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        검색결과 80

        61.
        2012.09 KCI 등재 서비스 종료(열람 제한)
        홍수 발생 시 모래하천의 수위-유량 관계가 고리형을 이룬다는 것은 많은 현장 계측을 통해 보고되어 왔다. 또한, 홍수파 해석이나 사련에서 사구로 변동되는 하상해석을 통해 고리형 수위-유량 관계의 원인이 규명되어서 고리의 형태나 진행 방향 등에 대해서는 이론적으로도 상당부분 입증되어 있다. 그러나 경사가 급한 자갈 및 암반으로 구성된 산지하천의 경우, 현장유량계측의 어려움과 관측 정확도의 문제로 고리형 수위-유량 관계에 대한 연구가 매우 드물었다. 본 논문은 자갈 및 암반 지형의 산지하천인 제주도 한천에서 2011년 태풍 무이파 때 계측한 홍수 유량을 바탕으로 수위-유량 관계를 구축하고, 자갈하천에서 형성되는 고리형 수위-유량 곡선을 분석하고자 한다. 유량계측 방식으로는 홍수기에 적합한 비접촉식인 전자파 표면유속계를 사용하여, 홍수의 상승기와 하강기의 유량을 시간 단위로 계측하는 데 성공했다. 계측결과 수위-유량관계에서 뚜렷한 고리 형상을 확인할 수 있었다. 그리고 고리의 이력이 모래하천과 정반대로 동일수위에서 상승기의 유량이 하강기의 유량보다 작은, 고리 경로의 역전 현상을 발견하였다. 이러한 역전현상은 자갈하천의 조도의 변화가 모래하천의 경우와 반대로 발생하는 데 기인하는 것으로 추정한다.
        68.
        2008.03 KCI 등재 서비스 종료(열람 제한)
        The fate of two cyclic ethers, THF(Tetrahydrofuran) and 1,4-Dioxane, in conventional biological wastewater treatment plants was investigated using sequential activated sludge process. Removal efficiency of THF were about 86% in average, which was greater than that of 1,4-Dioxane, 30%. However, it was not clear whether the removal of cyclic ethers in biological system was caused by microbial activity or not. Thus treatability tests were conducted by batch experiments. The effects of mixing, aeration and the addition of activated sludge on the removal of cyclic ethers were investigated in batch experiments. THF was totally removed by mixing and aeration in 24 hours while removal ratio of 1,4-Dioxane was at most 30% for the same period. This results could be ascribed to the differences in Henry's law constants between the two chemicals. In addition, biological degradation including biosorption was not obviously observed in these batch tests.
        70.
        2006.06 KCI 등재 서비스 종료(열람 제한)
        화원 지점의 홍수시 유량은 수위가 상승할 때와 하강할 때 동일한 수위에 대해 많은 차이를 나타내고, 이와 같이 이력효과의 크기가 클 경우에는 많은 오차가 발생할 수 있다. 유량 환산 오차를 줄이기 위해 낙동강 본류 화원 수위관측소 지점에 대한 고리모양 수위-유량 관계곡선을 작성하였다. 하천유량과 단순 환산된 유량의 편차를 계산하기 위해 부정류 모의 사례로부터 (수위, 유량) 자료쌍을 획득하여 단순 수위-유량 관계곡선식을 작성하였다. 이 관계에서 이탈하는
        71.
        2006.03 KCI 등재 SCOPUS 서비스 종료(열람 제한)
        고리 원전 사용후핵연료 저장조의 저장용량을 확보하기 위하여 2002년부터 사용후핵연료 운반용기를 이용하여 400다발 이상의 PWR 사용후핵연료 집합체를 원전부지 내에 수송, 저장하였다. 이를 위하여 KN-12 운반용기, 관련장비 및 수송차량으로 구성되는 수송시스템을 구성하였다. KN-12 운반용기는 국내 원자력법 및 IAEA의 수송규정에 따라 설계, 제작되고, 정부로부터 인허가를 획득하였으며, 취급장비 역시 관련규정에 따라 구비하였다. 수송 저장작업은 2 대의 운반용기를 동시에 투입하여 수행하였으며, 모든 작업공정에 대하여 엄격한 품질관리 및 방사선 안전관리를 수행하여 수송 안전성을 확보하고 신뢰도를 제고하였다.
        77.
