A semi-natural composite of κ-carrageenan and bentonite, two natural biopolymers, was synthesized through free radical polymerization. This synthesis aimed to obtain a biodegradable, biocompatible, and swellable composite that is environmentally friendly. The components used in this synthesis are readily available, making it economically feasible and promising for potential biomedical applications. The composite is pH-responsive and intended for oral delivery of metformin hydrochloride and aminophylline, which have low bioavailability and undesirable side effects, respectively. The organic composite exhibits the advantage of reducing drug release in the acidic gastric medium. This composite is a stimuli-responsive polymeric material that has garnered significant attention in recent years for its application in oral drug delivery systems. These materials enable site-specific and controlled drug release while minimizing toxicity. The carrageenan-g-poly(acrylamide-co-acrylic acid)/bentonite composite was characterized using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), and field emission scanning electron microscopy (FE-SEM), which confirmed the successful synthesis of the composite. The swelling behaviour and point of zero charge of the composite were studied at different pH values, which showed a strong influence on the swelling properties of the composite. The drug loading capacity of the composite was measured at pH 5.3, and it was 70.60 mg/g for metformin and 95.66 mg/g for aminophylline at pH(3). The in vitro release profile of both drugs from the composite was also affected by the ionic strength, and it exhibited a lower release rate with higher salt concentration. The maximum release percentage of the drugs from carrageenan-g-poly(acrylic acid-acrylamide)/bentonite in simulated gastric, intestinal, and colon fluids was achieved within 40 h. The maximum release was 80% for metformin in simulated intestinal fluid (SIF) and 75% for aminophylline after 40 h.

PURPOSES : The wedge-type anchorage system requires a complex analysis of not only the tensile stress of the CFRP plate, but also the compressive stress and shear stress generated by the wedge action. The purpose of this study is to find a composite material failure theory that is suitable for analyzing the behavior of wedge-type anchorage system among various failure theories. METHODS : In this study, numerical analysis of various composite material failure theories was performed to analyze the anchorage strength and failure mode of the wedge-type anchorage system according to each failure theory, and compared with actual test results to determine the composite material failure theory most suitable for analyzing the behavior of a wedge-type anchorage system. RESULTS : Since the Maximum Stress failure theory shows similar results to the actual test in terms of failure mode and anchorage strength, there is no significant problem in applying it to the wedge-type anchorage system. However, it is judged to be difficult to apply under property conditions where interactions between stresses are highlighted. The Tsai-Hill and Tsai-Wu failure theories are considered unsuitable for application to wedge-type anchorage systems because the wedge angle conditions at which the most advantageous anchorage strength occurs are significantly different from other theories and the fracture type cannot be predicted. The Hashin-Rotem failure theory is considered to be the most appropriate to apply as a failure theory for the wedge-shaped anchorage system because the anchorage strength was slightly lower than the actual test results, but there was no significant difference, and the failure mode was consistent with the test results. The Hashin failure theory is judged to be unsuitable for application as a failure theory for the wedge-type anchorage system because the anchorage strength and failure mode were interpreted differently from the actual test results. CONCLUSIONS : The Hashin-Rotem failure theory was presented as the composite material failure theory most suitable for analyzing the behavior of wedge-type anchorage system.

강진에 대한 다양한 비선형 거동을 하는 부재요소들로 이루어진 교량시스템의 현재까지의 일반적인 지진취약도 평가방법은 부재- 수준에서 평가하는 것이다. 본 연구의 목적 부재-수준의 지진취약도 평가결과로부터 구조시스템을 대표하는 시스템-수준의 지진취 약도 평가방법을 개발하는 것이다. 교량의 지진 거동을 일반적으로 교축방향과 교축직각방향으로 구분하기 때문에 본 연구에서도 시 스템-수준 지진취약도를 두 방향에 대하여 구분해 평가하였다. 길이 방향에 대한 부재-수준의 지진취약도평가는 교각, 교량받침, 충 돌, 교대, 낙교에 대하여 수행하였다. 교축직각 방향에 대해서는 충돌, 교대, 낙교의 손상이 영향을 주지 않으므로 부재-수준의 지진취 약도평가는 교각과 교량받침에 대하여만 수행하였다. 다양한 구조부재의 비선형모델을 이용한 지진해석은 OpenSEES 프로그램을 사용하여 수행하였다. 시스템-수준의 지진취약도는 부재-수준 사이의 손상이 직렬연결이라고 가정하고 평가하였다. 교각의 손상이 다른 부재-수준의 손상보다 시스템-수준의 지진취약도에 지배적인 영향을 주는 것을 알 수 있었다. 다시 말하면 가장 취약한 부재-수 준의 지진취약도가 시스템-수준의 지진취약도에 가장 지배적인 영향을 주는 것을 의미한다.

