Applicability of corrosion inhibitor was evaluated using pilot scale water distribution pipe simulator. Calcium hydroxide was used as corrosion inhibitor and the corrosion indices of the water were investigated. Corrosion indices, Langelier saturation index (LI) increased by 0.8 and calcium carbonate precipitation potential (CCPP) increased by 9.8 mg/L. This indicated that corrosivity of water decreased by corrosion inhibitor and the effects lasted for 18 days. Optimum calcium hydroxide dose was found to be 3~5 mg/L for corrosion inhibition. We suggest that monitoring of CCPP as well as LI need to be conducted to control corrosivity of water.

Distribution basins are used widely in the water treatment process. Uniform distribution at the distribution basin is an important because it affect precipitation efficiency of sedimentation basin. Generally distribution basin has a free surface water and is consisted of a weir. Study result, when inflow of distribution basin is less, amount of overflow is much at the nearest weir from the inlet. But when inflow is much, amount of overflow is much at the far weir from the inlet. The difference of distribution amount at the pipe is affected by the curvature and length of the pipe. The magnitude of the effect is determined by the relative energy loss and the flow state of the distribution basin. Optimization of the response surface method for minimizing an amount of deviation of the distribution is a very useful technique to determine the optimal ratio of the valve opening.

The H water treatment plant has been operating since 1982 and has had no renovation. It is assumed that the filters have been operated for more than 30 years and therefore are deteriorated. Many of the filters show an unequal state of air scouring during backwashing. For this study one filter, which was presumed most deteriorated among eighteen filters, was selected as a model filter for renovation. Some of the effects seen after renovation of the underdrain system were a lower average filtrated turbidity by approximately 0.02 NTU and an equal backwash state throughout the filter bed. Sand wash efficiencies by backwash before renovation of the underdrain system were 28%, 8%, and 5% at the surface, 50 cm depth, and 100 cm depth, respectively, and after renovation of the underdrain system were 94%, 26%, and 15% , respectively. The standard deviation of the effective sand size was 0.025-0.033 mm before renovation of the underdrain system and 0.002-0.011 mm after renovation of the underdrain system, meanings there was equal backwash pressure throughout the filter. Filtration time after renovation was approximately 2 times longer than before renovation.

In Korea, many drinking water treatment plants (DWTPs) have introduced and are going to introduce biological activated carbon (BAC) process to treated dissolved organic matter (DOM) in water which are difficult to control by conventional water treatment processes. Even though more decade have passed since introduced BAC in Korea, most of BAC operating method was followed to the modified sand filter operating manuals. In case of BAC backwashing, many DWTPs set the periods of backwashing about 3∼5 days. In this study, we have collected data to set the proper BAC backwashing periods from both pilot-plant and real DWTPs. We had measured heterotrophic plate count (HPC), turbidity, water temperature, dissolved organic carbon (DOC) and headloss from just after backwashing to the next backwashing time for two years. Considering water quality factors, the BAC run time from backwashing to the next backwashing could extend more 30 days without water quality deterioration if the head loss do not reach the limited level which depends on each BAC facilities’ condition. It means the BAC treated water could be saved in the proportion of extended the backwashing period to the existing backwashing period.

This study carried out continuous column test for estimating the regeneration efficiency with regeneration times and temperatures. More times regenerated granular activated carbon (GAC) has more ash in the GAC and has less apparent density. Two times regenerated GAC (2nd re-GAC) could removed the Trihalomethanes (THMs) in the water for the first two week after starting continuous column test, on the other hand five times regenerated GAC (5th re-GAC) did not have adsorption capacity. The THMs concentration in the effluent was almost equal or higher than that of influent at the first time of continuous column test. 2nd re-GAC showed much more DOC adsorption capacity than 5th re-GAC and the GAC which was regenerated with 700 ℃ had highest DOC removal efficiency among the GACs with 600, 700, 800, 900 ℃ regeneration temperatures. It is anticipated the cost of GAC regeneration could be saved more 100 million won by reducing the furnace temperature of 3rd~4th and 5th~6th about 150 ℃ compared to the current regeneration condition.

