Biodiesel is a traditional energy field that can replace low-quality marine fuels for ships and various studies have been conducted. Since the 2000s, Korea has introduced a mandatory supply system of biodiesel for domestic vehicle diesel, gradually raising the blending ratio from 0.5% to 3.5%, and is expected to raise the mandatory blending ratio to about 8.0% by 2030. Therefore, in this study attempted to blend high-quality samples that meet the biodiesel quality standards manufactured by domestic companies with MGO in ratios ranging from 0 to 60%. We utilized a 1-ton combustion chamber to compare and analyze the exhaust gas emissions characteristics. As a result, in the BD60 condition, which represents the maximum range in this study, the O2 increased by approximately 1.5%p, and CO2 tended to decrease by 1.1%p. NOx decreased by approximately 18.2%p from 34.1 ppm to 27.9 ppm. In the case of SOx, a very low concentration of 0.08 ppm was detected under the BD0 condition, and it was undetectable under all other conditions containing biodiesel. This suggests that MGO itself has excellent low-sulfur oil quality and can implement zero SOx through biodiesel mixing. Furthermore the combustion efficiency decreased by approximately 1.91%, from 72% to 70.2%, and the exhaust gas temperature also decreased by about 4.5%p. However despite the lower calorific value of biodiesel compared to MGO, it demonstrated relatively close thermal output per unit content. This indicates sufficient potential for biodiesel to serve as a viable alternative fuel for ships in the future.

In this study, blending oils of diesel oil and butanol were used as fuel oil for diesel engine to measure combustion pressure, fuel consumption, air ratio and exhaust gas emission due to various operating conditions such as engine revolution and torque. Using these data, the results of analyzing the engine performance, combustion characteristics and exhaust emission characteristics such as NOx (nitrogen oxides), CO2 (carbon dioxide), CO (carbon monoxide) and soot were as follows. The fuel conversion efficiency at each load was highest when driven in the engine revolution determined by a fixed pitch propeller law. Except 30% butanol blending oil, fuel conversion efficiency of the other fuel oils increased as the load increased. Compared to diesel oil, using 10% and 20% butanol blending oil as fuel oil was advantageous in terms of thermal efficiency, but it did not have a significant impact on the reduction of exhaust gas emissions. On the other hand, future research is needed on the results of the 20% butanol blending oil showing lower or similar levels of smoke concentration and carbon monoxide emission rate other than those types of diesel oil.

약과 반죽시 참기름 대용으로 쇼트닝을 이용할 목적으로 쇼트닝의 혼합비율을 달리하여(참기름 100%, 참기름 75%+쇼트닝 25%, 참기름 50%+쇼트닝 50%, 쇼트닝 100%) 약과를 제조하고, 약과 유지의 지방산 조성, 유지함량, 원료유지의 잔존율, 저장 중의 유지산패도(산가, 과산화물가, 카르보닐가)를 측정하여 쇼트닝 약과의 유지안정성을 비교 분석한 결과 다음과 같았다. 1. 약과 반죽의 유지 함량은 9.33%였으나, 튀김 후 시료 구별 약과의 유지함량은 25.20-29.12%로서 아주 높았다. 이들 약과의 유지 구성은 반죽에 첨가되었던 원료유지와 튀김에 사용된 튀김유(대두유)의 비율이 각각 16-10%와 84-90%로서 튀김유가 대부분을 차지하였다. 2. 모든 약과의 지방산 조성은 쇼트닝의 첨가수준에 관계 없이 시료구간에 거의 유사하여 linoleic acid 49.71-51.27%, oleic acid 26.05-26.77%, palmitic acid 10.07-11.71%, linolenic acid 5.51-5.72% stearic acid 4.51-4.68%였으며, 이것은 튀김유(대두유)의 지방산 조성과 유사하였다. 3. 쇼트닝 첨가에 따른 약과의 저장중 산가, 과산화물가, 카르보닐가의 변화는 쇼트닝 첨가가 산가의 증가를 다소 지연시켰으나 과산화물가와 카르보닐가는 시료구간에 차이를 나타내지 않았다. 약과 제조시에 반죽에 첨가되는 유지의 지방산 조성이 크게 다르더라도 약과의 유지 산패도는 큰 차이를 보이지 않았다. 이것은 튀김 과정 중 튀김유가 약과내로 다량 흡유되어 약과반죽의 원료유지보다도 큰 영향을 준 것으로 생각된다. 따라서 쇼트닝은 약과 반죽에 참기름 대용으로 사용될경우 약과의 유지 산패 면에서는 참기름 100% 약과와 차이가 없어 약과 제조시 참기름 대체효과가 있을 것으로 기대된다.

