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        검색결과 119

        41.
        2020.10 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/cm3, which is 0.017 g/cm3 less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.
        4,200원
        45.
        2020.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        The composite PAN fibers which incorporated with CNTs and Titania were prepared by mean of wet spinning. These fibers were then pre-oxidized with microwave heating in an air atmosphere. A combination of characterizations was carried out to study the impact of nanoparticles fillers on the properties of as-spun fibers and their performance during the microwave pre-oxidation. The addition of an equal amount of fillers made obvious changes in the chemical and crystalline structure, consequently improves the strength, and this could lower the capability to creep over a wide range of temperatures in the subsequent processes. FTIR and NMR analyses results of the pre-oxidized fibers exhibited clear changes in the PAN structure, where the dehydrogenation reaction and the degree of cyclization were investigated. Additional confirmation of the occurrence of cyclization reaction was achieved by XRD and thermal analysis. According to the TGA results, the pre-oxidized CNT1/ Ti-PAN fibers exhibit greater thermal stability suggesting high carbon content and good quality could result in the dependent carbon fibers.
        4,200원
        46.
        2020.04 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구에서는 “이온젤” 이라고 불리는 고분자 기반의 PVA(polyvinyl alcohol) 기반의 고체 전 해질에 이온성 액체 BMIMBF4 (1-buthyl-3-methylimidazolium tetrafluoroborate)를 첨가하여 제조한 전 고체 전해질과 활성탄소와 금속유기골격체 복합재료 기반의 전극 재료를 이용하여 슈퍼커패시터를 제작 하였으며, 유기골격체의 유 무에 따른 전기화학적 특성을 분석하여 보았다. 슈퍼커패시터의 전기화학적 특 성은 순환전압전류법(CV), 전기화학적 임피던스 분광법(EIS) 및 전정류 충·방전법(GCD)을 통하여 비교 및 분석하여 보았다. 그 결과로, 금속유기골격체가 함유되지 않은 슈퍼커패시터의 전기용량값은 380 F/g 으로 확인 할 수 있었고, 이 값은 금속유기골격체를 첨가하였을 때 340 F/g로 감소하는 현상을 확인할 수 있었 다. 이러한 결과로 1 wt%의 금속유기골격체의 함유량은 전기화학적 특성 감소에 영향을 주는 것으로 사료 되며 이러한 결과를 바탕으로 금속유기골격체의 첨가량을 최적화 할 필요가 있다고 판단된다
        4,000원
        47.
        2020.02 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Commercial carbon fiber is sized with Bisphenol A type epoxy, a thermosetting resin, to prevent fiber damage due to friction during weaving and manufacturing processes. When the thermoplastic resin is used as the base material, the interface between the carbon fiber and the thermoplastic resin is very weak because the bonding force with the thermosetting resin is not good, which greatly affects the mechanical properties of the composite material. Therefore, in order to improve the mechanical properties of the thermoplastic composite material, a process of removing the epoxy sizing layer on the surface of the carbon fiber in a furnace is required. In this process, the physical properties of the carbon fiber are changed according to the change of carbon fiber heat treatment conditions. In this paper, the study was carried out to evaluate the tensile strength required for automobile parts by extrusion and injection of thermoplastic resin based carbon fiber composites. Depending on the heat treatment temperature and time of the carbon fiber was a slightly tensile strength of the carbon composite material occurs, the tensile strength of the carbon composite material with a 6 hour heat-treated carbon fiber was measured at 550 ℃ the highest to 93 MPa. When the heat treatment holding time is more than 6 hours or the heat treatment temperature is more than 600 ℃, it may be the damage to the carbon fiber, which can cause a decrease in the tensile strength of the carbon fiber composite material.
        4,000원
        48.
        2020.02 KCI 등재 구독 인증기관 무료, 개인회원 유료
        The reduced graphene oxide (rGO)/activated carbon (AC) composites are coated on the aluminum substrate using spray coating technique to fabricate nanocarbon-based supercapacitor. Polymer-based solid-state xanthan-gum/Na2SO4 electrolyte is also introduced to increase stability of the supercapacitor. The electrochemical properties of the supercapacitor are evaluated using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge/discharge tests. The highest capacitance value of the rGO/AC composite-based supercapacitor is 120 F/g. The rGO/AC composite-based supercapacitor has also retained ~ 85% of its initial capacitance value after 3000 galvanostatic charge/discharge cycles.
        4,000원
        49.
        2019.12 KCI 등재 구독 인증기관 무료, 개인회원 유료
        As carbon fibers have the high performance, such as high strength, light weight, and high corrosion resistance, they are gradually expanding and growing at various industries. In particular, this study was conducted to determine whether the market could be applied to street lanterns among the construction sectors expected to grow in scale. In this study, the material characteristics of street lanterns using carbon fiber composites were studied in order to determine whether carbon fiber composites could be applied as a substitute for stainless steel and cast iron street lanterns. The physical relationship was experimentally evaluated to obtain a suitable material through the comparison of physical properties of fiber composite materials.