Most of the wastes generated when dismantling nuclear power plant were contaminated with lowlevel radioactive materials, therefore, applying a plasma melting system is a good option to dispose of the complex wastes safely. Melting system with plasma technology was developed to dispose single metal or composite objects. Its purpose is to secure final emissions satisfying final treatment conditions by controlling oxidization/ reduction reaction condition in detail during the melting process. A hollow plasma torch applied at plasma melting system could be operated with various plasmaforming gasses such as N2, Air, Ar, O2, and etc. The melting furnace was designed based on a double sealing structure to prevent risk factors; such as leaks, etc. in the reaction condition. The effect of the external air inflow on the melting conditions was minimized by carefully designing the object input device, torch mounting part, final object discharge part, etc.

This paper presents the effect on the inelastic behavior and structural performance of concrete and filled steel pipe through a numerical method for reliable judgment under various load conditions of the CJS composite structural system. Variable values optimized for the CJS synthetic structural system and the effects of multiple variables used for finite element analysis to present analytical modeling were compared and analyzed with experimental results. The Winfrith concrete model was used as a concrete material model that describes the confinement effect well, and the concrete structure was modeled with solid elements. Through geometric analysis of shell and solid elements, rectangular steel pipe columns and steel elements were modeled as shell elements. In addition, the slip behavior of the joint between the concrete column and the rectangular steel pipe was described using the Surface-to-Surface function. After finite element analysis modeling, simulation was performed for cyclic loading after assuming that the lower part of the foundation was a pin in the same way as in the experiment. The analysis model was verified by comparing the calculated analysis results with the experimental results, focusing on initial stiffness, maximum strength, and energy dissipation capability.

The connection of the steel structure serves to transmit external forces to the main components. The same is true for the behavior of modular systems composed mainly of steel or composite members. In this study, the joint performance of the composite and steel modules proposed was evaluated. The analytical models of the two joint types were constructed and were subjected to cyclic loading to assess the safety and the energy dissipation capacity of the joint types. The analysis results of the joints showed that the joints of the modular systems remain stable when the joint rotation reached the seismic performance limit state of the 0.02 rad required for steel intermediate moment frame. It was also observed that the joint of the composite modular system showed higher energy dissipation capacity compared with the steel modular system.

In relation to the development of automatic discharging and grinding system producing eco-friendly composite fertilizer raw materials, the performance test was proceeded. and We had obtained the following results. 1. Of the evaluation items set as performance indicators for this technology development, the “grinding capacity” of the composite fertilizer roll mill is higher than the current market-sufficient performance (1500kg/hr) of 1800kg/hr.For “grind particle size”, results of less than 1.8 mm on average were obtained, which is smaller than market-sufficient performance (average less than 2 mm). 2. As a result of the evaluation of “1batch 400kg discharge time”, the results of less than 10min/1bach were obtained, which is shorter than the market satisfaction performance (15min/1bach).

Synthesis of composite powders for the Fe2O3-Zn system by mechanical alloying (MA) has been investigated at room temperature. Optimal milling and heat treatment conditions to obtain soft magnetic composite with fine microstructure were investigated by X-ray diffraction, differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM) measurement. It is found that α-Fe/ZnO composite powders in which ZnO is dispersed in α-Fe matrix can be obtained by MA of Fe2O3 with Zn for 4 hours. The change in magnetization and coercivity also reflects the details of the solid-state reduction process of hematite by pure metal of Zn during MA. Densification of the MA powders was performed in a spark plasma sintering (SPS) machine at 900 ~ 1,000 ℃ under 60 MPa. Shrinkage change after SPS of sample MA'ed for 5 hrs was significant above 300 ℃ and gradually increased with increasing temperature up to 800 ℃. X-ray diffraction results show that the average grain size of α-Fe in the α-Fe/ZnO composite sintered at 900 ℃ is in the range of 110 nm.

This paper assesses the structural performance (force-slip response, slip modulus, and failure modes) of a CLT-concrete composite by conducting fifteen push-out test specimens. In addition, non-linear 3D finite element analysis was also developed to simulate the load-slip behavior of the CLT-concrete specimens under shear load. All 15 test specimens simulating the effect of concrete thickness, connection angle and penetration depth with four different shear connector types were built and tested to evaluate the flexural performance. Experimental results show that the maximum shear capacity for the composite action is obtained when the fixing angle is 90° and the penetration depth of 95mm for SC normal screw was used to achieve ductile failure compared to other shear connectors.