There are increased in using the bio-ethanol, as the carbon neutral attracts many researchers due to a reduction in carbon dioxide spotted as the global warming gas. A gasoline engine with 100% of the bioethanol was developed and used in Brazil already, but researches of using the bio-ethanol in diesel engines are lack. In this study, combustion tests with blend fuel of the gas oil and bio ethanol by 50% maximally due to a low cetane number of bio-ethanol were accomplished as a basic study of introduction of using the bioethanol in diesel engines. The result was that smoke emission was decreased with increase in proportion of the bio-ethanol, due to the increase of a amount of pre-mixed combustion with ignition delay. Although the amount of CO2 is reduced according as the bio-ethanol is used(carbon neutral), the emission of CO2 with increase in the proportion of the bio-ethanol was more increased due to lower a heat value of bio-ethanol than gas oil.

pH, 당과 Ca의 첨가량 및 혼합비율이 혼합유의 점도에 미치는 영향과 콩우유와 혼합유 제조시 가열과 혼합비율이 관능적 특성에 미치는 영향을 조사하였다. 혼합유의 점도는 pH에 따라 크게 영향을 받았으며 pH 6.0에서 43.0 cp로 가장 높았고 우유의 혼합비율이 증가함에 따라 점도의 변화가 완만해졌다. Ca와 당의 첨가는 혼합비율별 혼합유의 점도에 뚜렷한 영향을 주지 않은 것으로 나타났으나 우유의 첨가량이 증가할수록 점도가 감소되는 負의 관계를 보였다. 콩우유의 콩비린 맛과 냄새 그리고 풀냄새는 가열초기에 급격한 감소를 보였고, 고소한 맛과 냄새 및 기호도의 증가를 보였는데 그 이후에는 뚜렷한 변화가 없는 것으로 나타났다. 그리하여 콩우유를 30분 가열한 후 우유와 혼합한 혼합유에서는 우유의 혼합비율이 증가하면서 비린냄새와 맛은 직선적으로 감소하였고 익은콩 냄새와 단맛은 완만한 감소를, 우유맛과 우유냄새는 증가함을 보였다. 기호도는 우유의 함량이 높아가면서 증가하였으며 혼합유에서는 혼합비율이 50:50이었을 때 가장 기호도가 높은 것으로 나타났다.

콩우유와 우유를 혼합한 고단백음료의 제조를 위하여 콩우유 단백질의 열처리에 대한 안정성을 밝히고 혼합비율을 달리하여 제조된 혼합유의 가용성 단백질에 가열온도, pH, 당과 Ca의 첨가량이 미치는 영향을 조사하였다. 100℃에서 시간별로 열처리시킨 콩우유를 830×g∼29, 900×g의 범위에서 30분간 원심분리 시킨 상등액의 가용성 질소를 정량한 결과 11, 200×g가 적절한 조건으로 선택되었다. 콩우유를 70∼100℃에서 4시간까지 가열시켜 위의 원심분리조건으로 가용성 질소를 측정한 결과, 70℃에서는 28.0%, 100℃에서는 43.2%가 열에 의한 변성으로 침강되었음이 밝혀졌다. 혼합비율별 콩우유 및 우유의 혼합유를 80℃ 및 100℃에서 가열하였을 때 20 %의 콩우유 첨가구가 15% 내외의 변성이 일어나 빠른 혼합유보다 변성이 많았으며 1시간 가열로 대부분의 변성이 일어났다. 또한 혼합유의 pH를 3∼8의 범위로 100℃에서 30분간 가열하였을 때 pH 4.0에서 14.6 ∼ 20.5 %의 %SN이 측정되어 가장 많은 침강을 보였으며 pH 8.0까지 증가하면서 침강된 변성단백질의 양은 지속적으로 감소하였다. 당의 첨가영향은 sucrose를 9%까지 증가시켰을 때 혼합유의 %SN에 큰 영향을 주지는 않았으나 콩우유(100%)는 단백질의 침강정도가 약간 증가하는 경향을 보였다. Ca의 첨가에 의한 콩우유(100%)의 %SN은 약 55%로 가장 많은 단백질의 침강을 보였으며 우유의 혼합비율이 많아지면서 침강단백질이 감소하였다.