        1996.04 KCI 등재 서비스 종료(열람 제한)
        New thia-and diselena-crown ethers containing two suffer and selenium donor atoms have been prepared. And then, mercury (Hg^2+) ion-selective electrodes with PVC-plasticizer (STPB) based on some macrocycles as neutral carriers were also made. The electrochemical selectivities for various ions, and the effects for macrocycles, matrix of membranes, ratio of plasticizer to macrocycles, concentration and pH of test solution were investigated on the Hg^2+ ion selective electrodes. The 1,10-diselena-l8-crown-6-PVC-STPB (sodium tetraphenylborate) exhibited good linear responses of 28.2 ± 0.6 decade^-1 for Hg^2+ ion in the concentration ranges of 10^-2∼10^-6 M Hg^2+ ion. This electrode exhibited comparatively good selectivities for Hg^2+ ion in comparison with alkali and alkaline earth metal ions, some heavy metal ions and rare earth metal ion in the range of pH 2.5∼6.0. In addition, this electrode was applied as a sensor in the titration of Hg^2+ ion with I^- ion in water.
        79.
        1995.06 KCI 등재 서비스 종료(열람 제한)
        New two macrocyclic compounds using as carriers of liquid emulsion menbrame, have been synthesized. These reuslts provide evidance for the usefulness of the theory in designing the systems. The efficiency of selective transport for heavy metal ions have been discussed from the membrane systems that make use of SCN^- I^- , CN^- and Cl^- ion as co-anions in source phase and make use of S_2O_3^2- and P_2O_7^4- ion as receiving phase, respectively. The transport, rate of M(Ⅱ) was highest when a maximum amount of the M(Ⅱ) in the source phase was present as Cd(SCN)_2([SCN^-]=0.40M, Hg(SCN)_2([SCN^-]=0.40M) and Pb(CN)_2([CN^-]=0.40M). The Cd(Ⅱ) and Pb(Ⅱ) over each competitive cations were well transprted with 0.3M-S_2O_3^2- and 0.3M-P20_7^4 , respectively in the receiving phase. Results of this study indicate that two criteria must be met in order to have effective macrocycle-mediated transport in these emulsion system. First one must effective extraction of the M^n+ into the toluene systems. The effectiveness of this extraction is the greatest if logK for M^n+-macrocycle interaction is large and if the macrocycle is very insoluble in the aqueous phase. Second, the ratio of the logK values for M^n+-receiving phase (S_2O_3^2- or P_2O_7^4-) to M^n+-macrocycle (L_1 or L_2) interaction must be large enough to ensure quantitative stripping of M^n+(Cd^2+, Hg^2+ or Pb^2+) at the toluene receiving phase interface. L_1(3.5-benzo-10,13,18,21-tetraoxa-1,7,diazabicyclo(8,5,5) eicosan) forms a stable Cd^2+ and Pb^2+ complexes and L_1 is very insoluble in water and its Cd2^+ and Pb^2+ complex is considerably less stable than Cd^2+-(S_2O_3)_2^2- and Pb^2+-P_2O_7^4- complexe is On the other hand, the stability of the Hg^2+-L_1 complex exceed that of the Hg^2+-(S_2O_3)_2^2- and Hg^2+-P_2O_7^4- , and the distribution coefficient of L_2(5,8,15,18,23,26-hexaoxa-1,12- diazabicyclo-(10,8,8) octacosane) is much smaller than that of L_1. Therefore, the partitioning of L_2 is favored by the aqueous receiving phase, and little heavy metal ions transport is seen despite the large logK for Hg^2+-L_1 and M^n+(Cd^2+, Pb^2+ and Hg^2+)-L_2 interactions.
        80.
        1993.03 KCI 등재 서비스 종료(열람 제한)
        Result of this study indicate that two criteria must be met in order to have effective macrocycle-mediated transport in these emulsion system. First, one must effective extraction of the post transition metals, Cd^2+ Pb^2+ and Hg^2+,into toluene membrane. The effectiveness of this extraction is greatest if log K values for the metal-macrocycle interaction is large. Second, the ratio of the log K values for the metal ion-receiving phase to the metal ion-macrocycle interaction must be large enough to ensure quantitative stripping of the metal ion at the toluene phase interface. Control of the first step can be obtained by appropriate selection of macrocycle donor atom, substituents, and cavity radius. The second step can be controlled by selecting the proper complexing agent for inclusion in the receiving phase. The order of the transport, when using the several A^- species such as SCN^-,I^-,Br and Cl^- is the order of the changing degree of solvation for A^- and the transport of the metals is also affected by the control of concentration for receiving species because of solubility-differences. In this study, we can seperate each single metal ion from the mixture of Cd^2+, Pb^2+, and Hg^2+ ions by using the toluene membranes controlled by optimized conditions. Transport of the single metal is also very good, and alkaline and alkaline earth metals as interferences ions did not affect the seperation of the metals in this macrocycle-liquid membrances but transition metal ions were partially affected as interferences for the post transition metal ions.
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