In this study, the refinement of Multiwalled Carbon Nanotubes (MWCNTs) derived from chemical vapor decomposition is investigated. An ultrasonic pretreatment method is employed to disentangle carbon and metal impurities intertwined with MWCNTs. The pretreated MWCNTs exhibit a marginal decrease in C–O/C = O content from 8.9 to 8.8%, accompanied by a 2.5% increase in sp3 carbon content, indicating a mildly destructive pretreatment approach. Subsequently, selective oxidation by CO2 and hydrochloric acid etching are utilized to selectively remove carbon impurities and residual metal, respectively. The resulting yield of intact MWCNTs is approximately 85.65 wt.%, signifying a 19.91% enhancement in the one-way yield of pristine MWCNTs. Notably, the residual metal content experiences a substantial reduction from 9.95 ± 2.42 wt.% to 1.34 ± 0.06 wt.%, representing a 15.68% increase in the removal rate. These compelling findings highlight the potential of employing a mild purification process for MWCNTs production, demonstrating promising application prospects.

고성능 분리막 제조기술과 더불어 새로운 분리막 다단공정 설계를 통해 용매사용량 감소 및 선택도 향상이 가능 하다. 본 연구에서는 내용매성 셀룰로스 나노분리막을 제조하여 용매에 따른 용질의 선택도 차이를 비교하였다. 제막한 셀룰 로스 막을 기반으로 비극성 용매의 선택도 평가를 진행하였으며, 비극성 용매에서 용질에 대한 음배제율이 관측되었다. 특히, 분자량이 클수록 음배제율이 높아지는 역선택도의 거동을 확인하였다. 이를 기반으로 설계한 공정에서는 기존 분획 공정 대 비 3배 이상의 용매저감이 가능한 것을 확인할 수 있었다.

This study quantitatively evaluated size selectivity for three netting shapes (T0; regular, T45, T90) and hanging ratio (35%, 70%) of T0 netting used for trawl codend. The size selectivity experiment was performed in a tank using a cube experimental model with a length of 50 cm on one side and 389 experimental individuals, jack mackerel (Trachurus japonicus). In the selectivity analysis, a selectivity curve was created based on the selection ratio using a logistic function, and the 25%, 50%, and 70% selection length and selection range  were obtained. The T0 netting was 19.54 cm when the 50% selective length, which is a selectivity evaluation index, had a hanging ratio of 35%, a selection range of 0.51 cm, and 22.70 cm and 3.08 cm for the hanging ratio of 70%. The T45 netting was 24.34 cm and 2.13 cm, and the T90 netting was 23.51 cm and 2.84 cm. The results of the T45 netting and the T90 netting are similar, and the 50% selection length and selection range were relatively larger than the T0 netting. There was a significant difference in the correlation between the circumference of the inner circle of the mesh by the shape of the netting and the body girth of the experimental individual (Pearson test,      ). There was no significant difference in the correlation between the selection ratio by the T0 netting, T45 netting, and T90 netting with a 70% hanging ratio (one-way ANOVA,   ). The results of this study showed that selectivity such as T45 netting and T90 netting appeared when the hanging ratio, which maximizes the area of T0 netting, was maintained at 70%.

In this study, a comparative test operation was conducted through the alternate haul method to examine the selectivity of the four mesh sizes (60 mm, 90 mm, 110 mm, and 130 mm) of the trawl codend. The selectivity was analyzed using the SELECT model considering the fishing efficiency (split parameter) of each fishing gear in the comparative test fishing operation in the trawl and the maximum likelihood method for parameter estimation. A selectivity master curve was estimated for several mesh sizes using the extended-SELECT model. As a result of analyzing the selectivity for silver croaker based on the results of three times hauls for each experimental gear, it was found that the size of the fish caught increased as the size of the mesh size increased. When the selectivity for each mesh size analyzed by the SELECT model considering the split ratio was evaluated based on the size of the AIC value, the estimated split model was superior to the equal split model. Based on the master curve, the 50% selection length value was 2.893, which was estimated to be 136 mm based on the mesh size of 60 mm. In some selectivity models, there was a large deviance between observed and theoretical values due to the non-uniformity of the distribution of fished length classes. As a result, it is considered that appropriate sea trials and selectivity evaluation methods with high reliability should be applied to present trawl fishery resource management methods.

