In order to prevent the oxide formation on the surface of nano-size iron particles and thereby to improve the oxidation resistance, iron nanoparticles synthesized by a chemical vapor condensation method were directly soaked in hexadecanethiol solution to coat them with a polymer layer. Oxygen content in the polymer-coated iron nanoparticles was significantly lower than that in air-passivated particles possessing iron-core/oxide-shell structure. Accordingly, oxidation resistance of the polymer-coated particles at an elevated temperature below in air was times higher than that of the air- passivated particles.

In this study, equivalent linear damping and stiffness of a single-degree-of-freedom(SDOF) structure with a rotational friction damper are estimated using the result of experiments and compared with those obtained from non-linear time history analyses. First, the transfer function of the test model is constructed and then the equivalent stiffness and damping are calculated, using the half-power bandwidth (HPB) method. For comparative study, those properties are estimated based on stochastic theory in the time domain. Both equivalent linear systems identified from experiments and numerical analyses correspond well. Further, it is observed that there exists an optimal clamping force on the rotational friction damper from estimated equivalent damping.

본 논문의 목적은 탄성과 비탄성 구조물의 지진응답제어를 위한 마찰감쇠기의 설계절차를 제시하는 것이다. ATC-40과 ATC-55를 이용하여 비탄성 구조물의 등가선형감쇠비와 등가선형주기를 구하였고, 이에 기초하여 목표 성능을 만족하기 위한 마찰감쇠기의 최대마찰력을 결정하는 식을 제시하였다. 이 식은 항복 전후 강성비와 요구되는 탄성강도에 대한 항복강도비, 그리고 구조물의 주기에 따라 비선형 수치해석과 오차가 발생한다. 수식에 의해 산출한 최대마찰력과 비선형 수치 해석에 의해 산출된 값과의 오차를 줄이기 위하여, 최소 제곱법을 사용하여 오차 보정식을 제시하였다. 수치해석결과는 제안된 보정식을 사용하면 탄성 및 비탄성 지진응답제어를 위한 마찰감쇠기의 설계를 합리적으로 수행할 수 있음을 보여준다

In this study, hetero-electrode structures have been fabricated to increase luminescence efficiency. The presence of a thin layer of Sn or Ag at the organic-aluminum interface enhanced both electron injection efficiency and electroluminescence when compared to OLEDs using homogeneous electrode. In this paper, the effect of the cathode using Sn/Al hetero electrode structure is observed. Electric properties of the OLED using Sn/Al hetero cathode are improved in comparison of only Al cathode. The hetero-electrode existing different energy level induces the advanced structure of OLED can accumulate electron density. The luminescence efficiency of OLED with Sn/Al of Ag/Al cathode is higher because of their higher electron injection efficiency. And, the turn on voltage of the OLED device using Sn thin layer is lowest as about 10 V.

Using the nano Fe powders having 50 nm in diameter, Fe compact bodies were fabricated by injec-tion molding process. The relationship between microstructure and material properties depending on the volume ratio of powder/binder and sintering temperature were characterized by SEM, TEM techniques. In the compact body with the volume percentage ratio of 45(Fe powder) : 55(binder), which was sintered at the relative density was about and the values of volume shrinkage and hardness were about and 242.0 Hv, respec-tively. Using the composition of 50(Fe powder) : 50(binder) and sintered at the values of relative density, volume shrinkage and hardness of Fe sintered bodies were and 152.8 Hv, respectively. They showed brittle fracture mode due to the porous and fine microstructure.

Nano sized FeAl intermetallic particles were successfully synthesized by plasma arc discharge pro-cess. The synthesized powders shouted core-shell structures with the particle size of 10-20 nm. The core was metallic FeAl and shell was composed of amorphous Because of the difference of Fe and Al vapor pressure during synthesis, the Al contents in the nanoparticles depended on the Al contents of master alloy.

Iron-carbon nanocapsules were synthesized by plasma arc discharge (PAD) process under various atmosphere of methane, argon and hydrogen gas. Characterization and surface properties were investigated by means of HRTEM, XRD, XPS and Mossbauer spectroscopy. Fe nanocapsules synthesized were composed of three phases with core/shell structures. The surface of nanocapsules was covered by the shell of graphite phase in the thickness of nm.

Fe nanopowders were successfully synthesized by plasma arc discharge (PAD) process using Fe rod. The influence of chamber pressure on the microstructure was investigated by means of X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FE-SEM), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). The prepared particles had nearly spherical shapes and consisted of metallic cores (a-Fe) and oxide shells (FeO), The powder size increased with increasing chamber pressure due to the higher dissolution and ejection rate of H and gas density in the molten metal.