Due to the saturation of the on-site storage capacity of spent nuclear fuel within a few years, dry storage facility should be introduced. However, it is unclear when to start operating the dry storage facility, so in case of Kori Unit 1, which is being decommissioning, the spent fuel must be stored in the spent fuel pool of another power plant. In addition, in the case of damaged fuel, it is impossible to transfer and store it with general handling methods. Therefore, a damaged fuel canister (DFC) should be able to handle damaged or failed fuel as intact fuel, and both wet and dry storage should be possible. The canister developed by Korea Hydro & Nuclear Power is designed to satisfy criticality, shielding, cooling performance, and structural integrity in accordance with NUREG-1536 and 2215. In addition, it can be handled as existing fuel handling devices rather than new handling tools. Fastening of the DFC lid and body in the spent fuel pool is possible with a hexagonal socket wrench, one of the fuel repair tools. And it is designed to facilitate visual identification of whether it is fastenedor not. The lifting method for transferring DFC to another facility is the same as the nuclear fuel lifting method. And a unique sealing and mesh structure of the lid and body is devised to completely block leakage of nuclear fuel fragments of 0.2 mm or more during vacuum drying for dry storage. The usability of DFC has been verified through test operation of the prototype, and it will be manufactured before discharging spent fuel for the decommissioning of Kori Unit 1.

In ROK, when designing a spent nuclear fuel (SNF) storage facility and cask, criticality safety analysis is performed assuming that the SNF is a fresh fuel in order to ensure conservatism. Storage and transportation capacity can be increased by more than 30% by applying the burnup credit, but it has not been applied to the management of SNF. On the other hand, currently in criticality safety analysis, average burnup value is applied to axial burnup profiles, and it is not conservative because burnup of the middle of SNF is greater than average value. Thus, measuring burnup of SNF with high accuracy contributes to the economics and safety of the management of SNF. In this paper, nondestructive burnup evaluation methods for SNF are reviewed in order to study how to measure burnup more accurately. Gamma ray spectrometry and neutron counting have been used as non-destructive burnup evaluation methods of SNF. Gamma spectrum analysis uses the ratio of Cs-134/Cs-137 or Eu-154/Cs-137. The ratio of Cs-134/Cs-137 is used to SNF with cooling time less than 20 years, and the ratio of Eu- 154/Cs-137 is used to SNF with cooling time more than 20 years due to their half-life. In spectrum analysis, detector sensors with high efficiency and energy resolution are needed to clarify each spectrum. High-purity germanium (HPGe) detector has high energy resolution. However, it is not suitable for the analysis of the SNF in the spent fuel pool because it requires separate cooling system and large volume. Thus, CdZnTe (CZT) detector, which has medium energy resolution, is used as a detector of gamma ray spectrometry for the analysis of the SNF in the spent fuel pool. Recently, LaBr3 detector has been commercialized. Although it is difficult to compare clearly due to different conditions such as detector volume and crystal size, LaBr3 detector showed better resolution than CZT in the entire energy region. Neutron counting method has a large error compared to gamma spectrometry because the neutron flux is lower than gamma ray, and neutron absorption reaction, induced fission, and pool environment have to be considered. Large quantity of gamma energy is deposited in the detector by the fission fragments near the SNF. Therefore, fission chambers, which have the highest insensitivity to gamma rays, must be used as neutron detector in order to avoid noise from gamma rays.

Thermal analysis and safety assessment of spent fuel transport cask are mainly conducted using commercial Computational Fluid Dynamics (CFD) codes based on Finite Volume Method (FVM). The reliability and predictability of CFD codes have greatly been improved by the development in the computer systems, and are widely used to calculate heat flow in complex structures that cannot be analyzed theoretically. In the field of thermal analysis using the CFD code, it is important to clearly reflect the physical model of the transport cask, and a grid configuration suitable for the physical model is essential for accurate analysis. However, since there are no clear standard and guidelines for grid configuration and size, it is highly dependent on the user’s insight. Spatial discretization errors result from the use of finite-width grids and the approximation of the differential terms in the model equations by difference operators. Since the user usually cannot change the truncation error order of a given discretization scheme, spatial discretization errors can only be influenced by the provision of optimal grids. Therefore, it is necessary to quantify the spatial discretization errors caused by the grid. In the case of Orano TN’s NUHOMS® MP197 transport cask, considering four grids for two sets, the temperature uncertainty of the neutron shield, which has the lowest margin at the limit temperature among transport cask components, was quantified by applying 5-step procedure of the Grid Convergence Index (GCI) method for the uncertainty estimation presented in ASME V&V 20-2009. In the case of domestic spent nuclear fuel transport cask (KORAD21), neutron shield among the transport cask components has the lowest margin at the limited temperature. Accordingly, in this study, the temperature uncertainty of the neutron shield was quantified by applying GCI to three sets considering seven grids. As a result of the calculation, the uncertainty was less than ± 1°C, and the temperature of the neutron shield including the uncertainty was evaluated to be maintained below the limit temperature of 148°C.

