The effects of Rhizobium inoculant, nitrogen, phosphorus, and molybdenum on nodulation, dry matter production, yield attributes, pod and seed yields, protein and phosphorus contents in seed of pea (pisum sativum) var. IPSA Motorshuti-3 were assessed by a field experiment. Among the treatments Rhizobium inoculant in combination with 25kg P and 1.5kg Mo/ha performed best in recording number of nodules/plant, total dry matter yield, number of pods/plant, number of seeds/pod, 1000-seed weight, green pod yield, green and mature seed yields of pea. The highest green pod yield of 15.37 t/ha (97.05~% increase over control) and green seed yield of 9.6t/ha (69.31~% increase over control) were obtained by inoculating pea with Rhizobium inoculant in association with 25kg P and 1.5 Mo/ha. The effects of 60 or 120kg N/ha were comparable to Rhizobium inoculant in most cases. There were positive correlations among yield attributes, yield, protein and phosphorus contents in seeds of pea. From the viewpoint of yield attributes, yield, and seed quality, application of Rhizobium inoculant along with 25kg P and 1.5kg Mo/ha was considered to be the balanced combination of nutrients for achieving the maximum output from cultivation of pea in Shallow-Red Brown Terrace Soil of Bangladesh.

인은 다이아몬드 내에 함유될 수 있는 흥미로운 불순물 중의 하나로서 n 타입의 반도체가 될 수 있다는 점에서 흥미롭다. 그러므로 전기적 특성 및 광학적 특성이 많이 연구되고 있지만, 대부분이 CVD (화학 기상합성) 다이아몬드에 관한 것이다. 본 연구에서는 인을 첨가한 HPHT (고압과 고온) 다이아몬드를 합성하고 인이 어떻게 함유되는가 알아보기 위하여 CL 분광기로 광학적 특성을 살펴보았다. 그 결과, 기존에 발견된 발광피크(239 nm, 240～270 nm)뿐만 아니라 248, 603 nm에서 새로운 발광피크가 발견되었다. 이러한 발광피크들은 인과 같이 혼입된 질소나 붕소와 같은 불순물이 공존하여 발생한 복합 결함에 의한 것이라고 판단된다.

산지계류수에서의 T-N(총질소), T-P(총인) 및 COD(화학적산소요구량)의 농도와 유출부하의 변화를 파악하고 산림의 수질정화기능을 평가하였다. 충청북도에 있는 시험유역은 면적이 92.5 ha이며 59%의 혼효림과 30%의 침엽수림으로 구성되어 있다. 시험유역의 말단에서 평상시는 10일 간격으로 또한, 1개의 강우사상에 대하여 2-6 시간 간격으로 계류수의 유량과 농도를 1년간 측정하였다. 강우시의 평균농도는 COD만이 유의적인 수준(p<0.05)에서

The purpose of this study is to evaluate and to predict of eutrophication in lakes by using Vollenweider- OECD model and total phosphorus concentration and inflow rate which were measurded in 1993～2001. The results of study were as follows. The annual total phosphorus loading from the watershed was calculated to be 55～195tP/yr at lake Soyang, 221～466tP/yr at lake Taechong, 123～278tP/yr at lake Andong, 57～109tP/yr at lake Seomjin. These are discharged, for the most parts, from population and fishfarm facility. TP loading on the surface area at lake Soyang was 3.01gP/㎡/yr, 2.82gP/㎡/yr, 2.84gP/㎡/yr, 3.03gP/㎡/yr, 2.34gP/㎡/yr, 1.78gP/㎡/yr, 0.91gP/㎡/yr, 0.89gP/㎡/yr, 0.86gP/㎡/yr, lake Taechong was 6.71gP/㎡/yr, 7.25gP/㎡/yr, 7.24gP/㎡/yr, 6.53gP/㎡/yr, 6.50gP/㎡/yr, 7.06gP/㎡/yr, 7.04gP/㎡/yr, 4.05gP/㎡/yr, 3.44gP/㎡/yr and TP loading on the surface area of lake Andong, lake Soemjin were 5.39gP/㎡/yr, 4.47gP/㎡/yr, 4.56gP/㎡/yr, 4.45gP/㎡/yr, 3.33gP/㎡/yr, 2.38gP/㎡/yr, 2.53gP/㎡/yr, 2.46gP/㎡/yr, 2.54gP/㎡/yr, 4.09gP/㎡/yr, 4.10gP/㎡/yr, 3.98gP/㎡/yr, 3.73gP/㎡/yr, 2.80gP/㎡/yr, 3.46gP/㎡/yr, 3.22gP/㎡/yr, 2.19gP/㎡/yr, 2.13gP/㎡/yr respectively. The tropic states of four lakes can be assessed as eutrophy because phosphorus loading exceeds the critical phosphorus loading by Vollenweider-OECD model.

