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        검색결과 116

        82.
        2018.09 KCI 등재 서비스 종료(열람 제한)
        The volatile odor compounds emitted form a stuffing agent production process were quantified by ATD and GC-MS, and then odor causing compounds were identified by the method of EOI using each TLV. As the results, 72 odor compounds were detected and total concentration was turned up 87.6 ppmv level. In these compounds, aldehyde group is higher 45.49 ppmv than others group, the next is turn up the order of aliphatics, alcohols, esters, ketones. The EOA of aldehyde group show up 101,720 and 97.2%, respectively, the odor causing compounds were identified each of odor 2-Octenal 28.31%, Hexanal 24.06%, Valeraldehyde 16.07%, Butyraldehyde 9.69%, Heptanal 4.97%, Propionaldehyde 4.64%, Acetaldehyde 3.31%. The TLVs of 7 major odor compounds are lower value level of 0.001∼0.0001 ppmv, odor causing even in trace level. We need to be concerned with reduction of aldehyde compounds in the odor problem by a stuffing agent production process or ironing process of the textile containing a stuffing agent.
        83.
        2016.09 KCI 등재 서비스 종료(열람 제한)
        The purpose of this study was to obtain the basic data needed to identify the impact of the odor, emitted from the Ochang Scientific Industrial Complex area on the surrounding residential areas by measuring and confirming odor compounds. The analysis showed that complex odors were diluted from around 4 to 1. The offensive odor measurement results showed that among the sites, site 1 was highest in sulfur compounds, site 2 was highest in toluene, site 3 was highest in trimethylamine, and site 4 was highest in buthylaldehyde. It cannot be decided to be odor-causing compounds for higher odor concentration because each odor substance has a different odor threshold value. According to the odor contribution analysis for each site, site 1, site 2, and site 4 contained high buthylaldehyde concentrations, and site 3 had a high level of trimethylamine. It could be determined that highly evaluated substances were main causes to result in substance for each site.
        84.
        2016.04 KCI 등재 서비스 종료(열람 제한)
        In this study, GC-MS linked with an automatic thermal desorber was used to quantitatively analyze the odorous and volatile compounds in the gas emitted from a sewage sludge drying facility. In addition, the removal characteristics of these compounds were investigated by using a pilot-scale packed bed wet scrubber. A quantitative analysis for 58 odorous and volatile compounds in the gas was successfully achieved with GC-MS and GC-FPD. The a quantitative analysis revealed the major odorous compounds were hydrogen sulfide and acetaldehyde. In addition, D-type siloxane compounds such as octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6), were quantitatively measured. The concentrations of siloxane compounds measured in the gas were in the range of 4.54- 7.36 ppmv, higher than those in landfill gas. The average removal efficiency of the odorous and volatile compounds in a wet scrubber was 67.37%. D4, D5, and D6, which are hydrophobic compounds, were also removed by as much as 50.68%, 44.56%, and 70.26%, respectively.
        85.
        2015.11 서비스 종료(열람 제한)
        우리나라에서는 매몰지 가축사체의 유기물 분해 특성, 침출수 처리, 지하수, 토양의 환경영향, 악취물질, 발생가스, 사체 분해정도 등 신뢰성 있는 자료 확보가 필요한 실정이다. 또한, 가축 매몰지로 인한 2차 환경오염 발생 가능성에 대한 언론 및 국회에서의 문제제기 등 환경영향 저감 방안 필요성, 가축 매몰지의 사체분해와 관련된 ‘용도제한 3년’ 의 적정성 여부, 매몰지 조기안정화를 위한 국내의 환경적 특성에 맞는 자료의 확보, 매몰지 사후관리계획 수립을 위한 안정화 방안, 매몰지 설계 및 환경관리지침 개선, 악취조사항목 설정을 위해 자료 확보가 필요하다. 이에 본 연구에서는 돼지와 소의 사체를 매몰하여 우리나라에서 가장 넓게 분포되어 있는 사양질 토양과 식양질, 사질 토성별로 파일럿 규모 가축 매몰지 5기를 연구단지내 설치하여 약 3년(2012.2∼2015.2) 동안 매몰사체의 발생가스 농도변화, 악취물질 등을 조사하여 악취조사항목 설정 등 가축 매몰지역 환경조사지침 등 개선방안을 제시하고 구제역으로 인한 소와 돼지의 살처분 매몰지에서 시간 경과와 매몰지 토양의 성상에 따라 어떤 악취물질이 발생하는지, 발생농도는 어느 정도인지 모니터링하여 향후에 발생할 수 있는 민원발생에 대비하기 위한 기초자료를 제시하고자 한다. 분석결과에서는 토양특성과 매몰 가축의 종류에 따라 배출되는 악취물질의 농도가 뚜렷한 경향을 나타내지 않았다. 대부분의 지점에서 Sulfurs(5종)의 농도가 높았으며, 다음으로는 Ketones(7종), Aromatics(4종), Aldehydes(5종), Alchols(8종) 순으로 검출되었다. 이후 시간이 지남에 따라 후기 시료에서는 Sulfurs(5종)의 농도가 급격히 증가하여 조사 대상시료 전체농도의 90% 이상을 차지하는 것으로 나타났다.
