Poor bonding occurs with resin due to surface inertness of carbon fiber (CF), so CF surfaces were often treated. In some common surface treatments, sizing was a simple and effective modification method. Polyurethane (PU) was used as the main component of sizing agents due to its similar structure to polyamide 6 (PA6). The CF/PA6 composites’ interfacial properties were improved using PU as a sizing agent. Meanwhile, in this paper, glycidol (GLD) was introduced into the PU emulsion so that the epoxy group reacted with the carboxyl group on the acidified CF. After testing, when the content of glycidyl in the sizing agent is 2%, the CF/PA6 composites showed an important improvement in tensile, impact, and flexural strengths, which increased by 49.4%, 94.6%, and 53.2%, respectively. In addition, the effect of modified WPU sizing agents with different GLD contents on the properties of CF/PA6 composites was investigated.

In this study, a composite material based on agricultural waste coconut shells was successfully developed as an efficient, lightweight, and sustainable electromagnetic wave (EMW) absorber. Specifically, coconut shells were used as the raw material, and a simple one-step activation charring process was employed to obtain coconut shell porous carbon (CSPC). ZnFe2O4 with a hollow spherical structure was then in situ grown on the surface of CSPC, resulting in a special ZnFe2O4/ CSPC composite material. Due to its unique hollow structure, porous characteristics, and heterogeneous interfaces, the composite material achieved optimized impedance matching, leading to excellent EMW absorption performance. The fabricated ZnFe2O4/ CSPC composite demonstrated a minimum reflection loss ( RLmin) of − 37.32 dB at 10.80 GHz and an effective absorption bandwidth of 2.40 GHz at a thickness of only 2.0 mm. SEM and TEM analyses confirmed that the composite possessed a hollow and porous structure, while the BET specific surface area was measured at 133.709 m2 g⁻1. Based on the synergistic effects of ZnFe2O4 and CSPC, dielectric losses, magnetic losses, and impedance matching, the potential EMW absorption mechanisms were proposed. The ZnFe2O4/ CSPC composite material prepared in this study was a novel, green, and sustainable EMW absorber.

In the context of the global shipping industry's transition towards high efficiency and low carbon emissions, energy conservation and drag reduction for ships have become core research directions in marine engineering. Container ships, as the backbone of international trade, experience a significant increase in wind resistance under extreme wind conditions of level 8 and above, which affects their navigation efficiency, energy consumption, and safety. Optimizing wind resistance is crucial for enhancing ship performance and reducing carbon emissions. The fairing can reduce the air resistance of ships by optimizing the flow field and suppressing vortex flows, presenting broad application prospects. However, existing research has primarily focused on conventional wind conditions, and further analysis is needed under extreme wind conditions. Given the typicality and harmfulness of level 8 winds, this paper takes large container ships as the research object. Based on Computational Fluid Dynamics (CFD) numerical simulations, by establishing key structural models, optimizing computational domains and grids, and selecting the Realizable k-ε turbulence model and Volume of Fluid (VOF) multiphase flow model, this study investigates the drag reduction effect of polygonal curved fairings under level 8 wind speeds. It analyzes parameters such as drag coefficient and flow field distribution, reveals the flow field regulation mechanism, and provides theoretical support and data reference for the optimal design and engineering application of fairings.

This work concentrates on the design and implementation of aptamer-based electrochemical biosensors using a layer-by-layer approach for precise tracking of mucin-1 (MUC1), an important biomarker linked to breast cancer. The electrochemical biosensor was created by modifying a screen-printed carbon electrode (SPCE) with V2C MXene booster and gold nanoparticles (Au-NPs), along with Cd2+ integrated aptamer (AP) (SPCE/V2C-MXene/Au NPs/Cd2+-AP). This biosensor demonstrated high specificity and affinity for MUC1, establishing a sensitive quantification mechanism. The MXene nanolayer was produced and analyzed via TEM, XPS, SEM, AFM, BET, and MAP techniques. It served as a supportive material that enhanced electrochemical conductivity and allowed for the integration of the aptamer (AP) as the biological recognition component. The biosensor was constructed by immobilizing MUC1-specific aptamers onto the surfaces of SPCE/V2C-MXene/Au NPs, enabling selective recognition and binding with MUC1. The recorded signal, corresponding to Cd2+ integrated with AP at SPCE/V2C-MXene/Au NPs/Cd2+-AP, enabled quantitative assessment of MUC1 levels. The findings showed a linear concentration span of 1.0–500 pg/mL for detecting MUC1, achieving a detection limit of 3.45 fg/mL utilizing the SPCE/ V2C-MXene/Au NPs/Cd2+-AP biosensor. The SPCE/V2C-MXene/Au NPs/Cd2+-AP biosensor exhibited a good affinity for the detection of MUC1 in the presence of other breast cancer biomarkers, confirming its selectivity.