Phosphorus (P) is a macronutrient playing important roles in many plant processes. Significant interest has been devoted to search and utilize genotypic variations in P use efficiency in rice but with little effort to understand its physiological and biochemical bases. In this study, we examined responses to P deprivation of some primary and secondary traits in 3-week-old seedlings of the three genotypes, Sobi-byeo (japonica), Dasan-byeo (japonica ~times indica) and Palawan (indica). In general, percent weight due to root was increased up to 26%, but amounts of root protein and proteins secreted from roots were decreased by 11 to 19% and 31 to 51 %, respectively, by 3 to 21 days of P deprivation in the three genotypes. Interestingly, however, responses of Palawan to short-term P deprivation were contrasting to those of Dasan-byeo and Sobi-byeo in seedling weight and contents of shoot protein, chlorophyll and anthocyanin. Seedling weight was not decreased, but shoot protein content was decreased in P-deprived seedlings of Palawan. Contents of chlorophyll in leaves and anthocynin in roots were increased in Dasan-byeo and Sobi-byeo, but decreased in Palawan. The results suggest that responses of protein and pigment synthesis to P deficiency are different in modem and traditional varieties and the difference may at least in part be due to the selection for high yield under highly fertilized conditions.

국내 최초로 31PNMR 및 XRD를 이용하여 월성원자력 발전소 인근의 해저 저질토에 대하여 퇴적물의 광물학적인 성분 분석 및 인의 존재형태에 대한 연구를 수행하였다. 약 30 cm의 코아에 대한 연구결과, 광물종은 심도별로 변화가 없었으며 주 구성광물은 석영, 알바이트, 미사장석, 방해석과일라이트, 스멕타이트, 녹니석, 그리고 카올리나이트 등이 동정되었다. 31 P NMR 결과는 다른 외국의 해양 퇴적물에서 보고된 것과 같은 다양한 종의 인은 발견되지 않았으며, 단지 주로 orthophosphate-monoester와 함께 orthophosphate-diester로 판단되는 인이 아주 미량으로 같이 존재하는 것으로 밝혀졌으며 광물종의 경우와 마찬가지로 심도별 인의 종의 변화가 거의 없음을 보여준다. 본 연구 지역의 인은 주로 해양 생물로부터 기인한 것으로 판단된다. 인의 존재형태는 본 지역의 시료들이 산화환경에 있었음을 지시하며 XRD의 실험결과와 더불어 유추할 수 있듯이 본 시료에 대하여 동일한 퇴적환경과 산화환경이 계속되어 왔거나, 아니면 다양한 환경에 있던 것들이 후의 외부적 교란에 의하여 서로 혼합되어 표면의 산화환경에 계속적인 노출이 있었음을 지시한다.

This paper investigates preliminarily spatial distribution soil organic matter (SOM), nitrogen (N) and phosphorus (P) and its environmental influence in wetland soil of different vegetation landscape in the Yellow River Mouth. The result shows the SOM and total nitrogen (TN), efficient N, efficient P in top layer soils of different vegetation district have significantly different content, The SOM is shown as Calamagrostis epigeios wetlands > Phragmites cmmunis wetlands > Tamarix chinensi wetlands above tidal > Suaeda salsa wetlands in high tidal > Tamarix chinensi wetlands in high tidal > tidal flats, the arrange of the TN and efficient N content is the same except that the content in Suaeda salsa wetlands in high tidal is heavier than Tamarix chinensi wetlands in high tidal. In different vegetation landscape wetland types the vertical change of soil nutrients are obvious except for P, gradually decrease from the upper to the lower. This case reflects the function of the vegetation on the wetland development of soil, and proves the wetland soil has the characteristic of new born and bad degree of development. SOM, TN, efficient N and efficient P content in wetland soils have significantly positive correlation, but TP have no correlation with them but efficient P. The contents of TN in wetland soils range from 58~1480 mg/kg, total average content 408 mg/kg, average content of above 30 cm is 625 mg/kg. The range of TP content in the soil is 372~1042 mg/kg, total average is 569 mg/kg, average content of above 20 cm is 611 mg/kg. According the P it occurs mainly as calcium phosphates, and the validity is lower, therefore, N and P in the new born wetlands cannot produce serious impact on the environments at present.