        86.
        2014.11 KCI 등재 서비스 종료(열람 제한)
        Increasing public concerns over odors and air regulations necessitates the remediation of a wide range of odor substances for industrial and indoor purpose. Currently, the wet scrubbing technique by neutralization using oils is being used to treat odor substances such as Ammonia(NH3), Methyl Mercaptan(CH3SH), Hydrogen Sulfide(H2S), Methylamine(CH3NH2), Acetaldehyde(CH3CHO). The chemical analysis is performed to analyze the composition of an Arctium Lappa Root extract by VOC analyzer(Phocheck 5000Ex, ION SCIENCE co.) The objectives of the this study are to clarify the possibility of the neutralization of odors sprayed in the fixed bed and determine the removal efficiencies for different input odor concentrations. It is found that Ammonia(NH3), Methyl Mercaptan(CH3SH), Hydrogen Sulfide(H2S), Methylamine(CH3NH2), Acetaldehyde(CH3CHO) are significantly removed and their removal efficiencies are higher than 98%. The kitchen detergent with Arctium Lappa Root extract showed excellent removal efficiencies of odor substances and high possibility for the development of kitchen detergent with odor removal.
        87.
        2014.09 KCI 등재 서비스 종료(열람 제한)
        Odor control technology include absorption, adsorption, incineration and biological treatments. But, most of processes have some problems such as secondary organic acids discharge at the final odor treatment facility. In order to solve the problems for effective treatment of organic acids in odor, it is necessary to develop a new type advanced odor control technology. Some of the technology are plasma only process and plasma hybrid process as key process of the advanced technology. In this study, odor removal performance was compared DBD(Dielectric Barrier Discharge)plasma process with PCHP(plasma catalysis hybrid process) by gaseous ammonia, formaldehyde and acetic acid. Plasma only process by acetic acid obtained higher treatment efficiency above 90%, and PCHP reached its efficiency up to 96%. Acetic acid is relatively easy pollutant to control its concentration other than sulfur and nitrogen odor compounds, because it has tendency to react with water quickly. To test of the performance of DBD plasma process by applied voltage, the tests were conducted to find the dependence of experimental conditions of the applied voltage at 13 kV and 15 kV separately. With an applied voltage at 15 kV, the treatment efficiency was achieved to more higher than 13 kV from 83% to 99% on ammonia, formaldehyde and acetic acid. It seems to the odor treatment efficiency depends on the applied voltage, temperature, humidity and chemical bonding of odors.
        88.
        2012.07 KCI 등재 서비스 종료(열람 제한)
        Emission characteristics of gaseous odor compounds emitted from the charcoal manufacturing process were investigated, and evaluated the odor removal efficiency of odor control devices. It was found that the measured odor dilution ratio of emission gases ranged from 10,000 to 44,814, which exceed largely the emission standard in the stack. Methylmercaptan, trimethylamine, hydrogen sulfide, acetaldehyde were turned out as major odor compounds of the charcoal manufacturing process. It was revealed that the odor removal ratio of odor control devices were very low due to the its improper maintenance and wrong design.
        89.
        2012.01 KCI 등재 서비스 종료(열람 제한)
        In this study, the characteristic of offensive major odorous compound from the Bon-San industrial complex in Gimhae were determined by analytical methods of Gas Chromatography, High Performance Liquid Chromatography and UV/VIS Spectrophotometer. The kind of major odorous compounds examined acetaldehyde, sulfur compounds, ammonia and styrene. The concentration of all odorous compounds at 3 sampling points of industrial complex were lower than those of regulation standard levels of the industrial complex in Korea. The mean concentration of hydrogen sulfide was 0.0235 ppm at sampling point 2, it was higher than other sampling point. Complex odors was lower than regulation standard levels of the industrial complex in Korea.
        90.
