Chelating agents in low and intermediate radioactive wastes can form complexes with radionuclides and increase the mobility of the radionuclides. According to the Korea Radioactive Waste Agency (Acceptance criteria for low and intermediate radioactive waste, WAC-SIL-2022-1), if the amount of residual chelating agents in the waste are greater than 0.1%, the chemical names and residual amounts should be specified; if greater than 1%, the waste must be solidified and contain no more than 8%. The existing method for analyzing chelates in radioactive waste was based on UV–Visible spectrophotometry (UV-Vis), but the new method is based on liquid chromatography/mass spectrometry (LC-MS). The analysis was performed in aqueous solution before applying to real samples. Since the real sample may contain several heavy metals, it is expected that the chelates will exist as complexes. Therefore, 1.0×10-4 mol L-1 of EDTA (Ethylenediaminetetraacetic acid), DTPA (Diethylenetriaminepentaacetic acid), NTA (Nitrilotriacetic acid), and excess metals in aqueous solution were analyzed using HPLC using RP (Reverse Phase) column and HILIC (Hydrophilic interaction) column. When the RP column was used, each substance eluted without separation at the beginning of the analysis. However, when analyzed using a HILIC column, the peaks of each substance were separated. LC-MS measurements using HILIC conditions resulted in separations with better sensitivity.

As existing nuclear power plants reach the end of their lifespan, 22 nuclear power plants in korea are scheduled to be permanently shut down and decommissioned by 2050. Chelates are used as decontamination agents during nuclear power plant operation and decommissioning, and as a result, decommissioning waste contains chelates. Chelates contained in radioactive waste are complexed with radionuclides and increases their mobility. So, qualitative and quantitative analysis of chelates contained in radioactive waste is necessary. However, the spectroscopic method (UVVis), previously used for chelate analysis in Korea takes too much time for analysis and cannot analyze two or more chemically similar chelates at the same time. Due to these problems, new methods for analyzing chelate must be developed. Overseas, many cases of chelate analysis using advanced analysis equipment have been reported. CEA in France has developed a chelate analysis method for application to radioactive waste using HPLC-MS (J. Chromatogram. A, 1276, 20-25, 2013). In this method, the existing method of measuring EDTA using a complex of Fe and EDTA was improved to measuring a complex of Ni and EDTA. Based on such overseas cases, we would like to develop an analysis method for chelates in radioactive waste. For this purpose, we will verify similar overseas papers and develop pretreatment methods for mixtures of chelates (EDTA, DTPA, NTA) and metals (Fe, Ni, Cu, etc.) in various media. Finally, we will develop a separation analysis technology for multi-component chelates in nuclear decommissioning waste based on LCMS.

Gamma imaging devices that can accurately localize the radioactive contamination could be effectively used during nuclear decommissioning or radioactive waste management. While several hand-held devices have been proposed, their low efficiency due to small sensors have severely limited their application. To overcome this limitation, a high-speed gamma imaging system is under development which comprises two quad-type detectors and a tungsten coded aperture mask. Each quad-type detector consists of four rectangular NaI(Tl) crystals with dimensions of 146×146 mm2 and 72 square-type photomultiplier tubes (PMTs). The detectors are placed in front and back to serve as scatter and absorber, respectively, for Compton imaging. In addition, a coded aperture mask was fabricated in rank 19 modified uniformly redundant array pattern and placed in front of the scatter for coded aperture imaging. The system offers several advanced features including 1) high efficiency achieved by employing large-area NaI(Tl) crystals and 2) broad energy range of imaging by employing a hybrid imaging combining Compton and coded aperture imaging. The imaging performance of the system was evaluated through experiments in various conditions with different gamma energies and source positions. The imaging system provides clear images of the source locations for gamma energies ranging from as low as 59.5 keV (241Am) to as high as 1,330 keV (60Co). The imaging resolution was within the range of 7.5–9.4°, depending on gamma energies, when a hybrid maximum likelihood estimation maximization (MLEM) algorithm was used. The developed system showed high sensitivity, as the 137Cs source at distance, incurring dose rate lower than background level (0.03 μSv/h above background dose rate), could be imaged in approximately 2 seconds. Even under lower dose rate condition (i.e., 0.003 μSv/h above background dose rate), the system was able to image the source within 30 seconds. The system developed in the present study broadens the applicable conditions of the gamma ray imaging in terms of gamma ray energy, dose rate, and imaging speed. The performance demonstrated here suggests a new perspective on radiation imaging in the nuclear decontamination and radioactive waste management field.

