This paper describes an experimental program to investigate the shear behavior of insulated concrete sandwich panels (CSPs) with different types of GFRP shear connector. The study included testing of 13 insulated CSP specimens with two types of surface conditions for extruded polystyrene (XPS) insulation and various shapes of shear connectors. All specimens were loaded in direct shear by means of push-out and were consist of three concrete panels, two insulation layer and four rows of GFRP shear connectors. Load-relative slip between concrete panel and insulation response of CSP specimens has been established through push-out shear test. Test results indicate that the surface condition of insulation has a significant effect on the bond strength between concrete panel and insulation. The specimen used XPS foam with 10mm deep slot shows higher bond strength than those used XPS foam with meshed surface. Corrugated GFRP shear connectors show equivalent strength to grid GFRP shear connectors. Cross-sectional area and embedded length of shear connector have a notable effect on overall response and inplane shear strength of the CSP specimens.

핵폐기물을 고화시키는 재료로 사용하는 붕규산염(borosilicate) 유리의 용해는 지층 처분장에 처리된 고준위 방사성 폐기물의 생태계 유출을 결정할 수 있는 중요한 화학반응이다. 습식 실험에서 유리의 용해속도(dissolution rate)는 유리 화학조성에 의해 크게 좌우되는 것이 관찰된다. 유리의 bulk 구조를 규명한 분광분석 실험에 의하면 유리의 화학조성과 분자수준(molecular-level) 구조(예: SiO4 사면체의 연결구조와 B 원소의 배위구조) 사이의 상관관계가 존재한다. 따라서 화학조성에 따른 유리 용해도의 차이는 조성에 따른 bulk 내부구조의 변화로 이해되어 왔다. 그런데 유리 표면은 수용액과 계면을 이루면서 용해 과정에서 가장 직접적으로 반응하는 부분이기 때문에, 화학조성에 따른 표면구조 변화에 대한 지식 또한 필요하다. 본 논문에서는 분자 동역학(molecular dynamics, MD) 시뮬레이션을 사용하여 4가지의 다른 화학조성을 가지는 소듐붕규산염 유리(xNa2O·B2O3·ySiO2 화학조성)에 대하여 bulk 구조와 실험으로 얻기 어려운 표면(surface) 구조를 연구하였다. MD 시뮬레이션은 유리 표면의 화학조성과 분자수준 구조가 bulk의 것과 매우 상이한 결과를 보여준다. 본 연구의 MD 시뮬레이션 결과는 화학조성에 따른 유리 용해도(특히 초기 용해과정)는 bulk 구조의 변화보다 유리 표면구조의 변화에 의해 크게 좌우될 수 있다는 표면구조에 대한 이해의 중요성을 역설한다.

Many existing building in korea, constructed according to an out-date standard, were found to be inadequate to withstand major earthquake. Accordingly, significant research effort has been devoted to develop and evaluate different strengthening techniques to increase to seismic resistance of R/C structure. In our previous research[1], the galss fiber sheet and carbon fiber brace system for seismic strengthening was developed. In the study, a three-story R/C building that represent a typical Korean school constructed in 1980s was selected, and its seismic performance before and after strengthening was evaluated based on the seismic capacity evalution method.

This study is to understand the flexural behaviors of hollow core beam using GFRP reinforcing Bar. The ultimate goal of this study is to apply the hollow core slab using GFRP reinforcing bar in a construction site. To achieve this, five specimens is planned and conducted on experimental study. The shape and size of specimen are rectangular shape of cross section with 210mm x 230mm. As a results of test, to add deformed bar in hollow core beam using GFRP reinforcing bar demonstrated superior flexural performance. Therefore hollow core beam using GFRP reinforcing bar is considered appropriate to apply in the field.

Domestic expressway are exposed to damage of combined deterioration by excessive use of deicer and a lot of cost is required for maintaining damage structures. Therefore, now is the time that durability of subsidiary concrete structures is required to enhanced in order to reduce maintenance cost of structures and to promote road safety. Thus, in this study measured compression strength and scaling resistance of concrete using the waste glass sludge

Expanding economic growth, the increased and shortened of electronic products rapidly last a couple of decades in Korea. Furthermore, as converting to digital broadcasting system, the amount of discarded analog type TV containing cathode ray tube(CRT) glasses are increasing significantly. Accordingly, since there is no demand for CRT glass anymore, it is very important to find out how to recycle a waste CRT glass. The research was carried out to investigate the best available technologies for recycling waste CRT glass. Primary feasibility studies to find the appropriate technologies were performed in advance and then the use as aggregates of cement bricks was found as a simple and economic way of recycling CRT panel glass cullet. Based on the selection of proper technology, which is the aggregate of cement bricks fabrication using CRT glass crushed, the evaluation of recyclability were made by replacing CRT glass particles to aggregates in the mixture of cement bricks. Up to 50% of sand or stone powder was replaced and the bricks with CRT glasses were manufactured and tested in their qualities as concrete bricks. The bricks including 20 to 30% of CRT particles instead sand or stone powder were good enough to meet the standard in bending strength and absorption rate.