        4,000원
        50.
        2019.12 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구에서는 구리 이온(Cu2+ ion) 제거를 위한 산화철(Fe3O4)/다공성 탄소 복합체를 합성하였으며, 이를 바탕으로 구리 이온 제거에 대한 특성 평가를 실시하였다. SEM, XRD 분석을 진행하여 수열합성(hydrothermal) 반응을 이용한 산화철/다공성 탄소 복합체의 형태와 구조를 확인하였다. BET 분석을 통해 비표면적과 기공 크기를 확인하였으며, UV-vis 장비를 통해 성능 평가를 실시하여 자성이 있는 Fe3O4와 다공성 탄소와의 시너지효과를 통해 액체 상태에서 존재하는 구리 이온을 제거할 수 있는 가능성을 제시하였다.
        4,000원
        55.
        2018.12 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구에서는 탄소나노튜브/화이버/폴리머 복합소재 구조에 대한 재료 물성 및 강성 추정을 다룬다. 수정된 Halpin-Tsai 모델을 적용한 멀티 스케일 해석은 탄소나노튜브의 함유량 비율, CNT 두께-길이 비율, 화이버 부피 함유량, 그리고 화이버 보강각도 변화에 따라서 수행되었다. 본 연구에서 제시한 멀티-스케일 접근방법은 기존 모델을 적용하여 얻은 결과와 비교하여 검증하였다. 매개변수 해석을 통하여 CNT의 적절한 함유량은 적층된 CNTFPC 구조의 구조성능의 향상시킬 수 있는 중요한 특성을 규명하였다.
        4,000원
        56.
        2018.11 구독 인증기관·개인회원 무료
        Carbon molecular sieve (CMS) membrane surpasses the upper-bound trade-off and plasticization phenomenon of polymer membrane. Recently, supported CMS membranes have been investigated to provide both high performance and mechanical strength. Herein, we have investigated the supported CMS hollow fiber membranes on low-cost alumina hollow fiber. To prepare the thin and uniform layers, the dip-coating parameters for intermediate and polymeric layers were varied in terms of the withdrawal rate and solution viscosity, respectively. Then, in order to confirm its feasibility in real industry, mixture gas was permeated through prepared CMS membranes. Moreover, the property of long-term stability was characterized in harsh conditions and further modified.
        57.
        2018.08 KCI 등재 SCOPUS 구독 인증기관 무료, 개인회원 유료
        Nickel oxide(NiO) thin films, nanorods, and carbon nanotube(CNT)/NiO core-shell nanorod structures are fabricated by sputtering Nickel at different deposition time on alumina substrates or single wall carbon nanotube templates followed by oxidation treatments at different temperatures, 400 and 700 oC. Structural analyses are carried out by scanning electron microscopy and x-ray diffraction. NiO thinfilm, nanorod and CNT/NiO core-shell nanorod structurals of the gas sensor structures are tested for detection of H2S gas. The NiO structures exhibit the highest response at 200 oC and high selectivity to H2S among other gases of NO, NH3, H2, CO, etc. The nanorod structures have a higher sensing performance than the thin films and carbon nanotube/NiO core-shell structures. The gold catalyst deposited on NiO nanorods further improve the sensing performance, particularly the recovery kinetics.
        4,000원
        58.
        2018.05 구독 인증기관·개인회원 무료
        본 연구에서는 해수를 유도용액으로 사용하고 하수처리수를 공급수로 사용하는 정삼투막 공정의 유기/바이오 오염물에 의한 막오염을 저감하기 위해 폴리도파민/탄소 나노 튜브 복합 분리막을 제작하였다. 분리막은 기존 계면중합반응에 탄소 나노 튜브를 첨가하여 초박형 복합 분리막을 제조한 후, 폴리도파민으로 코팅시켜 제조하였다. 제작 된 분리막은 알긴산나트륨(Sodium alginate)용액과 미생물(Pseudomonas aeruginosa PA01) 부착 실험을 통하여 수투과도와 막오염도를 평가하였다. 그 결과, 폴리도파민/탄소 나노 튜브 복합 분리막은 복합되지 않은 분리막에 비하여 높은 수투과도와 낮은 막오염 성능을 보였다.
        60.
        2018.04 구독 인증기관·개인회원 무료
        We carried out a dynamic instability assessment of carbon nanotube reinforced composite (CNTRC) and carbon nanotubes/fiber/polymer composite (CNTFPC) skew plates based on the high-order shear deformation plate theory (HSDT). The multiscale interactions between carbon nanotube (CNT) ratios and skew angles on the dynamic instability for various length-thickness ratios are studied using a two-dimensional finite element model developed for this study. The results were verified by those reported in the literature show the interactions between the CNT reinforcement and skew angles in the skew laminate. Numerical examples show the importance of CNT reinforcement when assessing the dynamic instability of CNTRC and CNTFPC skew plates.
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