As the zircaloy cladding absorbs an excessive amount of hydrogen and cooled down under hoop stress, radial hydride may be precipitated by hydride reorientation phenomenon. There have been many previous studies about the threshold stress of the reorientation, but it is known that the quantitative degree of hydride reorientation rather than the threshold is important for the prediction of mechanical properties. A thermodynamic model for Radial Hydride Fraction (RHF) prediction has been developed in this study. The model calculates RHF with respect to temperature, cooling rate, hydrogen content, and applied stresses. Once the cooling rate is given, the solid solution concentration at each temperature is determined by Hydrogen-Nucleation-Growth-Dissolution model. Subsequently, the increment of radial hydride is derived by nucleation and growth theory. The code based on the thermodynamic theory can provide the prediction of RHF under hoop stress, as well as a change in precipitation behavior over time. RHF of the zircaloy cladding in long-term dry storage can be obtained by the implementation of the code and the degradation of the cladding is directly estimated according to the correlation between RHF and mechanical properties. Ongoing experimental validation of the developed model is discussed.

According to the ‘Basic Plan for High-Level Radioactive Waste Management (draft)’, the total amount of CANDU spent nuclear fuel is expected to be approximately 660,000 bundles. To safely and efficiently transport this amount to interim storage facilities, it is essential to develop a large-capacity transport cask. Therefore, we have been developing a large-capacity PHWR spent nuclear fuel transport cask, called the KTC-360 transport cask. According to the transport-cask related regulations, the KTC-360 transport cask was classified as a Type B package, and such packages must be able to withstand a temperature of 800°C for a period of 30 min. It is desirable to conduct a test using a fullscale model of a shipping package when performing tests to evaluate its integrity. However, it is costly to perform a test using a full-scale model. Therefore, to evaluate the thermal integrity of the KTC-360 transport cask, the fire test was conducted using a slice model. For comparison purposes, the fire test was also carried out using a 1/4 scale model. In the fire test using a slice model and in the fire test using a 1/4 scale model, the maximum temperature of the cask body was lower than the permitted maximum temperature limit. Therefore, the thermal integrity of the KTC-360 transport cask could be considered to be maintained. The temperature results from the fire test using a slice model were higher than those of the fire test using a 1/4 scale model. Therefore, the effect of flame on a transport cask without combustible materials, such as the KTC-360 transport cask, seems to be affected by the reduction in the time rather than the size reduction.

A rod internal pressure increased by fission gas release is major factor that causes degradation during dry storage of spent fuel. Because rod internal pressure is greatly affected by fuel design, operation power history, it is essential to perform complex calculation using performance code to accurately predict rod internal pressure as function of burnup. However, because it is difficult to apply a complex method into dry storage design and to determine rod internal pressure based on conservative way this study presents a simple correlation that can predict an approximate rod internal pressure as function of burnup For the development of simple correlation, rod internal pressure and fuel rod void volume data measured through about 400 PIE (Post Irradiation Examination) data were used. The developed simple correlation can cover various fuel rod arrays, discharged fuel average burnup, operation history, cladding type, burnup range, and information on Westinghouse type fuel rods such as Spain ENUSA, USA EPRI/ANL/ORNL/PNNL, WEC, etc. In this paper, the data of simple correlation determination is briefly introduced, and the data analysis process and results are summarized. Two correlations that can conservatively determine rod internal pressure and free void volume in fuel rod according to fuel rod average burnup were presented, and the effect of initial He fill pressure was evaluated. In particular, the results of Post Irradiation Examination for 46 fuel rods conducted in Korea are also included, so it is expected that newly presented correlations can be used easily in various ways in the domestic research, industry, and academia.

