The soils contaminated with radionuclides such as Cs-137 and Sr-90 should be solidified using a binder matrix, because radioactively contaminated soils pose environmental concerns and human health problems. Ordinary Portland cement has been widely used to solidify various radioactive wastes due to its low cost and simple process. In this study, simulant soil waste was solidified using cement waste form. The soils were collected around ‘Kori Nuclear Power Plant Unit 1’ and they were contaminated with the prepared simulant liquid waste containing Fe, Cr, Cs, Ni, Co, and Mn. The water-to-dry ingredients (W/D) ratio of cement waste form was 0.40. The cement paste was poured into a cubic mold (5×5×5 cm) and then cured for 28 days at room temperature. The 28-day compressive strength, water immersion, and EPA1311-toxicity characteristic leaching procedure (TCLP) tests were performed to evaluate the structural stability of cement waste form. The compressive strength was not proportional to soil waste loading, and the lowest compressive strength (4±0.1 MPa) was achieved in cement waste form containing 50wt% soil waste. After the water immersion test for 90 days, the compressive strength of cement waste form with 50wt% soil waste increased to 7.5±0.6 MPa, meeting the waste form acceptance criteria in the repository. It is believed that long-term water immersion test contributed to the additional curing and hydration reaction, resulting in the enhanced compressive strength. As a result of the TCLP test, the released amount of As, Ba, Cd, Cr, Pb, Se, Co, Cs, and Sr was less than the domestic and international standards. These results imply that cement waste form can be a promising candidate for the solidification of radioactive soil wastes.

The intermediate level spent resins waste generated from water purification for the the moderator and primary heat transport system during operaioin of heavy water reactor (HWR). Especially, moderator resins contain high level activity largely because of their C-14 content. So spent resins are considered as a problematirc solid waste and require special treatment to meet the waste acceptance criteria for a disposal site. Various methods have been studied for the treatment of spent resins which include thermal, destructive, and stripping methods. In the case of solidification methods, cement, bitument or organic polymers were suggested. In the 1990s, acid stripping using nitric acid and thermal treatment methods were actively investigated in Canada to remove C-14 nuclide from waste resin. In Japan, thermal distructive method was studied in the 1990s. Since 2005, KAERI developed acid stripping method using phosphate salt. However, acid stripping method are not suitable due to large amounts of 2nd waste containing acid solution with various nuclides. To solve this probelm, KAERI has been suggested the microwave treatment method for C-14 selective removal from waste resin in the 2010s. Pilot scale demonstration tests using radioactive waste resin generated from Wolsung unit 1 and unit 2 were successfully conducted and 95% of C-14 was selectively removed from the radioactive waste resin. In recent years, price of C-14 source is dramatically increased due to market growth of C-14 utilization and exclusive supply chain depending on China and Russia. High purity of C-14 were captured in HWR waste resin. Interest of C-14 recovery research from HWR waste resin is currently increased in Canada. In this study, microwave method is suggested to treat HWR waste resin with C-14 recovery process. Additionally, status of waste resin management and research trends of HWR waste resin treatment are introduced.

Concrete decontamination tools capable of removing the nuclear contaminated surface are necessary to minimize the amount of concrete waste generated in the process of decontamination and dismantling of nuclear power plants. Laser scabbling is a decontamination technique that removes the contaminated surface layers concrete surface by inducing internal explosion. The application principle of laser scabbling technology uses the porous nature of concrete including moisture. When high thermal energy is applied to the concrete surface, an explosion at pores is induced along with an increase in water vapor pressure. High-powered laser beam can be an effective induction source of local explosive spalling on concrete surface. In this study, the scabbling test using a 5 kW highpowered fiber laser was conducted on the concrete blocks to establish the optimal conditions for surface decontamination. It was also measured the volume peeled off the concrete surface under the conditions of two different laser head speeds. Furthermore, we tested the removal efficiency of radioactive concrete particles generated during high-power fiber laser scabbling process. A 5 kW laser beam was applied to the concrete surface at two different laser head speeds - 120 mm/min and 600 mm/min. The laser beam repeatedly moved 200 mm horizontally and 40 mm vertically within the concrete block. The amount of surface concrete removed from concrete block was calculated from the measurement of the volume and mean depth using a 3D scanner device (laser-probed Global Advantage 9.12.8(HEXAGON)) for the two different the laser head speeds. By increasing the laser head speed, less explosive spalling occurred due to shorter contact time of the laser beam with the concrete. The laser head speed of 600 mm/min reduced about 89% of the waste generated by shallow depth of scabbling as compared to the waste generated at the laser head speed of 120 mm/min. The fiber laser scabbling system was developed for surface decontamination of radioactive concrete in nuclear power plants. Tests were performed to find the optimum parameters to reduce the generation of particulate waste from the contaminated concrete surface by controlling the laser head speeds. It was confirmed that the wastes from surface decontamination was reduced up to 89% by increasing laser head speed from 120 mm/min to 600 mm/min. It was also observed that the cylindrical tube effectively vacuumed the debris generated by the explosive spalling into the collector. Removal efficiencies of concrete particles were measured greater than 99.9% with ring blower power of 650 air watt of the filter system.

