본 연구는 안정동위원소 분석방법을 적용하여, 호소내 식물플랑크톤 성장에 영향을 미치는 외부 오염원의 기원을 추정함으로써, 효율적인 수질 관리 및 수생태계 기능해석을 제공하기 위하여 연구하였다. POC, PN, Chl. a, 탄소 안정동위원소비 및 질소 안정동위원소비의 자료로 유추해 보았을 때, 팔당댐, 남한강, 북한강 지역에 비해서 경안천 지역에서 계절에 따른 유기물의 기원 변동이 뚜렷하게 관찰되고 있다. 유입량 및 강우량이 많은 시기인 7, 8월경에 입자성 유기물의 기원이 자생기원 유기물보다는 외부기원 유기물이 높은 영향을 미치는 것으로 여겨진다. 한강 유역에서 입자성 유기물의 탄소 및 질소 안정동위원소비를 이용한 유기물 기원 연구는 적용가능 할 것으로 여겨지며, 추후 유역 오염원의 대표값(end member)의 지속적인 조사를 통하여 자료구축이 이루어져야 할 것이다.

해수와 담수가 공존하는 시화호 상류 기수역에서 입자성유기물에 대한 조류의 영향을 평가하기 위하여, 2005년과 2006년 3월부터 11월까지 기수역내 7개 지점을 대상으로 입자성유기탄소 (particulate organic carbon; POC), 식물플랑크톤 색소(chlorophyll a; Chl-a), pheophytin a; Pheo-a)의 시공간적 변동과 상관관계를 분석하였다. 조사기간 동안 POC 농도는 1.0~76.6 mg L-1 (평균 7.4 mg L-1)의 범위로 봄에 높은 계절변화를 보였으며, 염분성층이 강하고 고탁도층이 형성되는 중류부에서 높은 값을 보였다. 살아있는 식물플랑크톤의 현존량의 지표로 이용되는 Chl-a 농도는 1.3~942.9 μg L-1 (평균 71.0 μg L-1) 범위로 매우 높은 값을 보였고, 4월에 중류부에 최고치를 보여 POC와 유사한 변동을 보였다. 한편 Pheo-a 농도는 1.4~1,545.5 μg L-1 (평균 59.9μg L-1)의 범위로, total Chl-a의 평균 44.2%로 죽거나 활성을 잃은 식물플랑크톤의 양이 많은 것으로 나타났다. POC 농도는 식물플랑크톤 색소와 강한 양의 상관(Chla (r=0.93), total Chl-a (r=0.88), ¤Pheo-a (r=0.81))을 보였는데, 이는 시화호 기수역에서 식물플랑크톤이 POC의 중요한 기원임을 시사한다. 한편 식물플랑크톤 색소와 POC와의 회귀식으로부터 POC/Chl-a 비(82.9)보다 POC/total Chl-a 비(35.9)가 하구에서 조사된 POC/Chla 비(40~60)에 더 유사한 것으로 나타났다. 그러므로 시화호 기수역과 같이 Pheo-a 농도가 높은 수역에서는 조류기원성 POC를 산정하거나 또는 수체의 POC 농도에 대한 식물플랑크톤의 기여도를 평가할 때 Chl-a 농도와 함께 Pheo-a 농도도 함께 고려할 필요가 있다.

본 연구는 영산강하구역 입자물질 유입원의 시∙공간 적인 변화를 추정해 보고자 몽탄대교에서 영산강 하구둑 에 이르는 영산강하구역 세 정점에서 연 6회에 걸쳐 수 층 부유 물질의 탄소 및 질소 안정동위원소 비를 비교하 였다. 모든 정점에서 8월에 강우를 통한 외부기원 유기물 의 유입이 증가하였으며, 이 때 암모니아성 질소 및 규산 염의 유입 역시 함께 증가하였다. 탄소 안정동위원소 비 측정 결과 11월과 8월에 정점 별 유기물의 기원이 크게 차이 났으며, 안정동위원소 비 값을 이용하여 주요 유입 원 추정이 가능하였다. 11월에 모든 정점에서 질소 안정 동위원소 비가 무거운 값을 보였고, 인산염의 농도가 가 장 높게 나타났는데 이는 축산폐수 및 농경지를 통한 유 입이 영향을 준 것으로 판단된다. 또한 다른 정점에 비해 영산강 하구둑에서 모든 조사 기간 동안 비교적 높은 질 소 안정동위원소 비를 보였으며, 이를 통해 축산폐수 및 농경지를 통한 유기물 유입이 다른 정점에 비해 높을 것 으로 추정된다. 본 연구 결과를 통해 안정동위원소 비 분 석은 입자성유기물의 기원을 추정하는데 유용한 방법임 을 확인할 수 있었다.

