Environmental pollution has led to global warming, which threatens human life. In response, hydrogen is gaining attention as a next-generation energy source that does not emit carbon. Due to its explosive nature, special care must be taken in the safe storage and transportation of hydrogen. Among various storage methods, liquefied storage, which can reduce its volume to 1/800, is considered efficient. However, since its boiling point reaches -253°C, the design of an insulation system is essential. For the design of insulation systems applied to large containers, a membrane-type design is required, which necessitates the use of cryogenic adhesives. To evaluate whether the cryogenic adhesive is properly implemented, assessments such as tensile and shear tests are necessary. This study presents a methodology for shear evaluation. Conventional methods for shear evaluation of adhesives result in slippage, preventing proper assessment. Therefore, a method involving drilling holes in the gripper and pulling from the holes must be applied. Optimal design concerning the size and location of the holes is required, and this study derives optimal values based on finite element analysis. By conducting experiments based on the results of this study, it is expected that the risk of gripper damage will be minimized, allowing for accurate evaluation of the adhesive’s performance.
Liquefied hydrogen is attracting attention as an energy source of the future due to its hydrogen storage rate and low risk. However, the disadvantage is that the unit price is high due to technical difficulties in production, transportation, and storage. This study was conducted to improve the design accuracy and development period of needle valves, which are important parts with a wide technical application range among liquefied hydrogen equipment. Since the needle valve must discharge an appropriate flow rate of the liquefied fluid, it is important to determine the needle valve design parameters suitable for the target flow rate. Computational Fluid Dynamics and Artificial Neural Network technology used to determine the design variables of fluid flow were applied to improve the setting and analysis time of the parameter. In addition, procedures and methods for applying the design parameter of needle valves to Convolutional Neural Networks were presented. The procedure and appropriate conditions for selecting parameters and functional conditions of the Convolutional Neural Network were presented, and the accuracy of predicting the flow coefficient according to the design parameter was secured 95%. It is judged that this method can be applied to other structures and machines.
Liquified hydrogen is considered a new energy resource to replace conventional fossil fuels due to environmental regulations by the IMO. When building tank for the storage and transportation of liquified hydrogen, materials need to withstand temperatures of -253°C, which is even lower than that of LNG (-163°C). Austenitic stainless steel mainly used to build liquified hydrogen tank. When building the tanks, both the base material and welding zone need to have excellent strength in cryogenic condition, however, manual arc welding has several issues due to prolonged exposure of the base material to high temperatures. Laser welding, which has some benefits like short period of exposure time and decrease of thermal affected zone, is used many industries. In this study, laser bead on plate welding was conducted to determine the laser butt welding conditions for STS 304 and STS 316L steels. After the BOP test, cross-section observations were conducted to measure and compare four bead parameters. These tendency result of laser BOP test can be used as conditions laser butt welding of STS 304 and STS 316L steel.
In order to respond to environmental pollution, developed countries, including Korea, have begun to conduct research to utilize hydrogen energy. For mass transfer of hydrogen energy, storage as liquid hydrogen is advantageous, and in this case, the volume can be reduced to 1/800. As such, the transportation technology of liquefied hydrogen for ships is expected to be needed in the near future, but there is no commercialized method yet. This study is a study on the technology to test the performance of the components constituting the membrane type storage container in a cryogenic environment as a preparation for the above. It is a study to find a way to respond by analyzing in advance the problems that may occur during the shear test of adhesives. Through this study, the limitations of ISO4587 were analyzed, and in order to cope with this, the specimen was supplemented so that fracture occurred in the adhesive, not the adhesive gripper, by using stainless steel, a low-temperature steel, to reinforce the thickness. Based on this, shear evaluation was performed under conditions lowered to minus 243℃, and it was confirmed that the breaking strength was higher at cryogenic temperatures.
금속의 취성화는 수소와 접촉하는 구조물을 안정적으로 설계하는데 있어서 큰 문제가 되어왔다. 본 논문에서는 분자동역학 해석을 통해 균열선단 주변에 모인 수소원자들이 전위 이동 현상을 억제하고, 이로 인해 벽개 파괴 현상이 발생하는 것을 확인하였다. 다양한 수소 농도, 하중 속도, 수소 확산 속도 등을 바꾸어가며 분자동역학 해석을 수행하였고, 이에 따른 수소 취성화를 최소화시킬 수 있는 조건들을 조사하였다. 분자동역학 해석 결과는 기존의 실험결과와 잘 일치하였으며 이를 바탕으로 수소 취성화 현상을 정량화하여 평가하였다.
강화되는 환경규제에 대응하기 위해서 세계 각국이 수소 경제로의 전환을 본격화하고 있으며, 이에 중장기적으로 수소의 국가 간 물동량도 증가할 것으로 예상된다. 국가간 수소의 거래는 수출국의 신재생 에너지 자원과 수입국의 수소 사용 형태, 기술 성숙도 등을 고려하여 암모니아, 액화수소, LOHC 등의 형태로 이루어질 것이나, 어느 한 가지 형태로만 거래되지는 않을 것이다. 액화수소 대비 암모 니아와 LOHC의 해상운송은 상대적으로 성숙한 기술임에 본 글에서는 향후 액화수소 운반선 개발을 위하여 필요한 세부 기술들의 식별 및 다양한 기술적 대안들을 통해 가능한 설계안을 확보하면서, 그에 따른 기술적 타당성을 분석하였다.
액화 수소 운반선에서 증발가스의 발생은 불가피하며, 화물탱크 내부의 압력 문제를 피하기 위해 적절한 조치가 필요하다. 이 증발 가스는 선박의 추진연료로 사용 될 수 있으며, 추진에 사용되고 남은 나머지 부분은 재액화 또는 연소시키는 등 효과적으로 관리해야 한다. 본 연구에서는 수소 추진 시스템을 갖춘 160,000m3 액화 수소 운반선에 최적화된 증발 가스 재액화 시스템을 제안한다. 이 시스템은 수소 압 축 및 헬륨 냉매 섹션으로 구성되고, 화물탱크로부터 배출되는 증발가스의 냉열을 효과적으로 활용하여 효율을 증가시켰다. 본 연구에서는 공급 온도 -220℃인 수소 증발가스가 재액화 시스템에 들어가는 상태에서 증발가스의 재액화 비율에 따른 엑서지 효율 및 에너지 소모율 (SEC, Specific Energy Consumption) 분석을 통해 시스템을 평가하였다. 그 결과 재액화 비율 20%에서 4.11kWh/kgLH2의 SEC와 60.1%의 엑서지 효율을 보여 주었다. 아울러, 수소 압축압력, 수소 팽창기의 입구온도, 공급 증발가스 온도변화에 따른 영향을 확인하였다.