현재 철근콘크리트 분야에서 부재의 철근을 FRP 보강재로 대체하기 위한 연구가 활발히 진행되고 있다. CFRP(Carbon Fiber Reinforced Polymer)는 특히 내화학성이 우수하여 보수 및 보강재로 큰 장점을 가지 며, RC 구조물의 보강재로 주로 사용되고 있다. CFRP 그리드의 경우 수지를 이용하여 섬유를 결합한 형 태를 가진다. 이러한 형태는 외부의 영향에 의해 수지 혹은 섬유의 손상으로 강도 저하가 발생할 수 있다. CFRP 그리드의 산성에 대한 저항성을 침지기간에 따른 인장강도 변화량 및 SEM과 무게 변화를 통해 확인하고자 한다. 따라서 Ph 농도 1~3의 강산성에 CFRP 그리드를 침지시키는 방식을 통해 내 화학 실험을 진행한다. 황산()을 이용하여 산성 용액을 제작한 후 실험을 진행하였다. 실험은 항온장치에서 60℃의 온도로 침지기간은 30, 60, 90, 180일로 한다. 그리드의 인장강도 변화를 확인하기 위하여 기간 별 시편의 수는 5개로 하며 침지시키지 않은 그리 드를 포함하여 총 25개의 시편을 실험한다. 인장실험을 통해 변형률 및 인장강도 변화를 확인한다. 그 리드의 섬유 및 수지의 변화 확인을 위해 실험진행 전 그리드의 무게를 측정 및 SEM(전자주사현미 경) 데이터 확보 후 실험을 진행한다. 기간별 침지된 그리드와 비교를 통해 기간별 섬유 및 수지의 영 향 정도를 확인한다. 본 연구에서는 산성이 CFRP 그리드에 미치는 영향을 조사하기 위해 인장강도, SEM, 무게 변화를 통해 연구하였으며, 이를 통해 산성의 영향을 받는 CFRP 그리드 부재의 안정성을 평가하고자 한다.

탄소섬유 강화 플라스틱 (Carbon fiber reinforced plastics, CFRP)은 고함량의 탄소섬유 (Carbon fiber, CF)와 고분자로 이루어진 복합재료로서, 뛰어난 기계적 성능으로 항공우주, 자동차, 토목 등 다 양한 산업 분야에서 사용되고 있다. 하지만 사용량 증가에 따른 폐기물의 환경문제와 추출한 재활용 탄소섬유 (Recycled carbon fiber, rCF)의 적용 가능 분야의 한계로 인해 재활용이 제한적인 실정이 다. 본 연구에서는 rCF와 CF 혼입 시멘트계 전자파 복합재를 제작하여 그 성능을 비교 분석하기 위 한 실험을 수행하였다. 구성재료는 시멘트, 잔골재, 고성능 감수제를 사용하였으며, 비교 분석을 위해 CF와 rCF를 각각 6 mm, 12 mm 길이를 0.1, 0.3, 0.5, 1.0 wt.% 함량으로 사용하였다. 전자파 복합 재의 흡수 성능 향상을 위해 각각 다른 함량의 다층 구조를 형성하였으며, 전자파 투과를 낮은 함량에 서 높은 함량 방향이 되도록 측정을 진행하였다. 전자파 차폐성능은 재령 28일 이후 네트워크 분석기 를 사용하여 자유 공간에서 측정하였으며, C-band (4~8 GHz)와 X-band (8~12 GHz) 주파수 영역 에서의 반사율과 투과율을 각각 측정하였다.