        2011.08 KCI 등재 서비스 종료(열람 제한)
        The covered stream of cities are considered an odor source. Also, the public do not want a wastewater treatment plant(WWTP) near their properties due to the emission of odor emanating from such sources, although they play an important role in urban development. The purpose of this study is to analyze the pattern distribution of the odorous compounds from the Nambu WWTP and Youngho stream in Busan. odor sampled four times were analyzed by instrumental analysis method and indirect olfactory method. The kinds of offensive odorous compounds examined are acetaldehyde, propion aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and ammonia. Also, Concentration of air pollutants has been calculated by ISCST3 models. At the result of this study, The Nambu WWTP releases sulfur compounds. And the major odorous were hydrogen sulfide (1,475 ppb) and acetaldehyde (95 ppb) at Youngho stream. The stink which residents feel will point out the Nambu WWTP mainly if the odor is removed with the improvement of a Youngho stream. Accordingly, we should pay more attention to appropriate components to processes in odor reducing plan at Nambu WWTP.
        95.
        2009.10 KCI 등재 서비스 종료(열람 제한)
        In this study, the environmental behavior of malodor pollutants (MPs: H2S, CH3SH, DMS, and DMDS) was investigated around areas influenced by strong anthropogenic processes based on observations and modeling study (a CALPUFF dispersion model). The MP emission concentrations were measured from 8 industrial source regions (tire plants (S1-S3), waste water disposal plant (S4), and oil refinery (S5) in an urban center area and paper mill/incineration plant (S6) and livestock feedlots (S7-S8) in Ungsang area) in Yangsan city during a fall period in 2008 (21 October 2008). Overall, the most MPs emitted from the urban center area were found to affect the malodor pollution in their downwind areas during early morning (06:00 LST) and nighttime (18:00 and 21:00 LST), compared with those in the Ungsang area. For malodor intensity, the most MPs in the urban center area (especially S1 and S2) were found to be a significant contributor, whereas CH3SH and H2S in the Ungsnag area (especially S6) were the dominant contributor. The model study showed agreement in the spatial distributions of simulated MPs with those of the observations. The largest impact of MPs in the urban center area on the malodor pollution in its residential areas occurred at S1, S2, and S3 sites during nighttime, while that of MPs in the Ungsang area occurred at S6 and S8 sites. This may be caused mainly by the high MP emissions and in part by wind conditions (prevailing northeasterly winds with low wind speeds of 2-3 m/s).
        97.
        2007.01 KCI 등재 서비스 종료(열람 제한)
        The concentrations of offensive odorous compounds emitted from the two chemical plants in Chongju and Yeosu industrial complex in Korea were determined by uv/vis spectroscopy, gas chromatography, and high performance liquid chromatography. The odorous compounds examined in this study are ammonia, trimethyl amine, formaldehyde, acetaldehyde, propion aldehyde, butyl aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide. The concentrations of those were determined from the 10 sampling points of the two plants, respectively. The emission concentrations of all odorous compounds examined in the two plants were lower than those of the regulation standard levels of industrial complex in Korea, respectively. The propion aldehyde, n-valeric aldehyde, methyl mercaptan and dimethyl disulfide in Chongju and Yeosu plants, and butyl aldehyde and iso-valeric aldehyde in Yeosu plant were not detected at any sampling points examined.
        98.
        2007.01 KCI 등재 서비스 종료(열람 제한)
        In this study, the concentrations of offensive odorous compounds seasonally emitted from the chemical plant at Chongju industrial complex in Korea were determined by the analytical methods of gas chromatography, high performance liquid chromatography and uv/vis spectroscopy. The kinds of offensive odorous compounds examined are formaldehyde, acetaldehyde, butyl aldehyde, propion aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide, dimethyl disulfide, trimethyl amine and ammonia. The seasonally emission levels of all odorous compounds except dimethyl sulfide at 13 sampling points of plant were lower than those of the regulation standard levels of the industrial complex in Korea. The levels were the highest in June, and lowest in December. The propion aldehyde and iso-valeric aldehyde in June and December, butyl aldehyde in December, and n-valeric aldehyde were not detected in all the three seasons at any sampling points of the plant examined. But in June, dimethyl sulfide was emitted up to 16 times than that of the regulation level.
        99.
        2006.06 KCI 등재 서비스 종료(열람 제한)
        It was compared the reduction effect of contaminants and odor according to DO change and EM (effective microorganisms) addition in maturation process of piggery slurry. The maturation processes were divided into three cases as follows: R-1 was operated at 2.5 mg/ℓ of DO without the addition of EM, R-2 was operated at 7.5 mg/ℓ of DO without the addition of EM and R-3 was operated at 2.5 mg/ℓ of DO with the addition of EM. The addition of EM was more effective than the increase of DO for the reduction of CODcr, NH3-N and T-N in the maturation of piggery slurry. In addition, the reducing effect of odor intensity appeared high even in the short-term maturation period in case of adding EM and one could not even smell the stimulating odor of piggery slurry.
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