The quartz glasses were prepared by sintering of fumed silica powders and the effect of OH concentration on their surface on sintering was studied. Through the firing process, the fumed silica was crystallized from 1180 to region. The amount of hydroxyl group decreased with increase in calcination temperature and consequently the crystallization was prevented. A transparent quartz glass was obtained from fumed silica, previously calcined at , by the sintering at for 1 h.

The characteristics of abrasive wear on sliding speed of glass fiber reinforcement (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The cumulative wear volume, friction coefficient and surface roughness of these materials on sliding speed were determined experimentally. The major failure mechanisms were lapping layers, deformation of resin, ploughing, delamination, and cracking by scanning electric microscopy (SEM) photograph of the tested surface. As increasing the sliding speed the GF/PUR composites indicated higher friction coefficient. The surface roughness of the GF/PUR composites was increased as the sliding speed was higher in wear test.

TiO2 thin films consisting of positively charged poly(diallyldimethylammonium chloride)(PDDA) and negatively charged titanium(IV) bis(ammonium lactato) dihydroxide(TALH) were successfully fabricated on glass beads by a layer-by-layer(LBL) self-assembly method. The glass beads used here showed a positive charge in an acid range and negative charge in an alkaline range. The glass beads coated with the coating sequence of(PDDA/TALH)n showed a change in the surface morphology as a function of the number of bilayers. When the number of bilayers(n) of the(PDDA/TALH) thin film was 20, Ti element was observed on the surface of the coated glass beads. The thin films coated onto the glass beads had a main peak of the (101) crystal face and were highly crystallized with XRD diffraction peaks of anatase-type TiO2 according to an XRD analysis. In addition, the TiO2 thin films showed photocatalytic properties such that they could decompose a methyl orange solution under illumination with UV light. As the number of bilayers of the(PDDA/TALH) thin film increased, the photocatalytic property of the TiO2-coated glass beads increased with the increase in the thin film thickness. The surface morphologies and optical properties of glass beads coated with TiO2 thin films with different coating numbers were measured by field emission scanning electron microscopy(FE-SEM), X-ray diffraction(XRD) and by UV-Vis spectrophotometry(UV-vis).

본 연구에서는 유리단섬유로 보강된 분사식 섬유보강 복합재료의 인장거동 평가를 위한 실험 및 해석연구를 수행하였다. 이를 위해 다양한 변형율속도(strain rate)에 따른 에폭시수지 및 분사식 섬유보강 복합재료의 인장강도 실험을 수행하였다. 본 연구에 사용된 분사식 섬유보강 복합재료는 15mm 길이로 절단된 유리단섬유가 25% 부피비율로 혼입된 보수·보강용 재 료이다. 에폭시수지의 점탄성 특성을 고려하기 위해 역산모델링(inverse simulation)을 수행하여 변형율속도에 따른 점성변화 를 함수식으로 제안하였다. 역산모델링을 통해 제안된 함수식을 미세역학 기반의 점탄성 손상모델(micromechanics-based viscoelastic damage model; Yang et al., 2012)에 적용하여 분사식 섬유보강 복합재료의 인장거동을 수치적으로 해석하였다. 분사식 섬유보강 복합재료의 인장거동 해석결과와 실험결과를 비교하여 미세역학 기반의 점탄성 손상모델의 정확성을 검증 하였다.

A Li2O-2SiO2 (LS2) glass was investigated as a lithium-ion conducting oxide glass, which is applicable to a fast ionic conductor even at low temperature due to its high mechanical strength and chemical stability. The Li2O-2SiO2 glass is likely to be broken into small pieces when quenched; thus, it is difficult to fabricate a specifically sized sample. The production of properly sized glass samples is necessary for device applications. In this study, we applied spark plasma sintering (SPS) to fabricate LS2 glass samples which have a particular size as well as high transparency. The sintered samples, 15mmφ×2mmT in size, (LS2-s) were produced by SPS between 480˚C and 500˚C at 45MPa for 3~5mim, after which the thermal and dielectric properties of the LS2-s samples were compared with those of quenched glass (LS2-q) samples. Thermal behavior, crystalline structure, and electrical conductivity of both samples were analyzed by differential scanning calorimetry (DSC), X-ray diffraction (XRD) and an impedance/gain-phase analyzer, respectively. The results showed that the LS2-s had an amorphous structure, like the LS2-q sample, and that both samples took on the lithium disilicate structure after the heat treatment at 800˚C. We observed similar dielectric peaks in both of the samples between room temperature and 700˚C. The DC activation energies of the LS2-q and LS2-s samples were 0.48±0.05eV and 0.66±0.04eV, while the AC activation energies were 0.48±0.05eV and 0.68±0.04eV, respectively.