The removal of aqueous pollutants, including dye molecules from wastewater remains one of the pressing problems in the world. Because of chemical stability and conjugated structure, dye molecules cannot be easy decomposed by heat with oxidizing reagents such as H2O2 and light. The most common representative of widespread organic pollutant is methylene blue (MB) with molecular formula C16H18ClN3S, which is important colorant and used in various chemical and biological production industries and causes serious environment problems. Porous materials, including MOFs (metal-organic frameworks) have been applied for efficient MB photocatalytic degradation. However, one of the main barriers to using most MOFs to break down aromatic organics is wide band gap energy, which means that the catalyst can exhibit high photocatalytic performance only under UVlight irradiation. Moreover, most MOFs usually show the poor water stability of frameworks, which tend to dissolve in water with total destruction. In this work we report about two new copper based MOFs with high photocatalytic properties for efficient MB degradation from wastewater under UV-light and natural sunlight. Time, required for 100% MB degradation, equals 7 minutes under UV (source 4 W 254 nm VL-4.LC UV-lamp) and 60 minutes under natural sunlight irradiation in the presence of H2O2. Crystal structure information is provided using single crystal X-ray diffraction data. The composition and comparative characteristics of MOFs are given using powder X-ray diffraction, UV–visible diffuse reflectance spectroscopy, UVvisible spectroscopy and Fourier-transform infrared spectroscopy.

Laser scabbling has the potential to be a valuable technique capable of effectively decontaminating highly radioactive concrete surface at nuclear decommissioning sites. Laser scabbling tool using an optical fiber has a merits of remote operation at a long range, which provides further safety for workers at nuclear decommissioning sites. Furthermore, there is no reaction force and low secondary waste generation, which reduces waste disposal costs. In this study, an integrated decontamination system with laser scabbling tool was employed to test the removal performance of the concrete surface. The integrated decontamination system consisted of a fiber laser, remote controllable mobile cart, and a debris collector device. The mobile cart controlled the translation speed and position of the optical head coupled with 20 m long process fiber. A 5 kW high-powered laser beam emitted from the optical head impacted the concrete block with dimensions of 300 mm × 300 mm × 80 mm to induce explosive spalling on its surface. The concrete debris generated from the spalling process were collected along the flexible tube connected with collector device. We used a three-dimensional scanner device to measure the removed volume and depth profile.

KAERI has been developing a new decontamination process that does not contain any organic chemicals in the decontamination solution and minimizes the use of ion exchange resin in the solution as a purifying step. The process is hydrazine based reductive metal ion decontamination for decommissioning (HyBRID) and consists of N2H4, H2SO4 and Cu+ ions. The primary system of the LWR is composed of materials with high corrosion resistance, such as stainless steel and Inconel, but among the materials, the feeder and header of the primary system of the PHWR are composed of carbon steel (SA106Gr.B) with low corrosion resistance. Therefore, when decontamination of PHWRs, attention should be paid to corrosion of carbon steel. Since Fe3O4, a contaminating oxide film formed on the surface of carbon steel dissolves faster than ferrite or chromite formed on the surface of Inconel or stainless steel, the base material is exposed to the solution and is corroded during decontamination. When a large amount of iron ions is eluted into the decontamination agent due to corrosion of carbon steel, not only the soundness of the base metal is adversely affected, but also the amount of decontamination waste increases. The purpose of this study is to develop inhibitors that can minimize corrosion of carbon steel when decontamination of PHWRs using the HyBRID decontamination process. CG, 570S and PP3 were selected as corrosion inhibitors. In addition, corrosion tests of carbon steel were conducted in the HyBRID solution with corrosion inhibitors. The best corrosion inhibitors and optimal operating conditions were selected, and HyBRID decontamination agents with corrosion inhibitors were much better in corrosion resistance than existing commercial decontamination agents.

