The International Maritime Organization (IMO) is promoting the transition to eco-friendly fuels such as hydrogen and ammonia, with the goal of achieving net-zero greenhouse gas emissions in the shipping sector by 2050. Hydrogen does not emit greenhouse gases, but it must be stored at an extremely low temperature of -253°C when stored as a liquid. 316L stainless steel is mainly used as a tank material to store liquid hydrogen. FCAW (Flux Cored Arc Welding) is known for its excellent weldability with 316L stainless steel, and it is particularly suited for welding thick metals efficiently, making it an ideal choice for storage tank welding. Finite Element Method (FEM) analysis can simulate the thermal and mechanical deformations occurring during welding with high precision, allowing for accurate prediction of deformation patterns and the derivation of optimal welding conditions. This ensures the stability and quality of the structure while reducing costs. In this study, FCAW butt welding was performed on 316L stainless steel, followed by cross-sectional observation and deformation measurement of the weld area. Based on the cross-sectional observation, a 3D FE model was designed, and heat transfer analysis was conducted. Subsequently, thermo-mechanical analysis was carried out to predict welding deformation.

Super-duplex stainless steels are in great demand in various industrial fields such as chemical processing and seawater desalination due to their excellent pitting corrosion resistance. However, detrimental phases can easily form during fabrication, and even minor additions of alloying elements can significantly impact their microstructure and properties. This study investigated the effects Cu or Ti additions on a super-duplex stainless steel. First, the effects of annealing time at 950 °C on the microstructure and corrosion characteristics were investigated. It was found that as the annealing time increased, the fraction of sigma phase increased; however, the corrosion resistance in the electrochemical test using a 3.5 % NaCl electrolyte showed only a slight improvement. The microstructure of duplex stainless steel with added Cu or Ti did not differ significantly from that of the base steel. However, the overall corrosion resistance showed improvement, and in particular, an observed increase in pitting potential. Investigating the characteristics of the passive film on the alloy surface revealed that the stability of the passive film was higher in alloys with added Cu or Ti compared to the standard alloy. Among these, the alloy with Cu addition had the thickest film, while the Ti-added alloy had the highest Cr concentration and a film thickness greater than that of the standard alloy.

Molten salt reactors represent a promising advancement in nuclear technology due to their potential for enhanced safety, higher efficiency, and reduced nuclear waste. However, the development of structural materials that can survive under severe corrosion environments is crucial. In the present work, pure Ni was deposited on the surface of 316H stainless steel using a directed energy deposition (DED) process. This study aimed to fabricate pure Ni alloy layers on an STS316H alloy substrate. It was observed that low laser power during the deposition of pure Ni on the STS316H substrate could induce stacking defects such as surface irregularities and internal voids, which were confirmed through photographic and SEM analyses. Additionally, the diffusion of Fe and Cr elements from the STS316H substrate into the Ni layers was observed to decrease with increasing Ni deposition height. Analysis of the composition of Cr and Fe components within the Ni deposition structures allows for the prediction of properties such as the corrosion resistance of Ni.

원자력 발전소에서 배관 시스템은 냉각수 및 오염수를 운반하고 생성된 증기를 터빈으로 이동시켜 에너지를 생산하는 중요한 설비이다. 국내에 건설된 원자력 발전소의 가동연수가 증가함에 따라 배관 시스템의 물리적, 기계적 성질의 열화현상은 발생할 수 있으며 이를 경년열화로 정의한다. 배관 시스 템의 경년열화는 재료의 피로, 부식(국부감육), 마모 등과 같은 메커니즘을 통해 발생할 수 있으며 재 료의 강도 및 시스템의 성능 저하와 균열을 야기할 수 있다. 지속적이고 안정적인 에너지 생산을 위해 경제성과 정확도를 고려한 원전 배관 시스템의 손상 감시 기술은 필요하다. 따라서 본 연구는 원전 배 관 시스템의 손상 감시 기술을 개발하기 위한 기초적인 연구로써 배관 시스템의 취약요소로 판단되는 elbow의 국부적인 감육에 따른 거동의 변화를 분석하고자 한다.

The microstructure and mechanical properties of the heat-affected zone welded using the GTAW process on SDSS material used in offshore structures were analyzed. The chemical composition of the specimen material was analyzed using XRF. The microstructure of the heat-affected zone where the plate was welded was examined by SEM, and the ferrite volume fraction was assessed using the point count method of ASTM E562. A lot of ferrite was formed in the overheated weldment region, and In the weld cap where the cooling rate was fast, ferrite was not converted back to austenite and the microstructure was not uniform. From the ferrite phase fraction, it was shown that it can be applied to the pitting resistance equivalent numbers through changes in mechanical properties according to welding conditions.

