This study addresses the optimal design methodology for switching between active electronically scanned array (AESA) radar operating modes to easily select the necessary information to reduce pilots' cognitive load and physical workload in situations where diverse and complex information is continuously provided. This study presents a procedure for defining a hidden Markov chain model (HMM) for modeling operating mode changes based on time series data on the operating modes of the AESA radar used by pilots while performing mission scenarios with inherent uncertainty. Furthermore, based on a transition probability matrix (TPM) of the HMM, this study presents a mathematical programming model for proposing the optimal structural design of AESA radar operating modes considering the manipulation method of a hands on throttle-and-stick (HOTAS). Fighter pilots select and activate the menu key for an AESA radar operation mode by manipulating the HOTAS’s rotary and toggle controllers. Therefore, this study presents an optimization problem to propose the optimal structural design of the menu keys so that the pilot can easily change the menu keys to suit the operational environment. K
The magnetic Cs adsorbent functionalized with hierarchical titanium-ferrocyanide were fabricated for the highly efficient magnetic removal of radioactive cesium from water. The new magnetic Cs adsorbent has a core–shell structure that comprises a Fe3O4 core, an interlayer of SiO2, and a titanium-ferrocyanide-shell with hierarchical nanostructure. At first, the magnetic Fe3O4 nanoparticles synthesized via a hydrothermal reaction were coated with SiO2. Then, TiO2 were coated on the surface of SiO2 coated magnetic nanoparticles. Finally, the hierarchical titanium-ferrocyanide composed of 2-dimensional TiFC flakes was fabricated on the surface of core-shell MNP@SiO2@TiO2 microparticles using a TiO2 sacrificial template via a simple reaction with potassium ferrocyanide (FC) based on the Kirkendall-type diffusion. The resulting magnetic Cs adsorbent shows higher adsorption capacity of 416 mg/g than other magnetic Cs adsorbents (below 200 mg/g) because of the increased effective surface area of hierarchical titanium-ferrocyanide. Therefore, our Magnetic Cs adsorbent functionalized with hierarchical titanium-ferrocyanide has excellent potential for the treatment of various 137Cs-contaminated sources.
The utilization of carbonaceous reinforcement-based polymer matrix composites in structural applications has become a hot topic in composite research. Although conventional carbon fiber-reinforced polymer composites (CFRPs) have revolutionized the composite industry by offering unparalleled features, they are often plagued with a weak interface and lack of toughness. However, the promising aspects of carbon fiber-based fiber hybrid composites and hierarchical composites can compensate for these setbacks. This review provides a meticulous landscape and recent progress of polymer matrixbased different carbonaceous (carbon fiber, carbon nanotube, graphene, and nanodiamond) fillers reinforced composites’ mechanical properties. First, the mechanical performance of neat CFRP was exhaustively analyzed, attributing parameters were listed down, and CFRPs’ mechanical performance barriers were clearly outlined. Here, short carbon fiber-reinforced thermoplastic composite was distinguished as a prospective material. Second, the strategic advantages of fiber hybrid composites over conventional CFRP were elucidated. Third, the mechanical performance of hierarchical composites based on carbon nanotube (1D), graphene (2D) and nanodiamond (0D) was expounded and evaluated against neat CFRP. Fourth, the review comprehensively discussed different fabrication methods, categorized them according to performance and suggested potential future directions. From here, the review sorted out three-dimensional printing (3DP) as the most futuristic fabrication method and thoroughly delivered its pros and cons in the context of the aforementioned carbonaceous materials. To conclude, the structural applications, current challenges and future prospects pertinent to these carbonaceous fillers reinforced composite materials were elaborated.
Hierarchical porous carbons (HPCs) have been successfully prepared by a facile carbonization and subsequent CO2 activation process using corncob as a natural carbon precursor and Mg(C2H3O2)2 as a MgO nano-template precursor. The prepared corncob-based hierarchical porous carbons (C-HPCs) with desirable micropores and mesopores feature the excellent absorbency of gas (i.e., CO2 and CH4) and solution (i.e., methylene blue (MB)). Increasing the ratio of Mg(C2H3O2)2/corncob enlarged the specific surface area up to 1004 m2/ g, micropore and mesopore volumes, CO2, CH4, and MB adsorption capacities (112, 31 and 230 mg/g after 325 min, respectively). The results indicated that the pore structures of C-HPCs can be easily and suitably controlled by the amount of the template precursor and CO2 activation effecting concurrently, which leads to fascinating adsorption capacity for CO2, CH4, and MB.
