. To evaluate the structural integrity of the cask and ship, it is necessary to determine the analysis conditions that caused the greatest damage in the drop accident. There may be various conditions such as the drop angle of the cask, the initial falling speed, the drop position onto the ship, the size of the ship, etc. This study set the drop angle of the cask and the drop position onto the ship as the simulation variables, which have high possibility to occur during cask drop. However, the others are excluded since they are controllable by worker. In this paper, various drop angle (0, 15, 30, 45, and 70 degree) of the cask were simulated to define the greatest damage condition. KORAD-21 cask model was used for Finite Element Analysis (FEA), and FEA was performed to simulate a horizontal drop (1 m drop). The strain-hardening material properties for the deck were used as HT36 steel. The Cowper-Symonds constitutive model for HT36 was used to consider the strain rate effect. A Tie-down structure for supporting the cask was modeled with the cask model which contained inner structures like canister, basket, etc. Structural integrity of the cask and tie-down structure were evaluated using the von-Mises stress and equivalent plastic strain (PEEQ), and one of the ship deck was evaluated using deflection of ship deck and equivalent plastic strain. Compared with each cask drop angle conditions, 45 degree of the cask drop angle showed the highest deflection and PEEQ values, but did not exceed ultimate strain of HT36. In the ship deck, the corner of deck showed the highest PEEQ value in all simulation cases. As the result, the 45 degree of the cask drop angle condition results was more conservative than other conditions, and the corners of deck failure was able to evaluate ship safety.

In this study, for thermal neutron absorption, an aluminum metal composite in which B4C particles were uniformly dispersed was prepared using stirring casting and hot rolling processes. The microstructure, thermal neutron absorption rate, mechanical properties and dispersibility of the reinforcement of the prepared B4C/Al composite were analyzed. The composite in which the 40 μm sized B4C particles were uniformly dispersed increased the tensile strength as the volume ratio of the reinforcement increased.

In order to construct and operate the dry storage systems, it is essential to confirm the safety of the systems through safety analysis. If the dry storage cask is damaged due to an accident, a large amount of radioactive material may be leaked to the outside and cause radiation exposure to surrounding workers and nearby public, so the effect thereof should be evaluated. Many input parameter are required in the confinement evaluation for accident condition, and in this study, the change in the confinement evaluation result according to the change of major input parameter is to be studied. In this study, we selected fractions of radioactive materials available for release from spent fuel, cooling time, and distance to exclusive area boundary as the major input parameter. In general, the release fraction suggested by NUREG-1536 has been used, but NUREG-2224 provides the fraction for high burn-up spent fuel in fire and impact accident conditions, unlike NUREG-1536 which provide a single value. In the case of the distance to exclusive area boundary, 100 to 800 m was considered, and in the case of the cooling time, 10 to 50 years was considered in this study. In order to compare the dose change by the parameter, we set up the hypothetical storage system. A storage cask of the system contain 21 PWR spent fuel assemblies with an initial enrichment of 4.5wt%, burnup of 45,000 MWD/MTU. During the accident condition, it is assumed that the cask is leaked at 1.0×10−7cm3·sec−1. Since the main dose criterion for accident conditions is 50 mSv of effective dose, effective doses are calculated in this study. In an accident condition, transuranic particulate contribute most of the doses, so the doses are determined according to the fraction for the particulate. Therefore, it was confirmed that the dose was almost the same as the fraction for the accident conditions in NUREG-1536 and the fraction for the impact accident conditions in NUREG-2224 is 3×10−5, but the dose was also 100 times higher as the fraction for the fire accident conditions in NUREG-2224 is 3×10−3. In the case of the cooling time, it was confirmed that the dose change according to the cooling time was not significant because the dose contribution of transuranic elements having very long half-life was very large. In the case of the distance, it was confirmed that the dose decreased exponentially as the atmospheric dispersion factor decreased exponentially with the distance.

