In this study, nano-sized tin oxide powder with an average particle size of below 50 nm is prepared by the spray pyrolysis process. The influence of air pressure on the properties of the generated powder is examined. Along with the rise of air pressure from 0.1kg/cm2 to 3kg/cm2, the average size of the droplet-shaped particles decreases, while the particle size distribution becomes more regular. When the air pressure increases from 0.1kg/cm2 to 1kg/cm2, the average size of the dropletshaped particles, which is around 30-50 nm, shows hardly any change. When the air pressure increases up to 3kg/cm2, the average size of the droplet-shaped particles decreases to 30 nm. For the independent generated particles, when the air pressure is at 0.1kg/cm2, the average particle size is approximately 100 nm; when the air pressure increases up to 0.5kg/m2, the average particle size becomes more than 100 nm, and the surface structure becomes more compact; when the air pressure increases up to 1kg/cm2, the surface structure is almost the same as in the case of 0.5kg/cm2, and the average particle size is around 80- 100 nm; when the air pressure increases up to 3kg/cm2, the surface structure becomes incompact compared to the cases of other air pressures, and the average particle size is around 80-100 nm. Along with the rise of air pressure from 0.1kg/cm2 to 0.5kg/cm2, the XRD peak intensity slightly decreases, and the specific surface area increases. When the air pressure increases up to 1kg/cm2 and 3kg/cm2, the XRD peak intensity increases, while the specific surface area also increases.

In this study, nano-sized indium oxide powder with the average particle size below 100 nm is fab-ricated from the indium chloride solution by the spray pyrolysis process. The effects of the reaction temperature, the concentration of raw material solution and the inlet speed of solution on the properties of powder were studied. As the reaction temperature increased from 850 to , the average particle size of produced powder increased from 30 to 100 nm, and microstructure became more solid, the particle size distribution was more irregular, the intensity of a XRD peak increased and specific surface area decreased. As the indium concentration of the raw material solution increased from 40 to 350 g/l, the average particle size of the powder gradually increased from 20 to 60 nm, yet the particle size distribution appeared more irregular, the intensity of a XRD peak increased and spe-cific surface area decreased. As the inlet speed of solution increased from 2 to 5 cc/min., the average particle size of the powder decreased and the particle size distribution became more homogeneous. In case of the inlet speed of 10 cc/min, the average particle size was larger and the particle size distribution was much irregular compared with the inlet speed of 5 cc/min. As the inlet speed of solution was 50 cc/min, the average particle size was smaller and microstructure of the powder was less solid compared with the inlet speed of 10 cc/min. The intensity of a XRD peak and the variation of specific area of the powder had the same tendency with the variation of the average par-ticle size.

In this study, nano-sized powder of Ni-ferrite was fabricated by spray pyrolysis process using the Fe-Ni complex waste acid solution generated during the shadow mask processing. The average particle size of the produced powder was below 100 nm. The effects of the reaction temperature, the inlet speed of solution and the air pressure on the properties of powder were studied. As the reaction temperature increased from 80 to 110, the average particle size of the powder increased from 40 nm to 100 nm, the fraction of the Ni-ferrite phase was also on the rise, and the surface area of the powder was greatly reduced. As the inlet speed of solution increased from 2 cc/min. to 10 cc/min., the average particle size of the powder greatly increased, and the fraction of the Ni-ferrite phase was on the rise. As the inlet speed of solution increased to 100 cc/min., the average particle size of the powder decreased slightly and the distribution of the particle size appeared more irregular. Along with the increase of the inlet speed of solution more than 10 cc/min., the fraction of the Ni-ferrite phase was decreased. As the air pressure increased up to 1 , the average particle size of the powder and the fraction of the Ni-ferrite phase was almost constant. In case of 3 air pressure, the average particle size of the powder and the fraction of the Ni-ferrite phase remarkably decreased.