The decommissioning of Korea’s nuclear power facilities is expected to take place starting with the Kori Unit 1 followed by the Wolsong Unit 1. In Korea, since there is no experience of decommissioning, considerations of site selection for the waste treatment facilities and reasonable selection methods will be needed. Only when factors to be considered for construction are properly selected and their effects are properly analyzed, it will be possible to operate a treatment facility suitable for future decommissioning projects. Therefore, this study aims to derive factors to be considered for the site selection of treatment facilities and present a reasonable selection methodology through evaluation of these factors. In order to select a site for waste treatment facilities, three virtual locations were applied in this study: warehouse 1 to warehouse 3. Such a virtual warehouse could be regarded as a site for construction warehouses, material warehouses, annexed building sites, and parking lots in nuclear facilities. If the selection of preliminary sites was made in the draft, then it is necessary to select the influencing factors for these sites. The site of the treatment facility shall be suitable for the transfer of the waste from the place where the dismantling waste is generated to the treatment facility. In addition, in order for construction to take place, interference with existing facilities and safety should not be affected, and it should not be complicated or narrow during construction. Considering the foundation and accessibility, the construction of the facility should be economical, and the final dismantling of the facility should also be easy. In order to determine one final preferred plan with three hypothetical locations and five influencing factors, there will be complex aspects and it will be difficult to maintain consistency as the evaluation between each factor progresses. Therefore, we introduce the Analytic Hierarchical Process (AHP) methodology to perform pairwise comparison between factors to derive an optimal plan. One optimal plan was selected by evaluating the three virtual places and five factors of consideration presented in this study. Given the complexity and consistency of multiple influencing factors present and prioritizing them, AHP tools help users make decisions easier by providing simple and useful features. Above all, it will be most important to secure sufficient grounds for pairwise comparison between influencing factors and conduct an evaluation based on this.

The type of radioactive waste that may occur in the process of nuclear power plant dismantling can be classified into solid, liquid, gas, and mixed waste. In addition, according to the level of radioactivity, it can be divided into high level, intermediate level, low level, and clearance level waste. In the case of solid radioactive waste, it is necessary to secure disposal suitability in order to deliver it to a disposal facility, so safe and efficient treatment of a large amount of radioactive waste generated during decommissioning is one of the most important issues. For the treatment of radioactive waste generated during decommissioning, technologies in various fields such as cutting, decontamination, melting, measurement, and packaging are required. Therefore, this study intends to present and application plan for decommissioning domestic nuclear power plants through overseas case studies for the treatment of radioactive waste expected to occur during nuclear power plant decommissioning.

The concept of clearance is to manage radioactive waste by incineration, reclamation, or recycling as non-radioactive waste, excluding those found to have a concentration of less than the allowable concentration of clearance. Among the types of waste subject to clearance, concrete is managed by recycling and landfill, metal by recycling and reuse, combustible materials by incineration, and soil by landfill. In Korea, clearance has been implemented in earnest since 2000, and the types and quantity of waste subject to clearance are increasing. For clearance, the nuclear-related operator submits its clearance plan to the regulatory body, and the regulatory body reviews the clearance plan and notifies the operator of its suitability. Since a significant amount of radioactive waste generated when decommissioning nuclear power plants is expected to be classified as clearance waste, this study will present clearance waste disposal measures for nuclear power plant through a review of overseas cases related to clearance.