이 연구는 코르크보드를 보강하여 건축부재 및 놀이기구의 안전부재 등으로 폭넓게 활용할 것을 목적으로 코르크보드의 중층에 금속, 유리섬유, 탄소섬유를 삽입하여 보강한 3종의 코르크복합보드를 제조하였고, 코르크복합보드의 수분흡수에 따른 치수안정성 및 접착층 박리성능을 조사하였다. 코르크복합보드의 흡수율은 0.37% - 0.45%의 범위에 있었고, 코르크보드에 비해 0.61배 - 0.74배의 낮은 값을 나타내었다. 코르크복합보드의 두께팽창률은 0.92% - 1.58%의 범위에 있었고, 코르크보드 보다 1.4 - 2.4배의 높은 값을 나타내었다. 그러나 이 값들은 일반 목질보드보다 현저히 낮았고, KS규격의 12%이하를 하회하는 것이 확인되었다. 코르크복합보드의 준내수 및 내수침지박리시험후의 접착층박리율은 0%로 전혀 접착층의 박리가 일어나지 않아 우수한 내수성을 나타내었고, 흡수율과 흡수두께팽창률은 상온침지에 비해 다소 증가하였으나, 목질보드에 관한 KS규격을 하회하는 우수한 치수안정성을 나타내는 것이 확인되었다.

Along with the development of the automobile industry, the materials and processing technology of parts have also developed. In particular, various materials have been developed and applied to automobile bumpers, which are directly related to crash safety. In particular, the application of composite materials is expanding for weight reduction. In this study, a new composite material made of a mixture of carbon fiber and aramid fiber was developed and the possibility of application to an automobile bumper was reviewed, and significant results were obtained.

국내 건설현장에서 장스팬 구조물이 증가함에 따라 콘크리트와 강재를 조합한 충전형합성보의 적용이 증가하고 있 다. 충전형합성보는 경제적이며 시공성이 향상되고 콘크리트 축열효과에 따라 내화성도 우수하다. 충전형합성보 내부에 휨성능 을 향상시키기 위해 Re-bar로 보강하여 사용한다. 이는 콘크리트 균열에 의해 부식 되어 내력저하를 유발한다. CFRP Re-bar는 경량이며 내부식성이 우수하다. 그러나 임계온도가 250℃로 낮기 때문에 화재에 취약으로 적절한 내화피복재를 적용해야된다. 따라서 열전달해석을 통해 내부 CFRP Re-bar가 보강된 충전형합성보의 온도분포를 확인하였다. 온도 상승에 따른 휨내력을 산 정하여 피복두께를 제안하고자 한다. 해석결과 단면크기에 상관없이 콘크리트 피복두께 40mm와 뿜칠내화피복재 20mm를 적용 하면 표준화재에서 3시간 내화성능을 확보하는 것으로 평가되었다.

Cu matrix composites reinforced with chopped carbon fiber (CF), which is cost effective and can be well dispersed, are fabricated using electroless plating and hot pressing, and the effects of content and alignment of CF on the thermal properties of CF/Cu composites are studied. Thermal conductivity of CF/Cu composite increases with CF content in the in-plane direction, but it decreases above 10% CF; this is due to reduction of thermal diffusivity related with phonon scattering by agglomeration of CF. The coefficient of thermal expansion decreases in the in-plane direction and increases in the through-plane direction as the CF content increases. This is because the coefficient of thermal expansion of the long axis of CF is smaller than that of the Cu matrix, and the coefficient of thermal expansion of its short axis is larger than that of the Cu matrix. The thermal conductivity is greatly influenced by the agglomeration of CF in the CF/Cu composite, whereas the coefficient of thermal expansion is more influenced by the alignment of CF than the aggregation of CF.

In this research, carbon nanotubes(CNT) and graphene nanoplates(GnP) are deposited on the surface of carbon fibers(CF) at once. Investigating the effect between CNT and GnP on increasing the interfacial and mechanical properties of carbon fiber reinforced epoxy composites(CFRP). The cross section of the CFRP composites indicates that the GnPs/CNTs hybrid coating exhibits significantly higher mechanical performance in all coating samples. The interlayer shear strength of the GnPs/CNT hybrid coated CFRP composite was 90% higher than that of the uncoated CF composite. The flexural and tensile strength of CFRP composites using GnPs /CNT hybrid coatings were improved by 52% and 70%, respectively, compared to uncoated CF.

