This study was carried out to synthesis the zeolite using the bituminous coal fly ash emitted from power plant that occurs several environmental problems. In spite of fly ash has contained high content of SiO2 and Al2O3, it disposed mainly landfill. If the effective methods to recover the SiO2 and Al2O3 were developed, the fly ash could be utilized valuable raw materials. In this study, fly ash was used as raw material to synthesize the zeolite by pressurized hydrothermal reaction. Also, experimental parameters included temperature(70~110℃, and pressure(140~200 psi) of crystallization were investigated. The more crystallization pressure was increased, the more Zeolite 4A was synthesized at 70 and 90℃. Zeolite 4A of metastable phase tend to be transformed into sodalite of stable phase at 110℃.

Flying and solidification behaviors of the particles manufactured by centrifugal atomization were investigated. Both models were solved by the explicit FDM. Flying calculation supported the experimental results that the finer particles flied shorter than coarser particles and that particles flied shorter for lower rotation velocity than for higher velocity. Cooling curve and dendrite arm spacing were predicted by use of heat transfer analysis.

1990년 6월부터 전남지방에서 성훼로몬을 이용한 파밤나방의 발생소장, 일일비산활동 및 기주별 가해특성을 조사한 결과 성충은 6월 중순부터 trap에 유인이 시작되어 11월 하순까지 계속되었으며 발생 peak는 비닐하우스에서 8월 중순~하순, 9월 중순~하순, 11월 상순~중순이었으며 야외포장에서도 역시 6월 중순부터 유인이 시작되어 9월 상순~하순, 10월 중순~11월 하순에 유인량이 많았으며 노지에 비해서 비닐하우스에서 peak가 20일 가량 빨랐다. 유충의 biomass에 의한 발생 가능세대수는 남부지방에서 6회로 추정되었다. 일일중 비산활동은 주로 24시 이후부터 일출전까지 활발하였으며 peak는 4시~6시 사이였다. 기주에 따른 가해특성은 외대파에 있어서는 초장 10cm이하에서 유충 밀도 및 피해주율이 가가장 높았으며, 국화는 생육에 따라 피해주율이 점차 증가하다가 생육후기에는 오히려 떨어지는 경향이었고 가해부위는 시기에 관계없이 주로 엽상이 70%이상이었고 다음은 엽하 12.3%, 정단 9.3%순이었다. 또한 안개초에 있어서 피해주는 거의 생육을 하지 못하여 개화에 이르지 못하였다.

A zeolite material with a Si/Al molar ratio of 1.2 was synthesized by changing the NaOH/CFA ratio of coal fly ash (CFA) via a fusion/hydrothermal reaction in the HD thermal power plant. The change in the crystal structure of the zeolite was confirmed using XRD and SEM, and the ammonia adsorption capacities of the synthesized zeolitic materials and a commercial zeolite (Na-A zeolite) were analyzed via an ammonia temperature-programmed desorption (NH3-TPD) process. The SEM and XRD results revealed out the zeolitic materials from the coal fly ash maintained a hexagonal Linde-type crystal structure similar to that of Na-A zeolite, but the crystallinity of the synthesized zeolitic material was reduced due to impurities. The NH3 adsorption capacity, determined from the NH3-TPD analysis of was 1.122 mmol/g of the synthesized zeolitic material, which was lower than the NH3 adsorption capacity of the Na-A zeolite.

Zeolitic material, Z-Y3, was synthesized from coal fly ash (CFA) under low-alkaline conditions (NaOH/CFA ratio = 0.3 and NaOH solution concentrations of 0.0, 0.5, and 1.0 M) using a fusion/hydrothermal method. The adsorption capacities of the fabricated Z-Y3 samples for Cs and Sr ions and the desorption capacity of Na ions were evaluated. The XRD patterns of the Z-Y3 sample fabricated using a 1.0 M NaOH solution (Z-Y3 (1.0 M)) indicated the successful synthesis of a zeolitic material, because the diffraction peaks of Z-Y3 coincided with those of the Na-A zeolite in the 2θ range of 7.18-34.18. Moreover, the SEM images revealed that morphology of the Z-Y3 (1.0 M) sample, which presented zeolitic materials characteristics, consisted of sharp-edged cubes. The adsorption isotherms of Cs and Sr ions on all the fabricated Z-Y3 samples were described using the Langmuir model, and the maximum adsorption capacities of Cs and Sr were calculated to be 0.14-0.94 mmol/g and 0.19-0.78 mmol/g, respectively. The desorption of Na ions from the Cs and Sr ions adsorbed Z-Y3 samples followed the Langmuir desorption model. The maximum desorption capacities of Na ions from the Cs and Sr ions adsorbed Z-Y3 (1.0 M) samples were 1.28 and 1.49 mmol/g, respectively.