Domestic nuclear power plants developed the scaling factors for the radioactive waste generated from 2004 to 2008 for the first time. Afterwards, the effectiveness of continuous application of the scaling factors have been evaluated for newly generated radioactive waste over the past two years. It was confirmed that most of the initially developed scale factors were effective within a factor of 10 principle, which is an acceptable range. The scaling factors were updated using the analysis data base from 2004 to 2016. A scaling factor refers to the calculated abundance ratio between Key (Easy-to- Measure) and DTM (Difficult-to-Measure) nuclide at the time of generation of radioactive waste based on the source term in the reactor of an operating nuclear power plant. The effectiveness of continuous application of scaling factors can be evaluated at regular intervals regardless of operation status or when there are events that change scaling factors during nuclear power plant operation, such as zinc injection, large-scale facility replacement, and long-term shutdown etc. Even in the case of a permanently shut down nuclear power plant in which fuel is withdrawn from the reactor and generation of new nuclides by nuclear fission and radiation has stopped, periodic verification is conducted to confirm whether the scaling factor developed before permanent shutdown can be effectively applied to the radioactive waste generated after permanent shutdown. However, depending on the nuclear power plant decommissioning strategy or conditions, the period of permanent shutdown prior to decommissioning can be very long, so preparations are needed to ensure the appropriateness of scaling factor operation. In the case of domestic nuclear power plants, Kori Unit 1, a light water reactor, was permanently shut down in June 2017, and as a heavy water reactor nuclear power plant, the permanent shutdown of Wolseong Unit 1 was finally decided in December 2019 after twists and turns including large-scale facility replacement and long-term shutdown. In this paper, we have predicted when the scaling factors will change significantly due to radioactive decay and the difference in halflife between the Key and DTM nuclides over time after permanent shutdown. We also have tried to find appropriate countermeasures for the operation of scaling factors during permanent shutdown period, such as updating scaling factors or applying correction factors.

Korea currently has two permanent shutdown Nuclear Power Plants (NPPs), and the decommissioning project is expected to begin soon, starting with the first commercial NPP. The decommissioning project will eventually be the disposal of radioactive waste in the final stage of the work, and in that respect, proper tracking and history management should be well established in the management of waste. This is in line with the guidelines that regulatory agencies should also properly manage radioactive waste. Therefore, this study intends to examine the factors that should be considered in terms of tracking and management of radioactive waste in decommissioning nuclear facilities. The starting and final point of tracking radioactive waste generated during decommissioning is the physical inventory of the current as-is state and the final container. In this respect, the tracking of waste starts from the beginning of the dismantling operation. Thus, at the stage of approval of the decommissioning work, it may begin with an ID scheme, such as the functional location in operation for the target System, Structure, and Components (SSCs). As the dismantling work progresses, SSCs will be classified by nature and radiological level, which will be placed in containers in small packaging units. At this time, the small package should be given an ID. After that, the dismantling work leads to the treatment of waste, which involves a series of operations such as cutting, decomposition, melting, and decontamination. Each step in which these tasks are performed will be placed in a container, and ID assignment is also required. Until now, the small packaging container is for transfer after each treatment, and it is placed in the storage container in the final stage, at which time the storage container also gives a unique ID. Considerations for follow-up management were reviewed assuming solid waste, which is the majority of dismantled radioactive waste considered in this study. The ID system should be prepared from the start of the dismantling work, ID generation of the small transporting container and ID generation of the final disposal container during the intermediate waste treatment process, and each ID generation of the previous stage should be linked to each generation stage. In addition, each ID must be generated, and the definition of the grant scheme and attributes is required.

In this study, a manual that can be applied to conflict management of clearance waste recycling by stakeholders was researched to recycle clearance waste that is most frequently generated when decommissioning nuclear power plants. In order to develop a manual that can be applied to conflict management, the content of the conflict should be derived first. In order to derive conflict, it is necessary to organize major issues in recycling clearance waste in consideration of domestic nuclear energy and social environment. In order to organize major issues in consideration of the domestic environment, a literature survey and a domestic current situation investigation were conducted. At this time, the subject of the major issue was selected based on the Level 1 influencing factors of the previous study. As a result of the investigation, it was confirmed that there were many major issues due to lack of reliability/understanding in nuclear energy/radiation. Through this Conflicts caused by recycling clearance waste were derived based on the organized issues. As a result of deriving conflicts, eight conflicts were derived below. 1) Reduced business availability due to lack of understanding/reliability 2) Lack of reliability in the selection and technology of nuclide analysis technology 3) Additional time and equipment required due to establishment of clearance waste regulatory requirements 4) Low economic benefits due to reduction in the effect of substituting raw materials 5) Political interference due to worsening public opinion 6) Rejection of final products due to recycling due to distrust of radiation 7) Public acceptance along the transport route from the source to the recycling plant 8) Business promotion deteriorated due to changes in energy policy As a result of the derived conflict analysis, the most conflicts related to lack of reliability/understanding in nuclear energy/radiation were derived. Accordingly, in future research, it is necessary to prepare a specific plan to enhance the understanding of stakeholders about self-disposal waste recycling. Considering that research that can solve the conflicts that will be faced when the domestic/foreign clearance waste recycling industry is activated is not activated, this study is meaningful in that it derived the conflicts that will be faced when recycling clearance waste. Also, it is expected that the conflicts derived from this study will be used meaningfully in the establishment of the clearance waste recycling management manual.