It was investigated the state information for the atmospheric conditions around Dang-jin industrial complex in Chungnam area may be polluted by the constructing steel industrial complex. It is aimed at characterization of the fine particulate matter and other air pollutants involved in it. Samples were collected two sites for monitoring point representing steel industrial complex and one site which is placed a remote and secluded from this industrial complex, and the concentration of PM10, heavy metals, and ion components were analyzed. As a results, PM10 average concentration was 64.6㎍/㎥ for the adjacent site before Hyundai Steel Company, 70.5㎍/㎥ in Bugok immigration settlement complex, and 56.5㎍/㎥ for Jeonggok-ri contrastive point. The distribution of heavy metals was detected as very low level for all sampling points. According to the result of statistical evaluation for the heavy metal analysis, variation range of Cu, Mn, Ca, Fe, and Mg were significant higher than others. Also, the seasonal concentration change trend of heavy metals was remarkable strong in spring and low in summer because of instable meteorological phenomena such as yellow dust happened in spring. Monthly changing pattern of a sulphate ion has kept unusually high level for summer period different other components. Relationship among PM10, heavy metal, and ion component were analyzed that high positive correlation coefficient for PM10 between Fe, Mn, Pb, Ca, Mg, Cd, Al in order and PM10 between NO3-, Cl- successively. Accordingly, it is suggested that a present atmospheric conditions of the surrounding area of Dang-jin steel industrial complex is considered to be good level. Although air pollutants in emissions from their complex were below the existing emission limit, it is regarded that the systematic and continuous research is needed to preserve clean air through atmospheric monitoring, source tracing research, and citizen's surveillance for the fine particulate matter.

Recently Korean government introduced and strengthened the environmental polices to manage and enhance indoor air quality as a major assignment. As a result,“Indoor Air Quality Management Act”has been activated since May 2004. However, among many multi-usage facilities, the school environment has been excluded from such regulations. Thus, the purpose of this study is to survey indoor aerosol and CO2 concentrations in a university library which is one of major school facilities. Concentrations of PM10, PM2.5, and PM1 were intensively measured every 5 minute interval by means of a dust monitor with light-scattering principle. The mini-volume air samplers were used further to analyze inorganic elemental compositions of PM10 and to inter-compare with the dust monitor. Carbon dioxide was simultaneously monitored by a multi-gas monitor equipped with a non-dispersive infrared system. PM10 concentrations did not exceed the indoor air quality standard(150㎍/㎥) for all the sampling places. However, quick and steep increases of aerosol concentration were observed during the Asian Dust storm period. In addition, the concentration of PM10(74.1㎍/㎥) in the main university office was the highest among the entire sampling places. Although there was no specific pollution source in the library, the levels of aerosol and CO2 increased quickly due to various outdoor sources and human activities. The average CO2 concentration measured in three reading rooms, where ventilation was not fully operated, exceeded the indoor air quality standard of 1,000 ppm. Based on these case studies, effective management and reduction plans for indoor aerosol and CO2 were suggested for the large scale public buildings including university libraries.

2000년 춘계에 한국 농촌지역인 충남 서산에서 대기부유분진(SPM)과 곰팡이포자의 관계에 대해 조사하였다. 부유분진의 농도는 1차 황사기간(3월 23-24일)에 199.8μg m-3, 2차 황사기간(4월 7-9일)에 249.4μg m-3, 비황사기간(5월 12-6일)에 98.9μg m-3으로 각각 나타났다. 2회의 황사기간들간에 부유분진 농도는 차이를 보였지만 5μm 정도의 입경 크기를

This study analyzed the characteristics of high PM2.5 episodes that meets the concentration criteria of Emergency Reduction Measures Plan (ERMP) in Busan during the 2015-2020, and compared with those in Seoul. As a first step, the CAPSS-2017 emission data was employed to analyze the emission differences between Busan and Seoul, and pointed out that Busan emission included the dominance of ship emissions (37.7%) among total PM2.5 city emissions, whereas fugitive PM2,5 emission was the highest in Seoul. These emission characteristics are indicating that the controlling action plan should be uniquely applied to cope with ERMP in each region. We selected extremely high PM2.5 episode days that meet the criteria of ERMP levels. In Busan, Ulsan, and Gyeongnam region, 15, 16, and 8 days of extremely high PM2.5 cases were found, respectively, whereas Seoul showed approximately doubling of occurrences with 37 cases. However, the occurrences in summer season indicated big differences between two cities: the proportion of summer-season occurrence was 13-25% in Busan, whereas no single case have occurred in Seoul. This is suggesting the needs of comprehensive summer emission reduction plan with focusing on sulfur reduction to effectively cope with the ERMP levels in summer in the southeastern region, including Busan.