For safe management of spent nuclear fuels, they should be delivered to repository or waste disposal site. As the amount of spent nuclear fuel transportation is expected to increase in the future due to the provision of an intermediate storage facility, the necessity to secure transportation cask is emerging. In order to secure the spent nuclear fuel transportation cask, it is necessary to analyze the regulatory processes for domestic and foreign spent nuclear fuel transportation cask. In this study, the regulatory processes for domestic and foreign spent nuclear fuel transportation cask was analyzed. In this study, the IAEA, US, and Korea spent nuclear fuel transportation cask regulatory processes were analyzed. The domestic and foreign spent nuclear fuel transportation cask regulatory processes consist of design phase, manufacturing phase, and operation phase. In the design stage, the transport requirements are designed in accordance with the safety requirements of international organizations and countries. The application to be submitted when applying for approval should include a safety analysis report, evidence proving compliance with safety requirements et al. In the manufacturing stage, it is a stage to check whether the safety requirements are satisfied before the first use after manufacturing the transportation cask. Inspections include welding inspection, leakage inspection, shielding inspection, and thermal inspection. In the operation stage, it is a stage of periodically performing inspections for continuous maintenance of the package when the transportation cask is used. The inspection items to be performed are similar to the manufacturing stage and typically include performance inspection of components and leakage inspection. In this study, domestic and foreign spent nuclear fuel transportation cask regulatory processes were analyzed. It was found that the domestic and foreign spent nuclear fuel transportation cask regulatory processes consist of the design phase, the manufacturing phase, and the operation phase. The results of this study can be used as basic data for policy decision-making for the spent nuclear fuel cask.

This paper mainly focuses on the maximum decay heat estimation generated from spent fuel assemblies in the spent fuel pool of Kori units 3&4 at the beginning decommissioning. It is assumed that the spent fuel pool is fully occupied with 2,260 spent fuel assemblies, same as its design capacity. In addition, equally 56.5 spent fuel assemblies have been generated per year. The minimum cooling time is five years considering the transition phase between the permanent shutdown and the amendment of Operating License for decommissioning. Sending and receiving of spent fuel assemblies to/from other units are neglected. Seven representative spent fuel assembly groups are established based on the burnup rate and cooling time. Conservatively high values for the burnup rates and low values for the cooling times are applied. Calculation of the decay heat of each representative group has been performed by using ORIGEN decay solver of SCALE. Then, total decay heat has been calculated based on this. Group 1, 2, and 3 contain comparatively old spent fuel assemblies with 45 GWd/tU burnup rate and 20~30 cooling years. The calculation shows 489~586 watts of decay heat per assembly. Group 4, 5, 6, and 7 contain comparatively new spent fuel assemblies with 55 GWd/tU burnup rate and 5~20 cooling years. The calculation shows 741~1,483 watts of decay heat per assembly. The total maximum decay heat therefore is estimated as 1,609,459 watts.

The skeleton of fuel assembly is composed of top nozzle, bottom nozzle, grids, and guide tubes. In the reactor core, all the parts of the fuel assembly suffer degradations due to the condition of high temperature, pressure and water environment. Therefore, many material properties of high temperature mechanical strength, corrosion and irradiation resistance have been considered to choose the material for fuel assembly parts in the fuel development stage. The guide tubes have important roles to connect each parts and support the load of fuel assembly while the fuel is lifted. In Westinghouse 14×14 standard fuel assembly, Zircaloy-4 was used for the material of the guide tubes. Zircaloy-4 has a resistance to water corrosion and maintain good mechanical properties after the discharge from the core, so this alloy is also utilized for a fuel rod cladding material although the microstructure is slightly different due to the heat treatment difference. Thus, it is expected that there is no issue regarding the guide tube integrity after the discharge and during the storage in the pool, especially in case of low burn-up. However, the surface oxidation and resultant hydrogen pick-up can affect to the embrittlement to the Zr alloy. So, it is needed to know the actual status of spent fuel assembly by performing post-irradiation examination. In this study, the degradation level of the guide Tubes in low burn-up spent fuel assembly was investigated using the KAERI PIE facility in order to make some data which can be utilized to the baseline for evaluating the integrity of the spent fuel skeleton.