To investigate of C and N metabolisms in response to phosphorus-deficient stress during regrowth of Italian ryegrass (Lolium multiflorum L.), C and N metabolites were analyzed at 0, 6, 12 and 24 days after defoliation. P-sufficient (control, +P) and P-absent (-P) nutrient solutions were applied from 7 days before defoliation, and continued for one cycle of 24 day-regrowth period. During 24 days of regrowth, dry matter of regrowing shoots and remaining tissues were not significantly different between +P and -P treatment. In remaining stubble, 70% to 91 % decline of the initial level (at day 0) in all C compounds occurred during the first 6 days of regrowth. Initial amounts of nitrate and amino acids in roots were significantly higher in the +P medium. Nitrate contents in stubble in the +P medium significantly decreased for the first 12 days and then rapidly recovered, while that of the -P medium continuously decreased until day 24. Amino acids in stubble in the P medium were continuously increased during the whole regrowth period. Soluble proteins in stubble in the +P medium also largely fell down (46.0% of the initial) for only the first 6 days, however the decline in the -P medium continued until day 12. In regrowing shoots, the accumulation of C compounds was significantly higher, while that of N compounds except amino acids was largely lower in the -P medium. These results showed a stimulation of carbohydrate synthesis and a compensatory utilization of organic reserves occurred to support regrowth under P-deficient condition.

An on-line digestion system based on the flow injection analysis technique was presented for the determination of total phosphorus. The system converts condensed and organic phosphoruses into orthophosphate that can be analyzed spectrophotometically. The reaction between orthophosphate and ammonium molybdate in a strong acid medium forms the yellow complex of phosphomolybdate which is next reduced to a molybdic blue complex by stannous chloride. The quantitation of orthophosphate is based on the absorbance of the molybdic blue. To determine total phosphorus, the digestion system was installed between the sample injector and the reaction coil with the added lines of digestion solution(potassium persulfate+sulfuric acid) and the H_2O carrier. The system has shown that the digestion efficiencies were greater than 95% for the typical condensed and organic phosphoruses. When tripolyphosphate standards were used, the calibration data showed that the linear dynamic range extended to a concentration of 1.5ppm with the detection limit of 25 ppb total phosphorus. The typical relative standard deviation was less than 2%. The proposed system was successfully applied to lake water, wastewater, and streamwater. The analytical variables such as digestion efficiency, analysis time, and reproducibility were evaluated and compared with the manual digestion method.

Laboratory experiments were performed to investigate the effects of various factors on the phosphorus removal by electrolysis with aluminium electrodes. The efficiency of phosphorus removal increased with increasing of voltage applied, surface area of electrodes and electrolyte concentration, and decreasing of electrode distance. The phosphorus removal was not affected by the connection number of an electric circuit. The amount of aluminium ion eluted from electrodes according to Faraday's law was 4.47 ㎎ and the Al/P mole ratio was 2.14 at the electric current value of 20 ㎃.

The fundamental experiments on the phosphorus removal from water were carried out by the batch and continuous reactors which used aluminium and copper plate. In this systems, the phosphorus was removed by aluminium ion generated with the electrochemical interaction (pitting corrosion) of aluminium and copper. In the batch experiments, the efficiencies of phosphorus removal increased when the surfaces of aluminium and copper plate were brushed. The phosphorus removal by aluminium ion was affected the copper plate and NaCl in this system. The optimal pH values were 5 and 6 for the phosphorus removal. The efficiency of phosphorus removal increased with increasing NaCl concentration, surface area of aluminium and copper plate. The CuSO4·5H2O instead of copper plate could be used as Cu source. The effluent PO4-P concentration as low as 2㎎/ℓ could have been obtained during the continuous experiment at HRT of 48 hrs.

Sequencing Batch Reactor(SBR) experiments for organics and nutrients removal have been conducted to find an optimum anaerobic/anoxic/aerobic cycling time and evaluate the applicability of oxidation-reduction potential(ORP) as a process control parameter. In this study, a 6 ℓ bench-scale plant was used and fed with night-soil wastewater in K city which contained TCODcr : 10,680 ㎎/ℓ, TKN : 6,893 ㎎/ℓ, NH_4^+ -N : 1,609 ㎎/ℓ, PO_4^3- -P : 602 ㎎/ℓ on average. The cycling time in SBRs was adjusted at 12 hours and 24 hours, and then certainly included anaerobic, aerobic and anoxic conditions. Also, for each cycling time, we performed 3 series of experiment simultaneously which was set up 10 days, 20 days and 30 days as SRT. From the experimental results, the optimum cycling time for biological nutrient removal with night-soil wastewater was respctively 3hrs, 5hrs, 3hrs(anaerobic-aerobic-anoxic). Nitrogen removal efficiency was 77.9%, 77.9%, 81.7% for each SRT, respectively. When external carbon source was fed in the anoxic phase, ORP-bending point indicating nitrate break point appeared clearly and nitrogen removal efficiency increased as 96.5%, 97.1%, 98.9%. Phosphate removal efficiency was 59.8%, 64.5%, 68.6% for each SRT. Also, we finded the applicability of ORP as a process control parameter in SBRs.