최근 정부의 미세먼지 특별법이 발효됨에 따라 비상저감조치 시행시 건설현장 및 공장 작업시간을 조정 및 단축하도록 권고하고 있지만 정량적인 기준 및 저감기술 부재로 인해 기업의 자발적 참여를 유도하는 수밖에 없는 실정이다. 또한 최근 도로포장 재료생산 플랜트에서 발생하는 비산먼지 및 유해가스로 인한 피해사례가 다수 발생하고 있으며 이로 인한 공장 주변 주민들과의 갈등이 심각한 실정이다. 이에 본 연구에서는 국내외 도로포장 관련 비산먼지 발생현황 및 관련법에 대한 조사를 수행하고, 도로포장 전주기(생산-시공-운영)에서의 단계별 발생량 조사를 통해 각 단계에 적합한 비산먼지 저감기술 개발 및 적용방안을 제시하고자 한다.

A zeolitic material (Z-Y2) was synthesized from Coal Fly Ash (CFA) using a fusion/hydrothermal method under low-alkali condition (NaOH/CFA = 0.6). The adsorption performance of the prepared zeolite was evaluated by monitoring its removal efficiencies for Sr and Cs ions, which are well-known as significant radionuclides in liquid radioactive waste. The XRD (X-ray diffraction) patterns of the synthesized Z-Y2 indicated that a Na-A type zeolite was formed from raw coal fly ash. The SEM (scanning electron microscope) images also showed that a cubic crystal structure of size 1~3㎼ was formed on its surface. In the adsorption kinetic analysis, the adsorption of Sr and Cs ions on Z-Y2 fitted the pseudo-second-order kinetic model well, instead of the pseudo-first-order kinetic model. The second-order kinetic rate constant (k2) was determined to be 0.0614 g/mmol·min for Sr and 1.8172 g/mmol·min for Cs. The adsorption equilibria of Sr and Cs ions on Z-Y2 were fitted successfully by Langmuir model. The maximum adsorption capacity (qm) of Sr and Cs was calculated as 1.6846 mmol/g and 1.2055 mmol/g, respectively. The maximum desorption capacity (qdm) of the Na ions estimated via the Langmuir desorption model was 2.4196 mmol/g for Sr and 2.1870 mmol/g for Cs. The molar ratio of the desorption/adsorption capacity (qdm/qm) was determined to be 1.44 for Na/Sr and 1.81 for Na/Cs, indicating that the amounts of desorbed Na ions and adsorbed Sr and Cs ions did not yield an equimolar ratio when using Z-Y2.

In this study, zeolitic materials at Na2CO3/CFA ratio of 0.6 1.8 were synthesized from coal fly ash from a thermal power plant using a fusion/hydrothermal method. The zeolitic materials were found to have cubic crystals structure and X-ray diffraction (XRD) peaks of Na-A zeolite by XRD and SEM analysis. When the zeolitic materials were synthesized from the coal fly ash, the XRD peaks of the zeolitic materials at Na2CO3/CFA ratios of 0.9-1.8 had the same location as the XRD peaks of commercial Na-A zeolite. The XRD peaks of the Na-A zeolite (Na12Al12Si12O4827.4H2O) were confirmed in the 2θ in the range of 7.18-34.18. However, it was also confirmed that peaks of CaCO3, an impurity inhibiting synthesis of Na-A zeolite from CaO and Na2CO3 in the coal fly ash, occurred in the XRD peaks of the zeolitic materials at Na2CO3/CFA ratio of 1.5-1.8. The crystallinities of the zeolitic materials tended to increase gradually within the Na2CO3/CFA ratio range of 0.6-1.8.