Various dry actives wastes (e.g., gloves, wipers, shoes, clothes) are generated during operation and maintenance of nuclear facilities. Among those, latex gloves gets interest because they contain both organic and inorganic compounds. CaCO3 is a common filler material for production of latex rubbers. Here, latex gloves were thermally treated in a closed vessel to separate the organic and inorganic compounds. Using the closed vessel is beneficial as it can prevent escape of any species, including radioactive nuclides in a real case, generated during the treatment. It was found that thermal decomposition of latex gloves occurred above 250°C. Latex gloves were decomposed to gas, liquid, and solid compounds. The gas product is thought to be volatile organic compounds (VOCs). The liquid product seems to be a mixture of oils and water. A CaCO3 phase was identified in the solid product, as expected. The VOCs can be easily separated at room temperature by purging in vacuum or inert atmosphere. The liquid-solid mixture can be separated by distillation. It is thought that gammaemitting nuclides, such as Cs-137, Sr-90, and Co-60, dominantly remain in the solid product. In the best situation, the solid product is the only subject to be transferred to final wasteform fabrication stream and thus volume of final waste can be reduced. Surrogates of contaminated latex gloves (containing Cs, Sr, and Co) were prepared and they were treated at 350°C in the closed vessel. How these contaminants behaves in this thermal process will be discussed in the presentation.

Dry active wastes (DAWs) are a type of combustible radioactive solid waste, which includes decontamination paper, protective clothing, filters, plastic bags, etc. generated from operating nuclear facilities and decommissioning projects. The volume of DAWs could be increased over time, disadvantage to higher disposal costs and space utilitization of disposal site. Additionally, incineration methods cannot be applied to DAWs, unlike general environmental waste, due to concerns about air pollution and the release of harmful chemicals with radioactive nuclides into the atmosphere. Recently, KAERI developed an alternative thermochemical process for reducing the volume of DAW, which involves a step-wise approach, including carbonization, chlorination, and solidification. The purpose of this process is to selectively separate the radioactive nuclides from carbonized DAWs that are less than clearance criteria, which can be disposed of as non-radioactive waste. In this research, we investigated the thermal decomposition characteristics of DAWs using nonisothermal thermogravimetric analysis, which was performed with different categorized wastes and heating conditions. As a result, the cellulose DAWs such as decontamination paper and cotton were thermally decomposed in three or four-step depending on the heating conditions. On the other hand, the hydrocarbon and rubber DAWs such as plastic bags and latex were thermally decomposed in one or two-step. Therefore, it could be suggested the thermochemical treatment conditions that minimize the decomposition of DAWs by controlling the reaction steps, and we will try to apply these results for cellulose type DAWs such as decontamination paper and cotton, which is generated majorly from the nuclear facilities in the future.

Laser cutting has been recognized as one of key techniques in dismantling nuclear power plants as it has several advantages such as a remote operation and a reduced secondary waste. However, it generates a significant amount of aerosols that can pose a health risk to workers and further induce environmental pollution during the cutting operation. Thus, understanding the aerosol characteristics generated by the laser cutting is crucial for implementing an effective cutting operation and reducing the exposure to these hazardous particles. In this work, we established a methodology to collect the aerosols and investigate their properties in the laser cutting operation. We built an integrated laser cutting system for aerosol analyses, consisting of a high-power laser cutting module, a metal sample holder, an aerosol collector, and a closed chamber. We expect that this system will offer an opportunity for in-depth understanding of the aerosol properties, by connecting it with desired type of aerosol analysis platforms, and further safe dismantling operation of the nuclear power plants.