The decommissioning of nuclear power plant (NPP) consists of various activities, such system decontamination, take out of activated components, segmentation of the activated components, site remediation, etc. During various activities, the generation of radioactive wastes and radiation exposure to workers is expected. The systematic waste management during the activities is important to implement the decommissioning. The inefficient waste management usually bring significant delay in decommissioning process and results in increase of decommissioning cost. The radiation exposure management is also an important issue. It is generally accepted that the hot spot, generated from operation and decommissioning of NPP, is observed in many places within containment building. Although the health physicists measure the radiation in various points, the unintended hot spots are sometimes generated and observed. The effective radiation exposure management also requires the control of personnel and space during various activities. In this study, the radiation exposure and waste management experiences of Zion NPP is reviewed. The primary nuclides and radiation exposure during various activities are systematically studied to achieve the main objectives of this paper.

The decommissioning of Kori Unit 1 is expected to generate a large amount of clearance waste. Disposing of a large amount of clearance waste is economically costly, so a recycling method has emerged. However, clearance waste recycling is expected to cause many conflicts among various stakeholders. In the previous study, possible conflicts were selected in consideration of the domestic environment and major issues. Based on this, this study classifies stakeholders involved in conflicts by group, and suggests ways to enhance understanding by stakeholder and enhance reliability. In this study, stakeholders are classified into four groups that share the same conflicts, and each of the following measures is suggested. 1) Stakeholder Engagement. 2) Common understanding of radiation risks, dialogue between the public/recycling industry/ regulatory agency. 3) Incentives to promote recycling clearance waste. 4) Reliable outlet store for recyclable clearance waste. The above understanding enhancement measures are presented so that a solution to conflict can be smoothly derived when designing a clearance waste-related consultative body composed of interested parties in the future. As a more specific solution, measures to enhance stakeholder trust can be suggested for each understanding enhancement measure. Reliability enhancement measures are also presented so that they can be applied to each stakeholder group, and these are as follows. 1) Write a stakeholder engagement plan, Measures for stakeholder participation in measuring the radioactivity concentration of clearance waste. 2) Active use of easy-to-understand radioactivity comparison data, Expansion of information on environmental radiation dose to public, nuclear/radiation education, Held a tour event at the nuclear power plant decommissioning site, New website for clearance waste information disclosure. 3) Incentives for recycling industries in which the Ministry of Environment or KHNP partially bears the losses that occur when the sales rate is low. Incentives are provided to consumers by including recyclables of clearance waste for Green Card’s green consumption points. 4) Online outlets open for recyclable clearance waste with easy-to-understand radioactivity comparison data. It is expected that if the above-mentioned reliability enhancement measures are used, it will be possible to secure the trust of stakeholders and reduce the gap between stakeholders in the future clearance-related consultative body.

Kori unit 1 was permanently shut down in 2007 and is currently awaiting approval for decommissioning and dismantling (D&D). The wastes generated during decommissioning is estimated to be approximately 14,500 of 200 L drums. In this study, the treatment process of decommissioning wastes will be reviewed through the case of the US Zion nuclear power station (ZNPS). Zion unit 1 and 2 received an operating license in 1973 and were permanently shut down and the spent nuclear fuel was transferred to the pool in 1998. The decommissioning was carried out according to the following five steps; (1) safe storage (SAFSTOR) dormancy, (2) preparation for decommissioning, (3) establishment of independent spent fuel storage installation (ISFSI) and transfer of the spent fuel and greater than class C radioactive materials, (4) decommissioning operations and (5) site restoration. The total volume of waste generated during decommissioning was expected to be approximately 1.7×105 m3. This is far above the Kori unit 1 waste estimation because ZNPS has a history of accidents and includes soil waste. Wastes were treated differently according to their properties and locations.