To optimize the electrochemical properties of Ni-rich cathode materials, CPAN@SC-NCM811 is prepared via surface modification of single-crystalline LiNi0.8Co0.1Mn0.1O2 cathode material by adding 1, 2 and 3 wt.% of polyacrylonitrile, respectively. Significantly, the results obtained from X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) verify the successful synthesis of CPAN@SC-NCM811 cathode, which exhibits better electrochemical properties compared to SC-NMC811. After thorough milling and calcination of 2 wt.% polyacrylonitrile with SC-NCM811, the initial discharge specific capacity of prepared S2 sample is 197.7 mAh g− 1 and the capacity retention reached 89.2% after 100 cycles at a rate of 1.0 C. Furthermore, the S2 sample exhibits superior rate performance compared to the other three samples, in which these superior electrochemical properties are largely attributed to the optimal ratio of conductive cyclized polyacrylonitrile coatings. Overall, this work offers guidelines for modifying the surface of SC-NCM811 cathode materials for lithium-ion batteries with exceptional cycling and rate performance.

Biomass-derived carbon materials have attracted considerable attention in electromagnetic wave (EMW) absorption applications due to their advantages of low cost, light weight, and sustainability. Herein, bagasse-based porous carbon (BPC) was prepared by canonization and activation process from natural waste bagasse. The porous flower-like MoS2/ BPC composites were successfully prepared for efficient microwave absorption via hydrothermal process by in-situ formation of flower-like MoS2 into the porous structure of BPC. The effect of hydrothermal time and hydrothermal temperature on surface morphology, degree of graphitization, surface chemical composition and impedance matching of the prepared samples was investigated. Results demonstrated that when the hydrothermal temperature was 220 °C, and the hydrothermal time was 24 h, the obtained MoS2/ BPC sample (named as MoS2/ BPC-220 ℃) showed the minimum reflection loss value (RL) of − 41.6 dB at 8.96 GHz and exhibited effective microwave absorption bandwidth (EAB) of 4.32 GHz at a relatively thin thickness of 1.5 mm. This work provides a promising way to prepare novel biomass-derived porous carbon for strong broadband electromagnetic absorption.

On the wooden slabs unearthed from the tomb of Guojianao (formerly, Guo) in the period of Sun Wu of the Three Kingdoms, there is a sentence with the words “針囊一枚, 白糸一 , 青糸一”. Past scholars interpreted the three characters “ ” ,“ ” and “ ” as the word “縱 (zong)” , which means “silk thread”, and “ ” ,“ ” as the word “㢧 (卷, juan, volume)”, which is a measure word. This study verifies that the word “ ” is “ ”, and “ ”, “ ” are “ ”, which are all variants of the word “線 (xian, line)”. This was achieved by changing the phonetic note. The measure word “ ”, “ ” used for weighing silk thread should be a variant form of the word “斤 (jin)”, which is similar to the writing of “ (jin)” or “ (jin)” in the Pan’s clothing list of the Eastern Jin Dynasty.