Interests in molten salt reactor (MSR) using a fast spectrum (FS) have been increased not only for having a high power density but for burning the high-level waste generated from nuclear power plants. For developing the FS-MSR technologies, chloride-based fuels are considered due to the advantage of higher solubility of actinides and lanthanides over fluoride-based salts. Despite significant progress in development of MSR technology, the manufacturing technology for production of the fuel is still insufficiently understood. One of the option to prepare the MSR fuel is to use products from pyroprocessing where oxide form of spent nuclear fuel is reduced into metal form and useful elements can be collected via electrochemical methods in molten salt system at high temperature. In order to chlorinate the products into chloride form, previous study used NH4Cl to chlorinate U metal into UCl3 in an airtight reactor. It was found that the U metal was completely chlorinated into chloride forms; however, impurities generated by the reaction of NH4Cl and reactor wall were found in the product. Therefore, in this work, the air tight reactor was re-deigned to avoid the reaction of reactor wall by insertion of Al2O3 crucible inside of the reactor. In addition, the reactor size was increased to produce UCl3 over 100 g. Using the newly designed reactor, U metal chlorination experiments using NH4Cl chlorinating agent were performed to confirm the optimal experimental conditions. The detailed results will be further discussed.

It has been studied on the disposal area reduction for the used nuclear fuel by the management of high decay-heat nuclides, long-lived nuclides, and highly mobile nuclides. It was investigated on the management of the nuclides in KAERI. Strontium-90 is a high heat-generating nuclide in spent nuclear fuel. It is needed to separate the salt from the salt solution for the recovery of strontium after the chlorination of the strontium oxide in molten salt. Vacuum distillation was used for the separation of strontium from the molten salt. Potassium carbonate was chosen as a reactive distillation reagent for SrCl2 – LiCl – KCl system by the thermodynamic calculation. Reactive distillation experiments were carried out. The residual was mainly SrCO3 in the XRD analysis. It could be concluded that K2CO3 could be one of the suitable reagents for the reactive distillation. The salt in the long–lived nuclide powders should be removed to prepare the block for disposal. Experiments were carried out using W powders (surrogate) and U3O8 powders to develop a process for the removal of the residual salt from UOx powders. The salts were successfully removed from the W and U3O8 powders by distillation.

The effect of Li2O addition on precipitation behavior of uranium in LiCl-KCl-UCl3 has been investigated in this study. 99.99% LiCl-KCl eutectic salt is mixed with 10wt% UCl3 chips at 550°C in the Pyrex tube in argon atmosphere glove box, with 10 ppm O2 and 1 ppm H2O. Then, Li2O chunks are added in mixed LiCl-KCl-UCl3 and the system has been cooled down to room temperature for 10 hours to form enough UO2 particles in the salt. The solid salt has been taken out from the glove box, and cut into three sections (top, middle and bottom) by low-speed saw for further microscopic analysis. Three pieces of solid salt are dissolved in deionized water at room temperature and the solution is filtered by a filter paper to collect non-dissolved particles. The filter paper with particles is baked in vacuum oven at 120°C for 6 hours to evaporate remaining moisture from the filter paper. Further analysis was performed for the powder remaining on the filter paper, and periphery of the powder (cake) on the filter paper. Scanning electron microscopy (SEM), electron diffraction spectroscopy (EDS), and X-ray powder diffraction (XRD) are adopted to analysis the characteristic of the particles. From SEM analysis, the powders are consisted of small particles which have 5 to 10 m diameter, and EDS analysis shows they are likely UO2 with 23 at. % of uranium and 77 at. % oxygen. Cake is also analyzed by SEM and EDS, and needle like structures are widely observed on the particle. The length of needle is distributed from 5 to 20 m, and it has 6 to 10 at. % of chlorine, which are not fully dissolved into deionized water at room temperature. From XRD analysis, the particles show the peak position of UO2, and the result is well matched with the SEM-EDS results. We are planning to add more Li2O in the system for fully reacting uranium in UCl3, and compare the results to find the effect of Li2O concentration on UO2 precipitation.