Commercial carbon fiber is sized with Bisphenol A type epoxy, a thermosetting resin, to prevent fiber damage due to friction during weaving and manufacturing processes. When the thermoplastic resin is used as the base material, the interface between the carbon fiber and the thermoplastic resin is very weak because the bonding force with the thermosetting resin is not good, which greatly affects the mechanical properties of the composite material. Therefore, in order to improve the mechanical properties of the thermoplastic composite material, a process of removing the epoxy sizing layer on the surface of the carbon fiber in a furnace is required. In this process, the physical properties of the carbon fiber are changed according to the change of carbon fiber heat treatment conditions. In this paper, the study was carried out to evaluate the tensile strength required for automobile parts by extrusion and injection of thermoplastic resin based carbon fiber composites. Depending on the heat treatment temperature and time of the carbon fiber was a slightly tensile strength of the carbon composite material occurs, the tensile strength of the carbon composite material with a 6 hour heat-treated carbon fiber was measured at 550 ℃ the highest to 93 MPa. When the heat treatment holding time is more than 6 hours or the heat treatment temperature is more than 600 ℃, it may be the damage to the carbon fiber, which can cause a decrease in the tensile strength of the carbon fiber composite material.

As carbon fibers have the high performance, such as high strength, light weight, and high corrosion resistance, they are gradually expanding and growing at various industries. In particular, this study was conducted to determine whether the market could be applied to street lanterns among the construction sectors expected to grow in scale. In this study, the material characteristics of street lanterns using carbon fiber composites were studied in order to determine whether carbon fiber composites could be applied as a substitute for stainless steel and cast iron street lanterns. The physical relationship was experimentally evaluated to obtain a suitable material through the comparison of physical properties of fiber composite materials.

Carbon molecular sieve (CMS) membrane surpasses the upper-bound trade-off and plasticization phenomenon of polymer membrane. Recently, supported CMS membranes have been investigated to provide both high performance and mechanical strength. Herein, we have investigated the supported CMS hollow fiber membranes on low-cost alumina hollow fiber. To prepare the thin and uniform layers, the dip-coating parameters for intermediate and polymeric layers were varied in terms of the withdrawal rate and solution viscosity, respectively. Then, in order to confirm its feasibility in real industry, mixture gas was permeated through prepared CMS membranes. Moreover, the property of long-term stability was characterized in harsh conditions and further modified.

Multiwall carbon nanotubes (MWCNT) with two different (L/D) aspect ratios (7±2 μm/140±30 nm and 0.5–2 μm/8–15 nm) were surface treated using nitric acid (HNO3) and polyethyleneimine (PEI) prior to their deposition on carbon fibers (CF). Before the hierarchical reinforcement with CF-MWCNT, the CFs were treated with 3-glycidoxypropyltrimethoxysilane, a coupling agent (Z6040) and with poly(amidoamine) (PAMAM) a dendrimer containing an ethylenediamine core and amine surface groups. The MWCNT were deposited on the CF using two methods, by electrostatic attraction and by chemical reactions. The changes in the CF surface morphology after the MWCNT deposition were analyzed using SEM, which revealed a higher density and uniform coverage for the PAMAM-treated CF and the short MWCNTs. The interfacial adhesion of the composite materials was evaluated using the single fiber fragmentation technique. The results indicated an improvement in the interfacial shear strength with the addition of the short-MWCNTs treated with acid solutions and grafted onto the surface of the CF fiber using electrostatic attraction.

증류에 의한 올레핀/파라핀 분리는 끓는점이 유사하여 에너지 소모가 높기 때문에, 분리막을 이용한 연구가 많이 진행 중이다. 특히 CMS 분리막은 sieving separation에 의한 투과/분리 성능이 우수하다. 따라서 본 연구에서는 중공사형 α-alumina 지지체에 γ-alumina 중간층을 형성한 후 Matrimid로 코팅하여 열분해함으로써 높은 기계적 강도와 충진 밀도를 갖는 중공사형 CMS 복합막을 제조하였다. 제조된 CMS 분리막은 20 - 35 GPU 프로필렌 투과도와 10 이상의 프로필렌/프로판 분리도를 보였다. 이 연구는 2014년 정부(미래창조과학부)의 재원으로 국가과학 기술연구회 융합연구단 사업(No. CRC-14-01-KRICT)의 지원을 받아 수행된 연구입니다.