The blended oil was prepared from cottonseed oil and palm olien. The oxidative stability of blended oil after the addition of natural tocopherol and soybean lecithin during heating was investigated and the effects of lecithin were evaluated. The result obtained were as follows: 1. When the concentration of palm olein in blended oil during heating was increased, the oxidative stability was improved. 2. By both addition of natural tocopherol and soybean lecithin during heating in blended oil, induction period was considerably increased and residual ratio of tocopherol was high. 3. The oxidative stability of potato chips prepared from blended oil was higher in the prsence of lecithin than in the absence of it.

Influence of mixing ratio of blending oil (rice bran oil : RBD palm olein = 1 : 1, 1 : 4 mixture: w/w) and natural tocopherol, citric acid, and sodium polyphosphate on enhancement of oxidation stability of blending oil under the condition of tap water infulx(1 ml/min/200g oil) were compared by AOM test after heating these system at l80℃. In addition, the effects of tocopherol, and synergist on oxidition stability were also tested with potato chips fried with blending oil(1 : 4 mixture). The result obtained were as followes; 1. The test of RBD palm olein addition of 50% and 80% against rice bran oil on oxidation stability showed that the higher the palm olein contents in blending oil, the higher the oxidation stability. 2. The test of oxidation stability, adding l00ppm, 200ppm and 400ppm of natural tocopherol in two different types of blending oils, A(1 : 1 mixture) and B(1 : 4 mixture), disclosed that blending oil B was more positively effective, and this trend was superior at 200ppm level particularly, Furthermore, oxidation stability was enhanced remarkably upon addition of 100ppm of natural tocopherol, and 50ppm of citric acid together with 50ppm, 100ppm and 200ppm of sodium polyphosphate in general. Especially, 200ppm of sodium polyphosphate addition induced the most synergetic effect on oxidation stability showing as much as 3 times compare to control. 3. The results of oxidation stability obtained by peroxide value on potato chips fried with blending oil (1:4 mixture added tocopherol, citric acid and sodium polyphosphate and preserved at 60℃ revealed that addition of tocopherol and 50ppm of citric acid together with 200ppm of sodium polyphosphate treatment was the most synergistic coinciding with AOM test results.

Background: Sancho (Zanthoxylum schinifolium Siebold and Zucc) oil is used as a traditional medicinal material to treat severs stomach inflammation and as a diuretic. This study was carried out to investigate the effect of addition of antioxidants and blended oil the storage stability and safety of the biomaterial. Methods and Results: The effects of temperature and light on sancho oil were investigated, and the ability of antioxidants in preventing rancidity of the oil was discovered. Under fluorescent light and in darkness, the acidity of the oil was much lower than that under direct sunlight. The addition of antioxidants decreased the acid value of sancho oil; the antioxidant that showed the best results in this regard was 0.5% propolis. The acid value of canola oil, which had the lowest acid value compared with that of other oils, and blended oil, containing 5% canola oil in sancho oil, decreased by 5.5% and 15%, respectively. About one acid value decrease was observed for every 1% increase in blending with canola oil. As the concentration of canola oil increased, the viscosity and the elightness (L valu) of sancho oil increased slightly, while the blueness (b value) decreased. Conclusions: The results of this study may contribute to ensuring food safety during preservation and the industrialization of the presevation of sancho oil.