Numerous spent nuclear fuels are generated every year in Korea. To solve the spent nuclear fuel problem within saturated temporary storage, the authorities are readying to build an interim storage and a permanent disposal facility in the country. At the same time, the authorities are readying to establish a management procedure for spent nuclear fuel. In the future, the authorities need to make and apply the Database of spent nuclear fuel to practice the management procedure. However, the structure of a traditional database is not reasonable for information management because it has a problem with listing data and identifying data features due to its structure. In addition, the traditional database always exists human error from working in Excel program by a human. Therefore, this research proposes a new standard information management model based on Semantic Web technique. Semantic Web uses a data structure named ontology. By using the ontology in the information database of the spent nuclear fuel, users, such as institutions related to management, could more easily recognize and understand the Database. Furthermore, since this task proceeds in the ontology construction program, the human error in the new model reduces rather than an environment of the traditional database.

The effect of Li2O addition on precipitation behavior of uranium in LiCl-KCl-UCl3 has been investigated in this study. 99.99% LiCl-KCl eutectic salt is mixed with 10wt% UCl3 chips at 550°C in the Pyrex tube in argon atmosphere glove box, with 10 ppm O2 and 1 ppm H2O. Then, Li2O chunks are added in mixed LiCl-KCl-UCl3 and the system has been cooled down to room temperature for 10 hours to form enough UO2 particles in the salt. The solid salt has been taken out from the glove box, and cut into three sections (top, middle and bottom) by low-speed saw for further microscopic analysis. Three pieces of solid salt are dissolved in deionized water at room temperature and the solution is filtered by a filter paper to collect non-dissolved particles. The filter paper with particles is baked in vacuum oven at 120°C for 6 hours to evaporate remaining moisture from the filter paper. Further analysis was performed for the powder remaining on the filter paper, and periphery of the powder (cake) on the filter paper. Scanning electron microscopy (SEM), electron diffraction spectroscopy (EDS), and X-ray powder diffraction (XRD) are adopted to analysis the characteristic of the particles. From SEM analysis, the powders are consisted of small particles which have 5 to 10 m diameter, and EDS analysis shows they are likely UO2 with 23 at. % of uranium and 77 at. % oxygen. Cake is also analyzed by SEM and EDS, and needle like structures are widely observed on the particle. The length of needle is distributed from 5 to 20 m, and it has 6 to 10 at. % of chlorine, which are not fully dissolved into deionized water at room temperature. From XRD analysis, the particles show the peak position of UO2, and the result is well matched with the SEM-EDS results. We are planning to add more Li2O in the system for fully reacting uranium in UCl3, and compare the results to find the effect of Li2O concentration on UO2 precipitation.

It has been studied on the disposal area reduction for the used nuclear fuel by the management of high decay-heat nuclides, long-lived nuclides, and highly mobile nuclides. It was investigated on the management of the nuclides in KAERI. Strontium-90 is a high heat-generating nuclide in spent nuclear fuel. It is needed to separate the salt from the salt solution for the recovery of strontium after the chlorination of the strontium oxide in molten salt. Vacuum distillation was used for the separation of strontium from the molten salt. Potassium carbonate was chosen as a reactive distillation reagent for SrCl2 – LiCl – KCl system by the thermodynamic calculation. Reactive distillation experiments were carried out. The residual was mainly SrCO3 in the XRD analysis. It could be concluded that K2CO3 could be one of the suitable reagents for the reactive distillation. The salt in the long–lived nuclide powders should be removed to prepare the block for disposal. Experiments were carried out using W powders (surrogate) and U3O8 powders to develop a process for the removal of the residual salt from UOx powders. The salts were successfully removed from the W and U3O8 powders by distillation.