Laser cutting has many advantages, including high-speed cutting potential, no reaction forces, narrow kerf widths, ease of remote control, and more. This makes it the next generation cutting technology for nuclear decommissioning. For this reason, various groups in countries with nuclear power plants have been working on applying laser cutting to nuclear decommissioning. Our group has also been developing in-air and underwater laser cutting technologies. Previous research has focused on efficiently cutting thicker steels. To accomplish this, a cutting head with a long focusing element with a focal length of 600 mm was utilized. A long focusing head is advantageous for cutting thick objects at high speeds because it can maintain a high power density over a long distance. However, with such a long focused beam, the residual laser power that remains after passing through the target object can cut or damage other unwanted objects located behind the target. Utilizing a short focused element can solve this problem, but if the focal length is too short, the cutting capability will be reduced. In this work, we developed and applied a cutting head that utilizes a focused element with a short focal length of 300 mm. Cutting tests with this head allowed us to cut 10-60 mm thick stainless steel plates at a laser power of 6 kW. We also obtained the maximum cutting speed and kerf width for each thickness while increasing the laser power by 1 kW from 1 to 6 kW. The results obtained in this work are expected to be utilized for safe cutting in future nuclear decommissioning applications.

RUCAS (Recycling-Underlying Computational Dose Assessment System), a dose assessment program based on the RESRAD-RECYCLE framework, is designed to evaluate dose for recycling scenarios of radioactive waste in metals and concrete. To confirm the validity of the recycling scenarios provided by RUCAS, comparative evaluations will be conducted with RESRAD-RECYCLE for metal radioactive waste recycling scenarios and with MicroShield® for concrete radioactive waste recycling scenarios. In the evaluation of metal recycling scenarios without shielding, RUCAS showed similar results when compared to both MicroShield® and RESRAD-RECYCLE. This validates the function of dose assessments using RUCAS for metal recycling scenarios. However, when shielding was present, RUCAS produced results that were comparable to MicroShield®, but differed from those of RESRAD-RECYCLE. The underestimation of dose values up to 1.66E+08 times difference by RESRAD-RECYCLE could potentially decrease reliability and safety in evaluated doses, further emphasizing the importance of RUCAS. Because validation is also necessary for the expanded calculation capabilities resulting from methodological changes of RUCAS (i.e., various radiation source geometries), based on prior validations, it was determined that additional validations are required for different radiation source materials and shielding conditions. In case where the radiation source and shielding materials were identical, RUCAS and MicroShield® produced similar results according to both the Kalos et al. (1974) and Lin and Jiang (1996) methodologies. This demonstrates that the that differences in methodology are inconsequential when considering the same source and shielding materials. However, when the atomic number of the radiation source materials was larger than that of shielding material (HZ-LZ condition), RUCAS obtained results similar to MicroShield® only for the Kalos et al. (1974) methodology. While Lin and Jiang (1996) methodology yield higher results than MicroShield®. Lastly, in case where the atomic number of the radiation source material was smaller than that of the shielding material (LZ-HZ condition,) both methodologies yielded results comparable to MicroShield®. In conclusion, the validity of RUCAS’s shielding calculations has been verified, confirming improvements in dose assessment compared to RESRAD-RECYCLE. Additionally, we observed that shielding effectiveness calculations differ depending on the methodology of build-up effect. If the validity of these methodologies is confirmed, it is expected that selecting the most advantageous methodology for each condition will enable more rational dose assessments. Consequently, in future research, we plan to evaluate the validity of Lin and Jiang (1996) methodology using particle transport codes based on the Monte Carlo method, such as MCNP and Geant 4, rather than MicroShield®.

