Determination of explosion reference pressure is important in designing and testing flameproof enclosures (Ex d). Although relative humidity affects to explosion pressure, its effect is not well investigated for the gas group IIB, IIA, and I. This study tested explosion pressure for Ethylene (8 vol.%), Propane (4.6 vol.%), and Methane (9.8 vol.%), which are the representative gas of the gas group IIB, IIA, and I, at ambient temperature and atmospheric pressure (1 atm) under different relative humidity (0% ~ 80%). Ethylene- and Propane-air mixed gases generally tended to decrease as the relative humidity increased; however, explosion pressure was largely dropped at 20% of relative humidity compared to 0% and 10% of relative humidity. On the other hand, Methane-air mixture gas showed similar pressures at 0% and 10% of relative humidity; but no explosion occurred at more than 20%. The results of this study can be used in setting a testing protocol of explosion reference pressure for designing and testing a flameproof enclosure.
L.P SCR의 촉매 반응을 위해 선박의 발전기용 4행정 디젤엔진의 배기가스 온도를 높게 설계 할 수밖에 없었다. 본 연구의 목적은 밸브개폐시기와 연료분사시기를 조정을 통한 배기가스의 온도 감소가 L.P SCR의 운전조건을 만족시키고 고온으로 인한 발전기 엔진의 사고를 예방하기 위함이었다. 배기가스 온도를 하강시키기 위해 캠샤프트의 각도를 조정하고 연료분사펌프의 Shim을 추가하였다. 그 결과 최대폭발압력은 12.8 bar 증가하였고 터보차저 출구온도 평균값은 13.3 ℃ 하강하였다. 터보차저 출구에서 SCR 입구까지의 열손실을 감안하더라도 L.P SCR 운전조건인 SCR 챔버 입구 온도인 290 ℃를 만족하였다. 배기가스 온도 하강을 통해 디젤발전기의 안전운전이 가능하게 한 연구였다.
Gas detection is necessary for various reasons, including the prevention of gas leakages and the creation of necessary environmental conditions. Among the gas detection methods, leakage of gas can be confirmed using materials that undergo color changes that are easily distinguished by the naked eye. Metal nanoparticles (NPs) experience variations in their absorption wavelengths under the localized surface plasmon effect (LSPR) with mechanical stresses, which change the distance between NPs. In this study, we attempted to detect the presence of gas utilizing the LSPR-related color change of a chain of Au NPs. The assembly of Au NPs, arranged in a chain shape, experienced a color change from dark blue to purple with a change in the distance between the NPs by applying a physical force, i.e., compression, stretching, and gas pressure. As the force of compression and the degree of stretching increased, the absorption wavelength shifted from doublet peaks at 650 and 550 nm to a singlet peak at 550 nm. Further, applying gas pressure caused an identical color change. With this result, we propose a method that could be applied to all gases that require detection based on gas pressure.
SiAlON-based ceramics are some of the most typical oxynitride ceramic materials, which can be used as cutting tools for heat-resistant super-alloys (HRSA). SiAlON can be fabricated by using gas-pressure reactive sintering from the raw materials, nitrides and oxides such as Si3N4, AlN, Al2O3, and Yb2O3. In this study, we fabricate Ybm/3Si12-(m+n)Alm+nOnN16-n (m=0.3, n=1.9, 2.3, 2.7) ceramics by using gas-pressure sintering at different sintering temperatures. Then, the densification behavior, phase formation, microstructure, and hardness of the sintered specimens are characterized. We obtain a fully densified specimen with β- SiAlON after gas-pressure sintering at 1820℃ for 90 min. under 10 atm N2 pressure. These SiAlON ceramic materials exhibited hardness values of ~92.9 HRA. The potential of these SiAlON ceramics for cutting tool application is also discussed.
In this study, ultra-fine soft-magnetic micro-powders are prepared by high-pressure gas atomization of an Fe-based alloy, Fe-Hf-B-Nb-P-C. Spherical powders are successfully obtained by disintegration of the alloy melts under high-pressure He or N2 gas. The mean particle diameter of the obtained powders is 25.7 μm and 42.1 μm for He and N2 gas, respectively. Their crystallographic structure is confirmed to be amorphous throughout the interior when the particle diameter is less than 45 μm. The prepared powders show excellent soft magnetic properties with a saturation magnetization of 164.5 emu/g and a coercivity of 9.0 Oe. Finally, a toroidal core is fabricated for measuring the magnetic permeability, and a μr of up to 78.5 is obtained. It is strongly believed that soft magnetic powders prepared by gas atomization will be beneficial in the fabrication of high-performance devices, including inductors and motors.
