본 연구에서는 사행하는 자연하천에 유입된 오염물질의 2차원 확산 특성을 모의하기 위하여 2차원 수심적분 모형인 RMA2와 RMA4를 사용하였다. 먼저 2차원 동수역학적인 모형인 RMA2를 사용하여 흐름장을 모의한 후 이 결과를 2차원 수질모형인 RMA4에 입력하여 농도장을 모의하였다. 수치모형을 S자형 사행수로에서 측정한 흐름 및 추적자 농도자료를 이용하여 검증한 결과, RMA4 모형은 최대유속선이 만곡의 내측에 치우쳐 나타나는 현상을 잘 모의하고 있었

충북 청주시에 위치한 충북대학교에서 강수에 따른 습성강하물 중의 TN, TP 및 COD의 농도와 오염부하를 조사하였다 강수사상에 대한 샘플은 1998년에서 2003년까지 채집되었다. 오염물질의 강수량가중평균 농도는 TN이 0.60mg/L, TP가 0.014mg/L, COD는 4.8mg/L이었는데, 이는 각각의 산술평균보다 26, 18, 14% 작게 나타났다. TN, TP 및 COD의 농도는 강수량이 증가함에 따라 감소하는 경향을 나타냈다. 모든 수질항목

프랙탈 이송확산방정식은 정수 차수의 미분연산자로 구성된 고전적인 이송확산방정식과 비교하여 프랙탈 차수의 미분연산자로 구성된 보다 상위개념의 방정식으로써 정의된다. 지금까지의 프랙탈 이송확산방정식은 추계학적인 기법을 동원하여 푸리에-라플라스 공간에서 주로 해석되었으나, 본 연구에서는 실제 공간에서 유한차분개념을 도입하여 보다 직접적으로 하천에서의 오염물 이송확산에 관한 지배방정식을 유도하였다. 이러한 개념의 유도방법은 프랙탈 차수 및 관련 확산계수의 물리

Petroleum refineries have been considered as an important emission source for atmospheric volatile hazardous air pollutants(HAPs). The emission source includes petroleum refinery processes and process equipment. The control strategy for volatile HAPs requires emission estimations of these pollutants. However, systematic methods of volatile HAPs emission from petroleum refineries have not yet been established. Accordingly, present study surveyed the estimation method of volatile HAPs emitted from the petroleum refinery processes and process equipment. The emission estimation methods for the petroleum refinery processes are applied for 11 petroleum refining facilities: fluidized catalytic cracking, thermal cracking, moving bed catalytic cracking, compressed engine, blowdown system, vacuum distilled column condensator, natural gas or distilled boiler, natural gas or distilled heater, oil boiler, oil heater and flare. Four emission estimation methods applied for the petroleum refinery process equipment are as follows: average emission factor approach, screening ranges approach, EPA correlation approach and unit-specific correlation approach. The process equipment for which emission factors are available are valves, pump seals, connectors, flanges and open-ended lines.

Air pollution from the Daegu industrial complex (DIC) in Korea has been a common nuisance and cause of complaints for nearby residents. The current study measured the indoor and outdoor levels of six VOC (benzene, toluene, ethylbenzene, and three isomeric xylenes) at two residential areas with a different proximity to the DDIC, plus the ambient levels at two industrial areas within the boundary of the DDIC. The QA/QC program included the range of correlation coefficient (0.94～0.99) for calibration curves, within the permissible range. Toluene was the most abundant VOC in the ambient air both in residential and industrial areas. Both indoor and outdoor air concentrations of all target VOC except benzene were higher in residential area near the DIC compared to that further away from the DIC. Moreover, the ambient air concentrations of all target VOC except benzene for two industrial sites (A and B) were significantly higher than the outdoor or indoor air concentrations in the two residential areas. The findings further suggested that VOC ambient levels measured in a residential area near the DIC be used as a potential indicator of odor-causing unidentified air pollutants transported from the DIC. Moreover, it was found that the elevated ambient toluene levels outweighed the indoor sources with respect to the environmental exposure of residents nearby the DIC. However, in the residential area further away from the DIC, the toluene indoor sources outweighed the outdoor sources.

본 논문에서는 유역과 강우특성을 통합하여 오염물질 부하량을 계산할 수 있는 접근방법을 제시하였다. 이 기법의 기본적인 개념은 특정유역에서 강우시 발생하는 오염물질의 유량 가중평균 농도, 즉 EMC 변화는 오로지 강우패턴에 의해 결정된다는 가정에 기초하고 있다. 이러한 가정은 적어도 유역의 토지이용에 급격한 변화가 없고(적어도 강우가 집중되는 경작기간동안) 점 오염원이 적은 농촌유역에서는 타당하다. 따라서, 다양한 농촌유역과 강우 패턴 조건에서 조사된 많

하천에 오염물질이 순간적으로 유입된 경우에는 연속적인 유입의 경우와 다르게 분산계수의 변화에 따라 오염물질의 거동 특성이 민감하게 변한다. 하천에 순간적으로 유입된 오염물질의 거동특성을 분석하기 위하여 한강하류부에서 수리인자 및 수질인자를 실측하였다. 분산계수 추정에 사용되는 경험식에 실측된 수리인자를 적용하여 갈수시 한강하류부의 분산계수의 규모를 분석하고, 적용 가능성이 큰 경험식을 제시하였다 또한, 실측된 수질인자를 RMA-4 모형의 계산치와 비교하

In this study, the material cycle model was applied to suggest alternative management of water quality for Jeju Harbor. The distribution of COD, DIN (dissolved inorganic nitrogen) and DIP (dissolved inorganic phosphorus) concentrations was reasonably reproduced by simulations on the model area of the Jeju Harbor using a material cycle model. The simulations of COD, DIN and DIP concentrations were performed under the conditions of 20～100% pollution loadings reductions from pollution sources. In case of the 100% reduction of the input loads from Sanzi river, concentrations of COD, DIN and DIP were reduced to 39%, 78% and 52%, respectively at Jeju harbor. In contrast, in case of the pollutant loadings reductions from sediment, the effect of DIN and DIP reduction relatively seemed to increase around the center of study area. The 95% reduction of the pollutant loadings from river and sediment is required to meet the COD and nutrients concentration of second grade of ocean water quality criteria.

The purpose of this study is to investigate the characteristics of water quality in Jeju harbor and to estimate pollutant loadings discharged into Jeju Harbor. To know characteristics of water quality in Jeju harbor and pollutant loadings of Sanzi river, we have investigated from August, 2000 to May, 2001. The results showed that the concentrations of COD, DIN and DIP were in the range of 1.00～4.85㎎/L (mean 2.15㎎/L), 2.14～74.0㎍-at/L(mean 12.20㎍-at/L) and 0.52～4.00㎍-at/L(mean 1.18㎍-at/L), respectively. These values were under Ⅲ class of seawater quality criteria. The ratio of nitrogen to phosphorus was lower than 16 except for Station 1 in Jeju harbor. Therefore, nitrogen was playing an important role in phytoplankton growth as limiting factor in Jeju harbor. The mean values of eutrophication index were exceeding 1, which was the eutrophication criteria. The results of estimating pollutant loadings at Sanzi river are 0.30 ton/day for COD, 300㎏/day for DIN and 18.0㎏/day for DIP, respectively.