Irradiated uranium dioxide in damaged used fuel could oxidize during transportation, interim storage or disposal, resulting that the fuel pellet fragments are reduced to a grain-sized powder that can easily escaped from the damaged rod. It has been reported that oxidized spent fuel (i.e. U4O9+x) that was in contact with water could increase the dissolution rate by making the grain boundaries more accessible to the water. Therefore, the damaged used fuel requires stabilization technology including nuclear material recovery, pellet manufacturing process, and stabilization fuel rod manufacturing that can secure safety in terms of permanent disposal. In this study, we prepared pure UO2 and SIMFUEL pellets that are a mixture of UO2 and surrogated metallic oxides for fission products equivalent to a burn-up of 35 GWd/tU and 55 GWd/tU as the stabilized spent fuel. The UO2 and fission products powders were milled and pressed into pellets at 250 MPa and sintered at 1,550°C and 1,700°C for 6 hours in an atmosphere of 4%H2-Ar. The prepared UO2 and SIMFUEL pellets were placed in PTFE Teflon vessels and filled with deionized water to identify the leaching behavior by a long-term leaching experiment under the similar condition to a repository for the safe disposal.

Interests in molten salt reactor (MSR) using a fast spectrum (FS) have been increased not only for having a high power density but for burning the high-level waste generated from nuclear power plants. For developing the FS-MSR technologies, chloride-based fuels are considered due to the advantage of higher solubility of actinides and lanthanides over fluoride-based salts. Despite significant progress in development of MSR technology, the manufacturing technology for production of the fuel is still insufficiently understood. One of the option to prepare the MSR fuel is to use products from pyroprocessing where oxide form of spent nuclear fuel is reduced into metal form and useful elements can be collected via electrochemical methods in molten salt system at high temperature. In order to chlorinate the products into chloride form, previous study used NH4Cl to chlorinate U metal into UCl3 in an airtight reactor. It was found that the U metal was completely chlorinated into chloride forms; however, impurities generated by the reaction of NH4Cl and reactor wall were found in the product. Therefore, in this work, the air tight reactor was re-deigned to avoid the reaction of reactor wall by insertion of Al2O3 crucible inside of the reactor. In addition, the reactor size was increased to produce UCl3 over 100 g. Using the newly designed reactor, U metal chlorination experiments using NH4Cl chlorinating agent were performed to confirm the optimal experimental conditions. The detailed results will be further discussed.

The damaged spent fuel rods must be stabilized by encapsulation or dry re-fabrication technologies before geological disposal. For applying the dry re-fabrication technology, we manufactured a vertical type furnace to perform both fuel material recovery from damaged fuel rods by oxidative decladding and sinterability improvement of fuel powder by repetition of oxidative and reaction treatment. A horizontal type furnace provides only a diffusion-controlled reaction resulting in longer reaction time and decreasing amount of powder for oxidation and reduction, whereas a vertical type furnace with a submerged gas distributor gives rapid reaction due to flowing gas-solid contact by fluidization. For observation of fluidization behaviors of uranium oxides at room temperature, fluidized column was prepared with transparent cylindrical tube, pressure transmitter and gas flow meter. Number of size of orifice holes was determined by equations in Fluidization Engineering [D.Kunii, O. Levenspiel]. Before uranium oxide test, as surrogates, WO2 (10.8 g/cm3) and Ta2O5 (8.2 g/cm3) powder similar to density of UO2 (10.96 g/cm3) and U3O8 (8.3 g/cm3), respectively were used to achieve fluidization operation conditions in the region from minimum to expanded fluidization. Fluidization behaviors and pressure drop of powder bed was observed according to operation parameters such as gas velocity, number and size of orifice holes, and powder amount.

Ag-containing aluminosilicate sorbents capable of capturing iodine were prepared by sol-gelation from Na, Al, and Si alkoxides using co-solvent exchange, Ag/Na ion exchange, solvent exchange, and ambient-pressure drying. The Na+AlSi-OH gel was prepared using sodium methoxide (NaOMe): aluminum tri-sec-butoxide (Al(OsBu)3): tetraethyl orthosilicate (TEOS) molar ratios of 1.05:1:1, 1.3:1.1:1, 1.5:1.3:1. The solvent effect on textural properties such as Brunauer-Emmett-Teller (BET) surface areas and pore size distributions and Ag0 particle sizes was investigated using water with high surface tension, isopropanol and n-heptane with low surface tension. The BET surface area, average pore size, and cumulative pore volume for sorbents strongly increased with decreasing surface tension of solvents and increasing Al/Si atomic ratios. In addition, Ag0 particle sizes increased with decreasing surface tension of solvents.

