리튬이온배터리는 높은 에너지 저장 효율과 환경 지속 가능성으로 점점 더 많은 관심을 받고 있다. PU 기반 리튬이온배터리에 사용되는 기존의 고분자 (polyurethane, PU) 바인더는 높은 유연성과 기 계적 강도를 제공하여 전극의 부피 변화를 감소시키고 구조적 안정성을 확보하는데 효과적이지만, 이와같 은 고분자 계열의 바인더는 전기전도도가 낮고 생산 및 폐기 과정에서 환경 문제를 야기할 수 있다. 따라 서, 본 연구에서는 이러한 고분자계 바인더의 단점을 해결하고자 고분자계 바인더로 많이 사용되는 PU 기 반 리튬이온배터리에 비해 향상된 전기화학적 성능과 안정성을 가진 새로운 바인더로서 석유계 피치 (SM260)/고분자 (polyurethane, PU) 복합소재 기반 바인더를 개발하였다. 특히, PU 바인더가 적용된 리튬 이온배터리는 100 사이클 후 가역 용량이 80 mAh/g으로, 초기 용량의 25%의 용량 유지율을 나타낸 반면, 본 연구에서 개발한 석유계 피치 (SM260)/고분자 (polyurethane, PU) 복합소재 복합 바인더가 적용된 리 튬이온배터리는 100 사이클 후 가역용량이 208 mAh/g으로 유지되고, 초기 용량의 68% 용량 유지율을 나 타내었다.

To analyze the effect of fire in electric-vehicle battery on concrete cement structure. A scenario evaluation was conducted for fire occurrence due to external influences on lithium battery cells used in electric vehicles. Visual inspection was conducted at each stage of the battery fire, and the fire duration and temperature were measured. The battery temperature rise curve and temperature during fire have been examined previously. The stability of a cement structure was evaluated via X-ray diffraction and SEM analyses of the reaction-product changes with respect to temperature. The battery temperature rise curve shows that the battery begins to change at 200 °C–300 °C. However, the general stage of battery damage cannot be readily confirmed from the literature. The current experiment and literature review indicate that battery fire can cause the fire temperature to increase beyond 1000 °C within a few seconds. The reaction product changes structurally in cement from 300 °C or higher. Many voids are generated owing to the decomposition of Ca(OH)2 and C-S-H gel. The temperature of an electric-vehicle fire increases rapidly to 1000 °C or higher within a few seconds. High temperatures change the reaction products in cement structures, thus creating internal voids and cracks and reducing the stability of the structure; therefore, the appropriate countermeasures must be identified.

To improve the lithium-ion battery performance and stability, a conducting polymer, which can simultaneously serve as both a conductive additive and a binder, is introduced into the anode. Water-soluble polyaniline:polystyrene sulfonate (PANI:PSS) can be successfully prepared through chemical oxidative polymerization, and their chemical/mechanical properties are adjusted by varying the molecular weight of PSS. As a conductive additive, the PANI with a conjugated double bond structure is introduced between active materials or between the active material and the current collector to provide fast and short electrical pathways. As a binder, the PSS prevents short circuits through strong π‒π stacking interaction with active material, and it exhibits superior adhesion to the current collector, thereby ensuring the maintenance of stable mechanical properties, even under high-speed charging/discharging conditions. Based on the synergistic effect of the intrinsic properties of PANI and PSS, it is confirmed that the anode with PANI:PSS introduced as a binder has about 1.8 times higher bonding strength (0.4 kgf/20 mm) compared to conventional binders. Moreover, since active materials can be additionally added in place of the generally added conductive additives, the total cell capacity increased by about 12.0%, and improved stability is shown with a capacity retention rate of 99.3% even after 200 cycles at a current rate of 0.2 C.