Korea Atomic Energy Research Institute (KAERI) has investigated Pyroprocessing technology in order to decrease the burden of disposal system and increase availability of useful radionuclides in the spent nuclear fuel (SNF) for future. The treatment and the disposal of SNF, however, are very sensitive issues socially. In addition, under the energy transition policy phasing out nuclear energy gradually there have been demands for alternatives so far. Thus various alternatives should need to be investigated in preparation for unexpected situations. This study has been conducted roughly in effectiveness point of view of alternative pre-managements for SNF, not pyroprocessing technology, in disposal system, consisting of three stages according to the degree of burden in disposal system. Stage I is the case for making safety increase with removing highly-mobile radionuclides from SNF. Stage II is the case for eliminating high-heat radionuclides additionally, alleviating thermal risk in the disposal system. And Stage III is the case for recovering Uranium in addition to Stage II. These options of pre-management are thought to be able to provide an intuitive strategy for effective diversification of the disposal system. Because several types of waste form from pre-management make it possible to develop the effective, newly-composed waste disposal system according to the properties of radionuclides. And the processability of SNF through pre-management might be combination with available core-drilling technology, being able to design various disposal system as well. Even though the whole, detailed unit processes have not designed yet, mass balance and distributions of radionuclides are performed under the appropriate assumption of engineering processes. As a first step the alternative approaches for SNF pre-management for disposal system might be expected to be widely used in implementing SNF management policy in the future.

PWR spent nuclear fuel generally showed an oxide film thickness of 100 um or more with a combustion rate of 45 MWD/MTU or higher, while CANDU spent nuclear fuel with an average combustion rate of about 7.8 MWD/MTU had few issues related to hydride corrosion. Even based on the actual power plant data, it is known that the thickness of the oxide film is 10 μm or less on the surface of the coating tube, and brittleness caused by hydride is shown from the thickness of the oxide film of about 80 μm, so it is not worth considering. However, since corrosion may be accelerated by lithium ions, lithium ions may be said to be a very important factor in controlling the hydro-chemical environment of heavy water. Lithium has a negative effect on the corrosion of zirconium alloys. However, since local below 5 ppb to prevent corrosion. maintained at a concentration between 0.35 and 0.55 ppm. Hydrogen is known to have a positive effect by suppressing radioactive decomposition of the coolant and suppressing cracks in nickelbased alloys. However, too much hydrogen can produce hydride in a pressure tube composed of Zr-2.5Nb, so DH (Disolved Hydrogen) maintains the range of 0.27–0.90 ppm. pH and conductivity are completely determined by lithium ions, and DH can be completely removed below 5 ppb to prevent corrosion. Therefore, for cladding corrosion simulation of the CANDU spent nuclear fuel, a hydrochemical of the equipment, not 310°C, and 14 uS·Cm−1 is targeted as conditions for corrosion acceleration. In addition, for acceleration, the temperature was set to 345°C (margin 10°C), which is the maximum accommodation range of the equipment, not 310°C.

To dry storage of spent nuclear fuel withdrawn the wet storage, all moisture inside the dry storage container must be removed to ensure the long-term integrity and retrievability. Substantial amounts of residual water in dry storage container may have potential impacts on the fuel, cladding, and other components in the dry storage system, such as fuel degradation and cladding corrosion, embrittlement, and breaching. The drying could perform as a vacuum drying process or a forced helium dehydration process. In NUREG-1536, the evacuation of most water contained within the canister is recommended a pressure of 0.4 kPa (3 torr) to be held in the canister for at least 30 minutes while isolated from active vacuum pumping as a measure of sufficient dryness in the canister. Monitoring the moisture content in gas removed from the canister is considered as a means of evaluating adequate dryness. Dew point monitoring and special techniques could be used to evaluate this adequacy. Various studies are continuing for quantitative evaluation of residual moisture inside the dry storage system. Andrawes proposed a methodology for determining trace water contents in gaseous mixtures, utilizing gas chromatography together with a helium ionization source. A microwave plasma source and emission spectrometry were utilized to determine trace amounts of bound water in solid samples using peak areas of atomic oxygen (O) and hydrogen (H) emissions. Bryans measured the gas samples taken from the High Burn-Up Demonstration Cask at three intervals: 5 hours, 5 days, and 12 days after the completion of drying and backfilling in the North Anna power Station. To measure water content, a Vaisala humidity probe was used. Final results indicated that the cask gas water content built up over 12 days to a value of 17,400 ppmv ±10%, equivalent to approximately 100 g of water within the entire cask gas phase. Tahiyats also proposed a methodology that involves a direct current (dc) driven plasma discharge and optical emission spectroscopy for detecting and quantifying water vapor in a flowing gas stream under both trace and high water vapor loading conditions. For detecting water vapor concentration, the emission from H at 656.2 nm was employed. The H emission is the red visible spectral line generated by a hydrogen atom when an electron falls from the third lowest to the second lowest energy level, this suggests that the normalized H intensity can be used as a marker for water vapor detection and quantification. Several of the attempts are continuing to quantify water contents in dry storage system. Lessons learned by Case studies would be provided insights into how to improve future measurements.