This study analyzes the effect of negative air ions on the concentration of airborne particulate matter and evaluates the expected purification efficiency of open spaces for particulate matter by investigating the amount of negative air ions generated by plants. This study establishes a negative air ion generation treatment environment, plant environment, and control environment to measure the purification efficiency of particulate matter under the conditions of each, analyzing the expected purification efficiency by designing a particulate matter purification model. Results show that the amount of generated negative air ion according to environment was negative air ion generation treatment environment > plant environment > control environment; this order also applies to the particulate matter purification efficiency. Moreover, it took 65 min for the negative ion generation treatment environment, 90 min for the plant environment, and 240 min for the control environment to reach the standard expected purification efficiency of particulate matter concentration of 960 mg/m³ for PM10. For PM2.5, with the designated maximum concentration of 700 mg/m³, it took 60 min for the negative ion generation treatment environment, 80 min for the plant environment, and more than 240 min for the control environment. Based on these results, the expected purification efficiency compared to the control environment was quadrupled in the negative ion generation treatment environment and tripled in the plant environment on average.

To understand the composition, quantity, and quality of Suspended Particulate Organic Matter (SPOM) in the Gangneung Namdae Stream, Korea, we examined spatiotemporal variations in water temperature, salinity, chlorophlly a (Chl a), Particulate Organic Carbon (POC) and nitrogen (PON), and carbon stable isotope (δ13C) of SPOM at six stations in June (pre-monsoon), July (monsoon), and September (post-monsoon) 2017. With increasing precipitation, the average POC and C/N values increased significantly in July than in June. In September, the values decreased with decreasing precipitation. The δ13C values showed irregular spatiotemporal fluctuations among the stations and periods, thereby suggesting a greater contribution of autochthonous organic matter to the pool of SPOM than that of allochthonous organic matter derived from upstream. In addition, the large and irregular changes in POC, C/N ratio, C:Chl a, and δ13C compared to that of PON were observed for all periods among the stations, indicating a serial discontinuity of the stream. Our results suggest that the Gangneung Namdae Stream is significantly influenced by the increase in freshwater discharge caused by heavy rainfalls during the summer monsoon and post-monsoon periods.

We analyzed the recent characteristics of Particulate Matter (PM) including PM10 (PM with diameter of less than 10μm) and PM2.5 (PM with diameter of less than 2.5μm) observed in Busan metropolitan area, and compared them with those measured in Seoul metropolitan area. This analysis includes the monthly, seasonal, and annual variations and differences, in emissions and chemical compositions observed in both Busan and Seoul areas. Synoptic meteorological conditions were investigated at the time when high PM concentrations occurred in each of the two areas. The results showed clearly decreasing trends of annual mean concentrations with strong seasonal variations: lower in summer and higher in winter in both areas. In comparison with Seoul, the seasonal variation in Busan demonstrated relatively lower, but showed greater summer fluctuations than in Seoul metropolitan area. This is implying the importance of secondary generation of PM in summer via active photochemical reaction in Busan area. In high concentration days, Busan’s chemical composition of sulfate was higher than that of nitrate in summer, whereas nitrate was higher than sulfate in Seoul. The ratios of NO3 - to SO4 2-(N/S ratio) showed lower in Busan approximately by a factor of 1/2(half of N/S ratio) in Busan compared with that in Seoul. Others such as synoptic characteristics and emission differences were also discussed in this study.

미세먼지 대응기술이 종전의 관리용이성(PM10, 1차 배출) 중심에서 위해성(PM2.5, 2차 생성) 중심으로 패러다임이 전환된 현시점에서, 입자상 물질뿐만 아니라 초미세먼지 2차 생성 전구물질인 질소산화물(NOx) 제거를 통하여 대기오염을 극복할 수 있는 방안이 사회적으로 요구되고 있는 실정이다. 이에 본 연구에서는 도로이동오염원에서 배출되는 질소 산화물을 효율적으로 제거하기 위한 방안으로 미세먼지 전구체 저감 소재를 도로 및 도로변에 설치되어 있는 기존 콘크리트 구조물에 고정화하기 위한 기초연구를 진행하였다.

