본 연구에서는 이산화탄소 고정화에 있어 이산화탄소 전환을 위해 MEA를 이용한 습식화학흡 수법의 셔틀메카니즘을 도입하였다. 또한 알칼리 무기물질을 다량 함유한 산업부산물을 습식탄산화법을 이용해 처리하고자 하였다. 즉, 산업부산물의 화학적 처리를 통해 칼슘이온을 용출하였다. 산성물질을 이용한 용출상징수를 ICP로 분석한 결과, 칼슘이온이 최대 17,900 ppm(1.79%)을 확보하였다. 또한 MEA를 이용한 습식 흡수공정을 통해 상온, 상압조건의 이산화탄소 분위기에서 94%의 전환률을 얻었 다. 슬러지의 액상탄산화를 통해 슬러지 mg 당 0.175 mg의 이산화탄소를 고정하였으며, 최종생성물의 XRD 분석결과 일반적인 탄산칼슘의 결정구조인 calcite 형상을 확인하였다.

The relationship between storage stability and calcium contents extracted from anchovy according to particle sizes was investigated in this paper. The results are as follows; 1. The acid value (AV) and the peroxide value (POV) of anchovy were in the rank order of whole anchovy$lt;35$lt;50$lt;80 mesh by particle sizes and 6$lt;12$lt;18$lt;30 months by storage term. 2. The Calcium (Ca) and Phosphorus (P) contents extracted from anchovy were in the rank order of whole anchovy$lt;35$lt;50$lt;80 mesh by particle sizes and 10$lt;20$lt;30 minutes by heating time. The extracted amount of Ca was the largest when anchovy particles with 80 mesh were heated for 30 minutes. In that case the amount of Ca in the anchovy stocks was 52.54 mg. 3. The amount ratio between Ca and P was in the rank order of 30$lt;20$lt;10 minutes by boiling time and indicated 1:3.99-5.16 by each part. The lowest ratio of Ca to P was 1:3.99 when anchovy particles with 80 mesh were heated for 30 minutes. 196

In this study, the effect of calcium leaching on chloride ion penetration resistance of mortar specimens was evaluated. According to test results, the penetration depth of chloride ion was increased after the calcium leaching attack.

콘크리트는 장기수명이 요구되는 구조물에 적합한 건설재료로 내구성이 우수하지만 장기간 지하수에 노출되어 발생하는 칼슘용출 현상에 대한 이해 및 이에 따른 RC 부재의 휨 거동 특성을 평가할 필요가 있다. 실험결과에 따르면, 광물질 혼화재는 RC 부재의 장기강도 개선에 효과적이지만, 칼슘용출이 발생하면 RC 부재의 항복하중 및 휨 강성이 감소하고 중립축깊이와 처짐량이 증가하는 것으로 나타났다. 따라서 칼슘용출에 의한 열화는 RC 부재의 성능 저하를 유발하므로 칼슘용출 환경에 노출되는 지하구조물에 광물질 혼화재가 적용될 경우에는, 광물질 혼화재 종류에 따른 최적 혼입 비율이 마련되어야할 것으로 사료된다.

In this paper, the flexural test of concrete member damaged due to Calcium leaching were performed to evaluate the characteristics of structural behavior. From the results, yield load, maximum load and flexural rigidity of RC member damaged by calcium leaching were decreased and the depth of the neutral axis was increased.

Concrete is a very useful construction material for the sealing disposal of hazardous substances. In general, mass concrete is applied to these structures. And, the mineral admixtures are recommended for the long term performance. Calcium leaching could be happened due to the contact with pure water in underground structures. Thus, it is needed to evaluate the resistance of calcium leaching for concrete mixed with mineral admixtures. From the test results, the mineral admixtures are effective to the improvement of long term compressive strength and chloride diffusion coefficient in concrete members. When calcium leaching is happened, however, the reduction of compressive strength and chloride penetration resistance is severe than OPC case, the micro pore distribution is adversely affected. Consequently, when the mineral admixtures are applied to underground structures which is exposed to calcium leaching environment, it is desirable to reduce water-to-binder ratio, to expose after the sufficient pozolanic reaction, and to use BFS than FA.

In this study, chloride penetration of calcium leached concrete according to mineral admixture ratio were compared with OPC. From the results, it showed that chloride diffusion coefficient in calcium leached concrete were increased as calcium leaching period increase. However, the chloride diffusion coefficient of BFS case showed the better resistance than Fly Ash case. And, the distribution of chloride diffusion coefficient was significantly changed by calcium leaching period.

다양한 열화 인자에 의해 저감된 콘크리트의 내구성은 구조물의 구조적 성능과 사용 수명에 부정적인 영향을 미치게 되며 콘크리트 연구 분야 중에서도 매우 중요하고 매력적인 주제라고 할 수 있다. 이러한 이유로 콘크리트의 내구성과 관련된 많은 연구들이 발표되었으나 물리-화학적 열화에 기인하는 콘크리트의 본질적인 물성 변화에 주된 초점이 맞춰져 왔으며, 콘크리트 내구성과 구조물의 구조적 성능 사이의 관계 정립은 아직 미흡한 실정이다. 본 연구에서는 콘크리트의 강도 감소에 원인이 되는 칼슘 용출 열화를 적용하였으며, 열화 정도에 따른 구조적 거동을 평가하기 위하여 열화 손상을 입은 콘크리트 부재의 압축 및 휨 거동 실험을 수행하고 그 결과를 비선형 유한요소해석 결과와 비교 분석하였다. 연구 결과에 따르면 칼슘 용출 열화는 콘크리트의 압축 강도를 저하시키며, 열화가 진행됨에 따라 취성 거동에서 연성 거동으로 변화되는 경향을 나타냈다. 또한 열화에 의한 압축 영역의 손상 정도가 심화될수록 RC 부재의 내하력과 강성은 저하되었으며, 이러한 구조적 거동은 ABAQUS의 CDP 모델을 사용한 비선형 유한요소해석의 결과와도 비교적 잘 일치하였다.

In this study, to investigate differences between artificial and natural conditions, two acceleration test methods (electrochemical testing and chemical testing) were performed using concrete specimens. Following this, the quantity of calcium leaching and the degraded thickness obtained from each acceleration test were compared with those of the deionized water tests. According to results, the acceleration test method corresponds well to the leaching degradation and the chemical acceleration test method is most useful for accelerating the leaching of cement hydrate in concrete.

Radioactive waste repositories require long-term durability of concrete in contact with ground water. However, contact of the ground water leads to Ca2+ leaching process between pore water and pure water. Therefore, this study is aimed at investigating the effect of the leaching process of concrete based on their physical properties and durabilities. According to results, as the leaching period became longer, the pore volume is greatly increased and the chloride diffusion coefficient of the degraded concrete increased with leaching process.