In the study, we investigated the behavior and removal efficiency of organics, nitrogen, phosphorus with operating conditions in SBRs. Substrate used was synthetic wastewater in which the ratio of COD_cr : N : P was 100 : 12 : 2. The cycling time in SBRs was adjusted at 6 hours and 8 hours, and then certainly included anaerobic and aerobic conditions. Also, for each cycling time, we performed 2 series of experiment simultaneously which was set up 10 days and 20 days as SRT. The removal efficiency of COD_cr, was over 97% in all operating conditions. In the 6 hours cycling time, the removal efficiency of PO_4^3- -P reached almost 100% in steady state. And then we could observe a typical phenomena of phosphorus release and uptake, and the removal efficiency of N was 67%. Residual N source was almost TKN and most of the rest remained as NO_2^- -N. Also the difference in both SRTs was not observed practically. In the 8 hours cycling time, dissolution of sludge appeared. and, PO_4^3- -P was not nearly removed but nitrogen was removed up to 75%. And the residual nitrogen was accumulated as NO_2^- -N.

In the study, we investigated the behavior and removal efficiency of organics, nitrogen, phosphorus with operating conditions in SBRs. Substrate used was synthetic wastewater in which the ratio of COD_cr : N : P was 100 : 12 : 2. The cycling time in SBRs was adjusted at 6 hours and 8 hours, and then certainly included anaerobic and aerobic conditions. Also, for each cycling time, we performed 2 series of experiment simultaneously which was set up 10 days and 20 days as SRT. The removal efficiency of COD_cr, was over 97% in all operating conditions. In the 6 hours cycling time, the removal efficiency of PO_4^3- -P reached almost 100% in steady state. And then we could observe a typical phenomena of phosphorus release and uptake, and the removal efficiency of N was 67%. Residual N source was almost TKN and most of the rest remained as NO_2^- -N. Also the difference in both SRTs was not observed practically. In the 8 hours cycling time, dissolution of sludge appeared. and, PO_4^3- -P was not nearly removed but nitrogen was removed up to 75%. And the residual nitrogen was accumulated as NO_2^- -N.

Phosphorus and nitrogen loadings from the main tributaries into the Nakdong River were estimated by measuring phosphorus and nitrogen concentration in the main tributaries, Nakdong River(Kangjung), Kumho River, Heichun, Hwang River, Nam River, Milyang River, and Yangsanchun from May 1994 to October. Total phosphorus concentration of Kumho River was vary high, average 1.0 ㎎P/ℓ. The other rivers were the range 0.05∼0.15 ㎎P/ℓ. Total nitrogen concentration of Kumho River was vary high, average 6.27 ㎎N/ℓ. The other rivers were the range 1.5∼3.0 ㎎N/ℓ. The phosphorus loading from Kumho River, Nakdong River(Kangjung), Nam River, Milyang River, Hwang River, Yangsanchun, and Heichun were calculated to be 1,108, 603, 198, 57, 34, 23, and 21 tP/yr, respectively. Therefore, the loading from Kumho River accounted for 45 % of total loading, 2,042 tP/yr. The nitrogen loading from Nakdong River (Kangjung), Kumho River, Nam River, Milyang River, Hwang River, Heichun, and Yangsanchun were calculated to be 12,636, 7,411, 2,611, 1,523, 779, 608, and 391 tN/yr, respectively. Therefore, the loading from Nakdong River(Kangjung) and Kumho River accounted for 50 % and 30% of total loading, 25,959 tN/yr, respectively.