This study aims to evaluate the structural safety of a structural thermal barrier, installed inside the structure of a building and performed the role of a load-bearing element and an insulation simultaneously, contributing to the realization of net-zero buildings. To ensure the reliability of the analysis model, the analysis results derived from LS-DYNA were compared with the experimental results. Based on the results shown through the flexural experiment, the reliability of the thermal cross-section insulation structure model for slabs was validated. In addition, the effect of the UHPC block on the load support performance and its contribution to vertical deflection was verified.

A heat exchanger refers to a pressure vessel that indirectly exchanges heat between low-temperature/ high-temperature fluids with a solid wall interposed therebetween, and a shell-and-tube cylindrical heat exchanger is generally applied. The shell-and-tube cylindrical heat exchanger is widely used in ships and there is a problem in that the welding area is narrow and welding defects occur a lot due to high-level welding. In particular, in the case of a ship heat exchanger, if a problem occurs in the welding part during operation, the possibility of a safety accident is high, and repair is not easy. In this study, to solve this problem, the GTAW(Gas Tungsten Arc Welding) method was applied to secure the optimum conditions for pipe welding of STS304 material with a thickness of 5.5mm and to conduct a test. Afterwards, in accordance with the ASME rules, welding performance was verified through cross-sectional observation of welds, mechanical property tests, (tensile strength, bending strength, cryogenic impact strength) and non-destructive testing(PT, RT).

The effect of the laser beam diameter on the microstructure and hardness of 17-4 PH stainless steel manufactured via the directed energy deposition process is investigated. The pore size and area fraction are much lower using a laser beam diameter of 1.0 mm compared with those observed using a laser beam diameter of 1.8 mm. Additionally, using a relatively larger beam diameter results in pores in the form of incomplete melting. Martensite and retained austenite are observed under both conditions. A smaller width of the weld track and overlapping area are observed in the sample fabricated with a 1.0 mm beam diameter. This difference appears to be mainly caused by the energy density based on the variation in the beam diameter. The sample prepared with a beam diameter of 1.0 mm had a higher hardness near the substrate than that prepared with a 1.8 mm beam diameter, which may be influenced by the degree of melt mixing between the 17-4 PH metal powder and carbon steel substrate.

물체의 무게감은 감각 측면에서 중요하게 다뤄진 연구 주제로 물체의 무게뿐만 아니라, 크기, 색상, 재질 등의 영 향을 받아 크기-무게, 색상-무게 그리고 재질-무게 왜곡 현상을 갖는 것으로 알려져 있다. 온도는 우리의 일상생활에 매우 중요한 환경적 요소이나, 물체의 온도가 무게감에 어떤 영향을 미치는지에 대해 충분한 연구가 되어 있지 않다. 본 연구는 물체의 온도가 무게감에 미치는 영향을 파악하고자 하였다. 이를 위해 본 연구는 물체의 온도, 무게를 조정하기 용이한 스테인리스 컵을 무게감 측정 물체로 선정하였고, 온도 5 수준(0, 9, 20, 40, 70℃), 무게 2 수준(250, 400g)의 조합으로 10개의 스테인리스 컵을 준비하였다. 무게감 실험에는 건강한 20대 남여 40명이 참여하였고, modulus 방법에 따라 기준 컵 대비 주어진 컵의 무게감을 평가하였다. 실험 데이터의 분석 결과, 온도, 무게 모두 무게감에 유의한 영향을 주는 것으로 나타났다. 온도가 무게감에 주는 영향은 물체의 무게에 따라 다르게 나타났는 데, 적은 컵 무게(250g)로 컵의 무게감이 작은 경우 컵의 온도는 무게감에 영향을 주지 않았다. 반면, 큰 컵 무게 (400g)에서 낮은 온도에서 무게감이 커지는 것으로 나타났다. 이의 결과는 온도의 물체 무게감의 영향이 크기-무게 왜곡에 따라 달라짐을 의미한다.

The formation behavior of a passive state film on the surface of STS304 in electrolytic solution was analyzed to determine its metallic ion composition. The properties of passive state films vary depending on the Fe and Cr ions in the electrolytic solution. It was observed that the passive state film surface became flat and glossy as the concentration of Fe and Cr ions in the electrolytic solution increased. The corrosion resistance property of the passive state film was proportional to the amount of Fe and Cr in the electrolytic solution. An initial passive state film with high Fe concentration was formed on the surface of STS304 during early electrolytic polishing. Osmotic pressure of Fe ions occurs between the passive state film and electrolytic solution due to the Fe ion concentration gradient. The Fe in the passive state film is dissolved into the electrolyte, and Cr fills up the Fe ion vacancies. As a result, a good corrosion-resistant floating film was formed. The more Fe ions in the electrolytic solution, the faster the film is formed, and as a result, a flat passive state film containing a large amount of Cr can be formed.