리튬이온전지는 친환경적이고 우수한 전지 성능덕분에 배터리 산업의 핵심으로 자리 잡았으며, 이에 따라 수요가 급증하고 있다. 그러나, 리튬이온전지의 수요증가는 리튬과 광물자원들의 공급문제를 초래하며, 수명이 다한 폐 리튬이온전지의 폐기방안이 아직 마련되지 않아 환경적 문제를 발생시킨다. 이러한 문제를 해결하기 위해 폐 리튬이온전지를 재활용하는 연구가 진행되고 있으며, 그 중에서도 폐 리튬이온전지에서 폐 양극 소재를 추출하여 재활용하는 다이렉트 리사이클링 연구가 주목받고 있다. 그러나, 폐 양극 소재는 오랜 충/방전으로 인해 구조적 붕괴(열화)가 발생한 상태로, 새로운 리튬이온전지에 적용을 위해서는 리튬이온전지 사용 전의 구조 즉, 층상구조로의 회복이 필요하다. 본 연구에서는 이를 위해 폐 양극 소재(LiNi0.6C0.2Mn0.2O2)가 열역학적으로 층상구조를 형성하는 온도를 분석하기 위해 700 ºC, 800 ºC, 900 ºC 범위에서 XRD를 통해 구조분석을 진행하였다. 폐 양극 소재는 700 ºC와 900 ºC 대비 800 ºC 열처리 시 1.44로 가장 높은 I003/I104 value를 보였다. 또한 800 ºC 열처리 시 0.1 C 기준 비 용량이 171.3 mAh/g으로 가장 높은 것을 확인하였다. 이를 통해 우리는 열역학적으로 층상구조를 형성하는 온도를 800 ºC로 도출하였으며 폐 양극 소재의 구조를 성공적으로 복원하였다.

Mesocrystals are macroscopic structures formed by the assembly of nanoparticles that possess distinct surface structures and collective properties when compared to traditional crystalline materials. Various growth mechanisms and their unique features have promise as material design tools for diverse potential applications. This paper presents a straightforward method for metal–organic coordination-based mesocrystals using nickel ions and terephthalic acid. The coordinative compound between Ni2+ and terephthalic acid drives the particle-mediated growth mechanism, resulting in the mesocrystal formation through a mesoscale assembly. Subsequent carbonization converts mesocrystals to multidirectional interconnected graphite nanospheres along the macroscopic framework while preserving the original structure of the Ni-terephthalic acid mesocrystal. Comprehensive investigations demonstrate that multi-oriented edge sites and high crystallinity with larger interlayer spacing facilitate lithium ion transport and continuous intercalation. The resulting graphitic superparticle electrodes show superior rate capability (128.6 mAh g− 1 at 5 A g− 1) and stable cycle stability (0.052% of capacity decay per cycle), certifying it as an advanced anode material for lithium-ion batteries.

Na4MnV(PO4)3 (NMVP) cathode materials have attracted significant attention as potential candidates for grid applications due to their distinctive structure and high theoretical capacity. However, their inadequate electronic conductivity compromises both cycling stability and rate capability, presenting a challenge for practical implementation. To address this issue, we employed a strategy involving Zr4+ doping and dual-carbon coating to enhance the electrochemical performance of NMVP. The resulting Na3.8MnV0.8Zr0.2( PO4)3/C/rGO composite demonstrated markedly improved rate capability (71.9 mAh g− 1 at 60 °C) and sustained cyclic stability (84.8% retention at 2 C after 1000 cycles), as validated through comprehensive kinetics assessments. The enhanced performance can be attributed to the expanded Na-ion pathways facilitated by large size ion doping and the improved electronic conductivity enabled by the dual-layer coating.

As the demand for electric vehicles increases, the stability of batteries has become one of the most significant issues. The battery housing, which protects the battery from external stimuli such as vibration, shock, and heat, is the crucial element in resolving safety problems. Conventional metal battery housings are being converted into polymer composites due to their lightweight and improved corrosion resistance to moisture. The transition to polymer composites requires high mechanical strength, electrical insulation, and thermal stability. In this paper, we proposes a high-strength nanocomposite made by infiltrating epoxy into a 3D aligned h-BN structure. The developed 3D aligned h-BN/epoxy composite not only exhibits a high compressive strength (108 MPa) but also demonstrates excellent electrical insulation and thermal stability, with a stable electrical resistivity at 200 °C and a low thermal expansion coefficient (11.46×ppm/°C), respectively.

In this study, we report significant improvements in lithium-ion battery anodes cost and performance, by fabricating nano porous silicon (Si) particles from Si wafer sludge using the metal-assisted chemical etching (MACE) process. To solve the problem of volume expansion of Si during alloying/de-alloying with lithium ions, a layer was formed through nitric acid treatment, and Ag particles were removed at the same time. This layer acts as a core-shell structure that suppresses Si volume expansion. Additionally, the specific surface area of Si increased by controlling the etching time, which corresponds to the volume expansion of Si, showing a synergistic effect with the core-shell. This development not only contributes to the development of high-capacity anode materials, but also highlights the possibility of reducing manufacturing costs by utilizing waste Si wafer sludge. In addition, this method enhances the capacity retention rate of lithium-ion batteries by up to 38 %, marking a significant step forward in performance improvements.