Isroaniso matrix precursor synthesized from commercially available petroleum pitch was stabilized in air. The influence of oxygen mass gain during stabilization on the yield of matrix precursor was studied. Additionally, the influence of pressure on the yield of the stabilized matrix precursor in a real system was studied. The fourier transform infrared spectrometry (FTIR), thermogravimetric analysis (TGA), yield, yield rate, and yield impact were used to check the effect of stabilization and pressure on the yield of the matrix precursor and the end properties of the composite thereafter. The results showed that the yield increased with stabilization duration up to 20 h whereas it decreased for stabilization duration beyond 20 h. Further results showed that the stabilized matrix precursor for a duration of 5 h could withstand almost two-fold greater hot-pressing pressure without resulting in exudation as compared to that of a 1 h stabilized matrix precursor. The enhanced hot-pressing pressure significantly improved the yield of the matrix precursor. As a consequence, the densification and mechanical properties were increased significantly. Further, the matrix precursor stabilized for a duration of 20 h or more failed to provide proper and uniform binding of the reinforcement.

In the present study, exfoliated graphite nanoplatelets (xGnP) with different particle sizes were coated onto polyacrylonitrile-based carbon fibers by a direct coating method. The flexural properties, interlaminar shear strength, and the morphology of the xGnP-coated carbon fiber/phenolic matrix composites were investigated in terms of their longitudinal flexural strength and modulus, interlaminar shear strength, and by optical and scanning electron microscopic observations. The results were compared with a phenolic matrix composite counterpart prepared without xGnP. The flexural properties and interlaminar shear strength of the xGnP-coated carbon fiber/phenolic matrix composites were found to be higher than those of the uncoated composite. The flexural and interlaminar shear strengths were affected by the particle size of the xGnP, while the particle size had no significant effect on the flexural modulus. It seems that the interfacial contacts between the xGnP-coated carbon fibers and the phenolic matrix play a role in enhancing the flexural strength as well as the interlaminar shear strength of the composites.

Impact damages induced by a low-velocity impact load on carbon fiber reinforced polymer (CFRP) composite plates fabricated with various stacking sequences were studied experimentally. The impact responses of the CFRP composite plates were significantly affected by the laminate stacking sequences. Three types of specimens, specifically quasi-isotropic, unidirectional, and cross-ply, were tested by a constant impact carrying the same impact energy level. An impact load of 3.44 kg, corresponding to 23.62 J, was applied to the center of each plate supported at the boundaries. The unidirectional composite plate showed the worst impact resistance and broke completely into two parts; this was followed by the quasi-isotropic lay-up plate that was perforated by the impact. The cross-ply composite plate exhibited the best resistance to the low-velocity impact load; in this case, the impactor bounced back. Impact parameters such as the peak impact force and absorbed energy were evaluated and compared for the impact resistant characterization of the composites made by different stacking sequences.

The prime objective of this research was to study the influence of hot-pressing pressure and matrix-to-reinforcement ratio on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon-composite. Secondary objectives included determination of the physical and mechanical properties of the resulting composite. The ‘hybrid carbon-fiberreinforced mesophase-pitch-derived carbon-matrix’ composite was fabricated by hot pressing. During hot pressing, pressure was varied from 5 to 20 MPa, and reinforcement wt% from 30 to 70. Densification of all the compacts was carried at low impregnation pressure with phenolic resin. The effect of the impregnation cycles was determined using measurements of microstructure and density. The results showed that effective densification strongly depended on the hot-pressing pressure and reinforcement wt%. Furthermore, results showed that compacts processed at lower hot-pressing pressure, and at higher reinforcement wt%, gained density gradually during three densification cycles and showed the symptoms of further gains with additional densification cycles. In contrast, samples that were hot-pressed at moderate pressure and at moderate reinforcement wt%, achieved maximum density within three densification cycles. Furthermore, examination of microstructure revealed the formation of cracks in samples processed at lower pressure and with low reinforcement wt%.