For economic and safe management of Spent Nuclear Fuel (SNF), it is very important to maintain the structural integrity of SNF and to keep the fuel undamaged and handleable. The cladding surrounding nuclear fuel must be protected from physical and mechanical deterioration. The structural evaluation of SNF is very complicated and numerically demanding and it is essential to develop a simplified model for the fuel rod. In this study, a simplified model was developed using a new cladding failure criterion. The simplified model was developed considering only the horizontal or lateral static load utilizing the cladding material properties of irradiated Zirclaoy-4, and applicability in horizontal and vertical drop impacts was investigated. When a fuel rod is subject to bending, a very complicated 3D stress state is generated within the vicinity of the pellet–pellet interface. A very localized stress concentration is observed in the area where the edges of the pellets contact the cladding. If the failure strain criteria obtained from the uniaxial tension test or biaxial tube test is applied, failure is predicted at the beginning stage of loading with premature through-thickness stress or strain development. The localized contact stress or strain is self-limiting and is not a good candidate for the cladding failure criteria. In this work, a new cladding failure criterion is proposed, which can account for the localized stress concentration and the through-thickness stress development. The failure of the cladding is determined by the membrane plus bending stress generated through the thickness of the cladding, which can be calculated by a process called stress linearization along the stress classification line. The failure criterion for SNF was selected as the membrane plus bending stress through stress linearization in the cross-sections through the thickness of the cladding. Because the stress concentration in the cladding around the vicinity of the pellet–pellet interface cannot be simulated in a simplified beam model, a stress correction factor is derived through a comparison of the simplified model and detailed model. The applicability of the developed simplified model is checked through horizontal and vertical drop impact simulations. It is shown that the stress correction factor derived considering static bending loading can be effectively applied to the dynamic impact analyses in both horizontal and vertical orientations.

Barrier effect model developed by CRIEPI is used for the estimation of rate of radioactive material release from a transport cask submerged in the ocean. If the containment boundary of cask is broken in an accident during maritime transportation, the sea water comes into the cask cavity and the leaching of radioactive material occurs. If the release of radioactive material thorough the opening of the containment boundary of cask is less than the leaching rate of the radioactive material inside the cask, then the release rate is controlled by the saturation limit of the sea water inside the cask cavity. In this study, the release rate estimation using the barrier effect model is compared with the model used in other codes, such as MARINRAD. And by parameter study, important factors that affect the releaser rate are identified and prioritized. It is shown that the gap generated in the containment boundary is the key parameter that determine the release rate of the radioactive material and the leaching rate is the dominant parameter to determine the saturation time of the cavity sea water.

