본 연구에서는 사다리꼴형상 투과성 수중방파제에 의한 정현파의 Bragg반사에 대해 수리모형실험과 수치모형실험을 수행하였으며, 두 실험결과를 비교하였다. 수치해석에 적용된 모형에서는 공간 평균된 Wavier-Stokes 방정식을 투과체 내에서의 지배방정식으로 사용하였고, 자유수면변위를 추적하기 위해 VOF기법을 적용하였다. 수리실험결과와 수치해석결과는 비교적 잘 일치하였으며, 투과성 수중방파제에 의한 반사계수는 불투과성에 비해 낮게 나타나고, 방파제의 배

The photodegradations of pyrene, chrysene and benzo[a]pyrene that were similar in structure among polycyclic aromatic hydrocarbons (PAHs) were investigated with a low-pressure mercury lamp(the wavelength of 253.7 nm and UV output of 1.35x10-3 J/s). The optimum concentrations of TiO2 and H2O2 on the photodegradation of pyrene, chrysene and benzo[a]pyrene were 1 g/L and 1.5 x 10-3 M, respectively. By these optimum concentrations, their rates increased with increasing the concentration of TiO2 and H2O2 because the amounts of OH radical formed increased, but for the higher concentrations than the optimum, their rates decreased with increasing those concentrations because the white turbidity phenomena occurs in case of TiO2 and H2O2 acts as an OH radical inhibitor. The photodegradation rates among the photodegradation processes such as UV, UV/TiO2, UV/H2O2, and UV/H2O2/TiO2 decreased in the following sequences: UV/H2O2/TiO2> UV/H2O2> UV/TiO2> UV.

본 연구에서는 유한요소법을 이용하여 일정 수심상에서 사각형 형상의 불투과성 수중방파제에 의한 파랑의 Bragg 반사를 수치적으로 고찰하였다. 유한요소법에 의해 계산된 반사율은 수리모형실험을 통해 얻어진 결과와 비교하였을 때 비교적 잘 일치하였으며, 고유함수전개법에 의한 결과와도 좋은 일치를 나타내었다. 그밖에 본 연구에서 개발된 모형은 불투과성 수중방파제의 폭과 길이의 변화에 따른 반사율 계산에 적용되었다.

In order to examine the pre-treatment effect of crab shell on Pb2+ removal by crab shell in aqueous solution, acid and alkali pre-treated crab shell were used. Electron microscopy techniques such as TEM (transmission electron microscopy) and SEM (scanning electron microscopy), and EDX (energy dispersive X-ray) and FTIR (Fourier transform infrared) spectrometry techniques were used to investigate the process of Pb2+ removal by acid and alkali pre-treated crab shell. The Pb2+ removal by acid pre-treated crab shell was much lower than that by untreated crab shell because of the decrease of CaCO3 from the crab shell. However, the Pb2+ removal by alkali pre-treated crab shell increased compared to that by untreated crab shell. The results were confirmed by TEM, SEM, EDX and FTIR.

The photodegradation of pyrene, chrysene and benzo[a]pyrene, that were similar in structure among polycyclic aromatic hydrocarbons (PAHs), were investigated in water irradiated with a low-pressure mercury lamp (wavelength of 253.7nm and UV output of 1.35×10-3J/s). The effects of several factors (t-BuOH, HCO3- and pH) on photodegradation of above three PAHs were also examined. The photodegradation rates of PAHs decreased with increasing the concentration of t-BuOH, but decreased little with increasing the concentration of HCO3- under the concentrations used in this study. The photodegradation rates of PAHs decreased with increasing pH, but their change were greater in case of pH increase from acid to neutral and were little in case of pH increase from neutral to base. The photodegradation rates of PAHs fitted a first-order kinetic model and their photodegradation rates decreased in the following sequences: pyrene>chrysene>benzo[a]pyrene among the PAHs used.

본 연구에서는 일정수심상에 사각형형상의 불투과성 수중방파제를 설치한 후 파랑의 반사를 수리실험을 통해 조사하였다. 입사파는 규칙파를 사용하였으며, 고유함수전개법을 이용하여 예측한 반사율을 본 연구에서 수행한 수리모형실험 결과와 비교하였다. 예측된 결과와 수리실험에서 관측한 결과는 비교적 잘 일치하였으며, 수리실험에 의한 반사율이 고유함수전개법에 의한 결과보다 다소 작았다.