Building step-scheme (S-scheme) heterojunctions has recently emerged as a highly effective approach for developing superior photocatalysts for water purification. Herein, a C3N5/ Ag3PO4 (CA) S-scheme heterojunction was prepared by in situ growth of Ag3PO4 nanoparticles on 2D C3N5 nanosheets. Notably, under visible-light irridiation, CA exhibited significantly higher activity in the photodegradation of LEVO, which is about 28.38, 2.41, and 2.14 times higher than the rates for C3N5, Ag3PO4, and the mixture, respectively. Based on the radical scavenging experiments, the mechanism for enhanced photocatalytic performance has been analyzed, is attributed to improved interfacial charge separation, the elevated redox potential of photon-generated electrons and holes, and the increased generation of active species resulting from the S-scheme transfer of photoinduced carriers. Additionally, CA demonstrates greater stability than either C3N5 or Ag3PO4 alone in the photo-oxidation of LEVO and the photodegradation of RhB. In essence, this study not only deepens our comprehension of the photocatalytic mechanism of CA, but also pioneers a novel concept for the development of highly effective and stable S-type heterojunction photocatalysts.

Moso bamboo, as a kind of renewable functional material, exhibits outstanding development potential. It is promising to prepare activated carbon with good mechanical strength and high specific surface area using moso bamboo as raw material. In this work, we employed a hydraulic extruder to extrude the bamboo charcoal and the adhesive to obtain the moso bamboo activated carbon, and improved the specific surface area of the columnar activated carbon through high-temperature water vapor activation. Through the catalytic role of the water vapor activation process, the formation and expansion of the pores were promoted and the internal pores were greatly increased. The obtained columnar activated carbon shows excellent mechanical strength (93%) and high specific surface area (791.54 m2/ g). Polyacrylamide@asphalt is one of the most effective adhesives in the high-temperature water vapor activation. The average pore size (22.99 nm) and pore volume (0.36 cm3/ g) of the prepared columnar activated carbon showed a high mesoporous ratio (83%). Based on the excellent pore structure brought by the activation process, the adsorption capacity of iodine (1135.75 mg/g), methylene blue (230 mg/g) and carbon tetrachloride (64.03 mg/g) were greatly improved. The resultant moso bamboo columnar activated carbon with high specific surface area, excellent mechanical properties, and outstanding adsorption capacity possesses a wide range of industrial applications and environmental protection potential.

In the history of Chinese academics, Xu Shen’s Shuowen Jiezi (hereinafter referred to as Shuowen) is known as “the first of its kind in the world” because it has the dual characteristics of explaining the form, sound, and meaning of Chinese characters and the characteristics of theoretical works on philology, both of which are practical. It has not only become a treasure of codex for the compilation of character books and exegesis, but also laid down the basic patterns of traditional philology and biblio-linguistics, with far-reaching influence. Many scholars have researched Shuowen in the past dynasties, resulting in the formation of an independent thematic discipline called Shuowen, also known as Xuxue (許學). According to Ding Fubao (丁福保), Shuowen jiezi Gulin (hereinafter referred to as Gulin) attached to the Yingyong Zhushu Xingshi Lu (引用諸書姓氏錄) statistics, there were as many as 203 people in the Qing Dynasty who studied and wrote Shuowen. In fact, there are many scholars and their achievements that are not included in the statistics. After Gulin, especially in the last 30 years, a lot of new materials of scholars in the Qing Dynasty who studied the Shuowen have been excavated and published. Most of these new materials are dispersed in their original state in different large series, so they are rarely researched and utilized, and their documentary and scholarly value is in urgent need of formal recognition. Based on the preliminary results of the major project of the National Social Science Foundation (21&ZD299) chaired by Li Yunfu (李運富), this article discusses the excavation, collation, and research of new materials on Shuowen in the Qing Dynasty.

Herein, the present work focuses on the effective counter electrode for dye-sensitized solar cells. The bottom–up approach was adapted to synthesize Mn2O3 nanorods via the hydrothermal method and the reduced graphene oxide was merged with Mn2O3 to prepare a nanocomposite. The prepared nanocomposites were subjected to physio-chemical and morphological characterizations which revealed the crystalline nature of Mn2O3 nanorods. The purity level rGO was characterized using the Raman spectrum and the Fourier transform infrared spectroscopy employed to find the functional groups. The morphological micrographs were visualized using SEM and TEM and the high aspect ratio Mn2O3 nanorods were observed with 5–7 nm and supported by rGO sheets. The electrocatalytic nature and corrosion properties of the counter electrode towards the iodide electrolyte were studied using a symmetrical cell. The as-synthesized nanocomposites were introduced as counter electrodes for DSSC and produced 4.11% of photoconversion efficiency with lower charge transfer resistance. The fabricated DSSC devices were undergone for stability tests for indoor and outdoor atmospheres, the DSSC stability showed 93% and 80% respectively for 150 days.