Most of the spent nuclear fuel generated by domestic nuclear power plants (NPPs) is temporarily stored in wet storage which is spent fuel pool (SFP) at each site. Currently, in case of Kori Unit 2, about 93.6% of spent nuclear fuel is stored in SFP. Without clear disposal policy determined for spent nuclear fuel, the storage capacity in each nuclear power plant is expected to reach saturation within 2030. Currently, the SFP stores not only spent fuel but also various non-fuel assembly (NFA). NFA apply to all device and structures except for fuel rods inserted in nuclear fuel assembly. The representative NFA is control element driving mechanism (CEDM), in-core instrument (ICI), burnable poison, and neutral resources. Although these components are irradiated in the reactor, they do not emit high-temperature heat and high radiation like nuclear fuel, so if they are classified as intermediate level waste (ILW) and low level waste (LLW) and moved outside the SFP, positive effects such as securing spent fuel storage space and delaying saturation points can be obtained. Therefore, this study analyzes the status of spent fuel and Non Fuel Assembly (NFA) storage in SFP of domestic nuclear power plants. In addition, this study predict the amount of spent fuel and NFA that occur in the future. For example, this study predicts the percentage of current and future ICIs and control rods in the SFP when stored in the spent fuel storage rack. In addition, the positive effects of moving NFA outside the SFP is analyzed. In addition, NFA withdrawn from SFP is classified as ILW & LLW according to the classification criteria, and the treatment, storage, and disposal methods of NFA will be considered. The study on the treatment, storage, and disposal methods of NFA is planned to be conducted by applying the existing KN-12 & KN-18 containers and ILW & LLW containers being developed for decommissioning waste.

Concrete radioactive waste is divided into surface-contaminated concrete and activated concrete, and although the generation rate varies depending on the operating conditions of the nuclear power plant, it is reported that the amount of surface-contaminated concrete generated is greater. It is reported in the ‘US-NRC Inventory Report’ that 99% of radionuclides in surface-contaminated concrete are distributed within 1 mm of the surface. Since concrete radioactive waste accounts for a large amount of generation after metal radioactive waste, it is necessary to reduce the amount of radioactive waste disposal by applying appropriate treatment techniques to surface-contaminated concrete. In this study, a similar contamination environment work space with the size of 5.4 (W) × 3.6 (L) × 2.5 (H) [m] in which concrete specimens can be fixed on the wall and floor was established. And an integrated decontamination equipment was verified the automation performance for ‘location accuracy’, ‘radioactive contamination level measurement’ and ‘concrete surface laser scabbling’. It was confirmed that the average was 8.3 [mm] in the evaluation of the ‘location accuracy’ for the remote control and movement of the integrated decontamination equipment. For performance verification of ‘radioactive contamination level measurement’ and ‘laser scabbling’, it were used that size of 30×30×8 [cm] ordinary concrete specimens and concrete radioactively contaminated with Co-60 below the regulatory exemption concentration. ‘Radioactive contamination level measurement’ is measured as much as the set range, divied and display the measured values in different colors on the map of the control program. Ordinary concrete specimens are 0.066~0.089 μ Sv/hr, and contaminated concrete specimens are 0.107~0.121 μ Sv/hr, and it was confirmed that they are expressed in different colors on the map. For ‘laser scabbling’, the performance according to the laser scabbling speed and reproducibility with ordinary concrete specimens was verified. As a result, a weight change of up to 1.48 kg was confirmed. Contaminated concrete specimens were subjected to a direct method using a surface contamination detector and an indirect method using a smear paper to measure surface contamination before and after scabbling, and the debris generated after scabbling was analyzed using HPGe.

The spent filters used to purify radioactive materials and remove impurities from primary systems at nuclear power plants (NPPs) have been stored for long periods in filter storage rooms at NPPs due to concerns about the unproven safety of the treatment method, absence of disposal facilities, and risk of high radiation exposure. In the storage room at Kori Unit 1, there are approximately 227 spent filters of 9 different types. The radiation dose rates of filters range from 0.01 to 500 mSv/hr. Recently, a comprehensive plan has been established for the treatment and disposal of radioactive waste that has not yet been treated to facilitate decommissioning of NPPs. As a follow-up measure, compression and packaging optimization processes are being developed to treat the spent filters. KHNP plans to dispose of the spent filters after compressing, packaging, and immobilizing them. However, the spent filters are currently stored without being sorted by type or radiation intensity. If the removal and packing of the filters are done randomly without a plan for the order of withdrawal and subsequent processes, issues may arise such as a decrease in drum loading efficiency and exceeding the dose limit of the package. In this study, the number of drums needed to pack the spent filters was calculated, considering the filter size, weight, quantity, dose rate, shielding thickness of drum, and loadable quantity in a shielding drum (SD). Then, the spent filters that can be loaded on each drum were classified into one group. In addition, the withdrawal order for each group was set so that the filter withdrawal, compression, and packaging processes could be performed efficiently. The spent filter groups are as follows: (1) compression/12 cm SD (17 groups), (2) compression/16 cm SD (6 groups), (3) non-compression/ intermediate storage container (17 groups, additional radiation attenuation required due to high dose rate), and (4) unclassified (5 groups, determined after measurement due to lack of filter information). The withdrawal order of the groups was determined based on several factors, including visual identification of the filter, ease of distribution after withdrawal, work convenience, and safety. Due to the decay of radioactivity over time, the current dose rate of the spent filters is expected to be much lower than at the time of waste generation. Therefore, in the future, sample filters will be taken from the storage room to measure their radioactivity and radiation dose rate. Based on these measurements, a database of radiological characteristics for the 227 filters will be created and used to revise the filter grouping.