The conventional research trend on spent fuel was safety analysis based on mechanical perspective. Analysis of spent fuel cladding is based on the temperature of cladding and pressure inside cladding. To improve fuel cladding analysis, precise and accurate thermal safety evaluation is required. In this study a database which is about thermal conductivity and emissivity for the thermal modeling was established for a long-term safety analysis of spent fuel. As a result, we confirmed that the thermal conductivity of zirconium hydride was not accounted in conventional model such as FRAPCON and MATPRO. The conductivity of zirconium and its oxide was evaluated only as a function of temperature. However, the behavior of heat conductivity and emissivity is determined by the change of the material properties. The material properties depend on the microstructural characteristic. It can be seen that this conventional approach does not consider the microstructure change behavior according to vacuum drying process or burn-up induced degradation phenomena. To improve the thermal properties of spent nuclear fuel cladding, the measurement experiments of heat conduction and emissivity are required according to spent fuel experience and status such as the number of vacuum drying, cooling rate, burn up, hydrogen concentration and oxidation degree. In previous domestic reports and papers, we found that relative data between thermal properties and spent fuel experience and status does not exist. Recently, in order to understand the failure mechanism of hydrogen embrittlement, many studies have been conducted by accounting and spent fuel experience and status in a mechanical perspective. If microstructure information could be obtained from these studies, the modeling of thermal conductivity and emissivity will be possible indirectly. According to a recent abroad paper, it was confirmed that the thermal conductivity decreased by about 30% due to irradiation damage. The radiation damage effects on thermal conductivity also has not been studied in zirconium oxide and hydride. These un-revealed phenomena will be considered for the thermal safety model of spent fuel.

Dry head end process is developing for pyro-processing at KAERI (Korea Atomic Energy Research Institute). Dry processes, which include disassembly, mechanical decladding, vol-oxidation, blending, compaction, and sintering shall be performed in advance as the head-end process of pyroprocessing. An important goal of the head-end process is the fabrication of a proper feed material for the subsequent electrolytic reduction process. In the vol-oxidation process, the pellet type-SFs are pulverized by an oxidation under an air-blowing condition, and some volatile fission products are removed from the produced powders by using an air flow. After blending, the U3O8 powders are moved to a compactor of compaction process to obtain U3O8 porous pellets. In the fine powders removal system connected with compactor, for the improved performance of oxide reduction process coupled to dry head-end process, the removal/recovery system for fine powders potentially attached to the surface of oxide reduction raw material was developed and applied to the removal of fine powders from green pellets fabricated in dry head-end process. The removal efficiency of fine powders was also verified using porous U3O8 pellets in the fine powders removal system.

In KAERI, the nuclide management technology is currently being developed for the reduction of disposal area required for spent fuel management. Among the all fission products of interest, Cs, I, Kr, Tc are considered to be significantly removed by following mid-temperature and high-temperature treatment, however, a difficulty of spent-fuel thermal treatment experiment limits the development of such thermal treatment. In this study, we applied our previously developed two-stage diffusion release model coupled to UO2 oxidation model to the development of optima thermal treatment scenario. Since the formation of cesium pertechnetate should be avoided and the fission release behavior is considerably affected by the extent of oxygen, we obtained oxygen-content dependent model parameters for two-stage fission release model and applied the model to the evaluation of fission release behavior to different oxygen content and thermal treatment procedure. It was found that the developed fission release model closely describes the experimental behavior of fission product of interest, implying a validity of model prediction and the thermal treatment condition reducing the chemical reaction between cesium and technetium could be developed.

Disposal facilities for radioactive waste shall be sited to provide isolation from the accessible biosphere. The features shall aim to provide this isolation for tens of thousands to a million years after closure. For the safety assessments of repository, the long-term natural evolution and possible events of the site, that can cause disturbances to the facility over the period of interest, should be considered. Geological development processes that the site have been experienced can contribute to understanding and descripting the present-day conditions. Moreover, knowledge of the past is necessary to predict the future evolution of the site. With regard to disposal site, understanding past geological evolution history allows to access the possibility of hazardous events of the site that can cause disturbances to the facility over the period of interest, and to verify the change in the geological environment is within the safe performance range even after the period of interest. In addition, certain parameters that change with the geological evolution can affect the hydrological and geochemical characteristics which are essential to disposal performance. There are various factors in the evolution of the geological environment, but not all are related to disposal safety. The objective of this research is to develop a geological reconstruction method considering factors that should be derived preferentially for the geological characteristics of the disposal site and the evaluation of the long-term safety. As a preliminary study on this, we investigated case studies related to geological reconstruction of overseas disposal research institutes, and reviewed which factors are suitable for the domestic granitoid distribution environment. It is expected that systematic and consistent results will be possible in the future through this methodology.