Consumers increasingly prefer HDTV (high definition television), including LCD (liquid crystal display), LED (light emitting diode), and plasma TVs (television), and existing analog TV broadcasting system will be switched to digital broadcasting at the end of 2012 in Korea. Even for computer monitors, CRT (cathode-ray tube) monitors are no longer preferred because of customers’ increasing desire for thinner and lighter monitors and mobile computers. It is anticipated that these shifts will lead to a dramatic increase in disposal of analog TV sets. In 2012, it is estimated that about 117 thousand tons of CRT glass waste will be generated in Korea. CRT glass waste is not only Korea’s problem but also global issue, which needs worldwide attentions and policies for conserving useful resources and preventing groundwater pollution from heavy metals contained in CRT glass waste in case of landfill. It is important to develop BATs (best available technologies) to recycle CRT glass waste properly in short times. Therefore, in this study recycling possibility of CRT class was evaluated for the clay brick including powder of CRT glass of after crushing. Compressible strength and absorption factor of fabricated sample clay bricks were measured and observed whether they could satisfy the Korean Industrial Standard to use as normal bricks or not. The clay bricks containing under 5% of CRT panel glass powders were found to show enough quality as bricks, therefore the recycling of CRT cullet as materials of clay bricks could be utilized as one of the options.

The object of this research is to confirm the effect of Waste Glass Sludge on properties of concrete through compressive strength and Alkali-Silica reaction of concrete and to develop as construction material.

미국, 영국 등 외국에서는 설치되는 위치 및 내화성능 시간 등에 따라 방화유리 또는 내화유리의 사용을 명확히 규정하고 있는 반면, 국내 건축법에서는 방화유리를 발코니 방화벽 등 일부에만 사용할 수 있도록 규정하고 있다. 그러므로 국내에서 유리부재를 방화구획 등에 사용하려 하여도 관련 규정이 명확하지 않아 그 사용에 어려움이 있었다. 본 연구에서는 국외의 방화유리 및 내화유리 관련 기준 및 시험방법을 고찰하여, 화재시 건축물에서 유리부재의 적절한 방화성능기준 수준을 평가하고자 하였다. 연구된 자료는 유리부재 설치에 대한 규정 개정의 기초자료로 사용될 수 있을 것으로 판단되었다.

울릉도의 조면암질 응회암의 저온변질작용으로 할로이사이트가 생성되었다. 할로이사이트는 자연 상태에서 수화된 상태로 발견되었으며, 양파구조의 구상 또는 가장자리가 휘어진 판상 입자로 산출된다. 할로이사이트는 Si의 함량이 고령토 광물의 이상값보다 높아서 약간의 비정질이 혼재한 것으로 해석되었다. 또한 할로이사이트의 높은 Fe 함량은 판상 할로이사이트 생성의 원인이다. 조면암질 유리가 변질되면서 용탈된 원소들이 주로 화산유리의 입간 공극에 할로이사이트로 침전되었으며, 유리를 교대한 Si가 풍부한 반구상 비정질 집합체도 부분적으로 구상할로이사이트로 변질된 것으로 보인다. 할로이사이트는 조면암질 화산활동이 활발했던 울릉도에서 화산재의 주요 변질물 중의 하나이다.

GFRP 보강근은 콘크리트의 알칼리성분에 의해 손상 받을 수 있다. 본 논문은 이형 GFRP 보강근의 알칼리에 대한 내구성을증진시키기 위한 방법에 대한 실험적 연구이다. 기존 개발된 이형 GFRP 보강근의 표면물질에 삽입되는 초단유리섬유는 콘크리트와의 부착성능을 향상시키는 것으로 알려져 있다. 본 논문에서는 초단 알칼리저항섬유(AR-glass)와 E-glass 섬유를 표면이형의 구성물질로 활용하였을 때, 보강근의 내구성능에 미치는 영향을 흡습시험과 ISS 실험을 통하여 규명하고자 하였다. 혹독한 실내실험조건을 위하여 40℃의 온도가 적용되었다. 실험결과, 표면성형을 위한 레진과의 합성물로써, E-glass와 AR-glass 를 사용하였을 때, 내구성능에 큰 차이는 없는 것을 확인하였다. 오히려, 레진과 섬유의 혼합비가 작업성과 성형성에 영향을 미치고, 이것이 표면 이형부에 공극을 만들게 됨으로써, 큰 영향을 미치는 것으로 나타났다. 따라서, 장기적인 내구성능 확보를 위해서 혼입률의 결정에 주의를 기울여야 한다.

The aim of this study is investigated greenhouse gas emissions of glass industry, and when calculates greenhouse gas emission, using formula(Tier 3) advising in IPCC(Intergovernmental Panel on Climate Change) and using self designed formula(Tier 3+) authors of this study. Studied to propose calculation formula that can compare these two calculation results and apply to domestic. Formula of Tier 3 calculated to theoretical composition of carbonate material, And Formula of Tier 3+ calculated on the basis of chemical substance formation table that get from glass manufacture company(The S company). As a result, Dolomite, Soda ash, Limestone, Industrial Barium carbonate is calculated value of Tier 3+ lower than value of Tier 3, And Industrial Potassium carbonate, Industrial Strontium carbonate was calculated value of Tier 3 lower than value of Tier 3. This study finding, formula of Tier 3+ has higher confidence than formula of Tier 3 when consider revision about purity of injection raw material. And hereafter, When calculate greenhouse gas emissions about nonmetallic mineral industry, use of Tier 3+ is considered that should be encouraged.

Photocatalytic degradation of chlorpyrifos and diazinon, which are extensively used as an organophosphorous pesticide in the agriculture field, has been investigated with UV-radiated TiO2 in aqueous phase. Photodegradation rate was increased with increasing pH of the solution. The removal efficiencies of chlorpyrifos and diazinon were 100% after 200 min in pH 9. Photodegradation followed a pseudo-first-order reaction. The rate constants of chlorpyrifos and diazinon were 0.0160min-1 and 0.0180min-1, respectively. NO3-, PO43-, SO42- and Cl- were found as end products on the photocatalytic degradation of chlorpyrifos and diazinon with TiO2/UV.