For the transport of spent nuclear fuel, it is necessary to evaluate the amount of radioactivity for each assembly and the total amount of radioactivity for each cask. Currently, KHNP is evaluating the radioactivity using the Express mode of the OrigenArp program in the SCALE6.1 code. Express mode is a method to evaluate the radioactivity assuming that it has been burned with the same power per cycle, and Detail mode is a method to evaluate the actual combustion history such as power and cooling time for each cycle. For a total of 3,795 assemblies, including 1,391 assembliess for Kori Unit 1, 1,427 assemblies for Hanbit Unit 2, and 977 assemblies for Hanul Unit 3, the radioactivity was evaluated in Express mode and Detail mode, respectively, and the results were compared. As a result of the evaluation, it was confirmed that the results of the Express mode were evaluated more conservatively by 2.5~12.9% than that of the Detail mode. Accordingly, KHNP established a plan to change the evaluation method from Express mode to Detail mode in order to improve the accuracy of the radioactivity assessment results and eliminate conservatism.

Thermal analysis and safety assessment of spent fuel transport cask are mainly conducted using commercial Computational Fluid Dynamics (CFD) codes based on Finite Volume Method (FVM). The reliability and predictability of CFD codes have greatly been improved by the development in the computer systems, and are widely used to calculate heat flow in complex structures that cannot be analyzed theoretically. In the field of thermal analysis using the CFD code, it is important to clearly reflect the physical model of the transport cask, and a grid configuration suitable for the physical model is essential for accurate analysis. However, since there are no clear standard and guidelines for grid configuration and size, it is highly dependent on the user’s insight. Spatial discretization errors result from the use of finite-width grids and the approximation of the differential terms in the model equations by difference operators. Since the user usually cannot change the truncation error order of a given discretization scheme, spatial discretization errors can only be influenced by the provision of optimal grids. Therefore, it is necessary to quantify the spatial discretization errors caused by the grid. In the case of Orano TN’s NUHOMS® MP197 transport cask, considering four grids for two sets, the temperature uncertainty of the neutron shield, which has the lowest margin at the limit temperature among transport cask components, was quantified by applying 5-step procedure of the Grid Convergence Index (GCI) method for the uncertainty estimation presented in ASME V&V 20-2009. In the case of domestic spent nuclear fuel transport cask (KORAD21), neutron shield among the transport cask components has the lowest margin at the limited temperature. Accordingly, in this study, the temperature uncertainty of the neutron shield was quantified by applying GCI to three sets considering seven grids. As a result of the calculation, the uncertainty was less than ± 1°C, and the temperature of the neutron shield including the uncertainty was evaluated to be maintained below the limit temperature of 148°C.

For Dry Storage of Spent Nuclear Fuel (SNF), all moisture must be removed from the dry storage canister through subjected to a drying process to ensure the long-term integrity. In NUREG-1536, the evacuation of most water contained within the canister is recommended a pressure of 0.4 kPa (3 torr) to be held in the canister for at least 30 minutes while isolated from active vacuum pumping as a measure of sufficient dryness in the canister. In the existing drying process, the determination of drying end point was determined using a dew point sensor indirectly. Various methods are being studied to quantify the moisture content remaining inside the canister. We presented a moisture quantification method using the drying process variables, like as temperature, pressure, and relative humidity operation data. During the drying process, it exists in the form of a mixed gas of water vapor and air inside the canister. At this time, if the density of water vapor in the mixed gas discharged out of the canister by the vacuum pump is known, the mass of water removed by vacuum drying can be calculated. The canister is equipped with a pressure gauge, thermometer and dew point sensor. The density of water vapor is calculated using the pressure, temperature and relative humidity of the gas obtained from these sensors. First, calculate the saturated water vapor pressure, and then calculate the humidity ratio. The humidity ratio refers to the ratio of water vapor mass to the dry air mass. After calculating the density of dry gas, multiply the density by the humidity ratio to calculate the density of water vapor (kg/m3). Multiply the water vapor density by the volume flow (m3/s) to obtain the mass value of water (kg). The calculated mass value is the mass value obtained per second since it is calculated through the flow data obtained every second, and the amount of water removed can be obtained by summing all the mass values. By comparing this value with the initial moisture content, the amount of moisture remaining inside the canister can be estimated. The validity of the calculations will be verified through an experimental test in the near future. We plan to conduct various research and development to quantify residual water, which is important to ensure the safety of the drying process for dry storage.