This research was performed by means of several different virgin granular activated carbons (GAC) made of each coal, coconut and wood, and the GACs were investigated for an adsorption performance of iodine-131 in a continuous adsorption column. Breakthrough behavior was investigated that the breakthrough points of the virgin two coals-, coconut- and wood-based GACs were observed as bed volume (BV) 7080, BV 5640, BV 5064 and BV 3192, respectively. The experimental results of adsorption capacity (X/M) for iodine-127 showed that two coal- based GACs were highest (208.6 and 139.1 μg/g), the coconut-based GAC was intermediate (86.5 μg/g) and the wood-based GAC was lowest (54.5 μg/g). The X/M of the coal-based GACs was 2∼4 times higher than the X/M of the coconut-based and wood-based GACs.

This study accessed the adsorption characteristics of the 9 trihalomethanes (THMs) on coal-based granular activated carbon (GAC). The breakthrough appeared first for CHCl3 and sequentially for CHBr2Cl, CHBr3, CHCl2I, CHBrClI, CHBr2I, CHClI2, CHBrI2, and CHI3. The maximum adsorption capacity (X/M) for the 9 THMs with apparent breakthrough points ranged from 1,175 μg/g (for CHCl3) to 11,087 μg/g (for CHI3). Carbon usage rate (CUR) for CHCl3 was 0.149 g/day, 5.5 times higher than for CHI3 (0.027 g/day).

A comprehensive fractionation technique was applied to a set of water samples obtained along drinking water treatment process with ozonation and biological activated carbon (BAC) process to obtain detailed profiles of dissolved organic matter (DOM) and to evaluate the haloacetic acid (HAA) formation potentials of these DOM fractions. The results indicated that coagulation-sedimentation-sand filtration treatment showed limited ability to remove hydrophilic fraction (28%), while removal of hydrophobic and transphilic fraction were 57% and 40%, respectively. And ozonation and BAC treatment showed limited ability to remove hydrophobic fractions (6%), while removal of hydrophilic and transphilic fractions were 25% and 18%. The haloacetic acid formation potential (HAAFP)/dissolved organic carbon (DOC) of hydrophilic fraction was the highest along the treatment train and HAAFP/DOC of hydrophilic fraction was higher than hydrophobic and transphilic fraction as 23% 30%, because of better removal for hydrophobic fraction both in concentration and reactivity.

This study was investigated twenty two hazardous chemicals compounds for effluents of nine sewage treatment plants (STPs) and one waste water treatment plant (WWTP) in the Nakdong Ri-ver Basin. They are eleven phthalates(DMP, DEP, DIBP, DBP, BEEP, DNPP, DHP, DCP, DEHP, DNOP, Dinonyl phthalate, seven aliphatic hydrocarbons(n-Tridecane, n-Tetradecane, n-Pentadecan-e, n-Hexadecane, n-Heptadecane, n-Octadecane, n-Nonadecane, Isoquinoline, 2-Chloropyridine, 2-N-itrophenol, and Benzophenone. The twenty two compounds were analyzed by gas chromatograp-hy mass spectrometry (GC/MS) with liquid-liquid extraction (LLE). Twenteen of twenty two subs-tances were detected. They were DMP, DEP, DIBP, DBP, DEHP, n-Tetradecane, n-Pentadecane, n-Heptadecane, n-Octadecane, n-Nonadecane, Isoquinoline and Benzophenone. Among these, DEHP, DEP and Benzophenone were most frequently observed. They were obtained as ND~36.881 ㎍/L, ND~0.950 ㎍/L, ND~2.019 ㎍/L, respectively. When the substances were calculated the average concentration at 10 points, the maximum average detection concentration was investigated at the Dalseocheon STP.