The nuclear facilities at Korea Atomic Energy Research Institute (KAERI) have generated a variety of liquid radioactive waste and most of them have low-level radioactive or lower levels. Some of the liquid radioactive waste generated in KAERI is transported to Radioactive Waste Treatment Facility (RWTF) in 20 L container. Liquid radioactive waste transported in a 20 L container is stored in a Sewer Tank after passing through a solid-liquid separation filter. It is then transferred to a very low-level liquid radioactive waste Tank after removing impurities such as sludge through a pre-treatment device. The previous pre-treatment process involved an underwater pump and a cartridge filter device passively, but this presented challenges such as the inconvenience of having to install the underwater pump each time, radiation exposure for workers due to frequent replacement of the cartridge filter, and the generation of large amounts of radioactive waste from the filter. To address these challenges and improve efficiency and safety in radiation work, an automated liquid radioactive waste pre-treatment device was developed. The automated liquid radioactive waste pre-treatment device is a pressure filtration system that utilizes multiple overlapping filter plates and pump pressure to effectively remove impurities such as sludge from liquid radioactive waste. With just the push of a button, the device automatically supplies and processes the waste, reducing radiation hazards and ensuring worker safety. Its modular and mobile design allows for flexible utilization in various locations, enabling efficient pre-treatment of liquid radioactive waste. To evaluate the performance of the newly constructed automated liquid radioactive waste treatment device, samples were taken before and after treatment for 1 hour cycling and analyzed for turbidity. The results showed that the turbidity after treatment was more than about four times lower than before treatment, confirming the excellent performance of the device. Also, it is expected that the treatment efficiency will improve further as the treatment time and number of cycles increase.

With the recent concern regarding cellulose enhancing radionuclide mobility upon its degradation to ISA, disposal of cellulosic wastes is being held off until the disposal safety is vindicated. Thus, a rational assessment should be conducted, applying an appropriate cellulose degradation model considering the disposal environment and cellulose degradation mechanisms. In this paper cellulose degradation mechanisms and the disposal environment are studied to propose the best-suitable cellulose degradation model for the domestic 1st phase repository. For the cellulose to readily degrade, the pH should be greater than 12.5. As in the case of SKB, 1BLA is excluded from the safety assessment because the pH of 1BLA remains below 12.5. Furthermore, despite cellulose degradation occurring, it does not always produce ISA. At low Ca2+ concentration, the ISA yield rate is around 25%, but at high Ca2+ concentration, the ISA yield rate increases up to 90%. Thus, for the cellulose to be a major concern, both pH and Ca2+ concentration conditions must be satisfied. To satisfy both conditions, the cement hydration must be in 2nd phase, when the porewater pH remains around 12.5 and a significant amount of Ca2+ ion is leaching out from the cement. However, according to the safety evaluation and domestic research, 2nd phase of cement hydration for silo concrete would achieve a pH of around 12.4, dissatisfying cellulose degradation condition like in 1BLA. Thus, cellulose degradation would be unlikely to occur in the domestic 1st phase repository. To derive waste acceptance criteria, a quantitative evaluation should be conducted, conservatively assuming cellulose is degraded. To conduct a safety evaluation, an appropriate degradation model should be applied to determine the degradation rate of cellulose. According to overseas research, despite the mid-chain scission being yet to be seen in the experiments, the degradation model considering mid-chain scission is applied, resulting in an almost 100% degradation rate. The model is selected because the repositories are backfilled with cement, achieving a pH greater than 13, so extensive degradation is reasonably conservative. However, under the domestic disposal condition, where cellulose degradation is unlikely to occur, applying such model would be excessively conservative. Thus, the peeling and stopping model derived by Van Loon and Haas, which suggests 10~25% degradation rate, is reasonably conservative. Based on this model, cellulose would not be a major concern in the domestic 1st phase repository. In the future, this study could be used as fundamental data for planning waste acceptance criteria.