Currently, as the saturation capacity of wet storage pool for spent nuclear fuel (SNF) of PWR in Korea has reached approximately 75%, Dry Storage Facilities (DSF) are necessary for sustainable operation of nuclear power plants. It is necessary to develop acceptance requirements for the delivery of SNF from reactor storage site to Centralized DSF. To do this end, the mechanical integrity of SNF is directly related to its repacking, retrieving, and transporting/handling performances. And also, this integrity is a key factor associated with the criticality safety that is connected to the damaged status of SNF. According to the NUREG/CR-6835, the NRC expects that the potential for nuclear fuel failures will increase because of the increase of the fuel discharge burnup and the degradation of fuel and clad material properties. Due to such damages and/or degradation, the fuel rods in the fuel assembly may be extracted and empty for following treatments (transportation, storage, handling etc). This condition can have a detrimental effect on the criticality safety of SNF. Thus, this study investigated whether extracted and empty of damaged SNF rod affects criticality safety. In this analysis, it is assumed that up to four fuel rods are missed. As a result of the analysis, As the number of fuel rods miss up to a certain number, the value of multiplication factor value of the fuel assembly increases. In addition, since the fuel rods located at the outermost layer contained relatively less fissile material than the fuel rods located center of the lattice, and neutrons were lost by the absorption material, the effective multiplication factor value gradually decreased. Nevertheless, the criticality safety was assessed to be maintained.

Maintaining fuel sheath integrity during dry storage is important. Intact sheath acts as the primary containment barrier for both fuel pellets and fission products over the dry storage periods and during subsequent fuel handling operations. In KNF, in-house fuel performance code was developed to predict the overall behavior of a fuel rod under normal operating conditions. It includes the analysis modules to predict temperature, pellet cracking and deformation, sheath stress and strain at the mid-plane of the pellet and pellet-pellet interfaces, fission gas release and internal gas pressure. The main focus of the code is to provide information on initial conditions prior to dry storage, such as fission gas inventory and its distribution within the fuel pellet, initial volumes of storage spaces and their locations, radial profile of heat generation within the pellet, etc. To upgrade the developed code that address all the damage mechanisms, the first step was a review of the available technical information on phenomena relevant to fuel integrity. Potential degradation mechanisms that may affect sheath integrity of CANDU spent fuel during dry storage are: creep rupture under internal gas pressure, sheath oxidation in air environment, stress corrosion cracking (SCC), delayed hydride cracking (DHC), and sheath splitting due to UO2 oxidation for a defective fuel. The failure by creep rupture, SCC or DHC is in the form of small cracks or punctures. The failure by sheath oxidation or sheath splitting due to UO2 oxidation results in a gross sheath rupture. The second step was to examine the technical bases of all modules of the in-house code, identify and extend the ranges of all modules to required operating ranges. This step assessed the degradation mechanisms for the fuel integrity. The objective of this assessment is to predict the probability of sheath through-wall failure by a degradation mechanisms as a function of the sheath temperature during dry storage. Further improvements being considered include upgrades of the analysis module to achieve sufficient accuracy in key output parameters. The emphasis in the near future will be on validation of the inhouse code according to a rigorous and formal methodology. The developed models provide a platform for research and industrial applications, including the design of fuel behavior experiments and prediction of safe operating margins for CANDU spent fuel.