Adsorption and biodegradation performance of tetracycline antibiotic compounds such as ttetracycline (TC), oxytetracycline (OTC), minocycline (MNC), chlortetracycline (CTC), doxycycline (DXC), meclocycline (MCC), demeclocycline (DMC) on granular activated carbon (GAC) and anthracite-biofilter were evaluated in this study. Removal efficiency of seven tetracycline antibiotic compounds showed 54%∼97% by GAC adsorption process (EBCT: 5∼30 min). The orders of removal efficiency by GAC adsorption were tetracycline, demeclocycline, oxytetracycline, chlortetracycline, doxytetracycline, meclocycline and minocycline. Removal efficiencies of seven tetracycline antibiotic compounds showed 1%∼61% by anthracite biofiltration process (EBCT: 5∼30 min). The highest biodegradable tetracycline antibiotic compound was minocycline, and the worst biodegradable tetracycline antibiotic compounds were oxytetracycline and demeclocycline.

This study, changes in raw water quality is to indicate on the efficiency of ozone treatment of each pollutant as compared to derive the appropriate operating measures. The appropriate selection for injection rate of pre-ozone and did not inject pre-ozone assess changes in the water. When good water quality, you not injected of pre-ozone to evaluate the economic efficiency of electricity and put the most cost-effective ozone concentration were evaluated. Evaluation remove organic matter and chlorophyll-a concentration level in experiments with each factor of the water DOC> 2.5 ㎎ / L, THMFP> 70 ㎍ / L, Chl-a> 30 ㎎/ ㎥or less constant process, if you do not need to put pre-ozone showed little impact. It also does not put you in pre-ozone appropriate produce enough power rate savings was calculated as approximately 90 million won. Ability to remove organic materials and the ability to produce disinfection byproducts, and cost-effective decisions by considering the concentration of injection if pre-ozone 1 mg/L was investigated by the appropriate concentration of ozone injection.

This is made of domestic and foreign coal activated carbon of five species, physicochemical adsorption efficient about sterilize products and micro harmful substances and is a result of the economic evaluation. The most well-developed micropores bed volume 123,409 of AC-1 activate carbon appeared to be the best next AC-2, AC-3, AC-4, AC-5 followed by activated carbon was investigated. PFOA and PFOS in the BV 96,000 when evaluating foreign types of adsorption activated carbon adsorption capacity was greater when more than PFOA, PFOS showed that the adsorption well. The economic evaluation of activated carbon usage in chloroform (CUR) was most excellent as a AC-1 4.3 g/day, the next AC-2, AC-3, AC-4, AC-5 there are two types of foreign economic order appears to have appeared, but the current domestic market when applying the price AC-1, AC-3, AC-2, AC-4, AC-5 order was investigated.

The aims of this study were to investigate and confirm the occurrence and distribution patterns of iodinated X-ray contrast media (iopromide) in Nakdong river basin (mainstream and its tributaries). Iopromide was detected in 16 sampling sites. The concentration levels of iopromide on February 2011 and on October 2011 in surface water samples ranged from not detected (ND) to 1481.1 ng/L and ND to 1168.2 ng/L, respectively. The highest concentration level of iopromide in the mainstream and tributaries in Nakdong river were Goryeong and Jincheon-cheon, respectively. The sewage treatment plants (STPs) along the river affect the iopromide levels in river and the iopromide levels decreased with downstream because of dilution effects.

One of the Musty and earthy smell compounds in raw water is generally attributed to 2-methylisoborneol (2-MIB). It is well known that activated carbon and oxidants such as O3, ClO2 are effective ways to control 2-MIB. In isotherm equilibrium experiments, 2-MIB in distilled water was much more adsorbed to the activated carbon(A/C) than raw water containing dissolved organic carbon (DOC). The Freundlich constants(k) of distilled water and raw water were 3.36 and 0.049, and 1/n values were 0.80 and 0.42, respectively. The 2-MIB residual rate were Y = e-0.55x～ e-0.54x with Ozone(O3) dose by 5 minutes contact time at the 241 and 353 ng/L initial concentrations. The 2-MIB residual rate were Y = e-0.32x～ e-0.35x with Chlorine dioxide(ClO2) dose by 15 minutes contact time at the 89 and 249 ng/L initial concentrations. 2-MIB was decreased from 1911 ng/L to 569ng/L by post-ozonation(70%removal efficiency) and removal efficiencies of 2-MIB by the following 4 kinds Granular Activated Carbon(GAC) process such as coal base, coconut base, wood base and zeolite+carbon base were 95.8, 89.5, 88.4, and 93.7% respectively.