운전자 생명선인 차선은 주간 시인성, 야간 시인성, 야간 젖은 상태 시인성, 야간 강우시 시인성으로 구분된다. 본 연구는 특히, 비와 관련되어 기상이 불안전한 조건에서 운전자의 주행 안전 확보를 목적으로 하였다. 차선의 시인성은 사전 인지시간(Preview time) 과 감지거리(Detection distances)와 밀접한 관계가 있으며, 야간 교통사고 감소를 위하여 차선 재료 성능을 향상시켜 차선의 주야간과 우천시 주야간 시인성의 척도인 Dry 재귀반사도(Dry retroreflectivity) 및 Wet 재귀반사도(Wet Retroreflectivity)를 높이기 위한 방안을 마련하는 데 있다. 이를 위하여 일반적으로 사용되고 있는 차선 도료용 유리알 굴절률 nD=1.50의 분석과 시인성의 척도인 재귀반사도를 향상시키기 위하여 가장 중요한 변수인 기능성 차선 도료용 유리알 굴절률 nD=2.2.을 도입하였다. 국내외 최소 한계 재귀반사도(Minimum threshold retroreflectivity) 및 최소 인지 재귀반사도(Install minimum retroreflectivity)를 조사하여 차선의 시인성 확보를 위한 최소한의 관리 수치를 규명하였으며 아울러 국내기존 차선 재료의 물리적 특성 그리고 재귀반사도의 시험을 통하여 우천 시 야간 재귀반사도 향상 방안을 마련하였다.

유리강회플라스틱(GRP)은 재료의 자중에 비해 아주 높은 강도를 가지고 있다. 또한 부재의 두께에 따라서 투명 혹은 반투명의 효과를 거둘 수 있다. 하지만 Hand laminating의 특성상 일률적인 재료의 강도를 선뢰하기 어렵기 때문에 구조 계산 혹은 설계 시 반드시 재료 실험을 수행하여야한다. 본 논문은 두께 4mm, 높이 30m의 의장적 기둥을 구조적으로 설계하기 위한 재료 실험을 수행하였다. 또한 실험 결과에 대한 평가를 통해 DIN에서 규정하는 재료적인 강도와 비교 분석하였다. 이를 통해 규준에서 제시하는 값과의 차이를 확인했으며 실제 설계에 반영하기 위해 반드시 재료실험이 수행되어야함을 알 수 있다.

본 연구는 LED(light-emitting diode) 보광이 온실에서 키운 어린 고추의 생장과 식물성 화학물질(phytochemical) 함량에 미치는 영향을 조사하였다. 처리한 LED광원은 청색광(470nm), 적색광 (660nm), 청색 + 적색광, 근적색광(740nm), 그리고 자외선(UV-B 300nm)이며. 실험기간 중의 이들 광원의 Photon flux는 각각 49, 16, 40, 5.0, 그리고 0.82μmol m-2s-1이었다. LED 광은 낮 동안 16시간이며 UV-B 는 일몰 후 10분간 발아 후 12일간 매일 처리되었다. 실험 결과, 광처리는 무처리에 비하여 고추의 생장과 식물성 화학물질(phytochemical) 함량에 상당한 변화를 보였다. 적색광 처리는 고추의 엽수, 마디수, 엽폭과 생체중을 각각 약 34%, 27%, 50%와 40% 증가되었다. 청색광 처리도 엽장을 약 13% 증가시켰고, 근적색광 처리에 의해 경장과 절간장을 각각 17%와 34% 정도 증가시켰다. 파종 15일에 수확한 고추 잎의 총 안토시아닌(anthocyanin)과 엽록소(chlorophyll) 함량은 청색광 처리에서 무처리에 비해 각각 6배와 2배가 증가하였다. 적색광은 총 페놀성화합물(phenolic compound) 함량을 최소 2배로 증가시켰으며, 반면에 근적색광은 아스코르빅 산(ascorbic acid)과 항산화능(antioxidant activity)을 각각 31%와 66%를 감소시켰다.

