The pilot plant experiment was performed to investigate phosphorus and nitrogen removal from domestic wastewater by MLE process combined with aluminum corrosion reactor. When operating 0.5Q and 1Q to internal recycle and sludge recycle in the MLE process, the effluent CODMn concentration of internal recycle 0.5Q were higher than internal recycle 1Q, the removal efficiency rates of NH3-N in the internal recycle 0.5Q were was higher than internal recycle 1Q. Denitrification rates were about 86.8% in internal recycle and sludge recycle 0.5Q. When operating 0.5Q to internal recycle and sludge recycle in the MLE process, the removal efficiency rates of total nitrogen was the highest. The removal efficiency rates of total phosphorus was about 91.5% in the aluminum corrosion reactor.

This study was performed to evaluate the removal feasibility of nitrogeneous malodor compounds using AlPO4 zeolite manufactured by total phosphorus sludge (herein after TPS), which was produced from sewage treatment plant. Adsorbents in this study were activated carbon treated by H3PO4 (herein after AC), bead (herein after B-TPS) and pellet type adsorbents (herein after P-TPS) manufactured from total phosphorus sludge which was generated from sewage treatment plant. The breakthrough time of AC for ammonia gas (herein after NH3) removal was approximately 320 min, while those of BTPS and P-TPS were 1,140 min and 820 min, respectively. For trimethylamine (herein after TMA) removal, the breakthrough time of AC was 400 min, B-TPS and P-TPS were 1,180min and 1,100 min, respectively. From the results, it judged that adsorbents produced by TPS could be used to replace AC.

The purpose of this study is to investigate the effect of influent phosphorus concentration on the nitrogen and phosphorus removal in sequencing batch reactor(SBR) and sequencing batch biofilm reactors(SBBRs) in order to recover the enhanced biological phosphorus removal (EBPR) capacity at the sludge of the deterioration of EBPR capacity. In SBBRs, comparing to SBR, the organic removal was occurred actively at the 1st non-aeration period because of the active phosphorus release at this period. However, the variation of TOC removal according to the decrease of influent phosphorus concentration was not clearly shown both in SBR and SBBRs. In case of SBR losing EBPR capacity, the EBPR capacity was not recovered by the decrease of the influent phosphorus concentration from 7.5 mg/L to 0.9 mg/L. The nitrogen removal increased by the decrease of influent phosphorus concentration both in SBR and SBBRs.

A laboratory experiment was conducted to investigate nitrogen removal from plating wastewater by a soil reactor. A combination of soil, waste oyster shell and activated sludge were used as a loading media in a soil reactor. The addition of 20% waste oyster shell and activated sludge to the soil accelerated nitrification (88.6% NH4+-N removal efficiency) and denitrification (84.3% NO3--N removal) in the soil reactor, respectively. In continuous removal, the influent NH4+-N was mostly converted to nitrate nitrogen in the nitrification soil reactor and only a small amount of NH4+-N was found in the effluent. When methanol was added as a carbon source to the denitrification soil reactor, the average removal efficiency of NO3--N significantly increased. The NO3--N removal by methanol addition in the denitrification soil reactor was mainly due to denitrification. The phosphorus was removed by the waste oyster shell media in the nitrification soil reactor. Moreover, the phosphorus removal in the denitrification soil reactor was achieved by synthesis of bacteria and the denitrification under anaerobic conditions. The approximate number of nitrifiers and denitrifiers was 3.3×105 MPN/g soil at a depth of 1～10 cm and 3.3×106 MPN/g soil at a depth of 10～20 cm, respectively, in the soil reactor mixed with a waste oyster shell media and activated sludge.

This study was conducted to investigate the ratios of phosphorus release to COD uptake, phosphorus release to nitrate removal, and phosphorus uptake to phosphorus release by DNPAOs(denitrifying phosphate accumulating organisms). In case I～IV, influent 1 were fed with synthetic wastewater with influent 2 NO3--N injection to anoxic zone and the case V were fed with municipal wastewater with side stream oxic zone instead of influent 2 NO3--N injection. As a result, the ratio of phosphorus release to carbon uptake was increased in accordance with nitrate supply. The DNPAOs simultaneously took up phosphate and removed nitrate from the anoxic reactor. In case I～IV, with above 20 mg/L of sufficient NO3--N supply, phosphate was taken up excessively by the DNPAOs in anoxic condition. The large amount of both uptake and release of phosphorus occurred above 20 mg/L of nitrate supply, achieving the ratio of phosphorus uptake to phosphorus release to be 1.05. In case V, phosphate luxury uptake was not occurred in system due to 6.98 mg/L of insufficient NO3--N supply and the ratio of phosphorus uptake to phosphorus release was 0.98. Consequently, if nitrate as the electron acceptor was sufficient in anoxic zone, the ratio was found to be high.

This study was carried out to investigate the variation of organic, nitrogen and phosphorus in (AO)2 SBBR process according to the variation of operating cycle at the high TOC concentration. The operation time in anoxic (anaerobic) time to oxic time was 1:1. Three lab-scale SBBRs were fed with synthetic wastewater based on glucose as carbon source. The variation of total TOC removal was similar each other irrespective of operation time, however, the TOC concentrations in SBBRs showed a little difference according to the operating condition. In SBBR, complete nitrification was not occurred at all reactors, however, R3 showed a higher nitrification than R2. And in SBBR, the variation of operating time more affected at phosphorus removal than nitrogen removal. R2 which had the shortest time at the 1st aeration time showed the lowest phosphorus release and uptake efficacy.