Operating and decommissioning nuclear power plants generates radioactive waste. This radioactive waste can be categorized into several different levels, for example, low, intermediate, and high, according to the regulations. Currently, low and intermediate-level waste are stored in conventional 200-liter drums to be disposed. However, in Korea, the disposal of intermediate-level radioactive waste is virtually impossible as there are no available facilities. Furthermore, large-sized intermediate- level radioactive waste, such as reactor internals from decommissioning, need to be segmented into smaller sizes so they can be adequately stored in the conventional drums. This segmentation process requires additional costs and also produces secondary waste. Therefore, this paper suggests repurposing the no-longer-used spent nuclear fuel casks. The casks are larger in size than the conventional drums, thus requiring less segmentation of waste. Furthermore, the safety requirements of the spent nuclear fuel casks are severer than those of the drums. Hence, repurposed spent nuclear fuel casks could better address potential risks such as dropping, submerging, or a fire. In addition, the spent nuclear fuel casks need to be disposed in compliance with the regulations for low level radioactive waste. This cost may be avoided by repurposing the casks.

This study is about the production of radiation sources of simulated concrete and soil reference materials to verify the validity of the quality establishment and measurement of the detector (HPGe) of the radioactive soil and concrete waste classification system, which is being developed to quickly and accurately classify nuclear decommissioning waste. Specific activity of gamma nucleus among radioactive wastes is evaluated using gamma spectroscopy. At this time, in order to verify the validity and reliability of measuring equipment, it shall be a standardized substance of the same medium as nuclear decommissioning waste (chemical ingredients, particles, density, etc.) in order to correct the energy and efficiency of gamma nuclide analysis equipment. The CRM used for the detector’s energy correction used a 1 L Marinelli beaker standard correctional radiation source consisting of 10 radioactive isotopes. In order to correct efficiency, in accordance with the production and certification process of the Korea Standards and Research Institute, it has produced artificial simulated radioactive concrete similar to nuclear decommissioning waste (30% for cement, 60% for regulation and 10% for bentonite). The radioactive homogeneity of the simulated concrete reference materials was evaluated using dispersion analysis (ANOVA) in accordance with ISO Guide 35, while 137Cs and 60Co of concrete reference materials were able to obtain homogeneous measurements both in and between bottles. The self-absorption rate of the simulated concrete reference material was determined by the MCNP computer simulation measurement method, and the self-absorption correction coefficients of 137Cs and 60Co were assessed at 0.995 and 0.996, respectively, and the standard value for the radiation of the simulated concrete reference material was calculated on the weighted average of the measurements of 20 samples. The uncertainty about the reference value was calculated by combining measurement uncertainty (Type B evaluation), bottle to bottle standard deviation, and uncertainty within bottle by modifying the formula suggested in ISO Guide 35. The concentration of 137Cs and 60Co of reference materials was divided into high-speed measurement mode and precision measurement mode in consideration of the self-disposal standard. The reference value and uncertainty of expansion among reference materials for high-speed measurement mode were rated at 1,032.7 ± 64.0 Bq·kg−1and 1,083.7 Bq·kg−1, respectively. The standard value and expansion uncertainty for 137Cs and 60Co among reference materials for precision measurement mode were rated at 113.7 ± 10.0 Bq·kg−1 and 122.3 ± 10.3 Bq·kg−1, respectively.

The decommissioning of nuclear power plant (NPP) generates large amount of waste. Since the most of the concretes are slightly surface contaminated, the accurate characterization and regionspecific surface decontamination are important for the efficient waste management. After the effective surface decontamination and separation, most of the concrete waste from decommissioning of NPP can be classified as a clearance waste. Various surface characterization and decontamination technologies are suggested. The mechanical technologies are simple and offers direct application. The laser-based technologies offer efficient separation and surface contamination. The high price, however, hesitates the application of the process. The nitro-jet technology, which is based on the evaporation of liquid nitrogen, allows the effective decontamination. However, the high price and uncertainty of large are application hinders the practical application in NPP decommissioning. In this paper, various technologies for characterization, handling, treatment, etc., will be discussed. The advantages and disadvantages of the technologies will be discussed, in terms of practical applications.