We present 12CO (2-1) data for four spiral galaxies (NGC 4330, NGC 4402, NGC 4522, NGC 4569) in the Virgo cluster that are undergoing different ram pressure stages. The goal is to probe the detailed molecular gas properties under strong intra-cluster medium (ICM) pressure using high-resolution millime- ter data taken with the Submillimeter Array (SMA). Combining this with Institut de RadioAstronomie Millimetrique (IRAM) data, we also study spatially resolved temperature and density distributions of the molecular gas. Comparing with multi-wavelength data (optical, Hi, UV , Hα), we discuss how molecular gas properties and star formation activity change when a galaxy experiences Hi stripping. This study suggests that ICM pressure can modify the physical and chemical properties of the molecular gas sig- nificantly even if stripping does not take place. We discuss how this affects the star formation rate and galaxy evolution in the cluster environment.
중공사 고분자 분리막을 이용한 SF6를 분리 농축을 위한 운전조건을 결정하기 위해서는, 온도와 압력이 투과특성에 미치는 영향에 관한 연구가 필요하다. 본 연구에서는 다양한 온도와 압력이 부과된 조건에서 단일기체 투과실험을 수행하여, 중공사 고분자 분리막(PSF, PC, PI)을 통한 기체(N2, O2, SF6, CF4)의 투과특성을 연구하였다. 실험결과, 기체의 투과플럭스는 온도와 압력의 증가에 따라 일반적으로 증가하는 것으로 나타났으나, 분리막에 따른 투과플럭스의 차이가 관찰되었으며, 온도, 압력에 따른 투과플럭스 변화율은 기체의 특성(분자크기)에 따라 다른 것으로 나타났다. 온도 압력에 대한 투과플럭스를 3차원적으로 표현했을 때, 투과플럭스는 근사적인 평면 위에서 변화하는 것으로 관측되었다. 온도와 압력에 의한 투과플럭스 변화를 열역학적으로 분석하였으며, 투과플럭스 예측을 위한 경험적 모델로 평면특성의 1차 다항식 모델과 곡면 특성을 가진 2차 다항식 모델을 제안하였다. 그 결과 두 경험적 모델 모두 관측자료에 대한 높은 적합도를 보여 적용가능성을 확인하였다.
In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 of specific surface area and 45.6 nm of average particles diameter.
In this paper, rapid solidified Mg-4.3Zn-0.7Y (at.%) alloy powders were prepared using an inert gas atomizer, followed by a severe plastic deformation technique of high pressure torsion (HPT) for consolidation of the powders. The gas atomized powders were almost spherical in shape, and grain size was as fine as less than due to rapid solidification. Plastic deformation responses during HPT were simulated using the finite element method, which shows in good agreement with the analytical solutions of a strain expression in torsion. Varying the HPT processing temperature from ambient to 473 K, the behavior of powder consolidation, matrix microstructural evolution and mechanical properties of the compacts was investigated. The gas atomized powders were deformed plastically as well as fully densified, resulting in effective grain size refinements and enhanced microhardness values.
가스상의 체적분율과 압력강하는 기액이상류에 대한 이해와 예측에 있어서 매우 중요한 인자이다. 또한 그것들은 산업용 대용량의 열교환시스템 및 선박에 설치되는 보일러 및 냉동시스템의 설계에 있어서 필수적인 항목이다. 따라서 본 논문에서는 파이프의 모든 경사각도에서 기액이상류 가스상의 체적분율과 압력손실을 예측할 수 있는 이론적 해석 방법을 제시한다. 여기서의 이론적 해석은 2유체 층상류 모델을 기초로 하고 있다. 또한 이론적 해석결과와 기존의 실험결과와 비교한 결과에 대해서도 제시한다.
Close-coupled atomizers are of great interest and controlling their performance parameters is critical for metal powder producing and spray forming industries. In this study, designed close-coupled nozzle systems were used to investigate the effect of the nozzle types and protrusion length of the melt delivery tube on the pressure formation at the melt delivery tube tip. The observed metal flow rate was not behaving as what was earlier assumed, namely that, deeper aspiration enhanced metal flow rate. Higher aspiration pressure at the tip of the melt delivery tube increases the stability of atomization process.