수역 내 충돌 위험 식별은 항해의 안전을 위해 중요하다. 본 연구에서는 거리 요인을 기반으로 한 군집화 방법인 계층 클러스 터링을 포함하는 새로운 충돌 위험 평가 방법을 도입했으며, 주변의 선박이 많은 경우 실시간 데이터, 그룹 방법론 및 예비 평가를 사용하여 선박을 분류하고 충돌위험평가를 기반으로 평가하였다(HCAAP 처리라 부른다). 조우하는 선박들의 군집은 계층 프로그램에 의해 모아지고, 예비 평가와 결합되어 상대적으로 안전한 선박을 걸러내었다. 그런 다음, 각 군집 내에서 조우하는 선박 사이의 최근접점(DCPA) 및 최근접점까지의 도착시간(TCPA)까지의 시간을 계산하여 충돌위험지수(CRI)와의 관계를 비교하였다. 조우하는 선박들간의 군집에서 CRI와 DCPA 및 TCPA 수학적 관계는 음의 지수 함수로 구성되었다. 이러한 CRI로부터 운영자는 명시된 해역에서 항해하는 모든 선박의 안전성을 보다 쉽게 평가할 수 있으며, 프레임워크는 해상운송의 안전과 보안을 개선하고 인명 및 재산 손실을 줄일 수 있다. 본 연구에 서 제안된 프레임워크의 효과를 설명하기 위해 국내의 목포 연안 해역에서 실험 사례 연구를 수행하였다. 그 결과, 본 연구의 프레임워크가 각 군집 내에서 조우 선박 간의 충돌 위험 지수를 탐지하고 순위를 매기는 데 효과적이고 효율적이라는 것을 보여 주었으며, 추가연구를 위한 자동 위험 우선순위를 지정할 수 있게 해주었다.
To meet the increased performance and cost requirements of commercial supercapacitor, a N and O self-doped hierarchical porous carbon is fabricated via a green and simple self-activation route utilizing leaves of wild hollyhock as raw materials. Comparing to commercial activated carbon, the reported material exhibits some marked merits, such as simple and green fabrication process, low cost, and superior capacitance performance. The specific surface area of the obtained N and O codoped hierarchical porous carbon arrives 954 m2 g−1, and the content of the self-doped nitrogen and oxygen reaches 2.64 at.% and 7.38 at.%, respectively. The specific capacitance of the obtained material reaches 226 F g− 1 while the specific capacitance of the symmetric supercapacitor arrives 47.3 F g− 1. Meanwhile, more than 90.3% of initial specific capacitance is kept under a current density of 20 A g− 1, and no arresting degradation is observed for capacitance after 5000 times cycle, perfectly demonstrating the excellent cycle and rate capability of the obtained material. The obtained N and O co-doped hierarchical porous carbon are expected to be an ideal substitution for commercial activated carbon.
다층 구조를 가진 5A 제올라이트를 탄소 분자체 분리막에 첨가한 복합막을 제조하고 질소/산소의 분리 특성을 평가하였다. 제올라이트의 첨가는 선택도에는 미세한 영향을 주지만 투과도를 크게 증가시키는 방법으로 전체적인 탄소막의 질소/산소의 분리 성능을 상승시켰다. 특히 메조포어를 함유한 다층구조의 제올라이트 첨가제는 분리막의 투과도를 보다 효율적으로 상승시켜 아주 우수한 분리 성능에 도달하였다. 이 연구의 결과는 저렴한 탄소막 전구체와 제올라이트 소재를 활용하 고도 고성능의 질소/산소 분리막을 손쉽게 제조할 수 있다는 것을 제시한다.