A lot of solid wastes are generated when nuclear power plant is dismantled, and a lot of treatment costs and optimal waste treatment technologies are required to treat the generated solid wastes. Currently, there is no optimized reduction and solidification technology for each characteristics of radioactive dismantling waste, so the customized treatment technology for each waste is required to respond actively to this issue. This paper shows the evaluation results of molding and sintering characteristics using preliminary sample to derive operational characteristics and improvements for powder mixing device, molding device, and sintering device manufactured for solidification of dispersible radioactive waste. Zeolite was used as a preliminary sample for performing basic operation characteristics evaluation of each unit device. First of all, the basic operation characteristics of the powder mixing device was evaluated by analyzing the sample distribution, mixing degree, and tap density. It was confirmed that the preliminary sample was well mixed in all areas of the cylinder where the mixing was performed. In the tap density analysis, the increase effect of the volume reduction of the sample was confirmed according to the increase of the RPM speed (up to 2000 RPM). Since the particle size of zeolite sample is very small (nanometer size), the particular consistency of the change of average particle size with RPM speed couldn’t be confirmed, but the uniform of particle size distribution was confirmed with RPM speed size. The basic operation characteristics of the molding device was evaluated for each mold size (ID30, ID50, ID100) according to the moisture content (0-20%) and the molding pressure condition (25-200 MPa) for the preliminary sample. In the characteristics evaluation of the sintered body, the strength of the sintered body was much higher than that of the molded body. However, it was confirmed that as moisture evaporated during the sintering process according to the moisture content contained in the molded body, the swelling occurred in the sintered body due to vapor pressure, and this caused cracks in the longitudinal or transverse direction inside and outside the sintered body. Therefore, optimal moisture content conditions for sintering should be derived. In conclusion, if the operation characteristics and improvements of powder mixing, molding and sintering devices derived from this study are reflected and improved, it is judged that it is possible to derive the optimal process for solidification of dispersive radioactive wastes.

The homogeneity of radioactive spent ion exchange resins (IERs) distribution inside waste form is one of the important characteristics for acceptance of waste forms in long-term storage because heterogenous immobilization can lead to the poor structural stability of waste form. In this study, the homogeneity of metakaolin-based geopolymer waste form containing simulant IERs was evaluated using a laser-induced breakdown spectroscopy (LIBS) and statistical approach. The cation-anion mixed IERs (IRN150) were used to prepare the simulant spent IERs contaminated by non-radioactive Cs, Fe, Cr, Mn, Ni, Co, and Sr (0.44, 8.03, 6.22, 4.21, 4.66, 0.48, and 0.90 mg/g-dried IER, respectively). The K2SiO3 solution to metakaolin ratio was kept constant at 1.2 and spent IERs loading was 5wt%. For the synthesis of homogeneous geopolymer waste form, spent IERs were mixed with K2SiO3 solution and metakaolin first, and then the fresh mixture slurry was poured into plastic molds (diameter: 2.9 cm and height: 6.0 cm). The heterogeneous geopolymer waste form was also fabricated by stacking two kinds of mixtures (8wt% IERs loading in bottom and 2wt% in top) in one mold. Geopolymers were cured for 7d (1d at room temperature and 6d at 60°C). The hardened geopolymers were cut into top, middle, and bottom parts. The LIBS spectra and intensities for Cs were obtained from the top and bottom of each part. Cs was selected for target nuclide because of its good sensitivity for measurement. Shapiro-Wilk test was performed to determine the normality of LIBS data, and it revealed that data from the homogeneous sample is normal distribution (p-value = 0.9246, if p-value is higher than 0.05, it is considered as normal distribution). However, data from the heterogeneous sample showed abnormal distribution (p-value = 7.765×10-8). The coefficient of variation (CoV) was also calculated to examine the dispersion of data. It was 31.3% and 51.8% from homogeneous and heterogeneous samples, respectively. These results suggest that LIBS analysis and statistical approaches can be used to evaluate the homogeneity of waste forms for the acceptance criterion in repositories.

