Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UVvis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.

액체저장탱크의 지진 거동은 유체-구조물 상호작용에 의해 복잡하게 나타나므로, 이 시스템의 지진응답과 피해를 정확하게 예측 하기 위해서는 이를 엄밀히 고려하여야 한다. 이 연구에서는 유체-구조물 상호작용을 엄밀히 고려하여 양방향 수평 지반운동이 작용 하는 직사각형 액체저장탱크의 지진응답 해석을 수행하고 그 응답 특성을 분석하고자 한다. 이를 위해 지진하중 작용 시 발생하는 유체 동수압을 유한요소 기법을 사용하여 산정하고, 이 동수압을 구조물의 유한 요소에 작용하여 전체 시스템의 동적 거동을 모사한다. 예제 직사각형 액체저장탱크의 지진응답 해석을 통하여 대상 시스템의 동적 거동은 양방향 수평 지반운동이 작용하는 방위각에 의해 유의미한 영향을 받음을 확인할 수 있다. 그러므로 직사각형 액체저장탱크의 내진설계를 수행하거나 내진성능을 검토할 때는 이러한 특성을 고려하여야 할 것이다.

BiFeO3 with perovskite structure is a well-known material that has both ferroelectric and antiferromagnetic properties called multiferroics. However, leaky electrical properties and difficulty of controlling stoichiometry due to Bi volatility and difficulty of obtaining high relative density due to high dependency on the ceramic process are issues for BiFeO3 applications. In this work we investigated the sintering behavior of samples with different stoichiometries and sintering conditions. To understand the optimum sintering conditions, nonstoichiometric Bi1±xFeO3±δ ceramics and Ti-doped Bi1.03Fe1-4x/3TixO3 ceramics were synthesized by a conventional solid-state route. Dense single phase BiFeO3 ceramics were successfully fabricated using a two-step sintering and quenching process. The effects of Bi volatility on microstructure were determined by Bi-excess and Ti doping. Bi-excess increased grain size, and Ti doping increased sintering temperature and decreased grain size. It should be noted that Ti-doping suppressed Bi volatility and stabilized the BiFeO3 phase.

Piezoelectric ceramic specimens with the Pb(Mg1/3Nb2/3)0.65Ti0.35O3 (PMN-PT) composition are prepared by the solid state reaction method known as the “columbite precursor” method. Moreover, the effects of the Li2O-Bi2O3 additive on the microstructure, crystal structure, and piezoelectric properties of sintered PMN-PT ceramic samples are investigated. The addition of Li2O-Bi2O3 lowers the sintering temperature from 1,200oC to 950oC. Moreover, with the addition of >5 wt.% additive, the crystal structure changes from tetragonal to rhombohedral. Notably, the sample with 3 wt.% additive exhibits excellent piezoelectric properties (d33 = 596 pC/N and Kp = 57%) and a sintered density of 7.92 g/cm3 after sintering at 950oC. In addition, the sample exhibits a curie temperature of 138.6oC at 1 kHz. Finally, the compatibility of the sample with a Cu electrode is examined, because the energy-dispersive X-ray spectroscopy data indicate the absence of interdiffusion between Cu and the ceramic material.

In a seismic design, a structural demand by an earthquake load is determined by design response spectra. The ground motion is a three-dimensional movement; therefore, the design response spectra in each direction need to be assigned. However, in most design codes, an identical design response spectrum is used in two horizontal directions. Unlike these design criteria, a realistic seismic input motion should be applied for a seismic evaluation of structures. In this study, the definition of horizontal spectral acceleration representing the two-horizontal spectral acceleration is reviewed. Based on these methodologies, the horizontal responses of observed ground motions are calculated. The data used in the analysis are recorded accelerograms at the stations near the epicenters of recent earthquakes which are the 2007 Odeasan earthquake, 2016 Gyeongju earthquake, and 2017 Pohang earthquake. Geometric mean-based horizontal response spectra and maximum directional response spectrum are evaluated and their differences are compared over the period range. Statistical representation of the relations between geometric mean and maximum directional spectral acceleration for horizontal direction and spectral acceleration for vertical direction are also evaluated. Finally, discussions and suggestions to consider these different two horizontal directional spectral accelerations in the seismic performance evaluation are presented.