The behavior of abrasive wear on counterpart roughness of glass fiber reinforcement polyurethane resin (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The friction coefficient, cumulative wear volume and surface roughness of these materials against SiC abrasive paper were determined experimentally. The major failure mechanisms were lapping layers, ploughing, delamination, deformation of resin and cracking by scanning electric microscopy (SEM) photograph of the tested surface. As increasing the counterpart roughness the GF/PUR composites indicated higher friction coefficient. The surface roughness of the GF/PUR composites was increased as the sliding velocity was higher and the counterpart roughness was rougher in wear test.

In order to evaluate the fundamental properties of sewerage pipes for ductile properties and allowable deflection ratios, A field tests were conducted on the glass fiber reinforced plastic pipe. Also, Allowable deformation test was carried out to determine the soil-pipe relationship and earth pressure due to the loading of dump truck.

본 연구는 한국형 온실 표준설계도 및 Greenhouse Structure Design Manual(1999)에 의거하여 최대설계 하중을 받는 와이드스팬형파 2-bay벤로형 온실시스템에 대하여 해석적 연구를 진행하였다. 상부구조물을 라멘형식으로 단순화한 구조형식에 BOX형 및 I형 단면을 적용하여 다음과 같은 결과를 얻을 수 있었다. 한국형 유리용실 표준도를 활용하여 라멘형식의 단순화된 와이드스팬형 및 2-bay 온실구조시스템의 안전성 평가결과 기존의 트러스 등의 보강재가 적용되지 않을 경우 안전성확보에 문제가 발생할 수 있음을 확인할 수 있었다. 또한 유리온실 표준도를 라멘형식으로 단순화하고 Greenhouse Structure Design Manual (1999)이 제안하고 있는 최대하중에 대해 경량I형 단면 부재를 적용할 경우 안전성을 확보할 수 있다. 본 연구에서는 경제적인 경량 I형 단면 3가지의 적용성을 평가하였으며, 검토조건에 부합하는 최소 기둥단면(H200×175×3.2×6)을 제시하고 있다. 와이드스팬형 및 벤로형 온실형식의 안전성평가에서 발생되는 처짐은 매우 작은 값을 나타내고 있으며, 발생되는 응력이 보다 민감하게 발생하는 것을 알 수 있다. 따라서 검토된 온실표준단변형식이 전체적인 구조변형에는 안전하나 응력발생이 일부부재에서 취약함으로 변단면 등을 활용하여 경제성을 확보할 수 있다. 온실의 채광량, 시공성 및 안전성을 고려하여 벤로형 구조시스템이 널리 사용되고 있으며, 지붕높이의 변화를 통하여 보다 경제적인 형식이 개발가능하며, 3-bay 벤로형의 추가적인 연구가 필요하다.

Stained glass, which flowered with Gothic architecture, the climactic era ofMiddle Ages art, conveyed to the faithful theological messages encoded in light, aswell as protecting sacred places from thee elements, made visible the true sun, thatis, the light understood as seen consubstantial with God. The splendid light andbrilliance radiating from the gem-like glass fragments to all intends and purposesmade visible the new Jerusalem on earth. This stained glass with bound formed anexus for the aesthetics and theology of the Middle Ages was to change throughtime and varied ways.Stained glass, overshadowed by painting from the Renaissance till the 18thcentury, came into prominence in the 19th century with the appearance of theEnglish pre-Raphaelite school, the beginnings of art nouveau style, and therestoration of stained glass in French Gothic churches in which Viollet le Ducplayed a central role. Artists such as John Ruskin in the U.K., John la Farge andLouis Comport Tiffany in the U.S. had a great influence on the development of the19th century stained glass, resurrecting stained glass from the lowly status ofcommercial art, and reuniting stained glass decoration with architecture through artnouveau. Due to their efforts, the distinct character of stained glass was restored butits intrinsic religious value in the context of historic church architecture wascompromised.In the 19th century the relation between the church and the artist was not as close as during the Middle Ages or the Renaissance period. Secular artists working withreligious themes had few opportunity to furnish works for churches. Churches, intheir turn, were filled with archaic works following the dictates and styles of the pastand supported academism in religious art. But at the beginning of the 20th century anew wind of reform began to blow through the decadence of church art. As a resultmainly of the reformers in Germany and France, the artists of Europe and the U.S.created stained glass works that reflected the new modern aesthetic and once againrestored the place of stained glass in modern churches through its incorporation intoarchitecture.