A tensile test is performed to obtain the mechanical property data of the spent fuel cladding. In general, the elastic modulus, elongation, yield stress, tensile stress, etc. are obtained by axial tensile test of cladding attaching an extensometer. However, due to the limitation in the number of specimens for spent nuclear fuel that can be made, the ring tensile test (RTT) whose required length of the specimen is short is mainly performed. In the case of RTT, an extensometer or strain gauge cannot be attached because the gauge part of the specimen is formed around the cladding and is short. In addition, since a load is applied in the radial direction of the cladding, a curved portion of the circular cladding is spread out and becomes straight, and then the cladding is tensioned. For this reason, it is difficult to obtain the stress-strain curve directly from the RTT results. Isight, which is used to identify the optimization design parameters, was used to build an optimization process that minimizes the difference between the RTT and the analysis to estimate the material property. For this, the elastic modulus, plastic strain, and the radius of the RTT jig were taken as fixed variables. As variables, isotropic hardening data and plastic stress were taken. The objective function was taken as the minimization of the area difference of the load-displacement curve obtained from the tests and analysis, of the difference in the magnitude of the maximum reaction force, and of the difference in the location where the maximum reaction force occurred. Optimization workflow was configured in the following order. First, using the calculator component, plastic stress design variables were created. Next, ABAQUS was placed to perform analysis using design variables, and the reaction force or displacement was calculated. After that, the reaction force was calculated considering the 1/4 symmetry condition using the script component. After that, the data matching component performed quantitative comparison of test and analysis data. Finally, by utilizing the exploration component, the plastic stress design variable that minimizes the difference in the objective function was obtained by automatically changing six optimization algorithms. In this paper, the constructed optimization process and the obtained plastic stress by applying it to the SUS316 RTT results are briefly described. The established optimization process can be utilized to obtain mechanical property from the results of the cladding RTT of spent nuclear fuel or new material.

In ROK, when designing a spent nuclear fuel (SNF) storage facility and cask, criticality safety analysis is performed assuming that the SNF is a fresh fuel in order to ensure conservatism. Storage and transportation capacity can be increased by more than 30% by applying the burnup credit, but it has not been applied to the management of SNF. On the other hand, currently in criticality safety analysis, average burnup value is applied to axial burnup profiles, and it is not conservative because burnup of the middle of SNF is greater than average value. Thus, measuring burnup of SNF with high accuracy contributes to the economics and safety of the management of SNF. In this paper, nondestructive burnup evaluation methods for SNF are reviewed in order to study how to measure burnup more accurately. Gamma ray spectrometry and neutron counting have been used as non-destructive burnup evaluation methods of SNF. Gamma spectrum analysis uses the ratio of Cs-134/Cs-137 or Eu-154/Cs-137. The ratio of Cs-134/Cs-137 is used to SNF with cooling time less than 20 years, and the ratio of Eu- 154/Cs-137 is used to SNF with cooling time more than 20 years due to their half-life. In spectrum analysis, detector sensors with high efficiency and energy resolution are needed to clarify each spectrum. High-purity germanium (HPGe) detector has high energy resolution. However, it is not suitable for the analysis of the SNF in the spent fuel pool because it requires separate cooling system and large volume. Thus, CdZnTe (CZT) detector, which has medium energy resolution, is used as a detector of gamma ray spectrometry for the analysis of the SNF in the spent fuel pool. Recently, LaBr3 detector has been commercialized. Although it is difficult to compare clearly due to different conditions such as detector volume and crystal size, LaBr3 detector showed better resolution than CZT in the entire energy region. Neutron counting method has a large error compared to gamma spectrometry because the neutron flux is lower than gamma ray, and neutron absorption reaction, induced fission, and pool environment have to be considered. Large quantity of gamma energy is deposited in the detector by the fission fragments near the SNF. Therefore, fission chambers, which have the highest insensitivity to gamma rays, must be used as neutron detector in order to avoid noise from gamma rays.