The spray characteristics of two working fluids operating with a bi-fuel injector were investigated. A bi-fuel injector simultaneously sprays two working fluids, both of which possess different properties. An effervescent atomizer containing two separated aerator tubes was employed as the bi-fuel injector. Vegetable oil and kerosene were the working fluids. The mixing ratio and ALR were the experimental parameters. The mixing ratio is the mass fraction of vegetable oil in the total amount of working fluids. The ALR represents the ratio of the atomizing gas to the working fluid mass flow ratio. In order to examine spray characteristics, the spray angle, droplet size distribution, cumulative volume fraction, Sauter Mean Diameter and span factor were measured using a high resolution video camera and a Laser Diffraction Particle Analyzer. From the experimental results, spray angle is decreased with as the ratio of kerosene to vegetable oil in working fluid is increased. Regardless of ALR, SMD was the smallest when the only working fluid was kerosene and uniformity was the most stable when the only working fluid was vegetable oil.

This study focused on the development of Fe–Co/kaolin catalyst by a wet impregnation method. Response surface methodology was used to study the influence of operating variables such as drying temperature, drying time, mass of support and stirring speed on the yield of the catalyst. The catalyst composite at best synthesis conditions was then calcined in an oven at varied temperature and time using 22 factorial design of experiment. The catalyst with optimum surface area was then utilized to grow carbon nanofiber (CNF) in a chemical vapour deposition (CVD) reactor. Both the catalyst and CNF were characterized using high-resolution scanning electron microscopy, high-resolution transmission electron microscopy, thermogravimetric analysis (TGA), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy. On the influence of operating variables on the yield of catalyst, the results showed that an optimum yield of 96.51% catalyst was obtained at the following operating conditions: drying time (10 h), drying temperature (110 °C), stirring speed (100 rpm) and mass of support (9 g). Statistical analysis revealed the existence of significant interactive effects of the variables on the yield of the catalyst. The HRSEM/XRD/BET/TGA analysis revealed that the particles are well dispersed on the support, with high surface area (376.5 m2/g) and thermally stable (330.88 °C). The influence of operating parameters on the yield of CNF was also investigated and the results revealed an optimum yield of 348% CNF at the following operating conditions: reaction temperature (600 °C), reaction time (40 min), argon flow rate (1416 mL/min) and acetylene/hydrogen flow rate (1416 mL/ min). It was found from statistical analysis that the reaction temperature and acetylene/hydrogen flow rates exerted significant effect on the CNF yield than the other factors. The contour and surface plots bi-factor interaction indicated functional relationship between the response and the experimental factors. The characterization results showed that the synthesized CNF is thermally stable, twisted and highly crystalline and contain surface functional groups. It can be inferred from the results of various analyses that the developed catalyst is suitable for CNF growth in a CVD reactor.

The spray characteristics of two working fluids operating with a bi-fuel injector were investigated. A bi-fuel injector simultaneously sprays two working fluids, both of which possess different properties. An effervescent atomizer containing two separated aerator tubes was employed as the bi-fuel injector. Vegetable oil and kerosene were the working fluids. The mixing ratio and ALR were the experimental parameters. The mixing ratio is the mass fraction of vegetable oil in the total amount of working fluids. The ALR represents the ratio of the atomizing gas to the working fluid mass flow ratio. In order to examine spray characteristics, the spray angle, droplet size distribution, cumulative volume fraction, Sauter Mean Diameter and span factor were measured using a high resolution video camera and a Laser Diffraction Particle Analyzer. From the experimental results, spray angle is decreased with as the ratio of kerosene to vegetable oil in working fluid is increased. Regardless of ALR, SMD was the smallest when the only working fluid was kerosene and uniformity was the most stable when the only working fluid was vegetable oil.