Nano-sized Ni-ferrite powder was fabricated by spray pyrolysis process using the waste solution resulting from shadow mask processing. The average particle size of the powder was below 100 nm. The effects of the concentration of raw material solution, the nozzle tip size and air pressure on the properties of powder were studied. As the concentration increased, the average particle size of the powder gradually increased and its specific surface area decreased, but size distribution was much wider and the fraction of the Ni-ferrite phase greatly increased as the concentration increasing. As the nozzle tip size increased from 1 mm to 2 mm, the average particle size of the powder decreased. In case of 3 mm nozzle tip size, the average particle size of the powder increased slightly. On the other hand, in case of 5 mm nozzle tip size, average particle size of the powder decreased. Size distribution of the powder was unhomogeneous, and the fraction of the Ni-ferrite phase decreased as the nozzle tip size increasing. As air pressure increased up to 1 kg/, the average particle size of the powder decreased slightly, on the other hand, the fraction of the Ni-ferrite phase was almost constant. In case of 3kg/ air pressure, average particle size of the powder and the fraction of the Ni-ferrite phase remarkably decreased, but size distribution was narrow.

팔당호와 북한강, 남한강 및 경안천의 3개 지류에서 식물플랑크톤에 의한 일차생산력과 광합성 parameter의 계절적 변화를 조사하기 위하여 92년 4월, 8월과 10 월 그리고 93년 5월에 걸쳐 4회의 조사를 행하였다. 정점과 계절에 따른 secchi-depth는 0.8 (92년 10월, 경안천 정점 3)에서 2.0 m (92년 4월, 팔당댐 정점 4)까지, chl. a값은 1.7 (93년 5월, 남한강 정점 2)에서 32.8 mg m-3 (92년 8월, 팔당댐 정점 4)까지 변화하였다. 단위체 적당 일차생산력은 92년 8월(605~672 mgC m-3 hr-1)에 가장 높았으며, 정점 사이에서는 경안천 정점 3 (75~ 111 mgC m-3 hr-1)에서 가장 높은 값을 보였고, 이외의 정점에서는 16~68 mgC m-3 hr-1의 값을 보였다. 단위면 적당 일일 일차생산력은 역시 92년 8월에 가장 높았으며(8,195~9,341 mgC m-2 day-1), 92년 4월과 10월 그리 고 93년 5월에는 유사한 값을 보였다. 단위면적당 일일 일차생산력은 광도, 유광층의 깊이와 온도에 의해 영향 을 받는 것으로 밝혀졌다. Pmax와 α값은 8월에 가장 높았고, 정점간의 비교에서는 북한강 정점 1에서 가장 높았으며, 팔당댐 정점 4에서 가장 낮았다. 8월(하계)의 식물플랑크톤 군집은 4, 5월(춘계)과 10월(추계)에 비해 강한 빛에 적응되었다. Pmax와 α값은 밀접한 상관관계를 보였으나, Pmax와 Ik 그리고 Ik와 α 사이에는 상관관계를 발견하지 못하였다.

은 튜브에 장입되기 전의 초기 분말의 입자 크기가 Ag/Bi-2223초전도 선재의 미세구조와 상전이, 임계 전류 밀도등에 미치는 영향에 대해 고찰하였다. 분말의 입자 크기는 하소 분말을 볼밀을 이용하여 0-48 시간 동안 분쇄하여 조절하였다. 열처리 후 최종 초전도 선재의 전기적 성질은 초기 분말의 입자 크기에 영향을 받는 것으로 나타났으며 분말의 분쇄에 의한 반응성의 증가에 의해 열처리시 2223 상으로의 상전이가 빠르게 일어났고 이차상의 크기와 분율이 감소된 미세구조를 얻을 수 있었다. 그러나 과다한 분쇄에 의한 반응성의 증가에 의해 열처리시 2223상으로의 상전이가 빠르게 일어났고 이차상의 크기와 분율이 감소된 미세구조를 얻을 수 있었다. 그러나 과다한 분쇄는 분말의 비정질화를 유발하여 2223 상으로의 전이를 방해함으로써 선재의 임계 전류 밀도를 감소시키는 결과를 나타내었다.