In this study, a low-cost and easily recyclable porous green adsorbent (magnetic porous loofah biochar, MPLB) was synthesized by modifying the almost zero-cost loofah biochar material with Fe3O4. The successful synthesis of the material was demonstrated by XRD, FTIR, SEM, VSM, and BET. In addition, the material exhibits outstanding magnetic separation performance (40.01 umg/g) allowing for rapid recovery within just 90 s. The adsorption process of phenol on MPLB was found to be spontaneous and endothermic. The experimental data fit exceptionally well with the pseudo-second-order kinetic model and Langmuir model (R2 > 0.99), indicating that the dominant adsorption mechanisms involved monolayer adsorption and chemisorption. These interactions were attributed to host–guest interaction, π–π conjugation, hydrogen bonding, and pore filling. The maximum adsorption capacity calculated using the Langmuir model at 298 K is 39.4 mg/g. Importantly, even after undergoing seven cycles of recycling, MPLB retained 78% of its initial adsorption capacity. In simulated experiments employing MPLB for phenol removal in actual wastewater, an impressive removal rate of 96.4% was achieved. In conclusion, MPLB exhibits significant potential as an effective adsorbent for phenol removal in wastewater.

A glassy carbon electrode modified with a composite consisting of electrodeposited chitosan and carboxylated multi-walled carbon nanotubes (e-CS/MWCNTs/GCE) was used as a working electrode for simultaneous determination of dopamine (DA), serotonin (5-HT) and melatonin (MT), which were related to circadian rhythms. The electrochemical characterizations of the working electrode were carried out via electrochemical impedance spectroscopy and chronocoulometry. It was found that electrochemical modification method, that was cyclic voltammetry, may can cause continuous CS polymerization on MWCNTs surface to form a dense membrane with more active sites on the electrode, and the electrochemically active surface area of e-CS/MWCNTs/GCE obtained was about 7 times that of GCE. The electrochemical behaviour of DA, 5-HT and MT on working electrode were carried out via differential pulse voltammetry and cyclic voltammetry. The results showed that e-CS/MWCNTs/GCE solved the problem that the bare electrode could not detect three substances simultaneously, and can catalyze oxidation potential difference as low as 0.17 V of two substances reaction at the same time, indicating very good electrocatalytic activity. By optimizing the detection conditions, the sensor showed a good linear response to DA, 5-HT and MT in the range of 20-1000 μmol/L, 9-1000 μmol/L and 20-1000 μmol/L, and the detection limits were 12 μmol/L, 10 μmol/L and 22 μmol/L (S/N = 3), respectively. In addition, the proposed sensor was successfully applied to the simultaneous detection of DA, 5-HT and MT in human saliva samples.

An environmentally friendly and low-cost chitosan-containing polysaccharide (CP) composite ZIF-8/CP was designed and prepared based on the difficulty of separating the traditional adsorbent from the water phase. ZIF-8/CP was synthesized through in-situ growth approach. The physical, chemical and structure properties of ZIF-8/CP were determined through a series of characterization methods, including SEM, FT-IR and PXRD. The effects of touch time, pH, temperature, and coexisting ions on adsorption were assessed. In addition, kinetics, isotherms of adsorption and thermodynamics were examined. The data of isotherms for adsorption indicated that the adsorption of ZIF-8/CP on MG was similar to the Langmuir model, with a maximum adsorption capacity of 1428.57 mg/g. Moreover, the kinetic parameters were consistent with the pseudo- 2nd-order equation. Thermodynamic studies (ΔG < 0, ΔH > 0) demonstrated a heat-absorbing and spontaneous adsorption process. Our study reveals that ZIF-8/CP has good adsorption properties and environmental properties.