Batch experiments were performed to evaluate the effect of sludge acclimation and contact load on the behavior of phosphorus and organic substrates under anaerobic conditions. Four different sludges were acclimated in the sequencing batch reactors operated by intermittent aeration. All the experiments performed in a bench scale have shown the following results: 1. The unreleaseable phosphorus contents for four different sludges are the range of 16 ㎎ P/g SS to 24 ㎎ P/g SS, depending on the sludge acclimation conditions. 2. All the specific substrate uptake rates(SSUR) are expressed in the first order equation for releaseable phosphorus contents. The reaction rate coefficient, k, has the values of 4.0, 8.9, and 13.8 mg COD/㎎ P/hr, depending on the contact load and sludge species. 3. As reaction proceeds, the ratios of ΔP to - ΔCOD at high contact load are almost constant. in the range of 0.10 to 0.14, but at low contact load, they increase from 0.08 to 0.27.

수도의 냉해 경감을 위하여 인산 및 붕소의 시용효과를 구명코저 인산을 10a당 10, 20kg, 붕소를 0, 3, 5, 10, 20, 30kg을 분벽기, 유수형성기 및 감수분열기에 시용하고 유수형성기 이후부터 15-18℃ 로 냉수처리한 결과를 요약하면 다음과 같다. 1. 붕소의 시용량이 많아질수록 시용후 3일경부터 염색이 황변하며 생육이 억제되었으며 생육후기에는 염색이 암갈색으로 착색되고 엽선단의 양록이 말리며 고사되었다. 한편 조립의 선단부에도 암갈색으로 착색되었다. 2. 엽록소 함량은 분벽기와 유수형성기에 10a당 5, 10kg의 붕소 시용구에서 높았으며 감수분열기 처리에서는 일정한 경향이 없었다. 3. 광합성능력과 붕소시용간에는 일정한 경향이 없었으나 분벽기 시용구에서는 붕소량이 많을수록 증가되었다. 한편 엽록소 함량이 증가되어도 이에 비례하여 광합성능력은 별로 증대되지 않았다. 4. 근활력은 대체로 무처리구에 비하여 붕소처리구가 다소높았다. 특히 분벽기에 10a당 3, 5, 10kg의 붕소처리구에서 높았다. 5. 붕소처리에 의한 출수촉진효과는 붕소의 시용시기가 빠를수록 촉진되는 경향을 보였고 붕소수준간에는 무처리구에 비하여 붕소를 10a당 3, 5, 10kg 시용구에서 3-7일의 촉진효과를 보였다. 6. 붕소처리는 등숙에 영향을 미쳐 인산수준 및 처리시기에 관계없이 붕소를 10a당 3, 5, 10kg 시용한 구에서 약간 높아졌다.

냉온하(7~9월)에서 생육한 수도에 대한 재배수건별(표고별, 품종별) 냉해와 도체경엽중 유효규산 및 인산함량과의 관계를 밝히고져 경남북 일도에 걸처 냉해실태를 조사하여 분석해 본 결과는 다음과 같다. 1. 임실비율은 표고가 높아질수록 떨어졌으며 통일계품종에서 더욱 현저하였다. 2. 임실비율 증가에 따라 토양중 SiO2/P2 O5 함량비는 낮아졌고 도체경엽중에서는 높아졌다. 3. 규산이 인산함량에 비하여 도체의 경엽중에서는 10.5~20.5배 정도 토양중에는 0.28~0.78배로 함유되어 있었다. 4. 임실비율과 도체경엽중 SiO2/P2 O5 함량비와는 정의 유의상관이 인정되었다. 5. 식물체중 규산함량 증가에 따른 임실비율 증가는 일반계품종보다 통일계정종에서 현저하였다.

질소 및 인산시용이 수도의 지상, 지하부 생육에 미치는 영향을 검토하고 산소전극으로 측정한 근호흡과 지상, 지하부 생육과의 관련성을 알기 위하여 1978년 인공기상실에서 pot 실험을 수행하였으며 얻어진 결과를 요약하면 다음과 같다. 1. 질산시용량 증가에 따라 근호흡 및 지상부중은 증가되나 근중은 감소되었다. 2. 인산의 시용은 인산과 동량의 질소병용하에서만 근호흡을 증가시켰으며 근중 및 지상부중은 인산적량시비시에 증가되었다. 3. 저온하에서는 근호흡에 미치는 인산시비효과가 크지 않았으며 인산만의 단독증비는 근호흡을 크게 감소시켰다. 4. 근호흡은 근중과는 부의 상관을, 그리고 지상부중 및 양분흡수와의 정의 상관을 보였으며 단위면적당호흡 의미가 없고 단위근중당호흡만이 유효하였다. 5. 원연교잡종인 수원 258호는 일본형 품종인 진흥보다 저온에서의 인산반응이 낮은 경향이었다.