직경 10 μm 미만의 대기 미립자 물질(particulate matter, PM10)은 다양한 신체기관에서 산화 스트레 스와 염증반응을 유발한다. 본 연구의 목적은 인간 표피 각질형성세포(HEK)에서 PM10에 의해 유도되는 반응 성 산소종(ROS) 생성의 메커니즘을 알아보는 것이다. 배양된 HEK를 PM10에 노출시켰을 때 ROS가 증가하였으며, 이는 항산화제 apocynin에 의해 저해되었다. PM10에 의해 유도되는 ROS 생성에서 NADPH oxidase (NOX) family의 역할을 규명하기 위하여 이들의 mRNA 발현을 분석하였다. PM10은 NOX1, NOX2, dual oxidase (DUOX)1 및 DUOX2의 mRNA 발현을 증가시켰다. 다른 NOX들에 비교하여 DUOX1 및 DUOX2의 발현 수준이 높았으며, 이들 효소의 maturation factors, 즉 DUOXA1와 DUOXA2의 mRNA 발현도 PM10에 의하여 증가하였다. 칼슘 의존성 효소인 DUOX1과 DUOX2가 PM10에 의해 유도되는 ROS의 생성을 매개하는 지 조사하였다. 선택적인 세포내 칼슘 킬레이터인 BAPTA-AM은 PM10 및 칼슘 ionophore A23187에 유도된 ROS 생성을 감소시켰다. 작은 간섭 RNA (siRNA)에 의한 DUOX2의 하향 조절은 PM10에 의해 유도된 ROS의 생성을 감소시켰고 DUOX1 siRNA는 영향이 없었다. PM10은 interleukin (IL)-1β, IL-6, IL-8 및 interferon (IFN)-γ 등 사이토카인의 발현을 증가시켰다. siRNA에 의한 DUOX2의 하향 조절은 IFN-γ의 발현을 저해하였지만 다른 사이토카인의 발현은 저해하지 않았다. 본 연구는 PM10에 노출된 HEK의 ROS 생성 및 염증 반응에서 DUOX2가 중요한 역할을 함을 시사한다.

대기 오염은 피부의 산화적 손상, 염증 및 노화를 일으킬 수 있다. 레스베라트롤은 폴리페놀 화합물의 일종으로 항산화, 항염증, 멜라닌 생성 억제 작용 등 다양한 생물학적 활성이 있는 한편 열과 빛에 약한 단점이 있다. 레스베라트릴 트라이아세테이트(RTA)는 레스베라트롤에 비해 안정하고, 피부 안전성과 미백 효능이 보고된 화장품 신소재이다. 본 연구의 목적은 직경 10 μ m 미만 대기 미립자 물질(PM10)에 노출된 인간 표피 각질형성세포(HEK)의 염증 반응에 대한 레스베라트롤과 RTA의 영향을 조사하기 위한 것이다. 배양된 HEK세 포를 레스베라트롤과 RTA의 유무 조건에서 PM10에 노출시키고, 세포 생존율, 반응성 산소종(ROS)의 생성 및 염증성 사이토카인의 발현을 분석하였다. PM10을 처리하였을 때 세포 생존율이 감소하였고 종양괴사인자- α(TNF-α), 인터루킨-1β(IL-1β), 인터루킨-6(IL-6) 및 인터루킨-8(IL-8)의 발현이 증가하였다. 레 스베라트롤과 RTA는 PM10으로 유도된 세포의 사멸과 ROS 생성을 경감시켰다. PM10에 의해 증가되는 여러 염증성 사이토카인의 발현은 레스베라트롤과 RTA에 의해 경감되거나(IL-6), 증진되거나(IL-1β), 변화하지 않았다(TNF-α 및 IL-8). PM10에 의해 유도된 IL-6단백질의 발현이 레스베라트롤과 RTA에 의해 감소되 었다. 본 연구의 결과는 레스베라트롤과 RTA가 대기 미립자 물질에 노출된 피부의 세포 손상과 염증 반응을 조절하는 작용이 있음을 시사한다.