Asphalt pavement overlay method is one of widely chosen construction methods for remodelling existing aged concrete pavement layer. However, in this case reflective cracking is a challenging issue due to movement of transverse joints: built in existing concrete pavement layer with constant interval length. In this paper, collecting field data: collection of displacement and temperature data on existing concrete pavement layer for further complicated pavement performance analysis, was performed. To fulfil this objective, various types of thermometer were embedded into concrete layer with different depth level. Then, movement of existing concrete layer was measured numerically. Each Displacement Measuring Gauge (DMG) along with thermometer was embedded with depth of 3cm and 15cm, respectively. Additional thermometers were embedded at the middle depth of overlaid asphalt pavement layer for further extensive analysis and data collection. Total four testing sites were considered based on different asphalt mixture type and construction method. The 1st site was constructed with conventional construction approach, the 2nd site was constructed with a new pavement equipment contains simultaneous tack-coating function, the 3rd site was similar to 1st site but Guss-asphalt was constructed as a binder course, and in 4th site Noise-Reduction Porous Asphalt (NRPA) was constructed as a surface course and regular Dense Grade Asphalt (DGA) was constructed as a binder course. A field asphalt pavement layer sample coring works: along with basic material property tests, were also performed to acquire not only overlaid asphalt but also existing concrete pavement materials. This gauge measuring work in this study is an initial step therefore, long-term movement data of each pavement layer was not able to be collected, unfortunately. However through collecting and analysing initial data on each test site, two crucial findings were acquired. First, in all four tested site highest temperature variations were observed at the upper asphalt pavement layer and the variation trends decreased with increase of pavement depth (in case of concrete pavement layer, temperature and movement variations also decreased with increase of pavement depth). Secondly, when Guss-asphalt was applied as a binder course temperature variations of existing concrete pavement layer was crucially smaller than those of other comparison cases. These current findings and collected data set can provide successful input information for further pavement structure analysis such as 2D (and/or 3D) Finite Element Method (FEM) analysis as a future study.

사용후핵연료 파이로프로세싱에서는 방사성 희토류 염화물(RECl3)을 함유한 LiCl-KCl 공융염폐기물이 발생되며, 핫셀시설에서 운영을 목적으로 단순한 형태의 공융염폐기물 처리공정을 개발하는 것이 필요하다. 본 연구에서는, LiCl-KCl 공융염폐기물 내 희토류 핵종 분리/고화공정의 단순화를 목적으로 Li2O-Al2O3-SiO2-B2O3계의 무기합성매질을 이용하여 LiCl-KCl 공융 염 내 희토류 핵종(Nd)을 분리한 후 분리생성물을 바로 고화하는 시험을 실시하였다. 공융염 내 희토류 염화물(NdCl3) 대비 0.67의 무게비에 해당하는 무기합성매질의 양으로도 Nd 핵종을 98wt% 이상 분리할 수 있었고, 이 때 얻은 희토류 핵종 포집생성물은 약 50wt% 수준의 희토류 산화물 함량을 보유하고 있었으며, 이 포집생성물을 화학적 내구성이 우수한 단일상의 균질한 유리고화체로 제조할 수 있었다. 이 결과들은 LiCl-KCl 공융염폐기물 내 희토류 핵종의 분리/고화공정을 단순화하기 위한 방안수립에 활용될 수 있을 것이다.

Since it is impossible to predict earthquakes, they involve more casualties and property damage compared to meteorological disasters such as heavy snow and heat waves, which can be predicted through weather forecasts. This has highlighted the need for seismic design and reinforcement. Recently, the use of composite materials as reinforcement has surged because steel plate reinforcement and section enlargement are likely to result in increased weight and physical damage to structures. This study evaluates the seismic performance of panels created from composite materials, and their guide systems. The specimens were miniature versions of actual steel structures, and displacement loads were applied in the transverse direction. Seismic performance was found to improve when structures were reinforced with seismic panels.

To evaluate system reliability of a composite structure consisting of more than two structural members, it is necessary to identify that the members are connected to each others in parallel or in serial. Especially for parallel composite system, it is also necessary to confirm that mechanical properties of materials for the members are brittle or ductile. For parallel system of brittle materials, if one part fails, that part cannot resist load anymore and the whole load transfers to the other part. However, for parallel system of perfectly plastic materials, if one part fails, that part can maintain the amount of its maximum load capacity and the remaining load transfers to the other part. In this study, a methodology to determine reliability index for composite structures consisting of quasi-brittle materials. By assuming quasi-brittle materials as brittle or perfectly plastic materials, the upper and lower bounds of the reliability index can be determined. The reliability index for parallel system of quasi-brittle materials is then determined by interpolating the upper and lower bounds indices using ductility number extracted from stress-strain curves of quasi-brittle materials.

To improve the noise and vibration problems of the existing public parking systems, new floor system was proposed. This system consists of the Sandwich Plate System(SPS), steel beam and post-tensioned steel tendons. To verify the dynamic characteristics such as the natural frequency and damping ratio of the system, the free vibration test was performed. Test results showed that the natural frequency of the SPS composite beam was 23.8Hz and it was increased by 3.8% by installing the post-tensioned tendons. The damping ratio of the specimen with tendons was about 1.64%.