Because plastics are cheap and light, their use is indispensable in our daily lives. However, the extensive use of plastics causes the disposal issue. Among various disposal processes, plastic recycling is of great attention because of minimizing waste and harmful byproducts. Herein, we recycle the most popular thermoplastic materials, high-density and low-density polyethylene, producing the anode materials for the Li-ion batteries. The electrochemical properties of the as-recycled soft carbon are investigated to study the energy storage capability as the anode of Li-ion batteries. Our work demonstrates the soft carbon recycled from plastic wastes is a promising anode material.

The raw material selected for this research was Brazil chestnut shells (BCs), which were utilized to gain porous carbon as a positive electrode for lithium–sulfur batteries (LSBs). The effects of N/S co-doped on the electrochemical properties of porous carbon materials were studied using thiourea as nitrogen and sulfur sources. The experimental results indicate that the N/S co-doped carbon materials have a higher mesopore ratio than the undoped porous carbon materials. The porous carbon material NSPC-2 has a lotus-like structure with uniform pore distribution. The N and S doping contents are 2.5% and 5.4%. The prepared N/S co-doped porous carbon materials were combined with S, respectively, and three kinds of sulfur carbon composites were obtained. Among them, the composite NSPC-2/S can achieve the initial specific discharge capacity of 1018.6 mAh g− 1 at 0.2 C rate. At 1 C rate, the initial discharge capacity of the material is 730.6 mAh g− 1, and the coulomb efficiency is 98.6% and the capacity retention rate is 71.5% after 400 charge–discharge cycles.

Electric-propulsion systems for ships, also known as electric propulsion devices, represent the current direction of development for maritime power. Issues concerning the environment and fuel economy have compelled the maritime transport sector to seek solutions that reduce emissions and improve fuel efficiency. In this process, power electronics technology plays a significant role in the propulsion systems of ships. Selecting an efficient battery system is of great importance for enhancing the cruising range of yachts and minimizing environmental impact. The battery model is crucial for revealing the working principles of batteries, and it is extremely critical for the application and development of battery technology. The Battery Management System (BMS) serves a crucial regulatory function, optimizing both the safety and performance of battery cells. Central to its operation is the precise estimation of the battery's State of Charge (SOC), a process dependent on an exacting battery model. This system not only enhances longevity and reliability but also ensures that energy storage solutions meet high standards of efficacy. This study focused on testing the impedance characteristics of lithium-sulfur batteries (LSB) at various SOC points and establishing first- and second-order RC equivalent circuit models. The model parameters were identified through experimental data. Subsequently, a simulation platform was constructed using MATLAB/Simulink to simulate the behavior of LSB under a constant current discharge condition. The simulation results showed that the second-order RC model had significantly lower errors than the first-order model, demonstrating higher accuracy. These achievements can provide technical support for the research of energy storage systems in the green aviation and maritime industries.

환경오염을 제어하기 위한 청정에너지에 대한 수요 증가는 빠르게 증가하고 있습니다. 리튬 이온 배터리와 같은 충전식 배터리는 청정에너지의 우수한 원천이지만 높은 수요와 공급 불일치로 인해 리튬 금속이 빠르게 고갈되고 있습니다. 배터리 폐기물에서 귀금속을 회수하는 것은 환경오염 제어와 함께 가능한 해결책 중 하나입니다. 멤브레인 기반 분리 방법은 폐기물에서 리튬을 회수할 수 있는 매우 성공적인 상업적 공정입니다. 이 작업은 최근에 보고된 다양한 방법을 다룰 것이며 검토 형식으로 작성될 것입니다.

The lithium-ion battery has been utilized in various fields including energy storage system, portable electronic devices and electric vehicles due to their high energy and power densities, low self-discharge, and long cycle-life performances. However, despite of various research on electrode materials, there is a lack of research on developing of binder to replace conventional polymer-based binding materials. In this work, petroleum pitch (MP-50)/polymer (polyurethane, PU) composite binder for lithium-ion battery has fabricated not only to use as a binding material, but also to re-place conventional polymer-based binder. The MP-50/PU composite binder has also prepared to various ratios between petroleum pitch and polymer to optimize the physical and electro-chemical performance of the lithium-ion battery based on the MP-50/PU composite binder. The physical and electrochemical performances of the MP-50/PU composite binder-based lithium-ion battery were evaluated using a universal testing machine (UTM), charge/discharge test. As a result, lithium-ion battery based on the MP-50/PU composite (5:5, mass ratio) binder showed optimized performances with 1.53 gf mm− 1 of adhesion strength, 341 mAh g− 1 of specific discharge capacity and 99.5% of ICE value.