생활폐기물 및 산업폐기물로부터 고형연료를 제조하는 과정에서 폐기물 반입량 대비 30 ~ 45%의 비율로 잔재물이 발생되어 매립되거나 일부는 소각장으로 반입되어 처리되고 있다. 이러한 잔재물은 함수율 40% 이상을 나타내어 그대로 매립되었을 경우 오염부하를 증가시킬 수 있으며, 매립에 의한 처분비용으로 전체 시설 운영비의 약 20%가 요구되는 실정이다. 이러한 잔재물은 양 및 질적인 측면에서 볼 때 추가 공정을 통하여 충분히 고형연료로 생산이 가능하다. Bio-drying 기술은 폐기물 내에 존재하는 생분해성 유기물질에 대한 미생물의 호기성 분해열을 이용하여 폐기물의 수분을 건조시키는 건조에너지 소모 및 설치/운영비를 최소화 할 수 있는 경제성이 우수한 기술이다. 본 연구에서는 고형연료화 시설에서 발생된 잔재물을 대상으로 Bio-drying 기술을 적용시켜 생산된 비성형 고형연료의 벤치규모 연소실험을 통해 연소 공기비에 따른 바닥재와 비산재의 발생 특성을 고찰하였다. 또한 기존 시중에 판매되고 있는 비성형 고형연료와의 연소특성 비교/분석을 통해서 Bio-dyring 고형연료의 연소특성을 파악하고 연소 조건의 최적화를 진행하였다. Bio-drying 고형연료와 판매용 고형연료의 연소 바닥재의 XRF 분석 결과 CaO, SiO2, Al2O3, Fe2O3가 주성분을 이루며 그 중에서 CaO 성분이 각각 36.6%와 48.6%로 가장 높게 나타났다.

Recently, the velocity of vehicle in highway has been increased due to improved driving environment. Unfortunately, the impact resistance of present concrete median barrier is not enough for increased impact severity due to increased velocity, furthermore, these increased velocity occurs another secondary accidents due to the concrete fragmentation. Therefore, in this study, the evaluation of impact resistance for developed concrete median barrier was performed with shock absorber.

Zeolite (FZ), prepared from fly ash, was immobilized with polyacrylonitrile (PAN) to fabricate PAN/FZ beads. The prepared PAN/FZ beads were characterized by scanning electron microscopy, thermogravimetric analysis, and Fourier transform infrared spectroscopy. The optimum ratio to prepare PAN/FZ beads was 0.3 g of PAN to 0.3 g of FZ. The diameter of the prepared PAN/FZ beads was about 3 mm. Sr and Cu ion adsorption experiments were conducted with PAN/FZ beads. A pseudo-second-order model fit the kinetic data for Sr and Cu ion adsorption by PAN/FZ beads well. The equilibrium data fitted well with the Langmuir isotherm model, and the maximum adsorption capacities were 96.5 mg/g and 74.6 mg/g for the Sr and Cu ions, respectively. Additionally, the values of thermodynamic parameters such as Gibbs free energy (ΔGo), enthalpy (ΔHo) and entropy (ΔSo) were determined. The positive values of ΔHo revealed the endothermic nature of the adsorption process and the negative values of ΔGo were indicative of the spontaneity of the adsorption process.

범지구적으로 다양한 문제를 야기하는 지구온난화 현상은 해결해야하는 필수 과제 중 하나로 여겨져 왔다. 이 중에서 이산화탄소는 낮은 지구온난화 지수에도 불구하고 가장 많은 양으로 인해 지구온난화 현상에 대해 가장 큰 책임을 가지고 있다. 이산화탄소 저감을 위한 기술로 금속 이온과 이산화탄소의 결합을 통한 무기탄산화 기술이 최근 떠오르고 있다. 무기탄산화 기술의 가장 큰 가능성 중 하나는 다양한 금속이온을 가지고 있는 폐기물을 원료로 이용할 수 있다는 점이다. 본 연구에서는 이러한 폐기물 중 다량의 Ca를 가지고 있는 것으로 알려진 비산재를 이용하여 무기탄산화, 그 중에서도 수용액 내에 이산화탄소를 주입하여 반응시키는 직접수성 탄산화를 통한 탄산칼슘 생성에 대해 다루었다. 다량의 불순물을 포함하고 있는 비산재를 보다 순수한 형태로 이용하기 위하여 고온 (70℃)의 물로 세정하여 이용하였다. 총 500 g의 흡수제 중 세정한 비산재가 10 wt% (50g) 포함되었고, 5 wt% (25 g)의 NaOH 첨가 유무에 따른 CO2 저감량의 차이를 CO2 로딩 분석을 통해 비교하였다. 생성물에 대하여 XRD 그리고 TGA 분석을 통해 구성성분 및 순도 분석을 진행하였다.