In this study, the selection action on the mesh in the net pot for whelk (Buccinum opisthoplectum) is experimentally considered, and the selectivity was compared by the SELECT model and the Nashimoto’s method with the probability model according to the contact shape of the mesh and the whelk. The experiments of the mesh size selectivity was conducted for two mesh sizes: 70 mm (inner stretched size 65.4 mm) and 44 mm (inner stretched size 39.5 mm). Selectivity experiments were conducted three times in total for each mesh size used 264 whelks. In addition, Nashimoto’s method analyzed the retention probability using probability model for whether the mesh passed or not based on the carapace width of the whelk. As a result of the selectivity analysis, the 50% selection carapace width for the mesh size of 70 mm was similar to 43.62 mm in the SELECT model and 42.64 mm in the Nashimoto's method. However, the 44 mm mesh with relatively small mesh size showed differences of 40.01 mm and 26.80 mm, respectively. As for the mesh size selectivity of whelk, it was found that the smaller the mesh size, the lower the selectivity. In addition, in the selectivity study on the mesh size of whelk, an evaluation method that closely considers the contact shape between the mesh and the target species is required.

The effects on the size selectivity for Muraenesox cinereus caught by coastal longline fishery were investigated in the southern coast of Korea from June 2 to 17, 2019. Four sizes of hooks (sizes 15, 17, 18 and 19) and two sizes of bait (sizes 9.9 g and 18.3 g) were tested in seven and three fishing trials, respectively. Such results revealed that smaller hook and bait size improved capture efficiency. And our results demonstrate that there was no significant size selectivity effect for hook size (ANOVA, p>0.05), but small bait improved on catching smaller fish (ANOVA, p<0.05).

The mesh selectivity of a drum shaped pot for finely-striate buccinum (Buccinum striatissimum) was conducted a total of eight times with four different mesh sizes (22, 35, 50 and 60 mm) from May to September, 2019 in the eastern coastal waters of Korea. The size selectivity analysis was estimated by the SELECT method to express logistic selectivity curves. In the results, the catch of finely-striate buccinum was occupied about 90% in the total catch weight. The equation of the master curve of selectivity was estimated to s(R) = exp(-7.778R+9.983)/[1+exp(-7.778R+9.983)]. The relative shell height of 50% selection was 1.284 and the selection range (SR) was 0.282. The optimal mesh size for 50% selection on the minimum maturation size (75 mm, Shell height) was estimated more than 60 mm by the master selectivity curve.

The mesh selectivity of hairtail (Trichiurus lepturus) caught by coastal drift gill net was examined in field experiments with three different mesh sizes (45, 50 and 55 mm) from October to November, 2013 in the coastal areas of south-west of Jeju province. The mesh selectivity tests were conducted with the experimental net to be set middle part of conventional driftnets. The mesh selectivity tests were carried out the total of four times. The selectivity curve was estimated by the Kitahara’s and Fujimori’s method. In the results, the catch number of hairtail was 653 (125.8 kg) and occupied 34.8% in total catches weight. The optimal mesh size for 50% selection on the minimum landing size (180 mm, AL) and the first maturity size (260 mm, AL) of hairtail were estimated as 47.2 mm and 64.5 mm by master selectivity curves, respectively.

Discarding juvenile fishes under girth 16 cm nearly equal to inner perimeter of codend mesh size collected by a cover net method in bottom trawl. The body size of the main five species (mackerel, horse mackerel, sea bream, melon seed and black throat seaperch) was measured for their body length, girth, weight, height and width and analyzed size selectivity. Frequency of penetrating fish as retention in a cover net was less than 40% of total number of juvenile discarding fish. The most of body length or girth of five species were significantly different between in the codend and in the cover net. The 50% selection girth in the cover net ranged 8-11 cm were smaller than those in the codend ranged 9-13 cm by the species respectively. The 50% selection body length was significantly related with the ratio of body height (H) by body width (W) both for in the codend or in the cover net while 50% selection girth was not significantly related with H/W. Furthermore 50% selection fish size by fish species between in the codend and in the cover net was not significantly different both in body length or girth. Therefore, the girth selectivity represented possibly as one unique value regarding fish body shape was considered as more useful method for multi-species catch in trawl.