Heteroatoms in situ-doped hierarchical porous hollow-activated carbons (HPHACs) have been prepared innovatively by pyrolyzation of setaria viridis combined with alkaline activation for the first time. The micro-morphology, pore structure, chemical compositions, and electrochemical properties are researched in detail. The obtained HPHACs are served as outstanding electrode materials in electrochemical energy storage ascribe to the particular hierarchical porous and hollow structure, and the precursor setaria viridis is advantage of eco-friendly as well as cost-effective. Electrochemical measurement results of the HPHACs electrodes exhibit not only high specific capacitance of 350 F g−1 at 0.2 A g−1, and impressive surface specific capacitance (Cs) of 49.9 μF cm−2, but also substantial rate capability of 68% retention (238 F g−1 at 10 A g−1) and good cycle stability with 99% retention over 5000 cycles at 5 A g−1 in 6 M KOH. Besides, the symmetrical supercapacitor device based on the HPHACs electrodes exhibits excellent energy density of 49.5 Wh kg−1 at power density of 175 W kg−1, but still maintains favorable energy density of 32.0 Wh kg−1 at current density of 1 A g−1 in 1-ethy-3-methylimidazolium tetrafluoroborate ( EMIMBF4) ionic liquid electrolyte, and the excellent cycle stability behaviour shows the nearly 97% ratio capacitance retention of the initial capacitance after 10,000 cycles at current density of 2 A g−1. Overall, the results indicate that HPHACs derived from setaria viridis have appealing electrochemical performances thus are promising electrode materials for supercapacitor devices and large-scale applications.
In the molecular cloud G33.92+0.11A, massive stars are forming sequentially in dense cores, probably due to interaction with accreted gas. Cold dense gas, which is likely the pristine gas of the cloud, is traced by DCN line and dust continuum emission. Clear chemical differences were observed in different source locations and for different velocity components in the same line of sight. Several distinct gas components coexist in the cloud: the pristine cold gas, the accreted dense gas, and warm turbulent gas, in addition to the star-forming dense clumps. Filaments of accreted gas occur in the northern part of the A1 and A5 clumps, and the velocity gradient along these features suggests that the gas is falling toward the cloud and may have triggered the most recent star formation. The large concentration of turbulent gas in the A2 clump seems to have formed mainly through disturbances from the outside.
Energy and environmental are always two major challenges for the sustainable development of the modern human being. For avoiding the serious environmental pollution caused in the fabrication process of porous carbon, a popular energy storage material, we reported a facile, green and activating agent free route hereby directly carbonizing a special biomass, Glebionis coronaria. A nitrogen doped hierarchical porous carbon with a specific surface area of up to 1007 m2 g−1 and a N doping content of up to 2.65 at.% was facilely fabricated by employing the above route. Benefiting from the peculiarly hierarchical porous morphology, enhanced wettability and improved conductivity, the obtained material exhibits superior capacitance performance, which capacitance reaches up to 205 F g−1 under two-electrode configuration, and no capacitance loss is observed after 5000 cycles. Meanwhile, the capacitance retention of the obtained material arrives up to 95.0% even under a high current density of 20 A g−1, illuminating its excellent rate capability. The fabricated nitrogen-doped hierarchical porous carbon with larger capacitance than commercial activated carbon, excellent rate capability and cycle stability is an ideal cost-efficient substitution of commercial activated carbon for supercapacitor application.
The aim of this study is to identify the value structure of active seniors for noodles. Noodles are the secondly most preferred and familiar food in Korea, followed by rice. And noodles also have a variety of tastes/flavors and even a variety of ceremonial characteristics. The necessity of offering proper food to seniors has recently increasing because Korea becoming an aged society. This study conducted 1:1 in-depth interviews with 30 active senior participants using the soft laddering technique, which is based on the means-end chain theory. The Implication Matrix and HVM were derived from performing content analysis. The active seniors mainly consider the ‘taste’, expecting to obtain the ‘satisfying taste’, and pursuing the ‘family affair’, ‘pleasure’, and ‘self-satisfaction’. The results of this study indicated that the taste is the most important attribute and the active seniors consider their family as well as the pleasure and satisfaction of their own. Male seniors mainly pursue the ‘pleasure’ and ‘self-satisfaction’ by satisfying their taste through considering ‘taste’ and ‘familiarity’. But female seniors mainly pursue the ‘family affair’ by ‘satisfying taste’ through considering ‘taste’. These results can be used as a basic data for developing noodle products for the elderly. This study will also contribute to the development of special care food and product concepts for the silver generation.
Chlorella-derived activated carbon (CDAC) with a high specific surface area and hierarchical pore structure was prepared as a CO2 adsorbent and as a supercapacitor electrode material. During KOH activation of Chlorella-derived carbon, metallic K gas penetrated from the outer walls to the inner cells, and pores formed on the outer frame and the inner surface. Micropores were dominant in CDAC, contributing toward a high specific surface area (> 3500 m2/g) and a hierarchical pore structure owing to the cell walls. Consequently, CDAC exhibited a high CO2 adsorption capacity (13.41 mmol/g at 10 atm and room temperature) and afforded high specific capacitance (142 F/g) and rate capability (retention ratio: 91.5%) in supercapacitors. Compared with woody- and herbaceous-biomass-derived activated carbons, CDAC has a superior specific surface area when the precursors are used without any pretreatment under the same conditions due to their soft components such as lipids and proteins. Furthermore, developing microalgae into high-value-added products is beneficial from both economic and environmental perspectives.