본 연구에서는 가변 통기성 스마트 의류의 제작을 위해 필요한 형상기억합금 액추에이터의 작동 조건을 파악하였다. 의복의 개방, 폐쇄와 같은 양방향 작동 시 형태 변형 시에만 전력을 소모하는 저전력 소모 액추에이터 개발을 위해 복수 채널의 일방향 형상기억합금을 이용하여 스위치로 작동되는 액추에이터를 설계하였으며 가장 효율적으로 작동할 수 있는 와이어의 직경과 전압인가 단위시간을 도출하였다. 선행연구 결과 도출된 양방향 작동이 가능한 일방향 형상기억합금의 직경 범위 내에서 Arduino 스위치를 제작하여 3.7V 전압인가 시 변화량을 분석한 결과 0.4Φ의 액추에이터가 가장 적합한 것으로 나타났다. 0.4Φ 형상기억합금와이어를 사용한 양방향작동 액추에이터의 개방, 폐쇄에 필요한 최적전압인가 시간을 도출하기 위해 액추에이터의 최대개방, 최소폐쇄 도달 전압인가 시간으로부터 50ms씩 감소, 증가 시키며 냉각 후 액추에이터의 내경을 비교하는 방식으로 측정한 결과 개방 동작에 필요한 최적 전압인가 단위시간은 4,100ms로 나타났다. 각 채널간의 발열에 의한 간섭을 최소화하기 위한 양방향간 작동 시 필요 딜레이 분석을 위해 상온에서 형상기억합금에 최적 전압입가 시간인 4.1초 동안 전원을 공급하고 가열 후 냉각까지의 과정을 열화상카메라로 촬영하여 형상기억합금 와이의 온도가 냉각시의 상변태온 이하로 하강하는 시점을 파악한 결과, 액추에이터의 양방향간 작동 딜레이는 1.8초 이상이 확보되어야 함을 파악할 수 있었다.

Grain-growth behavior in the 95Na1/2Bi1/2TiO3-5BaTiO3 (mole fraction, NBT-5BT) system has been investigated with the addition of Na2CO3. When Na2CO3 is added to NBT-5BT, the growth rate is higher than desired and grains are already impinging each other during the initial stage of sintering. The grain size decreases as the sintering temperature increases. With the addition of Na2CO3, a liquid phase infiltrates the interfaces between grains during sintering. The interface structure can be changed to be more faceted and the interface migration rate can increase due to fast material transport through the liquid phase. As the sintering temperature increases, the impingement of abnormal grains increases because the number of abnormal grains increases. Therefore, the average grain size of abnormal grains can be decreased as the temperature increases. The phenomenon can provide evidence that grain coarsening in NBT-5BT with addition of Na2CO3 is governed by the growth of facet planes, which would occur via mixed control.

In this study, Bi-Sb-Te thermoelectric materials are produced by mechanical alloying (MA) and spark plasma sintering (SPS). To examine the influence of the milling atmosphere on the microstructure and thermo-electric (TE) properties, a p-type Bi-Sb-Te composite powder is mechanically alloyed in the presence of argon and air atmospheres. The oxygen content increases to 55% when the powder is milled in the air atmosphere, compared with argon. All grains are similar in size and uniformly, distributed in both atmospheric sintered samples. The Seebeck coefficient is higher, while the electrical conductivity is lower in the MA (Air) sample due to a low carrier concentration compared to the MA (Ar) sintered sample. The maximum figure of merit (ZT) is 0.91 and 0.82 at 350 K for the MA (Ar) and MA (Air) sintered samples, respectively. The slight enhancement in the ZT value is due to the decrease in the oxygen content during the MA (Ar) process. Moreover, the combination of mechanical alloying and SPS process shows a higher hardness and density values for the sintered samples.