인류 문명은 재료의 발달과 함께 진화를 해왔으며 20세기 후반부터 등장한 스마트재료는 외부 환경에 맞춰 스스로 적응을 하는 재료이다. 많은 종류의 스마트재료 중 대표물질이라고 할 수 있는 형상기억합금은 온도에 반응하여 자가 치유효과 를 볼 수 있는 재료이다. 외부 하중에 의한 변형을 자가치유 효과를 사용하여 회복을 하고자 하는 연구는 계속되어 왔지만 온 도의 변화를 구조물 전체적으로 줘야한다는 많은 불편이 있었다. 따라서 본 연구에서는 이 효과를 증진하여 상온에서도 자가 치유효과를 할 수 있는 초탄성 형상기억합금을 이용한다. 구조물에 있어서의 초탄성 형상기억합금의 능력을 스테인리스강과 함 께 비교하고 비교를 위해 강재가 가장 변형되기 쉬운 형태인 와이어형태로 가공하여 다양한 인장실험을 진행한다. 인장실험의 종류는 총 3가지로 변위를 다르게, 인장속도를 다르게, 선 인장력을 다르게 하는 실험으로 진행된다. 이때의 응력, 변형률간의 그래프를 그리고 잔류변형, 재료의 항복점 및 회복, 에너지 소산과 같은 구조물에 있어서의 재료적 능력을 파악하고 따로 그래 프를 도식화 하여 해석하였다.

In this study, we have prepared a Ti-6Al-4V/V/17-4 PH composite structure via a direct energy deposition process, and analyzed the interfaces using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The joint interfaces comprise two zones, one being a mixed zone in which V and 17-4PH are partially mixed and another being a fusion zone in the 17-4PH region which consists of Fe+FeV. It is observed that the power of the laser used in the deposition process affects the thickness of the mixed zone. When a 210 W laser is used, the thickness of the mixed zone is wider than that obtained using a 150 W laser, and the interface resembles a serrated shape. Moreover, irrespective of the laser power used, the expected  phase is found to be absent in the V/17-4 PH stainless steel joint; however, many VN precipitates are observed.

This study investigates the effect of process stopping and restarting on the microstructure and local nanoindentation properties of 316L stainless steel manufactured via selective laser melting (SLM). We find that stopping the SLM process midway, exposing the substrate to air having an oxygen concentration of 22% or more for 12 h, and subsequently restarting the process, makes little difference to the density of the restarted area (~ 99.8%) as compared to the previously melted area of the substrate below. While the microstructure and pore distribution near the stop/restart area changes, this modified process does not induce the development of unusual features, such as an inhomogeneous microstructure or irregular pore distribution in the substrate. An analysis of the stiffness and hardness values of the nano-indented steel also reveals very little change at the joint of the stop/restart area. Further, we discuss the possible and effective follow-up actions of stopping and subsequently restarting the SLM process.

This article suggests the machine learning model, i.e., classifier, for predicting the production quality of free-machining 303-series stainless steel(STS303) small rolling wire rods according to the operating condition of the manufacturing process. For the development of the classifier, manufacturing data for 37 operating variables were collected from the manufacturing execution system(MES) of Company S, and the 12 types of derived variables were generated based on literature review and interviews with field experts. This research was performed with data preprocessing, exploratory data analysis, feature selection, machine learning modeling, and the evaluation of alternative models. In the preprocessing stage, missing values and outliers are removed, and oversampling using SMOTE(Synthetic oversampling technique) to resolve data imbalance. Features are selected by variable importance of LASSO(Least absolute shrinkage and selection operator) regression, extreme gradient boosting(XGBoost), and random forest models. Finally, logistic regression, support vector machine(SVM), random forest, and XGBoost are developed as a classifier to predict the adequate or defective products with new operating conditions. The optimal hyper-parameters for each model are investigated by the grid search and random search methods based on k-fold cross-validation. As a result of the experiment, XGBoost showed relatively high predictive performance compared to other models with an accuracy of 0.9929, specificity of 0.9372, F1-score of 0.9963, and logarithmic loss of 0.0209. The classifier developed in this study is expected to improve productivity by enabling effective management of the manufacturing process for the STS303 small rolling wire rods.

Stainless steel, a type of steel used for high-temperature parts, may cause damage when exposed to high temperatures, requiring additional coatings. In particular, the Cr2O3 product layer is unstable at 1000oC and higher temperatures; therefore, it is necessary to improve the oxidation resistance. In this study, an aluminide (Fe2Al5 and FeAl3) coating layer was formed on the surface of STS 630 specimens through Al diffusion coatings from 500oC to 700oC for up to 25 h. Because the coating layers of Fe2Al5 and FeAl3 could not withstand temperatures above 1200oC, an Al2O3 coating layer is deposited on the surface through static oxidation treatment at 500oC for 10 h. To confirm the ablation resistance of the resulting coating layer, dynamic flame exposure tests were conducted at 1350oC for 5–15 min. Excellent oxidation resistance is observed in the coated base material beneath the aluminide layer. The conditions of the flame tests and coating are discussed in terms of microstructural variations.