This study provides experimental results of pH restoration of acidified desulfurization seawater by the addition of the alkalinity enhanced seawater and additives (limestone and fly ash). The conservative seawater desulfurization processes use chemical solutions such as caustic soda (NaOH) or calcium hydroxide(Ca(OH)2). The method proposed in this study was aimed at reducing usage of chemicals. A control test was conducted to simulate the existing process without addition of the alkalinity-enhanced seawater and additives (limestone and fly ash). The pH of desulfurized seawater was increased by pH 5.84 through the conservative restoration process (i.e., adding raw seawater and NaOH solution followed by aeration). The 20%, 50%, and 80% of added raw seawater was replaced by the alkalinity-enhanced seawater. From the experimental result, 0.28, 0.89, and 1.05 m3/hr of 48% NaOH solution could be saved when applying the proposed method of the alkalinity enhanced seawater addition. When desulfurized seawater with pH 3.5 was mixed with raw seawater at a ratio of 1:1, the pH of seawater was increased up to pH 6. Therefore, the seawater restoration goal was set as pH 3.5. Experiments were conducted to increase pH of desulfurized seawater to pH 3.5 using additives (fly ash and limestone). Based on these results, the addition of fly ash and limestone to seawater was proved effective for pH restoration of desulfurized seawater.

This study investigates the concentration sudden rise in fine particle according to resuspended dust from paved roads after sudden heavy rain in Busan on August 25, 2015. The localized torrential rainfall in Busan area occurred as tropical airmass flow from the south and polar airmass flow from north merged. Orographic effect of Mt. Geumjeong enforced rainfall and it amounted to maximum 80 ㎜/hr at Dongrae and Geumjeong region in Busan. This heavy rain induced flood and landslide in Busan and the nearby areas. The sudden heavy rain moved soil and gravel from mountainous region, which deposited on paved roads and near roadside. These matters on road suspended by an automobile transit, and increased fine particle concentration of air. In addition outdoor fine particle of high concentration flowed in indoor by shoes, cloths and air circulation.

In this study, analytical study on the missile impact behavior of the nuclear power plant SC(steel plate concrete) wall was carried out to set up the future direction for the reasonable design method development. Four set of pre-test impact analysis of the SC wall were performed. Finally, analytical results were compared with the actual test results, and the adequacy of the analytical method was verified. Calibrations of the analytical parameter will be performed, and the optimized analytical method is to be developed for the post-test analysis.

In this study, experimental study on the missile impact behavior of the nuclear power plant SC(steel plate concrete) wall was carried out to set up the future direction for the reasonable design method development. Four set of actual impact test of the SC wall were conducted at the EMRTC site located in Socorro, New Mexico. Initial and residual velocity of the missile, strain and acceleration of the back plate, local failure mode and deformation size, etc. were measured to study the local failure behaviour of the specimens. Finally, the experimental results are compared with the local failure evaluation formula and future research direction for the refined design method of the SC wall was reviewed.

사막의 모래는 바람의 영향으로 인한 비산 및 퇴적작용으로 사구(모래언덕)를 형성하거나, 이동시켜 사막 지형을 변화시킨다. 특히 사막에 철도궤도 부설시 이러한 사막모래의 비산으로 인한 퇴적은 철도유지보수에 지장을 주어 철도운행 및 안전에 심대한 악영향을 미치며, 심각한 경제적 손실을 야기할 수 있다. 이러한 문제는 모래의 비산 및 퇴적작용에 대한 예측을 이용한 적절한 예방대책 수립을 통하여 최소화 할 수 있다. 이 연구에서는 지형 및 기상조건 등을 고려하여 바람으로 인한 사막모래의 비산 및 퇴적작용을 예측할 수 있는 기법을 고찰하였다. 세부적으로는 지형에 따른 풍향 및 풍속의 예측 기법과 이에 따른 모래의 비산 및 퇴적 예측 기법, 모래 입자의 크기 및 성질에 따른 특성 변화 예측 기법들에 대하여 고찰하였으며, 기법의 적용 방법은 수치 예제를 통하여 제시하였다.