Improvement of water quality and Investigation of bacterial characteristics have been conducted in a pilot plant using biological activated carbon (BAC) in water treatment process at the downstream of the Nakdong River. Most of water control parameters were highly improved after passing through BAC. Approximately 54% of dissolved organic carbon was removed in coal-based BAC process. Bacterial biomass and bacterial production appeared 9.8×108 CFU/g and 7.l㎎-C/㎥·hr in coal-based BAC, respectively. Predominant bacteria species grown in BAC were identified as Pseudomonas, Flavobacterium, Alcaligenes, Acinetobacter and Aeromonas species. Particularly Pseudomonas vesicularis was dominant in both coal-based and coconut-based BACs, while Pseudomonas cepacia was dominant in wood-based BAC.

Activated carbons were prepared from Korean coal by steam activation in this study. The variation of pore structure of the activated carbons were investigated according to different carbonization temperatures. Yield, surface area, pore volume and pore structure of this activated carbon were compared with those of activated carbon prepared without carbonization. The investigated carbonization temperature ranged from 700℃ to 1,000℃. Carbonization was carried out in nitrogen atmosphere for 70 minutes and activation was performed by steam at 950℃ for 210 minutes. Surface area and pore volume of the resulting activated carbons increased with carbonization temperature. Also pore volume increased by 20% compared to the activated carbon without carbonization. Especially, in mesopore region, the activated carbon carbonized at 900℃ had more pores by 60% than that of activated carbon carbonized at other temperature.

Activated carbons were prepared from Youngwall coal by steam activation in this study. The feasibility of the Youngwall coal to commercial activated carbon was examined. The variation of pore structures and the development of porosity in activated carbons were investigated by changing activation conditions in batch type apparatus. The values of BET surface area and adsorption capacity of iodine and methylene blue of the resulting activated carbons were obtained as high as 1,000㎡/g, 900㎎/g, 150㎖/g, respectively. Youngwall activated carbon prepared in this study showed much higher pore volume in pore diameter over l0Å than that of commercial reference activated carbon(Ningxia Taihua ZJ-15C) produced from China anthracite.

This study was carried out to evaluate the variations of headloss rate and of specific deposit to depths with effective size of media and configuration of filter layer during algae blooming period. 0.51㎜ size media was disqualified because most of headloss occurred rapidly below 5㎝ from surface layer. however 0.91㎜ size media acted deep filtration more than 20㎝ from top, as result 0.91㎜ size media filter had 2∼3 times longer filtration time than 0.51㎜ size media filter, but 0.91㎜ size media have break-through potentiality. multi-layer filter with 1.02㎜ anthracite and 0.51㎜ sand had large deposit volume in upper layer that could longer filtration time, moreover smaller media in lower layer that could protect break-through.

This study was conducted to evaluate the effects of pressure and dissolved oxygen concentration on the activated sludge and to determine the optimum depth of deep shaft process. Some results from this study were summarized as follows. 1. It is considered that low sludge product in the activated sludge system maintaining high dissolved oxygen concentration is attributed to the increase of endogeneous respiration rate caused by the increase of aerobic zone in the sludge floc. 2. The increase of dissolved oxygen concentration does not affect to the increase of organic removal efficiency greatly and therefore the limiting factor is the substrate transfer into the inner part of floc. 3. The yield coefficient, Y is decreased in proportion to the increase of oxygen concentration. In this study, Y values arre ranged from 0.70 to 0.41 according to the variation of dissolved oxygen concentration from 18.0㎎/ℓ to 258 ㎎/ℓ. 4. The optimum depth of deep shaft process should be determined within the limits of non-toxicity to the microorganism and it is about 100m in this study.