The skeleton of fuel assembly is composed of top nozzle, bottom nozzle, grids, and guide tubes. In the reactor core, all the parts of the fuel assembly suffer degradations due to the condition of high temperature, pressure and water environment. Therefore, many material properties of high temperature mechanical strength, corrosion and irradiation resistance have been considered to choose the material for fuel assembly parts in the fuel development stage. The guide tubes have important roles to connect each parts and support the load of fuel assembly while the fuel is lifted. In Westinghouse 14×14 standard fuel assembly, Zircaloy-4 was used for the material of the guide tubes. Zircaloy-4 has a resistance to water corrosion and maintain good mechanical properties after the discharge from the core, so this alloy is also utilized for a fuel rod cladding material although the microstructure is slightly different due to the heat treatment difference. Thus, it is expected that there is no issue regarding the guide tube integrity after the discharge and during the storage in the pool, especially in case of low burn-up. However, the surface oxidation and resultant hydrogen pick-up can affect to the embrittlement to the Zr alloy. So, it is needed to know the actual status of spent fuel assembly by performing post-irradiation examination. In this study, the degradation level of the guide Tubes in low burn-up spent fuel assembly was investigated using the KAERI PIE facility in order to make some data which can be utilized to the baseline for evaluating the integrity of the spent fuel skeleton.

This paper mainly focuses on the maximum decay heat estimation generated from spent fuel assemblies in the spent fuel pool of Kori units 3&4 at the beginning decommissioning. It is assumed that the spent fuel pool is fully occupied with 2,260 spent fuel assemblies, same as its design capacity. In addition, equally 56.5 spent fuel assemblies have been generated per year. The minimum cooling time is five years considering the transition phase between the permanent shutdown and the amendment of Operating License for decommissioning. Sending and receiving of spent fuel assemblies to/from other units are neglected. Seven representative spent fuel assembly groups are established based on the burnup rate and cooling time. Conservatively high values for the burnup rates and low values for the cooling times are applied. Calculation of the decay heat of each representative group has been performed by using ORIGEN decay solver of SCALE. Then, total decay heat has been calculated based on this. Group 1, 2, and 3 contain comparatively old spent fuel assemblies with 45 GWd/tU burnup rate and 20~30 cooling years. The calculation shows 489~586 watts of decay heat per assembly. Group 4, 5, 6, and 7 contain comparatively new spent fuel assemblies with 55 GWd/tU burnup rate and 5~20 cooling years. The calculation shows 741~1,483 watts of decay heat per assembly. The total maximum decay heat therefore is estimated as 1,609,459 watts.

As the zircaloy cladding absorbs an excessive amount of hydrogen and cooled down under hoop stress, radial hydride may be precipitated by hydride reorientation phenomenon. There have been many previous studies about the threshold stress of the reorientation, but it is known that the quantitative degree of hydride reorientation rather than the threshold is important for the prediction of mechanical properties. A thermodynamic model for Radial Hydride Fraction (RHF) prediction has been developed in this study. The model calculates RHF with respect to temperature, cooling rate, hydrogen content, and applied stresses. Once the cooling rate is given, the solid solution concentration at each temperature is determined by Hydrogen-Nucleation-Growth-Dissolution model. Subsequently, the increment of radial hydride is derived by nucleation and growth theory. The code based on the thermodynamic theory can provide the prediction of RHF under hoop stress, as well as a change in precipitation behavior over time. RHF of the zircaloy cladding in long-term dry storage can be obtained by the implementation of the code and the degradation of the cladding is directly estimated according to the correlation between RHF and mechanical properties. Ongoing experimental validation of the developed model is discussed.