This study incorporates brand equity and brand identity, two vital factors influencing customer-brand perception, to explore the process from service recovery to perceived justice. This study adopted HLM as the research framework because brand perception differs at various levels and adopting HLM allows us to precisely understand the influence of brand identity and brand equity on the relationship between service recovery and perceived justice. The contributions of this study are listed as follows: a) online service recovery can positively affect customer-perceived justice; b) brand equity at the organizational level can undermine the relationships that courtesy and compensation have with perceived justice; c) brand identity at the individual level can undermine the relationships that courtesy and compensation have with perceived justice; and d) using hierarchical linear modeling can precisely measure the relationship between organizations and customers; therefore, this method is innovative and can contribute to the research on online service recovery.
본 논문은 Ni - Al2O3로 구성된 금속-세라믹 이종 입자복합재의 2차원 미세구조(microstructure) 생성과 미세구조 스케일 (scale)에 따라 정의되는 계층적 모델들의 역학적 특성 분석에 관한 내용이다. 이종 입자복합재의 미세구조는 수학적인 RMDF(random morphology description functions) 모델링기법을 복합재의 2차원 RVE(representative volume element) 영 역에 적용하여 생성하였다. 그리고 미세구조 생성에 필요한 가우스 함수들의 개수에 따라 미세구조의 계층적 모델을 정의하였다. 한편 임의 미세구조 내 금속과 세라믹 입자가 차지하는 체적분율(volume fraction)은 RMDF 함수의 레벨을 조정함으로서 설정하였다. RMDF기법에 의한 미세구조들은 가우스 함수들의 개수가 일정할지라도 랜덤하게 생성된다. 이렇게 랜덤 하게 생성되는 미세구조들을 2차원 보(beam) 모델에 적용하여 미세구조의 스케일에 따른 수직응력과 전단응력의 계층적 변 동을 수치 해석적으로 고찰하였다. 또한, 균열해석을 통해 RMDF의 랜덤성과 가우스 함수들의 개수가 균열선단에서의 응력 값에 미치는 영향을 고찰하였다.
This paper on language learner strategies utilizes a little used quantitative, datamining technique called cluster analysis to investigate characteristics of groups of South Korean learners of English. After 71 students in three first-year university liberal arts English conversation courses completed the Strategy Inventory for Language Learning (SILL), and the number of learning strategies was reduced from 50 to 26 based on standard deviation (SD) results, the non-hierarchical (K-means) 3-cluster procedure was applied to the self-reported data. Following statistical analysis, each of the three cluster groups could be profiled according to achievement scores. At this point, six items emerged as particularly meaningful with regard to the latter, including direct strategies (a memory one and a cognitive one) and indirect strategies (two affective and two metacognitive). These strategies and their significance with reference to the local context as well as results previously reported in the literature are discussed. Finally, limitations of the study and implications for future research using cluster analysis are reported.
A consumer is an individual entity with various motivations. This study is intended to incorporate a hierarchical structure of motivation to understand self-determined motivation for purchasing secondhand merchandise at thrift stores. A conceptual model adopted from Cadwallader et al. (2010)’s comprehensive model of motivation used in a marketing context was developed to investigate motivational process in secondhand merchandise shopping. The conceptual model includes the three levels of motivational structure–the global, contextual (environmental concern and frugality), and situational motivation. A series of the causal relationships among the three levels of self-determined motivations and buying intention to shop at thrift stores were hypothesized. A total of 219 respondents from two different northeastern state universities in the U.S. completed a self-administered survey. The results indicated that secondhand merchandise shopping is well explained in the hierarchical structure of self-determined motivation where the global motivation had a positive impact on the contextual motivations regarding environmental concern and frugality. Of the two contextual motivations, only environmental concern had a positive impact on situational motivation for shopping at thrift stores. Finally, the situational motivation positively influenced the intention to shop at thrift stores. The results of this model suggest that the hierarchical structure of self-determined motivation would be a very useful framework to understand consumer behavior for apparel shopping. Also, further research can be done to identify other contextual motivational factors to understand consumer motivation for shopping at thrift stores.