In order to examine the inhibition effect of other heavy metal ions on the removal of heavy metal ions by crab shell in aqueous solution, 10 heavy metal ions (Cr3+, Cd2+, Ni2+, Zn2+, Hg2+, Cu2+, Mn2+, Fe2+, Fe3+, Pb2+) were used as single heavy metal ions and mixed heavy metal ions, respectively. In single heavy metal ions, Pb2+, Cr3+, Cu2+ were well removed by crab shell, however, Cd2+, Ni2+, Zn2+, Mn2+ were not. The heavy metal removal increased as the increase of covalent index (Xm2r), and the relationship classified heavy metal ions as 2 heavy metal groups (Fe3+, Fe2+, Cu2+, Cr3+, Mn2+, Ni2+, Zn2+ group and Pb2+, Hg2+, Cd2+ group). In mixed heavy heavy metal ions, the removals of Fe2+, Fe3+, Pb2+, Cu2+ as 0.49 mmol/g, regardless of the existence of other heavy metal ions, were similar to the result of single heavy metal ions experiment. The removals of Mn2+, Cd2+, Ni2+ decreased as the existence of other heavy metal ions, however, the removal of Zn2+, Cr3+, Hg2+ increased.

This study was designed to analyse the odor from Nam river. The characteristic odor in the water occurred from geosmin and phenol, p-cresol and indol were detected from sediment/water samples. The others were detected as alcohols and fat acid compounds. Algae causing odor and taste were identified as Oscillatoria sp. and Synedra acus. 15 species of phytoplankton, a zooplankton, an eelworm and chironomus were identified in water/sediment sample.

Several effects on Pb2+ removal by crab shell from aqueous solution were investigated. As the increase of initial Pb2+ concentration and decrease of initial crab shell concentration, the time required to reach an equilibrium state and the residual Pb2+ concentration increased. In our experimental ranges, the optimum initial Pb2+ concentration and crab shell concentration were below 103 mg/l and over 0.5 mg/l, respectively. Also, in order to investigate the mechanism of Pb2+ removal by crab shell in aqueous solution, the crab shell was compared with chitosan and chitin on aspects of Pb2+ removal capacity and Pb2+ removal rate. The Pb2+ removal by crab shell was greater than that by chitin and chitosan. The role of chitin was not so great in Pb2+ removal by crab shell. The Pb2+ removal by chitosan was not exactly correlated to the molecular weight of chitosan.

In order to examine the availability and effectiveness of crab shell for the removal of heavy metals in aqueous solution, the crab shell was compared with cation exchange resin (CER), zeolite, granular activated carbon (GAC) and powdered activated carbon (PAC) on aspects of heavy metal removal capacity, rate and efficiency. In the removal of Pb, Cd and Cr, the heavy metal removal capacity of crab shell was higher than those of any other sorbents (CER, zeolite, GAC, PAC), and the order of heavy metal removal capacity was crab shell > CER > zeolite > PAC =～GAC. However, in the removal of Cu, the result of crab shell was slightly lower than that of CER. The initial heavy metal removal rate was affected by the sorts of sorbents and metals. In all heavy metals, the heavy metal removal rate of crab shell was higher than those of any other sorbents. Under the heavy metal concentration of 1.0 mmole/ℓ, the heavy metal removal efficiency of crab shell was maintained as 93∼100 %, which was much higher than those of any other sorbents.

Numerical analysis of two-fluid flows for both water and air is carried out. Free-Surface flows with an arbitrary deformation have been simulated around two dimensional submerged hydrofoil. The computation is performed using a finite volume method with unstructured meshes and an interface capturing scheme to determine the shape of the free surface. The method uses control volumes with an arbitrary number of faces and allows cell-wise local mesh refinement. the integration in space is of second order based on midpoint rule integration and linear interpolation. The method is fully implicit and uses quadratic interpolation in time through three time levels The linear equation systems are solved by conjugate gradient type solvers and the non-linearity of equations is accounted for through picard iterations. The solution method is of pressure-correction type and solves sequentially the linearized momentum equations the continuity equation the conservation equation of one species and the equations or two turbulence quantities.

Heavy metal ions in water were removed using algal biomass as adsorbents. Absorbents were dried for 3 days, ground them by 40∼60 mesh and then were swelled in a buffer solution for 1hr. After being packed in the column, commercially available standard solution of Cd(Ⅱ) and Pb(Ⅱ) ions were diluted to get the suitable concentration and then it was eluted with the rate of 1 ㎖/min. Heavy metals on the adsorbents were recovered with nitric acid. More amounts of Cd(Ⅱ) or Pb(Ⅱ) ions in green algae, Ulva pertusa, than in brown algae, Sargassum hornerl, were adsorbed. Pb(Ⅱ) ion was adsorbed more than Cd(Ⅱ) ion in both algae. The pH effect of adsorbed amounts of Cd(Ⅱ), Pb(Ⅱ) ions on the biomass was shown the following order ; pH 10.5 > 8.5 > 7.0 > 5.5 > 3.5. Recovery ratio of metal ions from algae is shown higher in acidic or neural conditions than It in alkalis ones. Pb(Ⅱ) ion is recovered relatively more than Cd(Ⅱ) ion in our system.