This study suggests a machine learning model for predicting the production quality of free-machining 303-series stainless steel small rolling wire rods according to the manufacturing process's operation condition. The operation condition involves 37 features such as sulfur, manganese, carbon content, rolling time, and rolling temperature. The study procedure includes data preprocessing (integration and refinement), exploratory data analysis, feature selection, machine learning modeling. In the preprocessing stage, missing values and outlier are removed, and variables for the interaction between processes and quality influencing factors identified in existing studies are added. Features are selected by variable importance index of lasso regression, extreme gradient boosting (XGBoost), and random forest models. Finally, logistic regression, support vector machine, random forest, and XGBoost is developed as a classifier to predict good or defective products with new operating condition. The hyper-parameters for each model are optimized using k-fold cross validation. As a result of the experiment, XGBoost showed relatively high predictive performance compared to other models with accuracy of 0.9929, specificity of 0.9372, F1-score of 0.9963 and logarithmic loss of 0.0209. In this study, the quality prediction model is expected to be able to efficiently perform quality management by predicting the production quality of small rolling wire rods in advance.

In this study, the high-temperature oxidation properties of austenitic 316L stainless steel manufactured by laser powder bed fusion (LPBF) is investigated and compared with conventional 316L manufactured by hot rolling (HR). The initial microstructure of LPBF-SS316L exhibits a molten pool ~100 μm in size and grains grown along the building direction. Isotropic grains (~35 μm) are detected in the HR-SS316L. In high-temperature oxidation tests performed at 700oC and 900oC, LPBF-SS316L demonstrates slightly superior high-temperature oxidation resistance compared to HR-SS316L. After the initial oxidation at 700oC, shown as an increase in weight, almost no further oxidation is observed for both materials. At 900oC, the oxidation weight displays a parabolic trend and both materials exhibit similar behavior. However, at 1100oC, LPBF-SS316L oxidizes in a parabolic manner, but HR-SS316L shows a breakaway oxidation behavior. The oxide layers of LPBF-SS316L and HR-SS316L are mainly composed of Cr2O3, Febased oxides, and spinel phases. In LPBF-SS316L, a uniform Cr depletion region is observed, whereas a Cr depletion region appears at the grain boundary in HR-SS316L. It is evident from the results that the microstructure and the hightemperature oxidation characteristics and behavior are related.

Martensitic stainless steel is commonly used in the medical implant instrument. The alloy has drawbacks in terms of strength and wear properties when applied to instruments with sharp parts. 440C STS alloy, with improved durability, is an alternative to replace 420 J2 STS. In the present study, the carbide precipitation, and mechanical and corrosion properties of STS 440C alloy are studied as a function of different heat treatments. The STS 440C alloy is first austenitized at different temperatures; this is immediately followed by oil quenching and sub-zero treatment. After sub-zero treatment, the alloy is tempered at low temperatures. The microstructures of the heat treated STS 440C alloy consist of martensite and retained austenite and carbides. Using EDX and SADP with a TEM, the precipitated carbides are identified as a Cr23C6 carbide with a size of 1 to 2 μm. The hardness of STS 440C alloy is improved by austenitization at 1,100 oC with sub-zero treatment and tempering at 200 oC. The values of Ecorr and Icorr for STS 440C increase with austenitization temperature. Results can be explained by the dissolution of Cr-carbide and the increase in the retained austenite. Sub-zero treatment followed by tempering shows a little difference in the properties of potentiodynamic polarizations.

스테인레스 스틸에 대한 합성된 폴리우레탄-에폭시 수지의 기계적 특성은 SEM, FT-IR, 인장특성, 그리고 EIS에 의한 특정질량손실량, 입도분석 등에 의해 물성을 측정하였다. 친환경적인 NATM 도료에 관한 관심이 고조됨에 따라 스테인레스 등의 금속에 코팅하는 무용제 도료를 합성하였다. 폴리올, IPDI, 충진제, 실리콘 계면활성제, 촉매 등이 함유된 기존 중방식수지보다 폴리올, MDI, 충진제, 실리콘 계면활성제, 촉매가 함유되어 합성된 중방식수지의 도료가 온도변화에 따른 인장강도가 증가하였고, 전해성이 높은 용액 속에서 저헝력이 크게 측정되었으며, 내구력과 강도가 양호하였다. 견고한 NATM 수지의 기계적 특성은 가교와 부식환경의 차단력이 증가함에 따라 강도가 증가하였다. 결론적으로 중방식의 가교된 미세조직은 방청코팅이 어려운 스테인레스 스틸 같은 금속물질 코팅에도 좋은 실험 결과를 보여주었다.