예이츠의 초기 희곡 『모래 시계』의 수정 과정을 추적하여 그의 극작술의 발전을 연구한다. 특히 현자가 바보 앞에 무릎을 꿇고 구원을 간청하는 장면을 현자의 깨달음과 죽음의 수용으로 바꿈으로써 주제 전개의 걸림돌을 제거했고, 원래 산문극에 현자와 천사의 대사 등을 운문으로 바꿈으로써 주제를 강조했다.

The effect of load and sliding speed on abrasive wear characteristics of glass fiber/polyurethane (GF/PUR) composites were investigated at ambient temperature by pin-on-disc friction test. The friction coefficient, cumulative wear volume and surface roughness of these materials against SiC abrasive paper were determined experimentally. Experimental results showed that the surface roughness of the GF/PUR composites was increased as applied load was higher in wear test. The cumulative wear volume tended to increase nonlinearly with increase of sliding distance and depended on applied load and sliding speed for these composites. It could be verified by scanning electric microscopy (SEM) photograph of surface tested that major failure mechanisms were lapping layers, ploughing, delamination, deformation of resin and cracking.

Glass was fabricated using refused coal ore obtained from the Dogye coal mine in Samcheok. We additionally used soda ash and calcium carbonate to make a glass with the chemical composition of soda-lime glass, and we also used white, brown, and green glass cullet to make various kinds of colored glass. Transparent glass was fabricated by melting batch materials including refused coal ore at 1550˚C for 1 hr in an electrical furnace. The light transmittance and color chromaticity were measured by a UV/VIS/NIR spectrometer. Transparent glass with a light transmittance of over 80% was fabricated using normal refused coal ore and white glass cullet. Various kinds of colored glass with a light transmittance of 30-80% were fabricated using refused coal ore and brown or green glass cullet. The light transmittance of the mixed color glass samples, fabricated using normal refused coal ore and brown glass cullet and green glass cullet, indicated 30-47%, a relatively low value, in the condition of a cullet ratio of 20-50%. The characteristics of the color chromaticity of the glass samples were indicated in a chromaticity diagram by x-coordinates, y-coordinates, Y (lightness). The values of x-coordinates and y-coordinates were moved with a regular directional property according to the kind and amount of glass cullet. Therefore, we concluded that refused coal ore can be used for raw materials of color glass products like art glass and glass tile.

Geopolymer is a term covering a class of synthetic aluminosilicate materials with potential use in a number of areas, but mainly as a replacement for Portland cement. In this study, geopolymers with fly ash and meta kaolin were prepared using KOH as an alkali activator and water glass. The effect of water glass on the microstructures and the compressive strength of the geopolymer was investigated. As the amount of water glass increased, the dissolved inorganic binder particles in the geopolymers increased due to polymerization, resulting in a dense microstructure. The meta kaolin-based geopolymer showed a better extent of polymerization and densification than that of the fly ash-based geopolymer. XRD data also suggested that polymerization in meta kaolin-based geopolymers should be active resulting in the formation of an amorphous phase with an increasing amount of water glass. The compressive strength of the geopolymer was also dependent on the amount of water glass. The compressive strength of the geopolymers from both fly ash and meta kaolin increased with an increasing amount of water glass because water glass improved the extent of polymerization of the inorganic binder and resulted in a dense microstructure. However, the addition of water glass to the geopolymer did not seem to be effective for the improvement of compressive strength because the meta kaolin-based geopolymer mainly consisted of a clay component. For this reason, the fly ash-based geopolymer showed a higher value of compressive strength than the meta-kaolin geopolymer.