To improve the etch rate of Si3N4 thin film, H2SiF6 is added to increase etching rate by more than two times. SiO3H2 is gradually added to obtain a selectivity of 170: 1 at 600 ppm. Moreover, when SiO3H2 is added, the etching rate of the SiO2 thin film increases in proportion to the radius of the wafer. In Si3N4 thin film, there is no difference in the etching rate according to the position. However, in the SiO2 thin film, the etching rate increases in proportion to the radius. At the center of the wafer, the re-growth phenomenon is confirmed at a specific concentration or above. The difference in etch rates of SiO2 thin films and the reason for regrowth at these positions are interpreted as the result of the flow rate of the chemical solution replaced with fresh solution.

탄소나노튜브(CNT) 기반의 멤브레인은 높은 물 전달률과 직경에 따른 이온 배제율로 해수담수, 물질 정화 등을 위한 분리막으로써의 가능성을 보여 주었다. 이온 선택성은 CNT 기반 멤브레인의 응용 분야를 확대하기 위한 중요한 요소이며, 기능기를 이용하여 이온 선택성의 조절이 가능함이 보고되었다. 다양한 원자가/크기의 이온이 혼합될 경우, 이온-기능기간 작용력 뿐만 아니라 이온-이온간의 작용력, 이온의 크기에 의한 반발력 등이 복합적으로 작용한다. 이에 본 연구에서는 분자동역학 전산모사를 통하여, 상이한 원자가/크기를 가진 이온의 혼합이 기능화된 CNT의 이온 선택성에 미치는 영향을 연구 하였다. Potential of Mean Force 계산을 통하여 이온 투과에 대한 자유 에너지 장벽을 계산하였으며, CNT 크기 변화, 전하량 변화를 통하여 이온 선택성과 배제에 영향을 미치는 요소를 분석하였다. 본 연구는 CNT 멤브레인을 이용한 분리막 설계, 생체 이온 전달 채널 모사 등에 유용할 것으로 기대한다.

기체분리막을 이용한 바이오가스 및 천연가스 등의 CH4 고질화 공정은 타 공정에 비해 경제적이라는 장점이 있지만 필수적으로 CH4 손실이 발생하는 단점이 있다. 이는 CO2에 의한 가소화현상으로 CH4의 투과도가 증가하기 때문이다. 이러한 현상을 개선하고자 CO2 가소화에 대한 영향이 적은 Cellulose계열의 고분자를 이용하여 고선택도 멤브레인을 제막하였으며, 이를 이용하여 CH4 고질화를 위한 연구를 하였다. CO2, CH4, N2, O2 등 단일가스를 이용하여 CA기반의 8종의 고선택도 중공사막에 선택도와 투과도를 측정하였다. CO2/CH4 혼합가스 분리 테스트를 수행하였다.

오랜 기후변화와 관련하여 지구온난화를 늦추고자 온실가스 중 대부분의 비율을 차지하고 있는 이산화탄소를 분리 및 저장 할 수 있는 연구가 활발하다. 본 연구에서는 고 투과성을 지닌 Polyhedral oligomeric silsesquioxane(POSS)와 이산화탄소에 대한 선택도를 지닌 Poly(ethylene glycol)을 이용하여 POSS-PEG 공중합체를 합성하였고 이를 다공성 지지체 위에 코팅하여 복합막을 제조하였다. 특성평가로는 NMR과 FT-IR 스펙트럼으로 합성의 유무를 확인한 뒤 복합막에 N2,O2,CO2 세 종류의 기체를 투과 특성함으로써 성능을 확인하였다. single gas를 투과시켰을 때 CO2/N2 선택도 24, Mixture gas를 투과시켰을 때 최대 70%의 CO2 분리성능을 나타내었다.