This study make a comparison between the phosphorus removal performance of FNR(Ferrous Nutrient Removal) process and A/O process by the laboratory experiments. For simultaneous removal of phosphorus, iron electrolysis was combined with oxic tank. Iron precipitation reactor on the electrochemical behaviors of phosphorus in the iron bed. The phosphorus removal in FNR process was more than A/O process. Iron salts produced by iron electrolysis might help to remove COD and nitrogen. And the demanded longer SRT is the more removes the removes COD, nitrogen, and phosphorus. Also, FNR process of sludge quantity more reduce than A/O process to input cohesive agents.

This study was carried out to get more operational characteristics of Anoxic(anaerobic)-Oxic-Anoxic-Oxic (AO)2 sequencing batch biofilm reactors (SBBRs) at the low TOC concentration. The operating time in anoxic (anaerobic) time to oxic time was 1：1. Experiments were conducted to find the effects of the aeration time distribution on the organic matters and nutrients removal. Three lab-scale reactors were fed with synthetic wastewater based on glucose as carbon source. During studies, the operation mode was fixed. The first aeration time to the second aeration time in SBBR-1 was 2：3, and those in SBBR-2 and SBBR-3 were 1：4 and 3：2, respectively. The organic removal efficiency didn't show large difference among three reactors of different aeration time distribution. However, from these study results, the optimum aeration time distribution in the first and the second aeration time for biological nutrient removal was shown as 3：2. The release of phosphorus was inhibited at the second non-aeration period because of the low TOC concentration and the nitrate produced by the nitrification at the first aeration period.

A laboratory experiment was performed to investigate phosphorus and nitrogen removal from synthetic wastewater by intermittently aerated activated sludge process packed with aluminum and silver plate. Three continuous experimental processes, i. e. an intermittently aerated activated sludge process(Run A), an intermittently aerated activated sludge process with an aluminum and silver plate packed into the reactor(Run B), and a reactor post stage(Run C) were compared. In the batch experiments, the phosphorus removal time in the reactor packed with aluminum and silver plate simultaneously was faster than that of the reactor packed with only an aluminum plate. More phosphorus was removed with an increase of NaCl concentration. The pitting corrosion of aluminum does not affect the performance of the biological treatment. The total nitrogen removal efficiency in Run B was 57% and 43.6% at the HRT of 12 and 6 hours respectively. The effluent PO4-P concentration as low as 1.0 mg/L could be obtainable through the continuous experiment in Run B at HRT of 6 hours.

Laboratory experiments were performed to investigate the effects of various factors on the phosphorus removal by electrolysis with aluminium electrodes. The efficiency of phosphorus removal increased with increasing of voltage applied, surface area of electrodes and electrolyte concentration, and decreasing of electrode distance. The phosphorus removal was not affected by the connection number of an electric circuit. The amount of aluminium ion eluted from electrodes according to Faraday's law was 4.47 ㎎ and the Al/P mole ratio was 2.14 at the electric current value of 20 ㎃.

The fundamental experiments on the phosphorus removal from water were carried out by the batch and continuous reactors which used aluminium and copper plate. In this systems, the phosphorus was removed by aluminium ion generated with the electrochemical interaction (pitting corrosion) of aluminium and copper. In the batch experiments, the efficiencies of phosphorus removal increased when the surfaces of aluminium and copper plate were brushed. The phosphorus removal by aluminium ion was affected the copper plate and NaCl in this system. The optimal pH values were 5 and 6 for the phosphorus removal. The efficiency of phosphorus removal increased with increasing NaCl concentration, surface area of aluminium and copper plate. The CuSO4·5H2O instead of copper plate could be used as Cu source. The effluent PO4-P concentration as low as 2㎎/ℓ could have been obtained during the continuous experiment at HRT of 48 hrs.

Sequencing Batch Reactor(SBR) experiments for organics and nutrients removal have been conducted to find an optimum anaerobic/anoxic/aerobic cycling time and evaluate the applicability of oxidation-reduction potential(ORP) as a process control parameter. In this study, a 6 ℓ bench-scale plant was used and fed with night-soil wastewater in K city which contained TCODcr : 10,680 ㎎/ℓ, TKN : 6,893 ㎎/ℓ, NH_4^+ -N : 1,609 ㎎/ℓ, PO_4^3- -P : 602 ㎎/ℓ on average. The cycling time in SBRs was adjusted at 12 hours and 24 hours, and then certainly included anaerobic, aerobic and anoxic conditions. Also, for each cycling time, we performed 3 series of experiment simultaneously which was set up 10 days, 20 days and 30 days as SRT. From the experimental results, the optimum cycling time for biological nutrient removal with night-soil wastewater was respctively 3hrs, 5hrs, 3hrs(anaerobic-aerobic-anoxic). Nitrogen removal efficiency was 77.9%, 77.9%, 81.7% for each SRT, respectively. When external carbon source was fed in the anoxic phase, ORP-bending point indicating nitrate break point appeared clearly and nitrogen removal efficiency increased as 96.5%, 97.1%, 98.9%. Phosphate removal efficiency was 59.8%, 64.5%, 68.6% for each SRT. Also, we finded the applicability of ORP as a process control parameter in SBRs.