This study observed particulate matter (PM2.5 and PM10) in the downtown area of Jeju City, South Korea, to understand the chemical composition of particulates based on an analysis of the water-soluble ionic species contained in the particles. The mass fraction of the ionic species in the sampled PM10 and PM2.5 was 44.3% and 42.2%, respectively. In contrast, in Daegu City and Suwon City, the mass fraction of the ionic species in PM2.5 was higher than that in PM10. The chloride depletion percentage of PM10 and PM2.5 in Jeju City was higher than 61% and 66%, respectively. The contribution of sea-salt to the mass of PM10 (5.9%) and PM2.5 (2.6%) in Jeju City was similar to that in several coastal regions of South Korea. The mass ratio of Cl- to Na+ in the downtown area of Jeju City was comparable to that in some coastal regions, such as the Gosan Area of Jeju Island, Deokjeok Island, and Taean City. The mass fraction of sea-salt in PM10 and PM2.5 was very low, and the concentration of sodium and chloride ions in PM10 was not correlated with those in PM2.5 (R2 < 0.2), suggesting that the effects of sea-salt on the formation of particulate matter in Jeju City might be insignificant. The relationship between NH4 + and several anions such as SO4 2-, NO3 -, and Cl-, as well as the relationship between the measurement and calculation of ammonium ion concentration, suggested that sea-salts may not react with H2SO4, and (NH4)2SO4 may be a major secondary inorganic aerosol component of PM2.5 and PM10 in Jeju City.

This study was carried out to provide preliminary information to grasp how many particulate matter (PM) which is a problem in urban area are absorbed and removed by street trees. The morphology, size and element composition of PM deposited on leaves of five street trees (Quercus glauca, Q. myrsinaefolia, Ginkgo biloba, Prunus serrulata var. spontanea, and Pinus densiflora) in Jinju city, South Korea were analyzed. The size of PM was classified into three as PM2.5 (0.2~2.5 μm), PM10 (2.5~10 μm), and PM100 (10~100 μm). The element composition of PM deposited on the leaves at the study sites mainly comprised of O, C, N, Si, and Al. The PM at industrial area and university campus was irregular and spherical shape, respectively. Total PM accumulated on the leaf surfaces of P. densiflora was 71.65 μg/cm² at industrial area and 40.66 μg/cm² at university campus, which was significantly higher than the other species. The ratio of PM2.5, PM10, and PM100 deposited on the leaves was 9.2%, 37.0%, 53.8% at industrial area and 15.8%, 27.1%, 57.1% at university campus, respectively. P. densiflora deposited the most PM2.5, PM10 and PM100 in leaf wax at the study sites, which was significantly higher than the other species.

Background: Small particles increase airway inflammation upon reaching the alveoli. Here, we investigated the protective or therapeutic effects of Salvia plebeia R. Br. (SP_R) extracts on airway inflammation. Methods and Results: To investigate the anti-inflammatory activity of SP_R extracts, we measured their inhibitory effect on the production of reactive oxygen species (ROS) expression of inflammatory mediators, and immune cell infiltration in MH-S alveolar macrophage cells and in the ambient particulate matter (APM)-exposed airway inflammation mice model. The SP_R extracts inhibited the production of ROS and expression of IL-4, IL-10, IL-15, and IL-17A mRNA in APM-stimulated MH-S cells. Oral administration of SP_R extracts suppressed APM-induced inflammatory symptoms, such as high alveolar wall thickness, excess collagen fibers, decreased mRNA expression of chemokines (Ccr9, Ccl5, Ccr3), inflammatory cytokines (IL-15, TNF-α), and IL-4 Th2 cytokine in the lung. The SP_R extracts also inhibited ROS production, granulocyte (CD11b+Gr-1+) infiltration, IL-17A, TNF-α, macrophage inflammatory protein (Mip-2), and chemokine (C-X-C motif) ligand 1 (Cxcl-1) production in the airway. The specific compounds in the SR-R extracts that mediate the anti-inflammatory effects were identified. Conclusions: In this study, SP_R extracts effectively inhibited airway inflammatory responses, such as ROS production and granulocyte infiltration into the airway, by regulating the expression of chemokines and inflammatory cytokines.

This study was carried out to elucidate the chemical compositions of water-soluble inorganic ions in PM10 and PM2.5 aerosols collected during summer and winter in downtown Jejusi city. The ratios of NO3 - to the total mass of ionic species in PM10 and PM2.5 aerosols largely increase in winter compared to summer, while SO4 2- ratios in both aerosols appear to follow the opposite trend. Moreover, concentrations of Na+, Mg2+, Ca2+ and Cl- in PM10 and PM2.5-10 aerosols are higher in winter than in summer. The nitrate concentrations in PM10 and PM2.5 aerosols increase with an identical increase in excess ammonium during winter, however, nitrate formation during summer is not important owing to ammonium-poor conditions.