Level measurement of liquid radwaste is essential for inventory management of treatment system. Among various methods, level measurement based on differential pressure has many advantages. First, it is possible to measure the liquid level of the system regardless of liquid type. Second, as the instrument doesn’t need to be installed near the tank, there is no need to contact the tank when managing it. Therefore, workers’ radiation dose from the system can be decreased. Finally, although it depends on the accuracy, the price of the instrument is relatively low. With these advantages, in general, liquid radwaste level in a tank is measured using differential pressure in the treatment system. Not only the advantages described above, there are some disadvantages. As the liquid in the system is waste, it is not pure but has some suspended materials. These materials can be accumulated in tanks and pipes where the liquids move to come into direct contact with pneumatic pipes that are essential in differential pressure instruments. As a result, in case of a treatment using heat source, the accumulated materials may become sludge causing interference in pneumatic pipes. And this can change the pressure which also affects the level measured. In conclusion, in case of liquid storage tanks in which the situation cannot be checked, the proficiency of an operator becomes important.

Radioactive waste must be stored for at least 300 years and must bear astronomical costs. In addition, unexpected potential risk factors are also a considerable burden. In the case of low-level radioactive waste, combustible and liquid low-contamination radioactive waste can be treated relatively easily through high-temperature plasma which the volume can be reduced by 1/250 and the weight by 1/30. It is possible to permanently dispose of the ash leached after plasma treatment in a more stable manner compared to the conventional methods. Types of low-level combustible radioactive waste, including paper, vinyl, clothing, filters, and resins, account for more than 30% of the total waste volume. Furthermore, high-temperature plasma treatment of low-level radioactive waste from petrochemical plants and medical institutions have many advantages, namely astronomical cost savings, securing free space in existing storage facilities, and improving the image of nuclear energy. Korea is preparing to decommission the Kori No. 1 nuclear power plant, and small and mediumsized enterprises and related organizations are conducting various studies to incinerate radioactive waste. In foreign countries, Britain began incineration technology in the 1970s, and Plasma Energy Group, LLC, headquartered in Florida, USA, physically changed the molecular structure of the material by combining plasma chambers and plasma arcs and obtained a patent application in 1992. Germany was approved for operation in 2002, and Switzerland completed a trial run of a plasma technologybased facility in 2004. Important radionuclides in terms of radioactive gas waste treatment include inert gases, radioiodine, and radioactive suspended particles. Gas waste is compressed in a compressor through a surge tank in the gas waste treatment system and filters at each stage. after that, the shortlife nuclide is naturally collapsed for 30 to 60 days in the storage or activated carbon adsorbent in the attenuation tank and released through HEPA filters. The radioactive concentration at discharge is monitored and managed using continuous monitoring equipment, and the oxygen concentration is managed in the gas waste treatment system to prevent explosion risk. The problem of radioactive waste disposal is not only a problem for people living in the present era, but also a big social issue that brings a burden to future generations While interest in plasma treatment is increasing from the decommissioning of the Kori Unit 1. in Korea, it is showed that there is a lack of systematic management and research especially in the radioactive volatile gases fields, that’s why I propose some ideas as follows. First, the government and related institutions should invest to the continuous radioactive monitoring system to produce and distribute continuous radioactive monitoring facilities with an affordable price. Second, it is recommended that radioactive waste incineration would be connected to the GRS system of the plant’s gas radwaste treatment system, and radioactive volatile materials should be monitored through continuous monitoring system. Third, radioactive volatile materials generated according to the temperatures and times during plasma incineration treatment are different. Therefore, prior classification of each expected radioactive volatile substance must be performed before incineration.